RO81117B - Procedeu de obtinere a sarurilor tiazolidenoxopropionitrililor - Google Patents
Procedeu de obtinere a sarurilor tiazolidenoxopropionitrililorInfo
- Publication number
- RO81117B RO81117B RO101142A RO10114280A RO81117B RO 81117 B RO81117 B RO 81117B RO 101142 A RO101142 A RO 101142A RO 10114280 A RO10114280 A RO 10114280A RO 81117 B RO81117 B RO 81117B
- Authority
- RO
- Romania
- Prior art keywords
- carbon atoms
- general formula
- alkyl
- indicated above
- meanings indicated
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- 150000003839 salts Chemical class 0.000 title 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 125000001153 fluoro group Chemical group F* 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 abstract 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 1
- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 abstract 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
- C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Thiazole And Isothizaole Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Inventia se refera la un procedeu de obtinere a sarurilor tiazolidenoxopropionitrililor cu formula generala I: (vezi formula) în care R1 reprezinta fenil sau t-butil, R2 reprezinta clor, fluor sau triclormetil, trifluormetil, R3, R4 si R5 sunt identici sau diferiti si reprezinta fiecare hidrogen, alchil cu 1 la 6 atomi de carbon, cicloalchil cu 3 la 8 atomi de carbon, benzil, eventual substituit în nucleul fenil cu halogen sau alchil cu 1 la 3 atomi de carbon, eventual întrerupt cu unu, doi sau trei heteroatomi sau doi dintre radicalii R3, R4 si R5 formeaza împreuna cu atomul de azot, un heterociclu cu 5 la 8 membri din care 1 la 3 membri pot fi oxigen, azot sau sulf. Procedeul consta în aceea ca un compus cu formula generala II: (vezi formula) în care R1 si R2 au semnificatiile aratate mai sus reactioneaza cu o amina cu formula generala III: (vezi formula) în care R3, R4 si R5 au semnificatia aratata mai sus, reactantii fiind utilizati în raport molar de circa 1:1, la temperatura de circa 25 degree C, în mediu de alcool alifatic inferior, eterii acestora, tetrahidrofuran, nitrili sau amide ale acizilor carboxilici apoi produsul de reactie este separat în mod cunoscut.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19792920182 DE2920182A1 (de) | 1979-05-17 | 1979-05-17 | Salze von thiazolyliden-oxo-propionitrilen, insektizide mittel enthaltend diese salze sowie verfahren zu ihrer herstellung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO81117B true RO81117B (ro) | 1983-06-30 |
| RO81117A RO81117A (ro) | 1983-07-07 |
Family
ID=6071132
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO80101142A RO81117A (ro) | 1979-05-17 | 1980-05-16 | Procedeu de obtinere a sarurilor tiazolidenoxo-propionitrililor |
Country Status (37)
| Country | Link |
|---|---|
| US (1) | US4320125A (ro) |
| JP (1) | JPS6050192B2 (ro) |
| AT (1) | AT366232B (ro) |
| AU (1) | AU534781B2 (ro) |
| BE (1) | BE883349A (ro) |
| BG (1) | BG31463A3 (ro) |
| BR (1) | BR8003060A (ro) |
| CA (1) | CA1135264A (ro) |
| CH (1) | CH644854A5 (ro) |
| CS (1) | CS214830B2 (ro) |
| DD (1) | DD150841A5 (ro) |
| DE (1) | DE2920182A1 (ro) |
| DK (1) | DK211480A (ro) |
| EG (1) | EG14252A (ro) |
| ES (1) | ES491253A0 (ro) |
| FI (1) | FI801380A7 (ro) |
| FR (1) | FR2456736A1 (ro) |
| GB (1) | GB2051060B (ro) |
| GR (1) | GR67664B (ro) |
| HU (1) | HU187277B (ro) |
| IE (1) | IE49801B1 (ro) |
| IN (1) | IN155588B (ro) |
| IT (1) | IT1140950B (ro) |
| LU (1) | LU82450A1 (ro) |
| MA (1) | MA18848A1 (ro) |
| MX (1) | MX6406E (ro) |
| NL (1) | NL8002109A (ro) |
| NZ (1) | NZ193682A (ro) |
| PH (1) | PH17239A (ro) |
| PL (1) | PL124375B1 (ro) |
| PT (1) | PT71247A (ro) |
| RO (1) | RO81117A (ro) |
| SE (1) | SE8003613L (ro) |
| SU (1) | SU906375A3 (ro) |
| TR (1) | TR20558A (ro) |
| YU (1) | YU118880A (ro) |
| ZA (1) | ZA802922B (ro) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4626543A (en) * | 1985-02-01 | 1986-12-02 | Shell Oil Company | Insecticidal 2,6-difluorobenzoyl derivatives of 4-substituted-1,3-thiazole-2-acetonitriles |
| DE3669160D1 (en) * | 1985-03-27 | 1990-04-05 | Zenyaku Kogyo Kk | Thiazolderivate. |
| DE3644030A1 (de) * | 1986-12-22 | 1988-08-04 | Siemens Ag | Aufgeladener, kohlebefeuerter dampferzeuger |
| JP3404558B2 (ja) * | 1994-04-28 | 2003-05-12 | ケイ・アイ化成株式会社 | 水中付着生物防汚剤 |
| EP0842931A4 (en) * | 1995-04-27 | 1998-09-02 | Nissan Chemical Ind Ltd | OXOPROPIONITRILE DERIVATIVES AND INSECT CONTROLLERS |
| ATE244219T1 (de) | 1996-04-25 | 2003-07-15 | Nissan Chemical Ind Ltd | Ethylenderivate und pestizide |
| AU6420498A (en) * | 1997-03-21 | 1998-10-20 | Nippon Soda Co., Ltd. | Triazole compounds, process for the preparation thereof, and insecticides and miticides |
| HUP0103324A3 (en) * | 1998-09-17 | 2003-05-28 | Nippon Soda Co | Thiazolylcinnamonitriles and pest controlling agents containing them |
| AU2003252394A1 (en) * | 2002-08-07 | 2004-02-25 | Nippon Soda Co., Ltd. | Process for producing acrylonitrile compound |
| WO2004035554A1 (ja) * | 2002-10-17 | 2004-04-29 | Nippon Soda Co.,Ltd. | チアゾリルケイ皮酸ニトリル化合物及び有害生物防除剤 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE814152C (de) | 1951-07-26 | I arbenfabriken Bayer | everkusen I Verfahren zur Herstellung von Estern der Phosphorsaure und Thiophosphor saure | |
| NO89105A (ro) | 1954-06-18 | |||
| BE587481A (ro) | 1958-08-07 | |||
| US3637707A (en) * | 1970-11-24 | 1972-01-25 | Pfizer | 2-(substituted) 2-thiazolines for the control of rice blast |
| JPS5324019A (en) | 1976-08-18 | 1978-03-06 | Sumitomo Chem Co Ltd | Inspecticide comprising optically active isomer of alpha-cyano-3-phenoxybenzyl-2-(4-chlorophenyl)-isovalerate as an effective component |
| DE2703542C2 (de) * | 1977-01-26 | 1985-09-26 | Schering AG, 1000 Berlin und 4709 Bergkamen | Thiazolylzimtsäurenitrile, Insektenbekämpfungsmittel enthaltend diese Verbindungen sowie Verfahren zu ihrer Herstellung |
-
1979
- 1979-05-17 DE DE19792920182 patent/DE2920182A1/de not_active Withdrawn
-
1980
- 1980-04-10 NL NL8002109A patent/NL8002109A/nl not_active Application Discontinuation
- 1980-04-21 SU SU802910600A patent/SU906375A3/ru active
- 1980-04-29 FI FI801380A patent/FI801380A7/fi not_active Application Discontinuation
- 1980-05-05 YU YU01188/80A patent/YU118880A/xx unknown
- 1980-05-06 TR TR20558A patent/TR20558A/xx unknown
- 1980-05-07 AU AU58159/80A patent/AU534781B2/en not_active Ceased
- 1980-05-07 ES ES491253A patent/ES491253A0/es active Granted
- 1980-05-08 CA CA000351537A patent/CA1135264A/en not_active Expired
- 1980-05-08 CH CH363280A patent/CH644854A5/de not_active IP Right Cessation
- 1980-05-12 NZ NZ193682A patent/NZ193682A/xx unknown
- 1980-05-13 US US06/149,449 patent/US4320125A/en not_active Expired - Lifetime
- 1980-05-13 MX MX808810U patent/MX6406E/es unknown
- 1980-05-14 BG BG047763A patent/BG31463A3/xx unknown
- 1980-05-14 SE SE8003613A patent/SE8003613L/xx not_active Application Discontinuation
- 1980-05-14 LU LU82450A patent/LU82450A1/de unknown
- 1980-05-14 CS CS803358A patent/CS214830B2/cs unknown
- 1980-05-14 FR FR8010869A patent/FR2456736A1/fr active Granted
- 1980-05-14 DK DK211480A patent/DK211480A/da not_active Application Discontinuation
- 1980-05-15 IN IN358/DEL/80A patent/IN155588B/en unknown
- 1980-05-15 GR GR61955A patent/GR67664B/el unknown
- 1980-05-15 PL PL1980224258A patent/PL124375B1/pl unknown
- 1980-05-15 PT PT71247A patent/PT71247A/pt unknown
- 1980-05-16 IE IE1017/80A patent/IE49801B1/en unknown
- 1980-05-16 DD DD80221167A patent/DD150841A5/de unknown
- 1980-05-16 ZA ZA00802922A patent/ZA802922B/xx unknown
- 1980-05-16 JP JP55065198A patent/JPS6050192B2/ja not_active Expired
- 1980-05-16 RO RO80101142A patent/RO81117A/ro unknown
- 1980-05-16 PH PH24039A patent/PH17239A/en unknown
- 1980-05-16 BE BE0/200655A patent/BE883349A/fr not_active IP Right Cessation
- 1980-05-16 IT IT22136/80A patent/IT1140950B/it active
- 1980-05-16 BR BR8003060A patent/BR8003060A/pt unknown
- 1980-05-16 HU HU801230A patent/HU187277B/hu unknown
- 1980-05-16 AT AT0263580A patent/AT366232B/de not_active IP Right Cessation
- 1980-05-17 EG EG302/80A patent/EG14252A/xx active
- 1980-05-17 MA MA19044A patent/MA18848A1/fr unknown
- 1980-05-19 GB GB8016522A patent/GB2051060B/en not_active Expired
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