RO120857B1 - Device for dispensing biologically active substance fluids into the liquid flushing the toilet vessel - Google Patents

Abstract

The invention relates to a device for distribution of biologically active substance fluids into the liquid flushing a toilet vessel. The distribution device comprises a support (1) that can be hung to the edge of the toilet vessel, provided therein with at least two feed recipients (2 and 3), which present a discharge orifice (4) wherethrough said biologically active substance fluid can be dispensed into the flushing fluid, wherein the feed recipients (2 and 3) are protected against the ingress therein of the flushing fluid, and the discharge orifices (4) of the feed recipients (2 and 3) are so located that only biologically active substance fluid comes out therefrom, on the support (1) there being provided a plate-shaped distribution element common for at least two feed recipients (2 and 3) which present an operation zone onto which the flush fluid flows for flushing, the inner side of each feed recipient (2 and 3) being permanently in connection with the distribution element, by means of the discharge orifice (4), possibly by inserting an element which prevents the free flow of the biologically active substance fluid, and, in the operation position, each discharge orifice (4) is located at the lower side of the feed recipients (2 and 3).

Description

The invention relates to a device for distributing fluids of biologically active substance in the washing liquid of a toilet bowl.

It is known, from documents DE 19930362 A1, EP 0775741A1 and EP 0960984 A2, that the notion of biologically active substance fluid refers to preparations of biologically active substances that are fluid, so liquid to viscous, possibly as a gel or even powdery or coarse, or , which can be poured elsewhere, having a cleaning, disinfection, deodorizing, bleaching or other similar effect.

The devices of distribution, of the type of the one that is the object of this description, are known, in different variants of execution, under the generic name of baskets for the WC.

The dispensing devices for a single fluid of biologically active substance, which is located in a feed container, fixed in a support or inserted in it, with the possibility of being replaced, are known, the feed container having , at the bottom, an outlet.

A first dispensing device (EP 785315 A1) is known for a single biologically active substance fluid, to which this biologically active substance fluid is added, via an actuator consisting of, for example, a pore-sponge material. open which can be soaked with it and, in that, it can penetrate the washing fluid. In this, after pushing out a sealing element of the feed container, the outlet of the feed container is largely sealed by a sealing element fixedly fixed on the support, so as to evacuate the fluid of biologically active substance , only a small diameter flow path is available. The device works by using the capillary effect of the spongy material with open pores. A similar composition is also known with ribbed plate for distribution.

incidentally, in both variants, it is not considered as an optimal solution to leave in principle the permanently open outlet orifice, so that, in the case of a longer use of the toilet bowl, the biologically active substance fluid will continue to leak.

There is also known another dispensing device for a single fluid of biologically active substance (DE 29902066 U1), in which a sealing element acting as a valve is formed on the feed container, which normally has a sealing position. positive closed, closing the outlet. This is done by the force of the weight of a ball valve that acts as a sealing member. This sealing member may be moved, contrary to the pretensioning force, to a position which to a certain extent releases the outlet. An actuator element formed as a rocker rocker located on an oscillating support on a tilting axis serves this purpose. On one side of the shaft, the drive element has a soaking area comprising a receiving element in the form of a tank. The arm of the actuator located on the other side of the shaft is in contact with the lower part of the sealing element. When the washer reaches the influent area, the sealing member is lifted by the actuator, from the valve seat at the outlet, and to some extent opens the outlet. The fluid of biologically active substance may penetrate next to the sealing element of the outlet in the flow of the washing liquid passing therethrough, respectively, it is driven by the washing liquid.

From the aforementioned document DE 19930362 A1, there is known a distribution device similar to the distribution device described above, which, however, presents, as an actuating element, a lever, with an arm, articulated with one of the ends on a support, on which it is located between the articulated end of the support and the joint area, the sealing member.

RO 120857 Β1

When using the dispensing devices referred to above, all of the component elements that reach the toilet fluid washer must be included with the biologically active fluid. Certain components of the biologically active substance 3, however, cannot be made so that they are stable if stored together. For this reason, a distribution device with several cameras 5 was proposed (EP 0960984 A2). This known dispensing device serves the distribution, in liquid or aqueous form, of at least two different or identical mediums, solid, in gel state, moist or liquid in the toilet bowl. In a support that can be hung on the edge of the toilet bowl, there is a container that presents for storing media at least two independent enclosures 9 located adjacent. Each of the two enclosures has a dispensing device provided with a dispensing pipe, which protrudes, with one of its free ends, 11 above the lower part of the container into the environment, being surrounded, at the other by its free ends which conducts the fluid, with a covering element. By means of 13 holes in the form of a groove, provided in a covering element, the two enclosures of the container can be filled with washing water flowing over them, which then exits, as at 15, a siphon or overflow, from the distribution pipe in the toilet bowl, taking with it the respective biologically active substance. Separating the enclosures from a container has the advantage that different media can be used which otherwise, in the case of joint storage in a single enclosure, would adversely affect the desired effect. Also, the consistency of the media can be different in the different enclosures.

In the distribution device described above, the operating principle 21 of the known WC baskets is used, according to which, the washing water that flows over them, coming from above, penetrates into the enclosures containing the fluid of biologically active substance 23, dissolves particles of the biologically active substance and leak again by training them. The problem, however, is that, once the 25 siphoning effect applied in this case is achieved, a large liquid mirror remains inside the enclosures. The action of the rinsing liquid on the fluid of biologically active substance in the respective enclosure continues 27 even though the washing process has been completed for a long time. Fluid consumption of biologically active substance, in practice, cannot be optimally regulated. 29

Also known is a dispensing device with two enclosures for fluids of biologically active substance, identical or different, with gel consistency (WO 92/20876 A1), in which 31 outlet holes are made in the form of perforations at the bottom of the and are permanently open. Due to the viscosity and surface tension, 33 of the gel, it normally cannot come out of itself under the action of the force of gravity. Certain parts of the amount of biologically active substance fluids can only be evacuated by 35 to the washing fluid that floods them, coming down from the outlet holes, and dissolving the gel near the outlet holes to some extent. In this two-chamber system, the exhaust ports are, in principle, also permanently open, so that even in the case of a longer non-use of the toilet vessel, the biologically active fluids 39 either leak out, either they are cured under the influence of the surrounding atmosphere and then cannot be activated anymore. 41

The technical problem, which the invention solves, consists in optimizing the known distribution device, presented above, for the distribution of fluids of biologically active substance 43 from at least two feeding enclosures, separated from each other, namely in terms of the possibility of to order the distribution of fluid of biologically active substance. 45

The device for distributing fluids of biologically active substance in the washing liquid of a toilet bowl, according to the invention, solves the proposed technical problem, in that, 47 comprises a support, which can be hung on the edge of the toilet bowl, provided inside with

RO 120857 Β1 at least two feed containers having an own outlet, through which the respective biologically active substance fluid can be distributed in the washing liquid, to which, the feed containers are protected against the penetration of the washing liquid inside, and the outlet holes, of the feed containers, are so located that from each of them only fluid of biologically active substance emerges, on a support being provided a distribution element, in the form of a plate, common for at least two feed containers, which have an actuating area over which the washing fluid flows for performing a wash, the inside of each feed container being permanently connected to the dispensing element through the outlet, possibly by intercalating an element that prevents a flow free of the fluid of substance biologically active, and in the operating position, each outlet is in the bottom of the storage container.

In the sense of solving the problems mentioned above, it is particularly important, for the purpose pursued, a variant of the delivery device according to the invention, in which, an outlet, located at the bottom of the feed containers, is sealed by means of an element seal which is inserted pretensioned into the closing position of each outlet and can be moved, contrary to the pretensioning force, to an opening position of the outlet, the sealing element being provided with an actuating element common to the one at least two feed containers, which cooperate with the sealing member so that in each operation with the washing liquid it may be temporarily subjected to a force, so that it may temporarily occupy, against the action of the pretensioning force, the position of opening and for this purpose, the drive element is located an area, driven by the flow of washing fluid.

In order to achieve the device, according to the invention, the techniques of the distribution devices for a single fluid of biologically active substance are used, which are known from the prior art, presented in a comprehensive manner, and will be referred to further.

Execution variants and preferred developments of the essence of the solution are the subject of secondary claims.

The following is a preferred embodiment of the invention, in conjunction with FIG. 1 ... 3, which represents:

FIG. 1 is a top view of a distribution device according to the invention in a preferred embodiment;

FIG. 2, section with a plan II - II, of fig. 1, through the distribution device;

FIG. 3, section with a plan III - III, of fig. 2, through the distribution device.

The dispensing device, shown in the figures, serves to distribute at least two fluids of biologically active substance with which a toilet bowl is washed. What is meant by biologically active fluid ", in the sense of the essence of the invention, has been defined previously, in the general part of the description, to which the following text will refer.

Such a dispensing device firstly has a support 1, which can be hung on the edge of the toilet bowl, as well as at least two feed containers 2,3, separated from each other, provided in the support 1, for a fluid each. biologically active substance. As regards the biologically active substance fluids, it may be concordant biologically active substance fluids, different, compatible with each other or not. Two feed containers for two fluids of biologically active substance or several feed containers for several fluids of biologically active substance may be provided.

Suitable biologically active fluid fluids according to the invention are for example the aromatic phases, in particular the fragrant aromatic phases. Such aromatic phases contain

EN 120857 Β1 usually at least one flavoring substance, preferably perfume oil, at least one surfactant 1 or an emulsifier and water, and possibly other substances, such as preservatives, thickening agents, bonding agents complexes, dyes, other tensides or emulsifiers, 3 stabilizers, lime solvents, etc.

According to the invention, they are as indicated as biologically active fluids 5 and bleaching phases, in particular bleaching phases containing chlorine, preferably bleaching phases based on hypochlorite, bleaching phases may contain in addition to the substance 7 bleaching itself and water, possibly other components such as thickening agents, tensides or emulsifiers, neutralizing substances, dyes, aromatic substances, etc. 9

Other fluids of biologically active substance, indicated according to the invention, are the phases of biologically active substance that dissolve lime. Such phases of biologically active substances, 11 which dissolve lime, may comprise in addition to the lime solvent itself, preferably herein is an organic or inorganic acid, and water, and other components such as tenacity, respectively. 13 ciders or emulsifiers, thickening agents, aromatic substances, preservatives, etc.

It is also possible that 15 highly concentrated tenside phases are used as fluids of biologically active substance, which favors foam intensification. Such highly concentrated tenside phases may include in addition to tensides and other common components. According to the invention, fluids of biologically active substance comprising a phase of biologically active substance with antibacterial and / or fungal and / or antiviral action are also indicated, which, in addition to the biologically active substance with antibacterial and / or action fungicide and / or antiviral may possibly also contain other components, such as 21 tensides or emulsifiers, thickening agents, aromatic substances, preservatives, etc.

In addition, it is possible that in the case of fluids of biologically active substance 23 these are phases of biologically active substance containing enzymes. Such phases of biologically active substance containing enzymes may also contain in addition to one enzyme and water, possibly, and other components, such as tensides or emulsifiers, thickening agents, aromatic substances, preservatives, etc. 27

It is also possible that, with regard to the biologically active substance fluids, used in accordance with the invention, they may be phases of biologically active substance 29 absorbents, in particular odor absorbers. These may also comprise, in addition to the absorption means, in particular the odor and water absorption means, and possibly other components such as stresses or emulsifiers, thickening agents, aromatic substances, preservatives, etc.

According to the particular embodiment, the dispensing device according to 33 of the invention provides the possibility of introducing combinations of different fluids of biologically active substance in the feeding vessels 2, 3, according to a preferred embodiment 35. from the feed containers 2,3 containing an aromatic phase, as defined above. 37

Examples for the fluid combinations of biologically active substances to be used are a fragrant aroma phase, combined with an active chlorine bleaching agent 39 (together they are not stable for storage), a fragrant aroma phase with a tenside phase. highly concentrated (favoring foam intensification), a flavored phase with a biologically active acid phase 41 capable of dissolving lime, a flavored phase with a biologically active antibacterial substance phase, various acid systems, an aromatic phase combined with a phase of 43 biologically active substances containing enzymes, a scented acid phase combined with a water coloring phase, an aromatic phase with an odor absorption phase, a scented acid phase 45 with active oxygen, a scented acid phase with a substance phase biologically active, thickened with polyacrylate, etc. Of particular interest here is the viscosity of biologically active substances 47 viscous to a gel having viscosities in the range of several thousand mPas, in particular from 2000 to 5000 mPas, preferably from 2500 to 3500 mPas. 49 (measured with Rotovisko LVT, axle 2.6 rpm, 20'C).

RO 120857 Β1

In the dispensing device shown, each of the feed containers 2.3 has an outlet of its own, through which the respective biologically active substance fluid can be delivered into the washing liquid. Unlike the prior art, which is the starting point for the principle of the invention, here the feed containers 2, 3 are protected against the penetration of the washing liquid inside them. The outlet ports 4 of the feed containers 2, 3 are located here so that only the biologically active substance fluid can come out of them. At each washing operation, a certain amount of biologically active fluid, from each of the feed containers 2, 3, is distributed in the washing liquid. In the exemplary embodiment shown, this is achieved by the fact that in the operating position, as shown in FIG. 2, the outlet 4 is located at the bottom of the respective feed container 2, 3. The wash water, which flows over the feed container 2, 3, eventually reaches the side thereof.

There are several possibilities for placing and securing the 2.3 food containers on holder 1. In the preferred embodiment shown in the figures, it is provided that the feed containers 2, 3 are fixed or can be fixed respectively on the support 1 so that they can be replaced separately. An alternative is a solution for the supply receptacles 2, 3 to be coupled, by means of an adapter or another element of the same type and to be fixed so coupled to the support 1.0. Another alternative is that the supply receptacles 2, 3 to be directly coupled to each other and to be fixed in the bracket 1, thus coupled, directly. Finally, we can also imagine that the feeding containers 2, 3 are made up in a common monobloc housing, for example, as separate enclosures in a connected housing, thus being fixed on the support 1. according to the practical wishes and by the different fluids of biologically active substances to be introduced, one or the other may be chosen.

The feed containers 2.3 can be formed, as described in the prior art (DE 29902066 U1, DE 19915322 A1), with the possibility of separate refilling of a container, possibly equipped with a valve. Particularly in this case, the feed receptacles 2, 3 may also be rigidly fixed or formed in the support 1, thus choosing a unitary composition, forming an assembly.

The embodiment shown shows, of course, the feeding containers 2, 3 as replaceable containers, disposable, which is likely to be a more widespread solution in practice. The exemplary and preferred embodiment shows the supply containers 2, 3 as being adjacent to the support 1. The same is also valid for a arrangement in which the supply containers 2, 3 are located one behind the other. As an alternative, the overlapping location of the feed containers 2, 3 could also be provided in order to obtain a cascade distribution of the products.

The exemplary and preferred embodiment also shows that the feed containers 2, 3 which are, as can be seen, separately replaceable, in this case are fixed in the support 1 by insertion at the top (in the position of use) . Alternatively, different fixing possibilities can be designed. We could also imagine that the feed containers 2,3 are applied laterally, on the support 1, and then folded, around a folding axis, to reach in the position of use. depending on the composition of the outlet holes 4 and the technical solution for their filling, one or the other may be chosen.

EN 120857 Β1 in principle, as a biologically active substance fluid, for example, high viscosity gels or pastes, which are not themselves flowing, can be used. In this case, it may be advisable for the feed containers 2, 3 to have a flexible wall portion, or, 3 for the entire wall to be flexible, the discharge of the biologically active substance inside them being made by applying pressure. on the feed containers 2, 3. 5

This application of pressure can be done, for example, by means of a suitable mechanical device or by the washing fluid flowing over it. 7

It has been pointed out, above, that, in the multi-enclosure dispensing device, according to the invention, the distribution mechanisms that are known in the prior art for dispensing devices of a single biologically active substance can be used in the prior art. . In this sense, it is applicable, the constructive possibility resulting 11 largely from EP 0538957 B1, namely, that on the support 1 there is provided a distribution element having the form of a plate having an inlet area over which the washing liquid 13 flows. when performing a wash, the inside of the feed containers 2, 3 being permanently connected to the dispensing element, through the outlet 4, 15 possibly by the intermediate provision of an element so formed, so as to prevent a free flow of the fluid of biological substance activate. In accordance with a particularly preferred embodiment 17, the distribution element having the form of a plate is jointly subordinate to all the feed containers 2, 3. 19

The embodiment shown and preferred shows a solution that works with a sealing element that allows an active closure. This is possible due to the fact that the outlet port 4 of each feed container 2,3, located at the bottom of it, is sealed by means of a sealing element 5. The sealing element 23 5 is inserted pretensioned in the closing position of the outlet 4 and may be moved contrary to the pretensioning force in an opening position which to some extent opens the outlet 4.

an actuating element 27 is provided for the purpose of moving the sealing member 5

6, which cooperate with the sealing member 5 and which, in each washing operation with the washing liquid, may be temporarily subjected to a force, so that the sealing element 29 5 becomes temporarily occupied, contrary to the action of the pretensioning force , an opening position. For this purpose, on the actuator element 6 there is an actuating zone 7, over 31 which, when carrying out the washing operation, flows the washing fluid, which, when carrying out the washing operation, therefore reaches the washing liquid. The actuator 6 is executed 33 as a lever with one arm having one of the ends hinged on the support 1. The sealing member 5 is located on the actuator 6 at a certain distance from the area 35

7, drive. By forming as a single-lever lever of the actuator 6 (fig. 3), the direction of action of the force exerted by the washing liquid is identical to the sense 37 of opening of the sealing element 5. Thus, the sealing element 5 can be the distance down from the outlet 4 of the feed containers 2, 3. Due to this 39 it is possible and possible for each of the feed containers 2,3 to be fitted with the possibility of replacing it without any particularities constructive. 41 in the embodiment shown, the sealing element 5 is located between the end of the actuating element 6, hinged on the support 1, and the actuating zone 7. 43 The distance traveled for opening the sealing element 5 is therefore relatively small,

RO 120857 Β1 the opening is made as desired only with an extremely small slot. In addition, in the case of an appropriate composition of the sealing member 5, this slot is opened asymmetrically, ie, with a larger opening in the direction of the actuating zone 7, so that the biologically active substance fluid is preferably discharged in this direction. . This is the direction towards the washing fluid, with which the biologically active substance fluid is then properly mixed. The fluid of biologically active substance can therefore flow on the upper part of the actuator 6 towards the actuating zone 7, and is mixed in this path itself with the washing fluid flowing over it.

It may be provided that the sealing member 5 is shaped monoblocly on the actuating member 6. This is particularly advisable if the actuating member 6 is made of plastic material, in particular by an injection of plastic material. In a particularly preferred manner, the support 1 may be made of plastic material, in particular by injection of plastic material, preferably from thermoplastic plastic material. In general, it can be provided that the actuating element 6 is shaped monobloc on the support 1 and that the pretensioning form is exerted by the own elasticity of this actuating element 6.

The embodiment shown and preferred is particularly distinguished by the fact that the actuating element 6 is jointly attached to the sealing elements 5 for at least two feeding containers 2, 3. in FIG. 1 shows, from the top, the actuator 6 flat, executed in the form of a plate, with the zone 7 actuating also flat, executed in the form of a tank and some small drain holes 8, which can be recognized therein, all in a base plate 9, of the support 1, in the form of a frame. Related to the above is also the location of the outlet holes 4 on the feed containers 2, 3. In front of the middle of the entire distribution device they are executed asymmetrically, with the outlet holes 4 as a whole offset from the middle of the distribution device (fig. . 2). By this composition, a concentration of the jet of biologically active substance is obtained in the tightly confined area, irrespective of the fact that two feed containers 2, 3 are provided.

Finally, a somewhat directed distribution of the biologically active fluid from the various feed vessels 2, 3, may also be achieved by the fact that the cross sections of the flows from the outlet ports 4 and / or from the feed elements Sealing 5 can be determined and / or adjusted differently.

Finally, there are a multitude of possibilities for constructively constituting the distribution device represented, especially with regard to the location and formation of the outlet holes 4 and the sealing elements 5. In this respect, there is a patent application. parallel, submitted by the patent applicant, concurrently with the present, the content of which we allow to draw attention. It is particularly possible to achieve a concomitant or time-varying dosage with the same or different concentration of the different feed containers.

The invention will be exemplified on the basis of the following embodiments, which in no case limit the invention. Various combinations of biologically active fluid fluids for feed containers 2, 3 of the dispensing device according to the invention are described in the embodiments.

1) The fragrant aromatic phase, combined with a bleaching agent with active chlorine: practically it cannot be achieved in a system with a single container in which it remains stable.

RO 120857 Β1

a) The aromatic phase

composition FAEOS-Na, C12-14 + 2 EO 24.50% Basic surfactant Alkyl (C8-10) -1.5 glucoside 2.88% Contensid / emulsifier 1,2 - propanediol 5.00% emulsifier Ethanol 96%, denatured 1% MEK 5.00% Coemulgator Hydroxyethylcellulose ex Natrosol 250 HHBR 0.45% Thickening substance Pine notes perfume oil 10.00% Flavored substance Semiacetal-isothiazoline combination 0.05% preservative dyes <1.00% Water from the pipeline ad. 100

approx. 3000 mPas, 20'C, RotoviskoLVT, axle 2.6 rot / min

PH 6.5, undiluted, clear solution

production

The hot water is prepared at 20-25'C. while the mixer is in operation add the dyes and preservative and dissolve 5 min. The thickening substance is introduced at medium to high speed. During the soak for about 60 minutes, the mixer continues to operate. The absence of solid bodies is verified by the glass plate test; If solid bodies persist, the mixing is continued. Add the tensides and then the alcohol. Finally add the perfume and check the parameters for the release of deposits.

b) Bleaching phase containing chlorine (about 1% active chlorine)

composition Sodium hypochlorite (12.5% active chlorine) 8.00% Bleaching agent with active chlorine Sodium hydroxide (50%) 2.50% neutralize Oxy-Rite 100 product BF Goodrich (BFG) 0.10% Stabilizer for rheological properties Polyacrylate polymer 1 BFG product, eg Carbopol 676 1.00% Thickening agent Coconut alchildimethylaminoxide e.g. Genaminox CS (Clariant) 2.00 Tensid / emulsifier Distilled water ad 100

approx. 2500 mPas, 20C, Rotovisk LVT, axle 2.6 rot / min

PH 12.7, undiluted, opaque solution

production

The water is being prepared. At medium speed (up to 800 rpm) the thickening substance is introduced. The absence of solid bodies is verified by the glass plate test; If polymer particles persist, mixing is continued. Then Oxirite is added.

RO 120857 Β1

The solution is neutralized with NaOH. For maximum viscosity the pH value should be set above 12.3. Introduce the sodium hypochlorite solution chewing at reduced speed.

2. Highly fragrant aroma phase combined with a foam intensification phase a) High aroma phase aroma phase

composition FAEOS-Na, C12-14 + 2 EO ex.Texapon N 70 24.50% Basic surfactant Alkyl (C8-10) -1.5 glucoside eg Glucopon 220 UP-W 2.88% Contensid / emulsifier 1,2 - propanediol 10.00% emulsifier Ethanol 96%, denatured 1% MEK 5.00% Coemulgator hydroxyethyl 0.45% Thickening substance Citrus notes perfume oil 20.00% Flavored substance Semiacetal-isothiazoline combination 0.05% preservative dyes <1.00% Water from the pipeline ad. 100

approx. 2500 mPas, 20'C, Rotovisco LVT, axle 2.6 rot / min

PH 6.5, undiluted, clear solution

production

Prepare hot water at 20-25 ° C. while the mixer is in operation add the dyes and preservative and dissolve 5 min. The thickening substance is introduced at medium to high speed. during the soaking of approx. 60 min the mixer continues to operate. The absence of solid bodies is verified by the glass plate test; If solid bodies persist, mixing is continued. Add the tensides and then the alcohol. At the end, add the perfume and check the release parameters of the deposits.

b) Highly concentrated tenside phase, thickened with betaine chloride

composition FAEOS-Na, C12-14 + 2EO 30.00% Basic surfactant Cocamidopropyl Betatine by eg Dehyton K 20.00% Cotensid Undenatured NaCI 1.50% Thickening agent Semiacetal-isothiazoline combination 0.05% preservative dyes <1.00% Water from the pipeline ad.100

approx. 5500 mPas, 20'C, Rotovisko LVT, axle 2.20 rot / min

PH 6.5, undiluted, clear solution

RO 120857 Β1

production

The water is being prepared. Dissolve the dye and preservative and then add the surfactants by mixing. The viscosity is adjusted with NaCI.

3. The aromatic phase, combined with a phase of biologically active acidic substance, capable of dissolving lime

a) The aromatic phase

composition FAS-Na, C12-14 ex.Texapon LS 35 29.50% Basic surfactant Alkyl (C12-14) - polyglucoside eg Glucopon 600 CS-UP 3.30% Contensid / emulsifier 1,2 - propanediol 5.00% emulsifier Ethanol 96%, denatured 1% MEK 5.00% Coemulgator hydroxyethyl 0.45% Thickening substance Perfume oil Note Aqua 10.00% Flavored substance Tricity of sodium 2 H ₂ O 2.00% For complex training Semiacetal-isothiazoline combination 0.05% preservative dyes <1.00% Water from the pipeline ad. 100

approx. 2500 mPas, 20 * C, Rotovisko LVT, 2.6 rot / min 8.0 pH, undiluted, clear solution

production

Hot water is prepared at 20-25'C. while the mixer is in operation add the dyes and preservative, and dissolve 5 min. The thickening substance is introduced at medium to high speed. During the soaking for about 60 min the mixer continues to operate. The absence of solid bodies is verified by the glass plate test; If solid bodies persist, mixing is continued. Add the tensides and then the alcohol. Finally, add the perfume and check the release parameters of the deposits.

b) Antiviral acid phase, thickened with polysaccharides

composition FAEOS-Na, C12-14 + 2 EO 8.11% Basic surfactant Alkyl (C8-10) -1.5 glucoside 5.44% Contensid Citric acid 3.00% Dissolved lime Polysaccharide Xantan Gum from former Rhodopol T 0.20% Thickening substance Ethanol 96%, denatured 1% MEK 3.00% Coemulgator Perfume oil Note Aqua 6.00% Flavored substance

RO 120857 Β1

Table (continued)

composition Semiacetal-isothiazoline combination 0.05% preservative dyes <1.00% Water from the pipeline ad. 100

approx. 3500 mPas, 20 * C, Rotovisco LVT, axle 2.20 rot / min

2.5 pH, undiluted, clear solution

production

The water is being prepared. while the mixer is in operation add the dyes and preservative and then dissolve 5 min. The thickening substance is introduced at medium to high speed. during the soaking of approx. 60 min the mixer continues to operate. Add the tensides and then the alcohol. At the end add the perfume and citric acid, and check the release parameters of the deposits.

4. Aromatic phase combined with a phase of biologically active antibacterial substance a) Foam activated aroma phase of the formula ABS

composition Sodium alkylbenzosulfonate e.g. Marlon A350 (Huls) 25.50% Basic surfactant C12-15 oxoalcool + 10 EO of ex. Genapol-OX-100 (Clariant) 10.00% Contensid / emulsifier 1,2- propanediol 5.00% emulsifier Ethanol 96%, denatured 1% MEK 5.00% Coemulgator hydroxyethyl 0.45% Thickening substance Lemon Note perfume oil 10.00% Flavored substance Semiacetal-isothiazoline combination 0.05% preservative dyes <1.00% Water from the pipeline ad. 100

approx. 2500 mPas, 20 "C, RotoviskoLVT, axle 2.6 rot / min

PH 9.1, undiluted, clear solution

production

The hot water is prepared at 20-25'C. while the mixer is in operation add the dyes and preservative and dissolve 5 min. The thickening substance is introduced at medium to high speed. during the soaking of approx. 60 min, the mixer continues to operate. The absence of solid bodies is verified by the glass plate test; If solid bodies persist, mixing is continued. Add the tensides and then the alcohol. At the end, add the perfume and check the release parameters of the deposits.

RO 120857 Β1

b) Antibacterial phase

composition FAEOS-Na, C12-14 + 2 EO 24.50% Basic surfactant Alkyl (C8-10) -1.5 glucoside 2.88% Contensid / emulsifier 1,2 - propanediol 5.00% emulsifier Ethanol 96%, denatured 1% MEK 5.00% Coemulgator hydroxyethyl 0.45% Thickening substance Lemon Note perfume oil 10.00% Flavored substance Semiacetal-isothiazoline combination 0.10% preservative Technical salicylic acid 0.60% Antibacterial active substance dyes <1.00% Water from the pipeline ad.100

approx. 2700 mPas, 20'C, RotoviskoLVT, axle 2.6 rot / min

5.5 pH, undiluted, clear solution

production

The hot water is prepared at 20-25'C. while the mixer is in operation add the dyes and preservative and dissolve 5 min. The thickening substance is introduced at medium to high speed. during the soaking of approx. 60 min the mixer continues to operate. The absence of solid bodies is verified by the glass plate test; If solid bodies persist, mixing is continued. Add the tensides and then the alcohol. Finally add the perfume and check the parameters for the release of deposits.

5. Different acid systems with intense activity for lime dissolution a) Lactic acid phase

composition FAEOS-Na, C12-14 + 2 EO 8.11% Basic surfactant Alkyl (C8-10) -1.5 glucoside 5.44% Contensid Lactic Acid - Purac 80 2.50% Dissolving of var Polizaharid / Xanthan Gum 0.22% Thickening substance Ethanol 96%, denatured 1% MEK 3.00% Coemulgator Orange Note perfume oil 8.00% Flavored substance Semiacetal-isothiazoline combination 0.05% preservative dyes <1.00% Water from the pipeline ad. 100

approx. 3500 mPas, 20 “C, RotoviskoLVT, 2.20 rot / min

PH 2.2, undiluted, clear solution

production

The water is being prepared. while the mixer is in operation add the dyes and preservative and then dissolve 5 min. The thickening substance is introduced at a medium speed

RO 120857 Β1 to the sea. during soaking, for approx. 60 min, the mixer continues to operate. Add the tensides and then the alcohol. At the end add the perfume and lactic acid and check the release parameters of the deposits.

b) Nio-tenside citric acid phase

composition FA-C12-C18 + 7 EO ex.Dehydol LT 7 12.50% Basic surfactant / emulsifier Alkyl (C8-10) -1.5 glucoside 5.44% Contensid 1,2 - propanediol 5.00 emulsifier Oleyl-cetyl alcohol + 5 EO 3.00 Coemulgator Citric acid 5.00% Dissolving of var Polizaharid / Xanthan Gum 0.20% Thickening substance Ethanol 96%, denatured 1% MEK 3.00% Coemulgator Orange Note perfume oil 12.00% Flavored substance Semiacetal-isothiazoline combination 0.05% preservative dyes <1.00% Water from the pipeline ad. 100

approx. 3500 mPas, 20'C, RotoviskoLVT, axle 2.20 rot / min

2.5 pH, undiluted, clear solution

production

The water is being prepared. while the mixer is in operation add the dyes and preservative and then dissolve 5 min. The thickening substance is introduced at medium to high speed. during the soaking of approx. 60 min the mixer continues to operate. Add the tensides and then the alcohol. At the end add the perfume and citric acid and check the release parameters of the deposits.

6. Flavored phase, combined with a phase of biologically active substance containing enzymes a) Flavored phase

composition FAEOS-Na, C12-14 + 2 EO 24.50% Basic surfactant Sodium alkane sulphonate e.g. Hostapur SAS 60 (Hoechst) 8.50% Cotensid 1,2 - propanediol 5.00% emulsifier Ethanol 96%, denatured 1% MEK 5.00% Coemulgator hydroxyethyl 0.45% Thickening substance Female flower perfume oil 9.00% Flavored substance 1 Semiacetal-isothiazoline combination 0.05% preservative dyes <1.00% Water from the pipeline ad. 100

approx. 2500 mPas, 20'C, Rotovisco LVT, axle 2.6 rot / min

PH 6.8, undiluted, clear solution

RO 120857 Β1

production

Prepare the hot water at 20-25 ° C. while the mixer is in operation add the dyes and preservative, and dissolve 5 min. The thickening substance is introduced at medium to high speed. during the soaking of approx. 60 min the mixer continues to operate. The absence of solid bodies is verified by the glass plate test; If solid bodies persist, mixing is continued. Add the tensides and then the alcohol. At the end, add the perfume and check the release parameters of the deposits.

b) Enzyme phase

composition FAEOS-Na, C12-14 + 2 EO 24.50% Basic surfactant Alkyl (C8-10) -1.5 glucoside 2.88% Contensid / emulsifier 1,2- propanediol 5.00% emulsifier Ethanol 96%, denatured 1% MEK 5.00% Coemulgator hydroxyethyl 0.45% Thickening substance Female flower perfume oil 9.00% Flavored substance Semiacetal-isothiazoline combination 0.05% Preservative / below. antibact. dyes <1.00% Water from the pipeline ad.100

approx. 3000 mPas, 20 * C, Rotovisk LVT, axle 2.6 rot / min

PH 6.5, undiluted, clear solution

production

The hot water is prepared at 20-25'C. while the mixer is in operation add the dye and dissolve 5 min. The thickening substance is introduced at medium to high speed. during the soaking of approx. 60 min the mixer continues to operate. The absence of solid bodies is verified by the glass plate test; If solid bodies persist, mixing is continued. Add the tensides and then the alcohol. At the end, add the perfume and check the release parameters of the deposits.

7. Scented acid phase combined with a phase of biologically active substance coloring the washing water

a) The acid phase

composition FAEOS-Na, C12-14 + 2 EO 20.10% Basic surfactant Alkyl (C8-10) -1.5 glucoside 5.44% Cotensid Citric acid 2.50% Lime dissolvent Formic acid 1.50% Lime dissolvent Polysaccharide / Xantan Gum 0.22% Thickening substance Ethanol 96%, denatured 1% MEK 3.00% Coemulgator

RO 120857 Β1

Table (continued)

composition Mint perfume oil 10.00% Flavored substance Semiacetal-isothiazoline combination 0.05% preservative dyes <1.00% Water from the pipeline ad.100

approx. 3500 mPas, 20'C, Rotovisco LVT, axle 2.20 rot / min

2.5 pH, undiluted, clear solution

production

The water is being prepared. while the mixer is in operation add the dyes and preservative and then dissolve 5 min. The thickening substance is introduced at medium to high speed. during the soaking of approx. 60 min the mixer continues to operate. Add the tensides and then the alcohol. At the end, add the perfume and acids and check the release parameters of the deposits.

b) Staining phase of washing water / Sodium trisulfate as a complexing agent

composition FAEOS-Na, C12-14 + 2 EO 9.11% Basic surfactant Alkyl (C8-10) -1.5 glucoside 5.44% Cotensid Tricity of sodium 2 H ₂ O 2.00% Complexing substance Polysaccharide / Xantan Gum 0.20% Thickening substance Ethanol 96%, denatured 1% MEK 3.00% Coemulgator Mint perfume oil 7.00% Flavored substance Semiacetal-isothiazoline combination 0.05% preservative Coloring (Basacidblau 755 g) 3.00% Water soluble dye Water from the pipeline ad.100

approx. 3500 mPas, 20C, Rotovisk LVT, axle 2.20 rot / min

PH 7.5, undiluted, clear solution

production

The water is being prepared. while the mixer is in operation add the dyes and preservative and then dissolve 5 min. The thickening substance is introduced at medium to high speed. during the soaking of approx. 60 min the mixer continues to operate. Add the tensides and then the alcohol. At the end add the perfume and citric acid and check the release parameters of the deposits.

8. The aromatic phase combined with a phase of biologically active substance that has the capacity to absorb the odor

a) The aromatic phase

composition FAEOS-Na, C12-14 + 2 EO 24.50% Basic surfactant Alkyl (C8-10) -1.5 glucoside 2.88% Cotensid / emulsifier

RO 120857 Β1

Table (continued)

composition 1,2 - propanediol 10.00% emulsifier hydroxyethyl 0.50% Thickening substance Field flowers perfume oil 10.00% Flavored substance Semiacetal-isothiazoline combination 0.05% preservative dyes <1.00% Water from the pipeline ad.100

approx. 2500 mPas, 20 * C, Rotovisco LVT, axle 2.6 rot / min

PH 6.5, undiluted, clear solution

production

Prepare hot water at 20-25 "C. while the mixer is in operation add the dyes and preservative, and dissolve 5 min. The thickening substance is introduced at medium to high speed. during the soaking of approx. 60 min the mixer continues to operate. The absence of solid bodies is verified by the glass plate test; If solid bodies persist, mixing is continued. Add the tensides and then the alcohol. At the end, add the perfume and check the release parameters of the deposits.

b) The absorbent phase

composition FAEOS-Na, C12-14 + 2 EO 24.50% Basic surfactant Alkyl (C8-10) -1.5 glucoside 2.88% Cotensid / emulsifier Ethanol 96%, denatured 1% MEK 10.00% emulsifier hydroxyethyl 0.45% Thickening substance Field flowers perfume oil 10.00% Flavored substance 1 Semiacetal-isothiazoline combination 0.05% Preservative / sub. antibact. Zinc roasting 1.00% Odor absorbent dyes <1.00% Water from the pipeline ad. 100

approx. 2700 mPas, 20 * C, Rotovisco LVT, axle 2.6 rot / min

5.5 pH, undiluted, clear solution

production

Prepare hot water at 20-25 ° C. while the mixer is in operation add the dyes and preservative, and dissolve 5 min. The thickening substance is introduced at medium to high speed. during the soaking of approx. 60 min the mixer continues to operate. The absence of solid bodies is verified by the glass plate test; If solid bodies persist, mixing is continued. Add the tensides and then the alcohol. At the end, add the perfume and check the release parameters of the deposits.

RO 120857 Β1

9. The scented acid phase combined with a phase of biologically active substance with active oxygen

a) Acid phase with active oxygen

composition FAEOS-Na, C12-14 + 2 EO 20.10% Basic surfactant Alkyl (C8-10) -1.5 glucoside 5.44% Cotensid Citric acid 2.00% Lime dissolvent Polysaccharide / Xanthan Gum 0.22% Thickening substance Ethanol 96%, denatured 1% MEK 3.00% Coemulgator Apple perfume oil 8.00% Flavored substance Semiacetal-isothiazoline combination 0.05% preservative Oxygenated water 35% 2.86% Active oxygen (1%) Sodium diethylenetriaminpentamethylene phosphonic acid (Dequest 2066 Monsanto) 0.16% stabilizer Dyes, pigments <1.00% Water from the pipeline ad. 100

approx. 3500 mPas, 20 * C, Rotovisco LVT, axle 2.20 rot / min

2.5 pH, undiluted, clear solution

production

The water is being prepared. while the mixer is in operation add the dyes and preservative and then dissolve 5 min. during the soaking of approx. 60 min the mixer continues to operate. Add the tensides and then the alcohol. The perfume and acids are introduced, finally the stabilizer and oxygenated water are added, and the parameters for the release of deposits are checked.

b) Aromatic phase

composition FAEOS-Na, C12-14 + 2 EO 20.10% Basic surfactant Alkyl (C8-10) -1.5 glucoside 5.44% Cotensid Citric acid 2.00% Lime dissolvent Polysaccharide / Xanthan Gum 0.22% Thickening substance Ethanol 96%, denatured 1% MEK 6.00% Coemulgator Apple perfume oil 10.00% Flavored substance Semiacetal-isothiazoline combination 0.05% preservative dyes 1 <1.00% Water from the pipeline ad.100

approx. 3500 mPas, 20'C, Rotovisko LVT, axle 2.20 rot / min

2.5 pH, undiluted, clear solution

RO 120857 Β1

production

The water is being prepared. while the mixer is in operation add the dyes and the conversant and then dissolve 5 min. The thickening substance is introduced at medium to high speed. during the soaking of approx. 60 min the mixer continues to operate. Add the tensides and then the alcohol. Introduce the perfume and acids and check the release parameters of the deposits.

10. The scented acid phase, combined with a phase of biologically active substance thickened with polyacryl

a) Acid phase with active oxygen

composition FAEOS-Na, C12-14 + 2 EO 20.10% Basic surfactant Alkyl (C8-10) -1.5 glucoside 5.44% Cotensid Citric acid 4.00% Lime dissolvent Polysaccharide / Xanthan Gum 0.22% Thickening substance Ethanol 96%, denatured 1% MEK 3.00% Coemulgator Citrus Notes perfume oil 8.00% Flavored substance Semiacetal-isothiazoline combination 0.05% preservative dyes <1.00% Water from the pipeline ad. 100

approx. 3500 mPas, 20 * C, Rotovisco LVT, axle 2.20 rot / min

PH 3.0, undiluted, clear solution

production

The water is being prepared. while the mixer is in operation add the dyes and preservative and then dissolve 5 min. The thickening substance is introduced at medium to high speed. during the soaking of approx. 60 min the mixer continues to operate. Add the tensides and then the alcohol. The perfume and acids are introduced, finally the stabilizer and oxygenated water are added, and the parameters for the release of deposits are checked.

b) The phase of biologically active substance thickened with polyacryl

composition FAEOS-Na, C12-14 + 2 EO 10.10% Basic surfactant Alkyl (C8-10) -1.5 glucoside 2.50% Contensid Ethanol 96%, denatured 1% MEK 3.00% Coemulgator Sodium hydroxide (50%) 1.50% Substance of neutralization Citrus Notes perfume oil 4.00% Flavored substance Polymerized polyacrylate (eg Carbopol ETD 2690 produced by BF Goodrich) 0.80% Water from the pipeline ad.100

approx. 3500 mPas, 20C, Rotovisco LVT, axle 2.6 rot / min

PH 10.0, undiluted, clear solution

RO 120857 Β1

production

The water is being prepared. At the medium to high speed (approx. 800 rpm) the thickening substance is introduced. The absence of solid bodies is verified by the glass plate test; If polymer particles persist, mixing is continued. Then the solution is neutralized with NaOH. At a reduced speed, add the perfume oil, mixing.

Claims (26)

1. Device for distributing fluids of biologically active substance in the washing liquid of a toilet vessel comprising a support (1), which can be hung on the edge of the toilet bowl, provided internally with at least two feed containers ( 2,3) having an outlet hole (4) of its own, whereby the respective fluid of biologically active substance can be distributed in the washing liquid, characterized in that the feed containers (2, 3) are protected against penetration of the washing liquid inside them, and the outlet holes (4) of the feed containers (2, 3) are so placed that only one of the fluid of biologically active substance comes out, that on the support (1) is provided with a plate-shaped distribution element common to at least two feed containers (2,3), which has an actuating area over which the washing fluid flows to perform a wash, that the interior of each feed container (2, 3) is permanently connected to the dispensing element through the outlet (4), possibly by intercalating an element that prevents a free flow of the biologically active substance fluid, and that, in the operating position, each outlet (4) is at the bottom of the feed containers (2, 3). Distribution device according to claim 1, characterized in that the supply containers (2, 3) are mounted, or can be mounted, in the support (1), with the possibility of being changed individually. Distribution device according to claim 1, characterized in that the supply containers (2,3) are coupled together and can be fixed, thus coupled, in the support (1). A dispensing device according to claim 1, characterized in that the feeding containers (2,3) are formed of a common housing, consisting of a single piece. A dispensing device according to any one of claims 1 to 4, characterized in that the supply receptacles (2,3) are provided with separate recharging holes and may be located or formed in a fixed manner in the support (1). ). A dispensing device according to any one of claims 1 to 5, characterized in that the supply containers (2, 3) are located on the support (1) side by side. Distribution device according to any one of claims 1 to 5, characterized in that the supply containers (2, 3) are located on the support (1) one above the other. A dispensing device according to any one of claims 1 to 7, characterized in that the supply containers (2, 3) can be mounted in the support (1) on the top thereof. Distribution device according to any one of claims 1 to 7, characterized in that the supply containers (2,3) can be mounted in the support (1) by pushing from the side thereof. RO 120857 Β1 A dispensing device according to any one of claims 1 to 7, characterized in that the supply containers (2, 3) can be mounted in the support (1) by being placed on the side thereof and folding. A dispensing device according to claim 1, characterized in that the feed containers (2, 3) each have a flexible wall segment, or generally a flexible wall, and the discharge of the biologically active substance fluid, located in this is done by applying pressure to the feed container.7 A dispensing device according to claim 1, characterized in that each outlet (4), located at the bottom of the feed containers 9 (2, 3), is sealed by a sealing element (5), which it is inserted purposely into the closing position of each outlet (4) and may be moved, contrary to the pretensioning force, 11 to an opening position of the outlet (4), the sealing element (5) being provided with an actuator (6), common to at least two 13 feed containers (2, 3), which cooperate with the sealing member (5) so that, in each operation with a washing liquid, it may be temporarily subjected to forces, such that 15 so that they may temporarily occupy, against the action of the pretensioning force, the opening position, and that, for this purpose, there is an area (7), 17 actuated on the actuator (6) from f the luxury of washing fluid. Distribution device according to claim 12, characterized in that the actuating element (6) is formed in the form of an arm lever, articulated at one end on the support (1), that the sealing member (5) it is located on the actuator 21 (6) between the end articulated on the support (1) and the area (7), the actuator, and preferably the actuator (6) extends from the sealing member (5 ) up to area 23 (7) operating in a horizontal straight line or downward sloping. 14. A dispensing device according to claim 12 or 13, characterized in that the actuating element (6), corresponding to the sealing elements (5), is common to at least two supply containers (2, 3). 27 Distribution device according to any one of claims 1 to 14, characterized in that, in the case of two feed containers (2, 3), they are executed 29 asymmetrically with respect to the central axis of the distribution device. Distribution device according to claim 15, characterized in that the outlet ports (4) are located on the feed receptacles (2,3) offset with respect to the central axis of the distribution device. 33 A dispensing device according to any one of claims 1 to 16, characterized in that the flow of the washing liquid at the cross-sections of the outlet holes 35 (4) and / or the pretensioning forces of the sealing elements (5) can be determined. be different and / or can be adjusted to be different. 37 18. A dispensing device according to any one of claims 1 to 17, characterized in that the feed containers (2, 3) contain different biologically active fluids 39, whether or not compatible with each other, and preferably filled with them. . A dispensing device according to claim 18, characterized in that a biologically active fluid 41 is a flavored phase, in particular a fragrant flavored phase. 20. A dispensing device according to claim 19, characterized in that the aromatic phase 43 contains at least one aromatic substance, preferably perfume oil, at least one tenside or an emulsifier and water, and possibly other substances, such as preservatives. , thickening agents, substances for complex complexes, dyes, other stresses or emulsifiers, stabilizers or solvents of lime. 47 RO 120857 Β1 A dispensing device according to claim 18, characterized in that the biologically active substance fluid contains a bleaching phase, in particular a bleaching phase containing chlorine, preferably based on hypochlorite, the bleaching phase possibly containing and other components such as thickening agents, tensides and emulsifiers, neutralizing substances, dyes and flavoring substances. Distribution device according to claim 18, characterized in that the biologically active substance fluid comprises a phase of biologically active substance capable of dissolving lime, preferably acid, the phase of biologically active substance capable of dissolving lime containing, in addition to the capable substance. to dissolve lime, and an organic or inorganic agent, and possibly other components such as tensides or emulsifiers, thickening agents, flavoring or preservatives. Distribution device according to claim 18, characterized in that the biologically active substance fluid comprises a highly concentrated tenside phase, favoring foam intensification. 24. A dispensing device according to claim 18, characterized in that the biologically active substance fluid comprises a phase of biologically active substance with antibacterial and / or fungicidal and / or antiviral action, which, in addition to the biologically active substance with antibacterial action and / or fungicide and / or antiviral, it may possibly also contain other components such as surfactants and emulsifiers, thickening agents, flavoring or preservatives. 25. A dispensing device according to claim 18, characterized in that the biologically active substance fluid comprises a phase of biologically active substance containing enzymes, which, in addition to enzymes, may possibly contain other components such as stresses and emulsifiers , thickeners, flavorings or preservatives. 26. A dispensing device according to claim 18, characterized in that the biologically active substance fluid comprises a phase of biologically active substance, which is absorbent, especially odor absorber, which, in addition to the absorption means, in particular the odor absorption means, can also possibly includes other components, such as surfactants and emulsifiers, thickening agents, flavorings or preservatives.