CN1474901A - Distributing device for distributing fluids containing active ingredients to flush liquid inside toilet bowl - Google Patents
Distributing device for distributing fluids containing active ingredients to flush liquid inside toilet bowl Download PDFInfo
- Publication number
- CN1474901A CN1474901A CNA018189539A CN01818953A CN1474901A CN 1474901 A CN1474901 A CN 1474901A CN A018189539 A CNA018189539 A CN A018189539A CN 01818953 A CN01818953 A CN 01818953A CN 1474901 A CN1474901 A CN 1474901A
- Authority
- CN
- China
- Prior art keywords
- hold
- vessel
- described conveying
- high effective
- effective substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0056—Lavatory cleansing blocks
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
- E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
- E03D9/03—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing consisting of a separate container with an outlet through which the agent is introduced into the flushing water, e.g. by suction ; Devices for agents in direct contact with flushing water
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
- E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
- E03D9/03—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing consisting of a separate container with an outlet through which the agent is introduced into the flushing water, e.g. by suction ; Devices for agents in direct contact with flushing water
- E03D9/032—Devices connected to or dispensing into the bowl
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Public Health (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Epidemiology (AREA)
- Detergent Compositions (AREA)
- Bidet-Like Cleaning Device And Other Flush Toilet Accessories (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention relates to a dispensing device for dispensing active substance fluid into the flushing liquid inside a toilet bowl. The dispensing device comprises a holder (1) that can be suspended-on the edge of the toilet bowl and comprises at least two reservoirs (2, 3), which are separate from one another, are provided inside the holder (1), and which each accommodate an active substance fluid. Each reservoir (2, 3) has its own discharge opening (4) via which the respective active substance fluid can be dispensed into the flushing liquid. The inventive dispensing device is characterized in that flushing liquid is not permitted to enter the interior of the reservoirs (2, 3), and the discharge openings (4) of the reservoirs (2, 3) are arranged so that only active substance fluid is discharged and a partial quantity of the active substance fluid is dispensed from each of the reservoirs (2,3) into the flushing liquid during each flushing.
Description
The present invention relates to conveying device, be used for to the high effective substance of flush toilet flushing liquor transport flow with claim 1 preamble feature.
The notion of mobile high effective substance is meant flowable, just liquid until the magma attitude, possibility gelatinous or paste in addition or high effective substance preparation granular or otherwise can be loose, have effects such as purification, sterilization, deodorizing, bleaching (particularly do not shift to an earlier date disclosed DE 199 30 362 A1, and introduced among EP 0 775 741 A1 and EP 0 960 984A2).
The conveying device of described type serves as that topic discloses various structure with " WC-corbeil ".Disclosed at first is the conveying device of single mobile high effective substance.The high effective substance that flows is in there and is fixedly installed in the hold-up vessel of inserting on the support or replaceable, and rack-mount hold-up vessel bottom is provided with floss hole.
In the conveying device of disclosed first kind of single mobile high effective substance, the high effective substance that flows is by being carried (EP 785 315 A1) by its control element that soak and that can supply with flushing liquor (for example with there being the foamed plastics of perforate to make).Here, the floss hole of hold-up vessel is after the closure member of hold-up vessel is gone out, and major part is fixedly installed on the seal sealing on the support, to such an extent as to only there is the flow path of very little cross section to ooze for the high effective substance that flows.This device is utilizing under the capillarity situation of sponge plastics and can play a role.The disclosed sheet with rib that takes up distributional effects in addition of similar structures.
In two kinds of modification, floss hole continues to open basically, even when just the long period is not used flush toilet, the high effective substance that flows continues outside water clock.This point allows the people feel not ideal enough sometimes.
The conveying device (DE 299 02 066 U1) of another kind of single mobile high effective substance is the seal that valve-type work is set on hold-up vessel, and it under normal circumstances takes to seal the detent position that the forward of floss hole seals.This point is to produce under the action of gravity of the ball body of valve that plays the seal effect.This seal can be adjusted reverse blas power a small amount of off-position that discharges in floss hole.Work to be used as that the equiarm bar constitutes for this, the control element of turntable supporting on the support swinging axle.On a side of axle, control element has the drainage area that ware shape holds flushing liquor.Control element is in arm on the opposite side from following and abut.If flushing liquor arrives the active region, by control element seal is promoted from the valve seat on the floss hole so, and floss hole is opened slightly.The high effective substance that flows can splash into the flushing liquor stream of flowing through from floss hole through seal, or is taken out of by flushing liquor.Do not shift to an earlier date disclosed DE 199 30 362 A1 from above-mentioned another, the similar conveying device of conveying device a kind of and that inquire into is before this disclosed, yet, it has single armed as control element, one end is hinged on the lever on the support, and seal is arranged between that end and drainage area that is hinged on the support on it.This structure is particularly suitable for the replaceable hold-up vessel that is arranged on the support.
In the application of the described type conveying device of Jie Shaoing, all compositions that enter in the flush toilet flushing liquor all must be included in the high effective substance that flows jointly in front.But some high effective substance composition can not be stored by jointly stabilizing.Therefore, the someone proposes multicell-conveying device (EP 0 960 984A2).This disclosed conveying device is used for carrying at least two kinds of different or identical solid-state, gels, paste or liquid mediums to flush toilet with liquid or water dilute form.One container is arranged, for the deposit medium has at least two independently chambers that are arranged side by side on the support that can be suspended on edge of closet.Each chamber has the conveying device that band is carried tubule, carries tubule to utilize the one free end to stretch out from container bottom, is encased by lid on another free end of the high effective substance of its transport flow.The flushing water of overflow can be injected by the clearance type opening of cover plate in two chambers of container, and flushing water according to the mode of syphon or overflow, enters flush toilet by the high effective substance of carrying tubule to carry separately then.The advantage of in container the chamber being separated is to use different media, otherwise be stored in an indoor meeting jointly the effect that requires them and reach is had a negative impact.And the concentration of medium also can be different in the different chamber.
In above-mentioned conveying device, utilize the action principle of known " WC-corbeil ", the flushing water of overflow contains the indoor of high effective substance of flowing from top inflow, and the dissolving high effective substance of part also carries them again from indoor outflow.The problem of Cun Zaiing is in this regard, and at the siphonic effect of indoor generation, liquid level obviously falls after rise along with here.That is to say that even the flushing process long period finishes, flushing liquor is still continuing the influence of the indoor high effective substance that flows separately.In fact the consumption of mobile high effective substance can not obtain Optimal Control.
Disclosed also have a kind of pair of chamber-conveying device, is used for the same or different gel high effective substance (WO92/20876 A1) that flows, and wherein, floss hole constitutes in hold-up vessel as bottom perforated and continues unlimited.Because the viscosity and the surface tension of gelinite can not discharged under gravitation under the gelinite normal condition automatically, have only the flushing liquor by overflow to enter floss hole and the gelinite of floss hole is dissolved a little from following, the high effective substance that just part can be flowed be taken out of.The same problem that exists is that floss hole continues to open basically, therefore in this pair of chamber system, even when not using flush toilet in the long period, mobile high effective substance or outside water clock perhaps harden under the effect of atmospheric pressure, after this again no longer include activity.
The objective of the invention is to, aspect the control ability of efficient mass transport that flows, be used in the above-mentioned disclosed conveying device optimization of the high effective substance of transport flow from least two separate hold-up vessels.
The proposition of above-mentioned purpose, in the conveying device with claim 1 preamble feature, the characteristic by claim 1 is achieved.According to the present invention, hold-up vessel prevents that flushing liquor from entering its inside, and can only be that the high effective substance that flows comes out from the floss hole of hold-up vessel.This point is achieved thus, and promptly in each flushing process, transport portion flows high effective substance in flushing water from each hold-up vessel.
State on the meaning of determining purpose being to use of particularly suitable in realization by the described foundation of claim 16 conveying device of the present invention.In this scheme, forward closes that floss hole is suitable especially determines the metering section consumption and the mobile high effective substance in the protection hold-up vessel when not using in the long period.
Be to realize according to structure of the present invention, be suitable for adopting in the prior art disclosed, the technology of the single efficient material delivery apparatus that flows that the front has extensively been introduced.Can consult above-mentioned prior art in detail to this.
Preferred moulding of the present invention and further formation are the themes of dependent claims.
By accompanying drawing the preferred embodiments of the present invention are elaborated below.Wherein:
Fig. 1 illustrates the vertical view according to conveying device preferred embodiment of the present invention,
Fig. 2 illustrates along the section of Fig. 1 device of II-II line,
Fig. 3 illustrates along the section of Fig. 2 device of III-III line.
The flushing liquor that conveying device shown in the figure is used for being used for washing in flush toilet is carried at least two kinds of high effective substances that flow.The mobile high effective substance of being understood on the meaning of the present invention can be consulted the definition of being done in the common segment of manual.
This conveying device at first has the support 1 that can be suspended on the edge of closet and at least two and is installed in being used on the support 1 and stores the hold-up vessel independent of each other 2,3 of each a kind of high effective substance that flows.These high effective substances that flow can be identical, different, the compatible with each other or inconsistent high effective substance that flows.Can or be that a plurality of high effective substances that flow use a plurality of hold-up vessels for two kinds of mobile high two hold-up vessels of effective substances use.
According to the present invention, suitable mobile high effective substance for example is fragrant phase, particularly adds the fragrant phase of spices.These fragrance contain at least a aromatic mutually usually, aromatic oil preferably, at least a surfactant or emulsifier and water, and other compositions in case of necessity are as anticorrisive agent, thickener, chelating agent, colorant, other surfactants or emulsifier, stabilizing agent, detergent etc.
According to the present invention, the same mobile high effective substance that is suitable for is the bleaching phase, particularly chloride bleaching phase, preferably based on the bleaching phase of hypochlorite, wherein, bleaching is general mutually except itself bleaching agent and water, also can contain other compositions in case of necessity, as thickener, surfactant or emulsifier, nertralizer, colorant, spices etc.
Other high effective substances that flow that are suitable for according to the present invention are high effective substance phases of de-sludging, preferably the high effective substance phase of acid de-sludging.The high effective substance of this de-sludging be divided by itself detergent-be preferably in be organic in this case or inorganic acid-and water outside, also contain other compositions in case of necessity, as surfactant or emulsifier, thickener, spices, anticorrisive agent etc.
Can be used as the concentrated surfactant phase in addition that the high effective substance that flows uses equally, so-called " foamed promoter ".This concentrated surfactant can also contain other compositions commonly used except surfactant.
Contain mobile high effective substance antibiotic and/or sterilization and/or sterilization activator phase in addition according to what the present invention was suitable for equally, wherein, activator is except activator and water with antibiotic and/or sterilization and/or Disinfection Effect, also can contain other compositions in case of necessity, for example surfactant or emulsifier, thickener, spices, anticorrisive agent etc.
In addition, mobile high effective substance can be the activator phase that contains enzyme.This activator that contains enzyme can also contain other compositions in case of necessity except enzyme and water, as surfactant or emulsifier, and thickener, spices, anticorrisive agent etc.
Equally, can absorb, particularly absorb the high effective substance phase of smell according to the high effective substance that flows used in the present invention.They particularly outside odour absorbents and the water, can also contain other compositions in case of necessity except absorbent, as surfactant or emulsifier, and thickener, spices, anticorrisive agent etc.
According to a special embodiment, can in hold-up vessel 2,3, use the combination of different mobile efficient materials according to conveying device of the present invention, wherein, foundation one preferred embodiment, one of hold-up vessel 2,3 contains particularly the fragrant phase by above-mentioned definition.
The example of mobile high effective substance-combination of using is spiced fragrance and chlorine bleaching combination (the common instability of storing), spiced fragrance and concentrated surfactant be (foamed promoter) mutually, fragrance and the acid high effective substance of de-sludging are mutually, fragrance with antibiotic high effective substance mutually, different acid-systems, fragrance is combined with the high effective substance that contains enzyme, spiced acid is combined with the hydration colorant, fragrance with odor adsorption mutually, spiced acid phase and active oxygen, perfuming acid and high effective substance utilize polyacrylate thickening etc. mutually.Wherein useful especially is the extremely gelatinous high effective substance that flows of magma attitude, and viscosity is in several thousand mPas scopes, and particularly 2000 to 5000mPas, best 2500 to 3500mPas (adopting spiral viscometer LVT to measure 2.6 rev/mins on axle, 20 ℃).
In the conveying device of being introduced, each hold-up vessel 2,3 has the floss hole 4 of itself, can be transported in the flushing liquor by its mobile high effective substance separately.Be that with the difference of the prior art that constitutes starting point of the present invention hold-up vessel 2,3 prevents that flushing liquor from entering its inside here.The floss hole 4 of hold-up vessel 2,3 is provided with in this regard like this, and the high effective substance that flows can only be discharged; When each flushing process, from the mobile high effective substance of each hold-up vessel 2,3 delivery section component in flushing liquor.In an illustrated embodiment, this point realizes that so promptly the floss hole 4 of each hold-up vessel 2,3 is arranged on the use location of bottom surface, as shown in Figure 2.The flushing water of overflow is flushed on the hold-up vessel 2,3 at most from the side.
For hold-up vessel 2,3 is provided with and is installed on the support 1, multiple different feasibility is arranged.Illustrated in the accompanying drawings with regard in this preferred embodiment, hold-up vessel 2,3 independent replaceable installations maybe can be installed on the support 1.A kind of selectable method is that hold-up vessel 2,3 interconnecting and being installed on the support 1 like this with connecting by means of adapter or class thing.Another kind of selectable method is, hold-up vessel 2,3 directly interconnect and so direct connection be installed on the support 1.It is also conceivable that at last hold-up vessel 2,3 constitutes in the shell of a common single-piece, for example, in relevant shell, be installed in then on the support 1 as independent chamber.With the mobile high effective substance that will use, can select a kind of or another kind of modification according to actual needs.
Hold-up vessel 2,3 can look like that prior art (DE 299 02 066 U1, DE 199 15 322A1) introduced like that, can annotate separately by filler separately, in case of necessity mounted valve.Particularly in this case, hold-up vessel 2,3 also can be fixedly installed on the support 1 or on support and constitute, and just selects the whole setting of sealing itself.
The hold-up vessel 2,3 of replaceable unidirectional container that probably can be more popular in illustrated embodiment yes the practice.Should shown in show that with preferred embodiment hold-up vessel 2,3 is arranged side by side on support 1.The corresponding therewith front and back of hold-up vessel 2,3 that also are applicable to are provided with continuously.Also can carry purpose for the goods of tandem type selects hold-up vessel 2,3 is stacked setting.
Shown shows in addition with preferred embodiment, and the hold-up vessel 2,3 that can change separately here can be installed on the support 1 by inserting from top (use location).Also can consider the fixed form that other are different as selecting.For example it is contemplated that, hold-up vessel 2,3 is pushed in the support 1 from the side.Also it is contemplated that hold-up vessel 2,3 is connected on the support 1 from the side, inwardly swing around swinging axle then and enter the use location.Formation and sealing mode thereof according to floss hole 4 can be selected a kind of or another kind of modification.
For example can use as the high effective substance that flows in principle having very full-bodied gelinite or cream that can individual flow.In this case, suggestion hold-up vessel 2,3 has flexible wall section or whole flexible wall, takes out the mobile high effective substance that is in the inside by exerting pressure to hold-up vessel 2,3.Applying this pressure for example can be finished by the flushing liquor of overflow by corresponding mechanism.
The front points out that in foundation multicell-conveying device of the present invention, conveying mechanism also can use the conveying device of the disclosed single high effective substance that flows of prior art in principle.Thus, structural feasibility comes from EP 0 538 957 B1 substantially in present case, on support 1, has board-like distribution member, the drainage area of flushing liquor overflow when it has flushing process, wherein, the inside of hold-up vessel 2,3 continues to combine with distribution member under the centre that stops the high effective substance that flows to flow freely setting is provided with by floss hole 4 in case of necessity.According to particularly preferred embodiment, board-like distribution member returns all hold-up vessels 2,3 total.
Shown shows a solution with preferred embodiment, and it adopts the sealing part works of forward sealing.Here, the floss hole 4 of the bottom of hold-up vessel 2,3 setting just is by means of seal 5 sealings.Seal 5 is subjected to bias voltage on the detent position of sealing floss hole 4, and can resist biasing force to the adjustment of the off-position of a small amount of release floss hole 4.
For adjusting seal 5, have and seal 5 coefficient control elements 6, in each flushing process, can apply power in short-term to it by flushing liquor, make seal 5 opposing biasing forces be in the off-position in short-term.When having on the control element 6, supply with the drainage area 7 of flushing liquor for this reason, flushing liquor occurs above when flushing process at flushing process.Control element 6 is as single armed, and the lever that an end is hinged on the support 1 constitutes.Seal 5 is arranged on the control element 6 with the certain distance with drainage area 7.By the lever (Fig. 3) that control element 6 single arm type structures constitute, the action direction of the power that flushing liquor applies and seal 5 to open direction consistent.Thus, seal 5 can be downwards leaves from the floss hole 4 of hold-up vessel 2,3.Thus, need not special structural measure and just can realize installing replaceably hold-up vessel 2 easily; 3.
In an illustrated embodiment, seal 5 is arranged on being hinged between the end and drainage area 7 on the support 1 of control element 6.Like this, seal 5 to open stroke quite little, opening has only minimum slit on request.In addition, this slit is asymmetric opening in the corresponding moulding of seal 5, just opens greatlyyer on the direction of drainage area 7, to such an extent as to the high effective substance that flows is preferentially discharged in this direction.This is the direction facing to flushing liquor, and flowing then, high effective substance is corresponding with flushing liquor to be mixed.The high effective substance that flows can flow on the direction of drainage area 7 on control element 6 like this, and mixes with the flushing liquor of overflow on this section.
Can be with seal 5 and control element 6 global formations.Ad hoc proposal control element 6 is by plastic material, and plastics that particularly can injection moulding are made.Support 1 also can particularly preferred mode by plastics, plastics that particularly can injection moulding, preferably thermoplastic is made.Generally speaking, control element 6 can with support 1 global formation, biasing force produces by the intrinsic elastic force of control element 6.
Shown shows in special mode that with preferred embodiment control element 6 is returned at least two hold-up vessels 2,3, preferably returns the seal 5 of all hold-up vessels 2,3 total.Can see that from the vertical view of Fig. 1 control element 6 wide and plank frame all is in the frame base plate 9 of support 1 together with the drainage area 7 of same wide slot type and the little overfall 8 that the inside can be seen.Consistent is that floss hole 4 is arranged on the hold-up vessel 2,3 therewith.Their utilize the asymmetric formation in center (Fig. 2) of floss hole 4 that the central whole to conveying device moves and whole conveying device.Thus, the discharging of high effective substance is concentrated on the limited range that is rather narrow, imperceptible have two hold-up vessels 2,3.
At last, in some way with different hold-up vessels 2; 3 mobile high effective substance control is carried and is achieved thus, promptly on the floss hole 4 and/or seal 5 on fluid cross-section can differently determine and/or adjust.
In a word, shown conveying device can have various moulding in configuration aspects, particularly aspect the setting and formation of floss hole and seal.The parallel patent application report that this is had the inventor propose simultaneously can be consulted its disclosure (DE............).Particularly can realize adopting identical or variable concentrations carries out while or time-delay is quantitative to different hold-up vessels.
Now the invention will be further described by the following examples, but these embodiment are unrestricted extremely to the present invention.In these embodiments, introduced the different mobile efficient combinations of substances that is used for according to conveying device hold-up vessel 2,3 of the present invention.1.) perfuming fragrance makes up with chlorine bleaching: realize the actual instability of storing in single containment system.a。) fragrant phase constituent FAEOS-Na, C12-14+2EO 24.50% surface of base activating agent alkyl (C8-10)-1.5-glucoside 2.88% concentrated surfactant/emulsifier 1.2-propane diols 5.00% emulsifier ethanol 96%, 1%MEK sex change 5.00% concentration emulsifier hydroxy ethyl cellulose
*0.45% thickener aromatic oil, pineapple type 10.00% spices hemiacetal-isothiazoline-combination 0.05% anticorrisive agent colorant＜1.0% tap water is by 100
Natrosol250HHBR for example
About 3000mPas, 20 ℃, spiral viscometer LVT, 2.6 rev/mins on axle
6.5pH, undiluted
Settled solution is made
Prepare 20-25 ℃ of warm water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.
When medium paramount rotating speed, add thickener.Agitator remain in operation (utilizing sheet glass-detection method to detect no bubble) during about 60 minutes swelling; If still there is bubble, must continue to stir.Add surfactant, add ethanol then.Add spices at last and check sedimental dropout value.
b。) chlorine bleach phase (about 1% active chlorine) composition clorox (12.5% active chlorine) 8.00% chlorine bleaching NaOH (50%) 2.50% nertralizer Oxy-Rite
100
* 10.10% stationary flow sex change polyacrylate-polymer
* 21.00% thickener coconut alkyl dimethyl amine oxide
* 32.00% surfactants distilled water is by 100
* 1The BF Goodrich of manufacturing firm
* 2The BF Goodrich of manufacturing firm, for example Carbopol
676
* 3Genaminox C S/Clariant limited company for example
About 2500mPas, 20 ℃, spiral viscometer LVT, 2.6 rev/mins on axle
12.7pH, undiluted
Opaque solution manufacturing
Prepare water.When medium paramount rotating speed, add thickener (about 800 rev/mins).(utilizing sheet glass-detection method to detect no bubble); If still there is polymer beads, must continue to stir.After this add Oxyrite.With the thorough neutralization solution of NaOH.The pH value is adjusted to be higher than 12.5 for reaching peak viscosity.Reduce rotating speed, the Na-hypochlorite solutions is stirred into.
2.) high spices fragrance is combined with foam improver:
a。) high flavour content fragrance phase constituent FAEOS-Na, C12-14+2EO
*24.50% surface of base activating agent alkyl (C8-10)-1.5-glucoside
*2.88% concentrated surfactant/emulsifier 1.2-propane diols 10.00% emulsifier ethanol 96%, 1%MEK sex change 5.00% concentration emulsifier hydroxy ethyl cellulose 0.45% thickener aromatic oil, citrus type 20.00% spices hemiacetal-isothiazoline-combination 0.05% anticorrisive agent colorant＜1.0% tap water is by 100
*Texapon N70 for example
*Glucopon220 UP-W for example
About 2500mPas, 20 ℃, spiral viscometer LVT, 2.6 rev/mins on axle
6.5pH, undiluted
Settled solution is made
Prepare 20-25 ℃ of warm water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.
When medium paramount rotating speed, add thickener.Agitator remain in operation (utilizing sheet glass-detection method to detect no bubble) during about 60 minutes swelling; If still there is bubble, must continue to stir.Add surfactant, add ethanol then.Add spices at last and check sedimental dropout value.
B) contain the concentrated surfactant phase/chloride thickening composition FAEOS-Na of betaine, C12-14+2EO 30.00% surface of base activating agent Cocoamidopropyl betaine
*20.00% concentrated surfactant NaCl, consistency 1.50% thickener hemiacetal-isothiazoline-combination 0.05% anticorrisive agent colorant＜1.0% tap water is by 100
*Dehyton K for example
About 5500mPas, 20 ℃, spiral viscometer LVT, 2.20 rev/mins on axle
6.5pH, undiluted
Settled solution is made
Prepare water.Dissolved colorants and anticorrisive agent stir into surfactant then.Adjust viscosity with NaCl.
3.) fragrance is combined with the acid high effective substance of de-sludging
A) fragrant phase constituent FAS-Na, C12-14
*29.50% surface of base activating agent alkyl (C12-14)-glucoside
*3.30% concentrated surfactant/emulsifier 1.2-propane diols 5.00% emulsifier ethanol 96%, 1%MEK sex change 5.00% concentration emulsifier hydroxy ethyl cellulose 0.45% thickener aromatic oil, distillation type 10.00% spices trisodium citrate
*2H
2O 2.00% chelating agent hemiacetal-isothiazoline-combination 0.05% anticorrisive agent colorant＜1.0% tap water is by 100
*Texapon LS35 for example
*Clucopon600 CS-UP for example
About 2500mPas, 20 ℃, spiral viscometer LVT, 2.6 rev/mins on axle
8.0pH, undiluted
Settled solution is made
Prepare 20-25 ℃ of warm water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.
When medium paramount rotating speed, add thickener.Agitator remain in operation (utilizing sheet glass-detection method to detect no bubble) during about 60 minutes swelling; If still there is bubble, must continue to stir.Add surfactant, add ethanol then.Add spices at last and check sedimental dropout value.
B) acid de-sludging phase, polysaccharide thickening composition FAEOS-Na, C12-14+2EO 8.11% surface of base activating agent alkyl (C8-10)-1.5-glucoside 5.44% concentrated surfactant citric acid 3.00% detergent polysaccharide/xanthan gum
*0.20% thickener ethanol 96%, 1%MEK sex change 3.00% concentration emulsifier aromatic oil, distillation type 6.00% spices hemiacetal-isothiazoline-combination 0.05% anticorrisive agent colorant＜1.0% tap water is by 100
*Rhodopol T for example
About 3500mPas, 20 ℃, spiral viscometer LVT, 2.20 rev/mins on axle
2.5pH, undiluted
Settled solution is made
Prepare water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.When medium paramount rotating speed, add thickener.Agitator remains in operation during about 60 minutes swelling.Add surfactant, add ethanol then.Add spices and citric acid at last and check sedimental dropout value.
4.) fragrance is combined with antibiotic high effective substance
A) fragrant phase/by ABS activation foaming composition sodium alkyl benzene sulfonate
*25.50% surface of base activating agent C12-15-oxo alcohol+10EO
*10.00% concentrated surfactant/emulsifier 1.2-propane diols 5.00% emulsifier ethanol 96%, 1%MEK sex change 5.00% concentration emulsifier hydroxy ethyl cellulose 0.45% thickener aromatic oil, lemon type 10.00% spices hemiacetal-isothiazoline-combination 0.05% anticorrisive agent colorant＜1.0% tap water is by 100
*Marion A350 for example, H ü ls factory
*Genapol-OX-100 for example, Clariant factory
About 2500mPas, 20 ℃, spiral viscometer LVT, 2.6 rev/mins on axle
9.1pH, undiluted
Settled solution is made
Prepare 20-25 ℃ of warm water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.
When medium paramount rotating speed, add thickener.Agitator remain in operation (utilizing sheet glass-detection method to detect no bubble) during about 60 minutes swelling; If still there is bubble, must continue to stir.Add surfactant, add ethanol then.Add spices at last and check sedimental dropout value.
B) antibiotic phase constituent FAEOS-Na, C12-14+2EO 24.50% surface of base activating agent alkyl (C8-10)-1.5-glucoside 2.88% concentrated surfactant/emulsifier 1.2-propane diols 5.00% emulsifier ethanol 96%, 1%MEK sex change 5.00% concentration emulsifier hydroxy ethyl cellulose 0.45% thickener aromatic oil, lemon type 10.00% spices hemiacetal-isothiazoline-combination 0.10% anticorrisive agent/antibiotic high effective substance salicylic acid, industry 0.60% antibiotic high effective substance colorant＜1.0% tap water is by 100
About 2700mPas, 20 ℃, spiral viscometer LVT, 2.6 rev/mins on axle
5.5pH, undiluted
Settled solution is made
Prepare 20-25 ℃ of warm water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.
When medium paramount rotating speed, add thickener.Agitator remain in operation (utilizing sheet glass-detection method to detect no bubble) during about 60 minutes swelling; If still there is bubble, must continue to stir.Add surfactant, add ethanol then.Add spices at last and check sedimental dropout value.
5.) the different acid of high de-sludging activity are
A) lactic acid phase constituent FAEOS-Na, C12-14+2EO 8.11% surface of base activating agent alkyl (C8-10)-1.5-glucoside 5.44% concentrated surfactant lactic acid
*2.50% detergent polysaccharide/xanthan gum, 0.22% thickener ethanol 96%, 1%MEK sex change 3.00% concentration emulsifier aromatic oil, orange type 8.00% spices hemiacetal-isothiazoline-combination 0.05% anticorrisive agent colorant＜1.0% tap water is by 100
*Purac80
About 3500mPas, 20 ℃, spiral viscometer LVT, 2.20 rev/mins on axle
2.2pH, undiluted
Settled solution is made
Prepare water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.When medium paramount rotating speed, add thickener.Agitator remains in operation during about 60 minutes swelling.Add surfactant, add ethanol then.Add spices and lactic acid at last and check sedimental dropout value.
B) the Nio-surfactant component FA-C12-C18+7EO on citric acid phase/basis
*12.50% surface of base activating agent/emulsifier alkyl (C8-10)-1.5-glucoside 5.44% concentrated surfactant oleylcetyl alcohol+5EO
*3.00% concentration emulsifier citric acid, 5.00% detergent polysaccharide/xanthan gum, 0.20% thickener ethanol 96%, 1%MEK sex change 3.00% concentration emulsifier aromatic oil, orange type 12.00% spices hemiacetal-isothiazoline-combination 0.05% anticorrisive agent colorant＜1.0% tap water is by 100
*Dehydol LT7 for example
*Eumulgin O5 for example
About 3500mPas, 20 ℃, spiral viscometer LVT, 2.20 rev/mins on axle
2.5pH, undiluted
Settled solution is made
Prepare water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.When medium paramount rotating speed, add thickener.Agitator remains in operation during about 60 minutes swelling.Add surfactant, add ethanol then.Add spices and citric acid at last and check sedimental dropout value.
6.) fragrance is with to contain the high effective substance of enzyme combined
A) fragrant phase constituent FAEOS-Na, C12-14+2EO 24.50% surface of base activating agent sodium alkyl sulfonate
*8.50% concentrated surfactant 1.2-propane diols, 5.00% emulsifier ethanol 96%, 1%MEK sex change 5.00% concentration emulsifier hydroxy ethyl cellulose 0.45% thickener aromatic oil, fruit juice 9.00% spices hemiacetal-isothiazoline-combination 0.05% anticorrisive agent colorant＜1.0% tap water is by 100
*Hostapur SAS60/Hoechst factory for example
About 2500mPas, 20 ℃, spiral viscometer LVT, 2.6 rev/mins on axle
6.8pH, undiluted
Settled solution is made
Prepare 20-25 ℃ of warm water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.
When medium paramount rotating speed, add thickener.Agitator remain in operation (utilizing sheet glass-detection method to detect no bubble) during about 60 minutes swelling; If still there is bubble, must continue to stir.Add surfactant, add ethanol then.Add spices at last and check sedimental dropout value.
B) enzyme phase constituent FAEOS-Na, C12-14+2EO 24.50% surface of base activating agent alkyl (C8-10)-1.5-glucoside 2.88% concentrated surfactant/emulsifier 1.2-propane diols 5.00% emulsifier ethanol 96%, 1%MEK sex change 5.00% concentration emulsifier hydroxy ethyl cellulose 0.45% thickener aromatic oil, fruit juice 9.00% spices hemiacetal-isothiazoline-combination 0.05% anticorrisive agent/antibiotic high effective substance lipase 0.50% enzyme colorant＜1.0% tap water is by 100
About 2700mPas, 20 ℃, spiral viscometer LVT, 2.6 rev/mins on axle
6.5pH, undiluted
Settled solution is made
Prepare 20-25 ℃ of warm water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.
When medium paramount rotating speed, add thickener.Agitator remain in operation (utilizing sheet glass-detection method to detect no bubble) during about 60 minutes swelling; If still there is bubble, must continue to stir.Add surfactant, add ethanol then.Add spices at last and check sedimental dropout value.
7.) the sour high effective substance painted with making flushing water of perfuming is combined
A) sour phase constituent FAEOS-Na, C12-14+2EO 20.10% surface of base activating agent alkyl (C8-10)-1.5-glucoside 5.44% concentrated surfactant citric acid 2.50% detergent formic acid 1.50% detergent polysaccharide/xanthan gum 0.22% thickener ethanol 96%, 1%MEK sex change 3.00% concentration emulsifier aromatic oil, peppermint 10.00% spices hemiacetal-isothiazoline-combination 0.05% anticorrisive agent colorant＜1.0% tap water is by 100
About 3500mPas, 20 ℃, spiral viscometer LVT, 2.20 rev/mins
2.5pH, undiluted
Settled solution is made
Prepare water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.When medium paramount rotating speed, add thickener.Agitator remains in operation during about 60 minutes swelling.Add surfactant, add ethanol then.Add spices and acid at last and check sedimental dropout value.
B) make flushing water form and aspect/trisodium citrate, C12-14+2EO 9.11% surface of base activating agent alkyl (C8-10)-1.5-glucoside 5.44% concentrated surfactant trisodium citrate as chelating agent composition FAEOS-Na
*2H
2O 2.00% chelating agent polysaccharide/xanthan gum 0.20% thickener ethanol 96%, 1%MEK sex change 3.00% concentration emulsifier aromatic oil, peppermint 7.00% spices hemiacetal-isothiazoline-combination 0.05% anticorrisive agent colorant
*3.0% water-soluble colorant tap water is by 100
*The Basacidblau755 group
About 3500mPas, 20 ℃, spiral viscometer LVT, 2.20 rev/mins
7.5pH, undiluted
Settled solution is made
Prepare water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.When medium paramount rotating speed, add thickener.Agitator remains in operation during about 60 minutes swelling.Add surfactant, add ethanol then.Add spices and citric acid at last and check sedimental dropout value.
8.) fragrance is combined with the high effective substance that absorbs smell
A) fragrant phase constituent FAEOS-Na, C12-14+2EO 24.50% surface of base activating agent alkyl (C8-10)-1.5-glucoside 2.88% concentrated surfactant/emulsifier 1.2-propane diols 10.00% emulsifier hydroxy ethyl cellulose 0.50% thickener aromatic oil, grass green 10.00% spices hemiacetal-isothiazoline-combination 0.05% anticorrisive agent colorant＜1.0% tap water is by 100
About 2500mPas, 20 ℃, spiral viscometer LVT, 2.6 rev/mins
6.5pH, undiluted
Settled solution is made
Prepare 20-25 ℃ of warm water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.
When medium paramount rotating speed, add thickener.Agitator remain in operation (utilizing sheet glass-detection method to detect no bubble) during about 60 minutes swelling; If still there is bubble, must continue to stir.Add surfactant, add ethanol then.Add spices at last and check sedimental dropout value.
B) absorbent phase constituent FAEOS-Na, C12-14+2EO 24.50% surface of base activating agent alkyl (C8-10)-1.5-glucoside 2.88% concentrated surfactant/emulsifier ethanol 96%, 1%MEK sex change 10.00% emulsifier hydroxy ethyl cellulose 0.45% thickener aromatic oil, grass green 10.00% spices hemiacetal-isothiazoline-combination 0.10% anticorrisive agent/antibiotic high effective substance zinc ricinate
*1.00% deodorant colorant＜1.0% tap water is by 100
*Tego-Sorb, conc50, Goldschmidt factory
About 2700mPas, 20 ℃, spiral viscometer LVT, 2.6 rev/mins
5.5pH, undiluted
Settled solution is made
Prepare 20-25 ℃ of warm water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.
When medium paramount rotating speed, add thickener.Agitator remain in operation (utilizing sheet glass-detection method to detect no bubble) during about 60 minutes swelling; If still there is bubble, must continue to stir.Add surfactant, add ethanol then.Add spices at last and check sedimental dropout value.
9.) perfuming acid is combined with the high effective substance that contains active oxygen
A) contain the sour phase constituent FAEOS-Na of active oxygen, C12-14+2EO 20.10% surface of base activating agent alkyl (C8-10)-1.5-glucoside 5.44% concentrated surfactant citric acid 2.00% detergent polysaccharide/xanthan gum 0.22% thickener ethanol 96%, 1%MEK sex change 3.00% concentration emulsifier aromatic oil, apple 8.00% spices hemiacetal-isothiazoline-combination 0.05% anticorrisive agent hydrogen peroxide, 35% 2.86% active oxygen (1%) DTPMP sodium 0.16% stabilizing agent colorants, pigment＜1.0% tap water is by 100
*Dequest2066, Monsanto factory
About 3500mPas, 20 ℃, spiral viscometer LVT, 2.20 rev/mins
2.5pH, undiluted
Settled solution is made
Prepare water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.When medium paramount rotating speed, add thickener.Agitator remains in operation during about 60 minutes swelling.Add surfactant, add ethanol then.Add spices and acid.Add stabilizing agent and hydrogen peroxide at last and check sedimental dropout value.
B) fragrant phase constituent FAEOS-Na, C12-14+2EO 20.10% surface of base activating agent alkyl (C8-10)-1.5-glucoside 5.44% concentrated surfactant citric acid 2.00% detergent polysaccharide/xanthan gum 0.22% thickener ethanol 96%, 1%MEK sex change 6.00% concentration emulsifier aromatic oil, apple 10.00% spices hemiacetal-isothiazoline-combination 0.05% anticorrisive agent colorant＜1.0% tap water is by 100
About 3500mPas, 20 ℃, spiral viscometer LVT, 2.20 rev/mins
2.5pH, undiluted
Settled solution is made
Prepare water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.When medium paramount rotating speed, add thickener.Agitator remains in operation during about 60 minutes swelling.Add surfactant, add ethanol then.Add spices and acid and check sedimental dropout value.
10.) perfuming acid is combined with the high effective substance of polypropylene thickening
A) contain the sour phase constituent FAEOS-Na of active oxygen, C12-14+2EO 20.10% surface of base activating agent alkyl (C8-10)-1.5-glucoside 5.44% concentrated surfactant citric acid 4.00% detergent polysaccharide/xanthan gum 0.22% thickener ethanol 96%, 1%MEK sex change 3.00% concentration emulsifier aromatic oil, citrus type 8.00% spices hemiacetal-isothiazoline-combination 0.05% anticorrisive agent colorant＜1.0% tap water is by 100
About 3500mPas, 20 ℃, spiral viscometer LVT, 2.20 rev/mins
3.0pH, undiluted
Settled solution is made
Prepare water.Under the agitator operation, add colorant and anticorrisive agent, dissolved then 5 minutes.When medium paramount rotating speed, add thickener.Agitator remains in operation during about 60 minutes swelling.Add surfactant, add ethanol then.Add spices and acid.Add stabilizing agent and hydrogen peroxide at last and check sedimental dropout value.
B) the high effective substance phase constituent FAEOS-Na of polyacrylate thickening, C12-14+2EO 10.10% surface of base activating agent alkyl (C8-10)-1.5-glucoside 2.50% concentrated surfactant ethanol 96%, 1%MEK sex change 5.00% concentration emulsifier NaOH (50%) 1.50% nertralizer aromatic oil, citrus type 4.00% spices polyacrylate-polymer
* 10.80% thickener distilled water is by 100
* 1The BF Goodrich of manufacturing firm, for example Carbopol ETD2690
About 3500mPas, 20 ℃, spiral viscometer LVT, 2.6 rev/mins
10.0pH, undiluted
Settled solution is made
Prepare water.When medium paramount rotating speed (about 800 rev/mins), add thickener.(utilizing sheet glass-detection method to detect no bubble); If still there is polymer beads, must continue to stir.Adopt the thorough neutralization solution of NaOH.When reducing, rotating speed adds aromatic oil.
Claims (32)
1. conveying device, be used for to the high effective substance of flush toilet flushing liquor transport flow, have the support (1) that can be suspended on the edge of closet and at least two on support (1), be used to store each a kind of high effective substance that flows, hold-up vessel (2 separated from one another, 3), wherein, each hold-up vessel (2,3) has oneself floss hole (4), can be transported in the flushing liquor by floss hole mobile high effective substance separately, it is characterized in that hold-up vessel (2,3) prevent that flushing liquor from entering its inside, and the floss hole (4) of hold-up vessel (2,3) is provided with like this, and the high effective substance that flows is only discharged; When each flushing process, from the mobile high effective substance of each hold-up vessel (2,3) delivery section component in flushing liquor.
2. by the described conveying device of claim 1, it is characterized in that the floss hole (4) of hold-up vessel (2,3) is arranged on the use location of bottom surface.
3. by claim 1 or 2 described conveying devices, it is characterized in that hold-up vessel (2,3) is installed separately, replaceably and maybe can be installed on the support (1).
4. by claim 1 or 2 described conveying devices, it is characterized in that hold-up vessel (2,3) is by means of adapter or similar item interconnects and can be installed on the support (1) with such connection.
5. by claim 1 or 2 described conveying devices, it is characterized in that hold-up vessel (2,3) directly connects mutually and can be installed on the support (1) with such connection.
6. by claim 1 or 2 described conveying devices, it is characterized in that hold-up vessel (2,3) constitutes in the shell of a common single-piece.
7. by the described conveying device of one of claim 1 to 6, it is characterized in that hold-up vessel (2,3) can be annotated separately by filler separately, be fixedly installed on support (1) in case of necessity and go up or on support, constitute.
8. by one of claim 1 to 7 described conveying device, it is characterized in that hold-up vessel (2,3) is arranged side by side on support (1).
9. by one of claim 1 to 7 described conveying device, it is characterized in that hold-up vessel (2,3) is overlapping to be arranged on the support (1).
10. by one of claim 1 to 9 described conveying device, it is characterized in that hold-up vessel (2,3) is by being installed on the support (1) from top insertion.
11., it is characterized in that hold-up vessel (2,3) can be installed on the support (1) by pushing from the side by one of claim 1 to 9 described conveying device.
12., it is characterized in that hold-up vessel (2,3) can and inwardly be swung by the side connection and be installed on the support (1) by one of claim 1 to 9 described conveying device.
13., it is characterized in that hold-up vessel (2,3) has flexible wall section or all flexible wall by one of claim 1 to 12 described conveying device, and take out the mobile high effective substance that is in the inside by exerting pressure to hold-up vessel (2,3).
14., it is characterized in that support is equipped with board-like distribution member on (1), the drainage area of flushing liquor overflow when it has flushing process by one of claim 1 to 13 described conveying device; The inside of hold-up vessel (2,3) is by floss hole (4), continues to combine with distribution member stoping the high effective substance that flows to flow freely under the centre position of setting in case of necessity.
15., it is characterized in that by the described conveying device of claim 14, be at least two hold-up vessels (2,3), be preferably all hold-up vessels (2,3) and have board-like distribution member jointly.
16., it is characterized in that the floss hole (4) that is arranged on hold-up vessel (2,3) bottom seals by means of seal (5) by one of claim 1 to 13 described conveying device; Seal (5) is subjected to bias voltage at the detent position of sealing floss hole (4), and can resist biasing force and adjust to the off-position of a small amount of release floss hole (4); Have and the coefficient control element of seal (5) (6) for adjusting seal (5), in each flushing process, can apply power in short-term to it, make seal (5) opposing biasing force be in the off-position in short-term by flushing liquor; When having at flushing process on the control element (6), supply with the drainage area (7) of flushing liquor for this reason.
17., it is characterized in that control element (6) is as single armed by the described conveying device of claim 16, the lever that an end is hinged on the support (1) constitutes; Seal (5) is arranged on the end and the control element (6) between drainage area (7) that is hinged on the support (1); Preferably control element (6) from seal (5) to drainage area (7) straight line or the extension that has a down dip.
18. by claim 16 or 17 described conveying devices, it is characterized in that control element (6) is returned at least two hold-up vessels (2,3), preferably return the seal (5) of all hold-up vessels (2,3) total.
19. by the described conveying device of one of claim 1 to 18, it is characterized in that, if two hold-up vessels (2,3), the asymmetric formation in center of they and whole conveying device.
20., it is characterized in that the floss hole (4) of hold-up vessel (2,3) can be arranged on to the off-centring of whole conveying device on the hold-up vessel (2,3) by the described conveying device of claim 19.
21., it is characterized in that the biasing force on fluid cross-section on the floss hole (4) and/or the seal (5) can be determined and/or be adjusted into inequality by one of claim 1 to 20 described conveying device.
22. by one of claim 1 to 21 described conveying device, it is characterized in that hold-up vessel (2,3) contains identical mobile high effective substance, particularly add hereby.
23., it is characterized in that hold-up vessel (2,3) contains different mobile high effective substances by one of claim 1 to 21 described conveying device, particularly add for this reason, wherein, different mobile high effective substances can be compatible with each other or inconsistent.
24., it is characterized in that the high effective substance that flows is fragrant phase, particularly spiced fragrant phase by claim 22 or 23 described conveying devices.
25. by the described conveying device of claim 24, it is characterized in that, fragrance contains aromatic mutually at least, aromatic oil preferably, at least a surfactant or emulsifier and water, and other compositions in case of necessity, as anticorrisive agent, thickener, chelating agent, colorant, other surfactants or emulsifier, stabilizing agent, detergent.
26. by claim 22 or 23 described conveying devices, it is characterized in that, the high effective substance that flows comprises the bleaching phase, particularly chloride bleaching phase, preferably based on the bleaching phase of hypochlorite, wherein, bleaching also can contain other compositions mutually in case of necessity, as thickener, surfactant or emulsifier, nertralizer, colorant and spices.
27. by claim 22 or 23 described conveying devices, it is characterized in that, the high effective substance that flows comprises the high effective substance phase of detergent, the high effective substance phase of preferably de-sludging acidity, wherein, the high effective substance of the de-sludging detergent that has been divided by, outside the particularly organic or inorganic acid, also contain other compositions in case of necessity, as surfactant or emulsifier, thickener, spices or anticorrisive agent.
28., it is characterized in that the high effective substance that flows comprises concentrated surfactant phase (foamed promoter) by claim 22 or 23 described conveying devices.
29. by claim 22 or 23 described conveying devices, it is characterized in that, the high effective substance that flows comprises the activator phase with antibiotic and/or sterilization and/or Disinfection Effect, it is except the activator with antibiotic and/or sterilization and/or Disinfection Effect, also can contain other compositions in case of necessity, as surfactant and emulsifier, thickener, spices or anticorrisive agent.
30., it is characterized in that the high effective substance that flows comprises the activator phase that contains enzyme by claim 22 or 23 described conveying devices, it also can contain other compositions in case of necessity except enzyme, as surfactant and emulsifier, and thickener, spices or anticorrisive agent.
31. by claim 22 or 23 described conveying devices, it is characterized in that, the high effective substance that flows comprises absorption, particularly absorb the high effective substance phase of smell, it particularly outside the odour absorbents, can also contain other compositions in case of necessity except absorbent, as surfactant and emulsifier, thickener, spices or anticorrisive agent.
32. by claim 23 to 24 with in case of necessity by one of claim 25 to 31 or many described conveying devices, it is characterized in that, hold-up vessel (2,3) contain different mobile high effective substances, wherein, one in the hold-up vessel (2,3) contains particularly by claim 24 and/or the 25 fragrant phases that define.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10057325 | 2000-11-17 | ||
| DE10057325.8 | 2000-11-17 | ||
| DE10113036A DE10113036B4 (en) | 2000-11-17 | 2001-03-17 | Device for delivering fluids with active substances into flushing water in a toilet bowl, has storage containers with outlets arranged so that they deliver fluids only during each flushing operation |
| DE10113036.8 | 2001-03-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1474901A true CN1474901A (en) | 2004-02-11 |
Family
ID=26007712
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA018189539A Pending CN1474901A (en) | 2000-11-17 | 2001-07-21 | Distributing device for distributing fluids containing active ingredients to flush liquid inside toilet bowl |
Country Status (21)
| Country | Link |
|---|---|
| US (2) | US20040068782A1 (en) |
| EP (4) | EP1614817A1 (en) |
| JP (1) | JP2004526075A (en) |
| CN (1) | CN1474901A (en) |
| AR (1) | AR031465A1 (en) |
| AT (3) | ATE315140T1 (en) |
| AU (1) | AU2001277547A1 (en) |
| CR (1) | CR6973A (en) |
| CZ (4) | CZ305484B6 (en) |
| DE (4) | DE10113036B4 (en) |
| ES (3) | ES2206080T3 (en) |
| HU (1) | HU228554B1 (en) |
| PL (1) | PL196974B1 (en) |
| PT (2) | PT2116656E (en) |
| RO (1) | RO120857B1 (en) |
| RU (1) | RU2266372C2 (en) |
| SI (1) | SI21141B (en) |
| SK (1) | SK5812003A3 (en) |
| TR (1) | TR200301652T3 (en) |
| UA (1) | UA74854C2 (en) |
| WO (1) | WO2002040791A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103270227A (en) * | 2010-08-10 | 2013-08-28 | 约翰逊父子公司 | Single -dose applicator for self-dhesive material in toilet bowls |
| CN103276784A (en) * | 2013-06-18 | 2013-09-04 | 毛雪斌 | Deodorization flush toilet |
| CN107724492A (en) * | 2017-02-21 | 2018-02-23 | 合肥龙精灵信息技术有限公司 | Feed robot and method based on image procossing |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10113036B4 (en) * | 2000-11-17 | 2005-02-17 | Henkel Kgaa | Device for delivering fluids with active substances into flushing water in a toilet bowl, has storage containers with outlets arranged so that they deliver fluids only during each flushing operation |
| US7511006B2 (en) * | 2000-12-14 | 2009-03-31 | The Clorox Company | Low residue cleaning solution comprising a C8 to C10 alkylpolyglucoside and glycerol |
| GB2372046A (en) | 2001-02-09 | 2002-08-14 | Jeyes Group Ltd | Liquid dispensing unit for a toilet bowl |
| DE10204928B4 (en) * | 2002-02-07 | 2004-04-01 | Henkel Kgaa | Dispensing device for dispensing an active fluid into the flushing liquid in a toilet bowl |
| EP1483456A1 (en) | 2002-03-12 | 2004-12-08 | Robert McBride Ltd | Dispenser |
| DE10227965B3 (en) * | 2002-06-22 | 2004-04-01 | Henkel Kgaa | Device for dispensing at least one liquid preparation of active substance into a toilet bowl |
| US6662380B1 (en) | 2002-08-29 | 2003-12-16 | S.C. Johnson & Son, Inc. | Dual action toilet rim mounted toilet bowl cleaner |
| DE10303155A1 (en) * | 2003-01-27 | 2004-08-12 | Henkel Kgaa | Dispensing device for dispensing an active fluid into the flushing liquid in a toilet bowl |
| ITRE20030016A1 (en) * | 2003-02-17 | 2004-08-18 | Re Le Vi Spa | "MULTIPLE DISPENSER FOR LIQUID ACTIVE SUBSTANCES, FOR WC POT" |
| ITRE20030038A1 (en) * | 2003-04-15 | 2004-10-16 | Re Le Vi Spa | "DISPENSER FOR LIQUID ACTIVE SUBSTANCES, FOR POT OF W. C." |
| EP1840280A3 (en) † | 2003-04-15 | 2007-10-10 | The Procter & Gamble Company | A lavatory bowl rim-block providing a combination of ongoing perfume delivery with a perfume boost upon flushing |
| WO2004097124A1 (en) | 2003-04-25 | 2004-11-11 | S. C. Johnson & Son, Inc. | Toilet rim mounted device for dispensing two liquids |
| DE102004013355B3 (en) * | 2004-03-17 | 2005-11-10 | Henkel Kgaa | Holding unit for a cleaning brush serving, in particular, for toilet cleaning comprises a holding section which is separable from the side section of the unit, and is formed by a cleaning fluid container |
| DE102005029609A1 (en) * | 2005-06-23 | 2007-01-11 | Henkel Kgaa | Rinse water supply for a toilet bowl |
| GB0605023D0 (en) | 2006-03-13 | 2006-04-19 | Jeyes Group Ltd | Liquid dispensing device |
| DE102006026800A1 (en) * | 2006-06-07 | 2007-12-13 | Henkel Kgaa | Dosing device for flowable compositions |
| PL2104773T3 (en) * | 2006-12-27 | 2017-03-31 | Henkel Ag & Co. Kgaa | System for dispensing active ingredient fluids to the flushing liquid of a toilet bowl |
| WO2008080643A1 (en) * | 2006-12-28 | 2008-07-10 | Henkel Ag & Co. Kgaa | Modular system for dispensing active ingredient fluids to the flushing liquid of a toilet bowl |
| DE102007011991A1 (en) | 2007-03-09 | 2008-09-11 | Henkel Ag & Co. Kgaa | Refill unit with detachable functional chamber for a WC active substance delivery system |
| FR2914661B1 (en) | 2007-04-03 | 2009-06-26 | Eurvest | DISTRIBUTOR OF MAINTENANCE FLUIDS WITH MULTIPLE COMPARTMENTS FOR TOILET BOWLS |
| US7976723B2 (en) * | 2007-05-17 | 2011-07-12 | International Business Machines Corporation | Method for kinetically controlled etching of copper |
| DE102007040327A1 (en) | 2007-08-24 | 2009-02-26 | Henkel Ag & Co. Kgaa | Toilet freshener with time-delayed release of active ingredient |
| DE102007040328A1 (en) | 2007-08-24 | 2009-02-26 | Henkel Ag & Co. Kgaa | Toilet freshener with directed release of active ingredient |
| DE102007040322B4 (en) | 2007-08-24 | 2013-07-11 | Henkel Ag & Co. Kgaa | Toilet freshener with defined amount of active ingredient |
| DE102007040323B4 (en) | 2007-08-24 | 2015-12-17 | Henkel Ag & Co. Kgaa | Toilet freshener with adjustable drug delivery |
| DE102007040329A1 (en) | 2007-08-24 | 2009-02-26 | Henkel Ag & Co. Kgaa | Toilet freshener with low-viscosity active substance |
| DE102007040324A1 (en) | 2007-08-24 | 2009-02-26 | Henkel Ag & Co. Kgaa | Toilet freshener with rinse water-independent active ingredient delivery |
| DE102007040325B4 (en) | 2007-08-24 | 2015-11-26 | Henkel Ag & Co. Kgaa | Toilet washer with electro-mechanically induced drug release |
| GB0717950D0 (en) * | 2007-09-14 | 2007-10-24 | Reckitt Benckiser Inc | Automatic toilet bowl treatment device |
| DE102008003358A1 (en) | 2008-01-08 | 2009-07-09 | Henkel Ag & Co. Kgaa | Dispensing device for dispensing at least one active substance fluid into the rinsing water of a toilet bowl and for scenting the environment |
| DE102008003359A1 (en) | 2008-01-08 | 2009-07-09 | Henkel Ag & Co. Kgaa | Dispensing device for dispensing at least one active substance fluid into the rinsing water of a toilet bowl and for scenting the environment |
| DE102008037723A1 (en) | 2008-08-14 | 2010-02-25 | Henkel Ag & Co. Kgaa | Toilet basket with Spülwasserverteilelement |
| DE102008037724A1 (en) * | 2008-08-14 | 2010-02-25 | Henkel Ag & Co. Kgaa | Cartridge for a toilet-dishwasher |
| WO2010078413A1 (en) | 2008-12-31 | 2010-07-08 | Apinee, Inc. | Preservation of wood, compositions and methods thereof |
| ES2661214T3 (en) | 2009-02-19 | 2018-03-28 | Henkel Ag & Co. Kgaa | Dispensing device, in particular a toilet cleaner, with attachable container |
| ES2653206T3 (en) | 2009-02-24 | 2018-02-06 | Henkel Ag & Co. Kgaa | Toilet cleaner with fixing means |
| WO2010097151A1 (en) | 2009-02-24 | 2010-09-02 | Henkel Ag & Co. Kgaa | Dispenser device in particular a wc rinser with fixing means |
| PL2334877T3 (en) | 2009-02-24 | 2018-01-31 | Henkel Ag & Co Kgaa | Method for operating a wc rinser |
| DE102010003810A1 (en) | 2010-04-09 | 2011-10-13 | Henkel Ag & Co. Kgaa | Dispensing device with piezoelectric element |
| DE102010034971A1 (en) * | 2010-08-20 | 2012-02-23 | Oerlikon Textile Gmbh & Co. Kg | textile machine |
| US9878464B1 (en) | 2011-06-30 | 2018-01-30 | Apinee, Inc. | Preservation of cellulosic materials, compositions and methods thereof |
| DE102012214898A1 (en) | 2012-08-22 | 2014-05-28 | Henkel Ag & Co. Kgaa | Toilet basket with variable product delivery |
| WO2014118113A1 (en) * | 2013-01-31 | 2014-08-07 | Purac Biochem Bv | Slow release gelled lactic acid bodies |
| DE102013210435A1 (en) | 2013-06-05 | 2014-12-11 | Henkel Ag & Co. Kgaa | Device for dispensing an active ingredient preparation in a toilet bowl |
| CN106795711A (en) | 2014-09-08 | 2017-05-31 | 约翰逊父子公司 | Bowl rim block and the method for preparing such edge block |
| USD752733S1 (en) | 2015-03-18 | 2016-03-29 | S.C. Johnson & Son, Inc. | Toilet rim block holder |
| USD752198S1 (en) | 2015-03-18 | 2016-03-22 | S.C. Johnson & Son, Inc. | Toilet rim block holder |
| EP3397817B1 (en) | 2016-01-25 | 2020-03-18 | Reckitt Benckiser (Brands) Limited | In-the-bowl dispensing device |
| USD784491S1 (en) | 2016-05-17 | 2017-04-18 | S. C. Johnson & Son, Inc. | Toilet rim block |
| USD789485S1 (en) | 2016-05-17 | 2017-06-13 | S. C. Johnson & Son, Inc. | Toilet rim block holder |
| US10669705B2 (en) | 2016-07-05 | 2020-06-02 | Willert Home Products, Inc. | Toilet bowl treatment apparatus and method of making same |
| USD850578S1 (en) | 2017-01-31 | 2019-06-04 | S. C. Johnson & Son, Inc. | Toilet rimblock |
| USD841120S1 (en) | 2017-01-31 | 2019-02-19 | S. C. Johnson & Son, Inc. | Toilet rim-block |
| USD911506S1 (en) * | 2018-05-23 | 2021-02-23 | Vectair Systems Limited | Air deodorizing apparatus |
| USD914131S1 (en) | 2019-06-07 | 2021-03-23 | S. C. Johnson & Son, Inc. | Toilet rim-block holder |
| USD912761S1 (en) | 2019-06-07 | 2021-03-09 | S. C. Johnson & Son, Inc. | Toilet rim-block |
| USD923139S1 (en) | 2019-06-07 | 2021-06-22 | S. C. Johnson & Son, Inc. | Set of toilet rim-blocks |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1067472A (en) * | 1912-10-14 | 1913-07-15 | Fred A Creed | Disinfectant-holder. |
| IT1030072B (en) * | 1973-11-02 | 1979-03-30 | Tamin El Sioufy | DEVICE FOR THE DISINFECTION AND CHEMICAL CLEANING OF THE TOILET VESSEL |
| DE2450197A1 (en) * | 1974-10-17 | 1976-04-22 | Tamin El Sioufy | Disinfectant injection mechanism for toilet bowl - has sprung valve opened by flush water press. on a flap lever |
| JPS5085601U (en) * | 1973-12-12 | 1975-07-22 | ||
| US4096593A (en) * | 1976-07-15 | 1978-06-27 | Eftichios Van Vlahakis | Toilet bowl dispenser |
| US4709424A (en) * | 1985-05-10 | 1987-12-01 | Dolan John E | Automatic toilet bowl cleaner device |
| DE3639686A1 (en) * | 1986-11-20 | 1988-05-26 | Henkel Kgaa | WC BASKET |
| US4995555A (en) | 1988-11-14 | 1991-02-26 | American Cyanamid Company | Air treatment device and method |
| GB9110746D0 (en) * | 1991-05-17 | 1991-07-10 | Davies Raymond C | Release device |
| NL9101759A (en) * | 1991-10-22 | 1993-05-17 | Sara Lee De Nv | LIQUID CLEANER AND / OR FRESHENER FOR A TOILET POT. |
| NL1001722C2 (en) * | 1995-11-22 | 1997-05-23 | Sara Lee De Nv | Cleaning and refreshing unit intended to be hung on a toilet bowl rim. |
| ES2124204T1 (en) * | 1995-11-22 | 1999-02-01 | Sara Lee De Nv | TOILET CLEANER / AIR FRESHENER SYSTEM. |
| US5955415A (en) * | 1997-08-04 | 1999-09-21 | Lever Brothers Company, Division Of Conopco, Inc. | Detergent compositions containing polyethyleneimines for enhanced peroxygen bleach stability |
| DE19823338A1 (en) * | 1998-05-26 | 1999-12-09 | Buck Chemie Gmbh | Dispenser |
| GB2338495B (en) * | 1998-06-15 | 2000-08-09 | Johnson & Son Inc S C | A unit for dispensing a liquid from the rim of a lavatory bowl |
| ES2288587T3 (en) * | 1998-06-15 | 2008-01-16 | S.C. JOHNSON & SON, INC. | LIQUID DISPENSER. |
| DE19912217C2 (en) | 1999-01-12 | 2002-09-05 | Jeyes Deutschland Gmbh | Device for dispensing active substances in the flushing water, especially in toilet bowls |
| DE29902066U1 (en) * | 1999-02-08 | 1999-04-22 | Georg Menshen Gmbh & Co Kg | Device for conditioning rinsing liquid in sanitary facilities |
| DE19915322C1 (en) * | 1999-04-03 | 2001-01-18 | Henkel Kgaa | Under-rim device for cleaning and/or freshening toilets on flushing has openable and closable unit, eg of silicone or other rubber membrane, to allow re-filling without demounting |
| CN1271047A (en) * | 1999-04-19 | 2000-10-25 | 莎拉李/迪有限公司 | Purifying and freshing apparatus suspending on edge of closet |
| GB2349157A (en) * | 1999-04-21 | 2000-10-25 | Unilever Plc | Apparatus for dosing an active agent into the flush water of a toilet |
| DE19930362C2 (en) * | 1999-07-01 | 2003-11-13 | Henkel Kgaa | Device for dispensing a liquid preparation of active substance into a toilet bowl |
| JP4145045B2 (en) * | 1999-12-14 | 2008-09-03 | エス．シー． ジョンソン アンド サン、インコーポレイテッド | Liquid discharge toilet rim mounted toilet bowl cleaner |
| US6178564B1 (en) * | 1999-12-14 | 2001-01-30 | S. C. Johnson & Son, Inc. | Liquid dispensing toilet rim mounted toilet bowl cleaner |
| DE10113036B4 (en) * | 2000-11-17 | 2005-02-17 | Henkel Kgaa | Device for delivering fluids with active substances into flushing water in a toilet bowl, has storage containers with outlets arranged so that they deliver fluids only during each flushing operation |
| NL1016631C2 (en) * | 2000-11-17 | 2002-05-22 | Sara Lee De Nv | Device with a multiple toilet care effect. |
| DE10057312C2 (en) * | 2000-11-17 | 2002-11-14 | Henkel Kgaa | Dispensing device for dispensing an active substance fluid into the flushing liquid for a toilet bowl |
| PL199593B1 (en) * | 2001-03-01 | 2008-10-31 | Alpla Werke | Device for dispensing portioned amounts |
| DE10204928B4 (en) * | 2002-02-07 | 2004-04-01 | Henkel Kgaa | Dispensing device for dispensing an active fluid into the flushing liquid in a toilet bowl |
| US6651261B1 (en) * | 2002-07-19 | 2003-11-25 | S. C. Johnson & Son, Inc. | Toilet rim mounted toilet cleaner with extension plate |
-
2001
- 2001-03-17 DE DE10113036A patent/DE10113036B4/en not_active Expired - Lifetime
- 2001-03-17 DE DE10164866A patent/DE10164866B4/en not_active Expired - Lifetime
- 2001-07-21 JP JP2002543093A patent/JP2004526075A/en active Pending
- 2001-07-21 PL PL361188A patent/PL196974B1/en unknown
- 2001-07-21 US US10/416,681 patent/US20040068782A1/en not_active Abandoned
- 2001-07-21 AU AU2001277547A patent/AU2001277547A1/en not_active Abandoned
- 2001-07-21 SK SK581-2003A patent/SK5812003A3/en not_active Application Discontinuation
- 2001-07-21 EP EP05022491A patent/EP1614817A1/en not_active Withdrawn
- 2001-07-21 TR TR2003/01652T patent/TR200301652T3/en unknown
- 2001-07-21 EP EP01955364A patent/EP1334239B1/en not_active Expired - Lifetime
- 2001-07-21 CZ CZ2008-377A patent/CZ305484B6/en not_active IP Right Cessation
- 2001-07-21 CN CNA018189539A patent/CN1474901A/en active Pending
- 2001-07-21 RU RU2003117796/03A patent/RU2266372C2/en active
- 2001-07-21 CZ CZ2008-375A patent/CZ305483B6/en not_active IP Right Cessation
- 2001-07-21 UA UA2003065546A patent/UA74854C2/en unknown
- 2001-07-21 DE DE50108626T patent/DE50108626D1/en not_active Expired - Lifetime
- 2001-07-21 ES ES01955364T patent/ES2206080T3/en not_active Expired - Lifetime
- 2001-07-21 RO ROA200300387A patent/RO120857B1/en unknown
- 2001-07-21 CZ CZ20031361A patent/CZ299957B6/en not_active IP Right Cessation
- 2001-07-21 CZ CZ2008-376A patent/CZ305459B6/en not_active IP Right Cessation
- 2001-07-21 HU HU0301545A patent/HU228554B1/en unknown
- 2001-07-21 SI SI200120062A patent/SI21141B/en active Search and Examination
- 2001-07-21 WO PCT/EP2001/008461 patent/WO2002040791A1/en active Application Filing
- 2001-07-21 AT AT01955364T patent/ATE315140T1/en active
- 2001-11-09 DE DE50115818T patent/DE50115818D1/en not_active Expired - Lifetime
- 2001-11-09 PT PT09008185T patent/PT2116656E/en unknown
- 2001-11-09 US US10/416,655 patent/US20040107484A1/en not_active Abandoned
- 2001-11-09 AT AT09008188T patent/ATE501316T1/en active
- 2001-11-09 EP EP09008188A patent/EP2123833B1/en not_active Expired - Lifetime
- 2001-11-09 ES ES09008185T patent/ES2370687T3/en not_active Expired - Lifetime
- 2001-11-09 AT AT09008185T patent/ATE523640T1/en active
- 2001-11-09 ES ES09008188T patent/ES2361806T3/en not_active Expired - Lifetime
- 2001-11-09 PT PT09008188T patent/PT2123833E/en unknown
- 2001-11-09 EP EP09008185A patent/EP2116656B1/en not_active Expired - Lifetime
- 2001-11-16 AR ARP010105364A patent/AR031465A1/en unknown
-
2003
- 2003-05-16 CR CR6973A patent/CR6973A/en not_active Application Discontinuation
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103270227A (en) * | 2010-08-10 | 2013-08-28 | 约翰逊父子公司 | Single -dose applicator for self-dhesive material in toilet bowls |
| CN103270227B (en) * | 2010-08-10 | 2015-05-20 | 约翰逊父子公司 | Single -dose applicator and method thereof |
| CN103276784A (en) * | 2013-06-18 | 2013-09-04 | 毛雪斌 | Deodorization flush toilet |
| CN107724492A (en) * | 2017-02-21 | 2018-02-23 | 合肥龙精灵信息技术有限公司 | Feed robot and method based on image procossing |
| CN107724492B (en) * | 2017-02-21 | 2020-09-01 | 安徽中鑫模具产业发展有限公司 | Feeding robot based on image processing |
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1474901A (en) | Distributing device for distributing fluids containing active ingredients to flush liquid inside toilet bowl | |
| CN1180395A (en) | Passive lavatory cleanser dispensing system | |
| CN1946908A (en) | Dispenser for releasing treatment composition into a toilet bowl | |
| KR102068142B1 (en) | Device for supplying bubble for toilet stool | |
| CN102703230A (en) | Spray-proof, olid-resistant, anti-sticking automatic foaming powder when wets for toilets | |
| JP2005537414A (en) | Toilet bowl cleaning agent that is attached to the edge of the toilet bowl and acts in two ways | |
| KR20070085111A (en) | Foamed cleanser with suspended particles, a method of producing same, and a dispenser therefore | |
| AU2003259133A1 (en) | Toilet rim mounted toilet cleaner with extension plate | |
| EP1840280A2 (en) | A lavatory bowl rim-block providing a combination of ongoing perfume delivery with a perfume boost upon flushing | |
| CN111101572B (en) | Method for slowly releasing toilet cleaning product | |
| CN107859128A (en) | A kind of self-cleaning device of achievable closestool | |
| JP5697514B2 (en) | Liquid fragrance cleaning composition for flush toilet | |
| TWI755360B (en) | Cleaning kit for drain and cleaning method using thereof | |
| CN1739435A (en) | Soft water shower | |
| KR101796290B1 (en) | Cleaning container for drain and cleaning method using thereof | |
| JP3241095U (en) | Sanitizing materials and tools for water storage tank type flush toilets | |
| KR102540064B1 (en) | Cleaning kit for drain and cleaning method using thereof | |
| CN215253255U (en) | Toilet cleaning device capable of quantitatively releasing sterilization and aroma enhancement of toilet cleaning | |
| JP2005290867A (en) | Chemical feed device for water closet | |
| KR200208548Y1 (en) | Cleaner Dispenser for Flushing Toilet | |
| CN111561034B (en) | Method for slowly releasing toilet cleaner | |
| KR102517756B1 (en) | Cleaning container for sink drain and cleaning method using thereof | |
| KR200291585Y1 (en) | a | |
| EP1469131A1 (en) | A lavatory bowl rim-block providing a combination of ongoing perfume delivery with a perfume boost upon flushing | |
| DE60217358D1 (en) | Thickened liquid bleaching compositions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |