EP2104773B1 - System for dispensing active ingredient fluids to the flushing liquid of a toilet bowl - Google Patents
System for dispensing active ingredient fluids to the flushing liquid of a toilet bowl Download PDFInfo
- Publication number
- EP2104773B1 EP2104773B1 EP07819948.6A EP07819948A EP2104773B1 EP 2104773 B1 EP2104773 B1 EP 2104773B1 EP 07819948 A EP07819948 A EP 07819948A EP 2104773 B1 EP2104773 B1 EP 2104773B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- active ingredient
- fluids
- dispensing
- reservoir
- reservoirs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000012530 fluid Substances 0.000 title claims description 108
- 239000004480 active ingredient Substances 0.000 title claims description 37
- 239000007788 liquid Substances 0.000 title claims description 20
- 238000011010 flushing procedure Methods 0.000 title claims description 12
- 238000005192 partition Methods 0.000 claims description 12
- 239000013543 active substance Substances 0.000 description 46
- 238000003860 storage Methods 0.000 description 20
- 239000003814 drug Substances 0.000 description 15
- 229940079593 drug Drugs 0.000 description 15
- 239000003205 fragrance Substances 0.000 description 15
- 239000004094 surface-active agent Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000003995 emulsifying agent Substances 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- 239000002562 thickening agent Substances 0.000 description 6
- 238000004061 bleaching Methods 0.000 description 5
- 239000003755 preservative agent Substances 0.000 description 5
- 102000004190 Enzymes Human genes 0.000 description 4
- 108090000790 Enzymes Proteins 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000002250 absorbent Substances 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000009969 flowable effect Effects 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000000840 anti-viral effect Effects 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 235000011837 pasties Nutrition 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229940088679 drug related substance Drugs 0.000 description 1
- -1 for example Substances 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
- E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
- E03D9/03—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing consisting of a separate container with an outlet through which the agent is introduced into the flushing water, e.g. by suction ; Devices for agents in direct contact with flushing water
- E03D9/032—Devices connected to or dispensing into the bowl
Definitions
- the invention relates to a storage container and a system for dispensing at least two active substance fluids according to the preamble of claims 1, 5 and 7.
- active ingredient fluid means flowable, that is liquid to viscous, possibly gelatinous or pasty or granular or otherwise pourable active substance preparations with cleansing, disinfecting, deodorizing, bleaching and the like. Effect (especially described DE 199 30 362 A1 , as well as in the EP 0 775 741 A1 and the EP 0 960 984 A2 ).
- Dispensers of the type in question are known under the keyword “toilet bowl” in different versions.
- dispensing devices for a single active substance fluid are known.
- the drug fluid is there in a fixed in a holder or interchangeably inserted reservoir with a mounted on the holder reservoir bottom outlet opening arranged.
- a first known dispensing device for a single active substance fluid the active substance fluid is added via an actuating element (eg made of an open-cell foam) which can be impregnated therewith and acted upon by the irrigation fluid (EP 785 315 A1 ).
- an actuating element eg made of an open-cell foam
- the outlet opening of the reservoir after expulsion of a closure member of the reservoir of a holder fixedly arranged on the sealing member is largely closed, so that only a flow path with a small cross-section for leakage of the active ingredient fluid is available.
- the device works by utilizing the capillary action of the open cell foam.
- a similar construction is also known with a distribution ribbed plate.
- Each chamber has a dispenser with a dispensing tube, which exits with its one free end over the bottom of the container into the environment and at its other free end fluid leading surrounded by a cover.
- the two chambers of the container can be filled via slit-like passages of a cover part of overflowing rinse water, which then exits in the manner of a siphon or overflow via the delivery tube with entrainment of the respective active ingredient in the toilet bowl.
- the separation of the chambers in the container has the advantage that different media can be used, which would otherwise be detrimental to their desired effect in a common storage in only one chamber. The consistency of the media may vary in the different chambers.
- valve arrangements are known in which a flushing water acted upon lever is connected to a valve that causes the release of a subset of active fluid from one of the reservoir during rinsing.
- Other dispensing devices are realized, for example, by capillary action that forms between the drug fluids and appropriately sized dispensing channels, thus preventing free flow of active fluid from the reservoir.
- the object of the invention is therefore to overcome the described, known from the prior art disadvantages and to provide a delivery system for at least two active fluids, which is to produce in a simple and cost-effective manner and that a simultaneous and uniform delivery of the active fluids in the rinsing fluid of a toilet bowl guaranteed.
- the object is achieved by a dispensing system according to claims 1 and 5 and by a storage container according to claim 7 for use in a dispensing system.
- the formation of a single discharge opening for a plurality of active substance fluids ensures that the active substance fluids are dispensed uniformly into the rinsing fluid and prevents uneven delivery, as may occur, for example, in the case of uneven loading of the rinsing plate in toilet rinsers with at least two discharge openings ,
- a storage container in the sense of this application is a container which is suitable for receiving a flowable or spreadable product.
- the storage container has a bottom-side discharge opening, from which the active substance fluids emerge.
- the storage container can be separated from each other by a partition at least in sections.
- the reservoir are formed in several pieces.
- the reservoirs have a common, bottom-side discharge opening.
- two reservoirs are provided, which are preferably separated from each other and each contain a drug fluid. But there may also be several reservoirs for multiple drug fluids.
- the reservoirs are separated from each other to prevent premature mixing of the drug fluids. They may be physically separate or formed as separate compartments in a contiguous body.
- a storage container having a bottom-side opening to be formed on the toilet freshener, wherein the active-substance fluids form in the reservoir substantially immiscible phases with vertically extending phase boundaries and the phase boundary is preferably centrally above the discharge opening.
- the bottom-side discharge opening may be arranged centrally or offset to the center of the toilet rinser.
- the floors may be sloping, in particular, towards the opening in order to ensure complete emptying of the active substance fluids from the storage containers.
- the reservoir transparent to allow a level control with respect to the stored drug fluids.
- the storage container is offered ready made together with a dispenser.
- the reservoir is configured as a refill or exchange unit.
- a dispensing device is an arrangement arranged downstream of the dispensing opening of the storage container in the direction of flow of the active substance fluids, which controls the dispensing of the active substance fluids into the rinsing liquid.
- Control in this context means that a free flow of the active substance fluids is prevented by the dispensing device and a release of product by the dispensing device takes place in particular immediately before, during or after a rinsing process of the toilet.
- the dispensing may be effected, for example, by the flushing water surge of the toilet bowl, for example, by the Spülwasserschwall opens a valve assembly.
- the dispenser may also be realized by an arrangement which prevents free flow of the active fluids from the reservoirs, for example by capillary action.
- the document WO 0240791 is considered to be the closest prior art. The document discloses the features described in the preamble of claims 1, 5 and 7.
- the flowable drug fluids are particularly configured by their respective viscosities in such that they can form substantially immiscible phases with vertically extending phase boundaries.
- exactly two different drug fluids form a vertically extending through the reservoir phase boundary, wherein the phase boundary extends approximately centrally above the discharge opening.
- the active substance fluids for example, do not differ conclusively with respect to their chemical composition, their pH, color, fragrance, flow properties or the like.
- the drug fluids may have substantially identical or different flow characteristics. By different flow properties, it is possible to provide different mixing ratios of the active fluids to each other.
- Active substance fluids which are suitable according to the invention are, for example, fragrance phases, in particular perfumed fragrance phases.
- scent phases usually comprise at least one perfume, preferably perfume oil, at least one surfactant or an emulsifier and water and optionally further ingredients such as preservatives, thickeners, complexing agents, dyes, other surfactants or emulsifiers, stabilizers, lime solubilizer etc.
- bleaching phases in particular chlorine-containing bleaching phases, preferably bleaching phases based on hypochlorite, wherein the bleaching phases may optionally contain, in addition to the actual bleaching agent and water, further ingredients such as thickeners, surfactants or emulsifiers, neutralizing agents, dyes, fragrances, etc.
- lime-dissolving active substance phases preferably acidic lime-dissolving active substance phases.
- Such lime-solubilizing active ingredient phases may contain, in addition to the actual lime solubilizer-preferably an organic or inorganic acid and water-optionally further ingredients such as surfactants, emulsifiers, thickeners, fragrances, or preservatives.
- Such highly concentrated surfactant phases may also contain other conventional ingredients in addition to the surfactants.
- active-ingredient fluids having an antibacterial and / or fungicidal and / or antiviral active phase, wherein the active-substance phase, in addition to the antibacterial and / or fungicidal and / or antiviral active and water, optionally further ingredients, such as, for example, surfactants or emulsifiers, thickeners, fragrances , Preservative, may contain.
- the active substance fluids are enzyme-containing active substance phases.
- Such enzyme-containing active substance phases may, in addition to enzyme (s) and water, optionally contain further ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives.
- the active substance fluids used according to the invention are absorbent, in particular odor-absorbing, active-substance phases. These may contain, in addition to the absorbent, in particular odor absorbent, and water, if appropriate, further ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives.
- the dispensing device offers the possibility of using combinations of different active substance fluids in the storage containers, wherein according to a preferred embodiment one of the storage containers contains a fragrance phase, in particular as defined above.
- active substance fluid combinations to be used are perfumed fragrance phase combined with chlorine bleach (together not storage-stable), perfumed fragrance phase with highly concentrated surfactant phase (foam booster), fragrance phase with lime-dissolving, acidic active phase, fragrance phase with antibacterial active ingredient phase, different acid systems, fragrance phase combined with enzyme-containing active substance phase, perfumed acid phase combined with water-coloring phase, fragrance phase with odor-absorbing phase, perfumed acid phase with active oxygen, perfumed acid phase with active substance phase, thickened with polyacrylate etc.
- viscous to gel-like active substance fluids with viscosities in the range of a few thousand mPas, in particular 2000 up to 5000 mPas, preferably 2500 to 3500 mPas (measured with Roto-Visko LVTV II, spindle 31, 5 rpm, 20 ° C).
- Fig. 1 shows a toilet freshener 1 with a first reservoir 2 and a second reservoir 3.
- the reservoirs are filled with each different drug fluids 4,5.
- the storage containers 2, 3 are separated from each other at least in sections by a partition wall 6. As in Fig. 1 shown, the partition 6 closes with the bottom 12, 11 from.
- the partition wall 6 may be formed as a closed surface.
- the partition wall 6 may also have openings, wherein the openings are designed in such a way that mixing of the active substance fluids 4, 5 is prevented.
- the partition can therefore be formed in a further embodiment as a close-meshed grid.
- the partition wall 6 may also be formed as a film or film.
- the partition 6 is firmly connected to one or both of the reservoir 2.3.
- the dividing wall 6 has no connection to the storage container, that is, it is floatingly mounted between the active substance fluids 4, 5.
- Fig. 1 it is also possible to remove the partition 6 from the reservoirs 2, 3 and to configure the active fluids 4, 5 in such a way that the mutually different active fluids form a phase boundary running vertically through the reservoir, the phase boundary being approximately runs centrally above the discharge opening.
- the storage container 2 has a container neck 8, in which a closure is located in the closed state of the storage container 2, 3.
- the storage containers 2, 3 are protected against the entry of rinsing liquid from the toilet rinse and each have a bottom 11, 12, the bottoms 11, 12 of the storage containers 2, 3 having a common bottom-side opening 7, from which the active-substance fluids 4 , 5 can escape.
- the mixing ratio of the active fluids 4, 5 can be influenced by the size and position of the opening 7 as well as by the configuration of the flow properties of the active substance fluids.
- a container nozzle 8 Extending from the opening 7 in the bottom-side direction is a container nozzle 8, on which there is a downstream delivery device 13 in the direction of flow, which controls the delivery of the active substance fluids 4, 5 into the environment and / or the rinsing liquid.
- the dispenser may be valve-controlled or may be implemented by an arrangement that prevents free flow of the active fluids, for example by capillary action.
- the active-substance fluids 4, 5 reach a rinsing plate 9, where they are dissolved and co-washed by the application of rinsing liquid.
Description
Die Erfindung betrifft einem Vorratsbehälter und ein System zur Abgabe von mindestens zwei Wirkstofffluiden gemäß dem Oberbegriff der Ansprüche 1, 5 und 7.The invention relates to a storage container and a system for dispensing at least two active substance fluids according to the preamble of
Der Begriff Wirkstofffluid meint fließfähige, also flüssige bis zähflüssige, ggf. gelartige oder auch pastenartige oder granulatförmige oder anderweit schüttfähige Wirkstoffzubereitungen mit reinigender, desinfizierender, desodorierender, bleichender u.ä. Wirkung (insbesondere beschrieben
Abgabevorrichtungen der in Rede stehenden Art sind unter dem Stichwort "WC-Körbchen" in verschiedenen Ausführungen bekannt. Bekannt sind zunächst Abgabevorrichtungen für ein einzelnes Wirkstofffluid. Das Wirkstofffluid befindet sich dort in einem in einem Halter fest angeordneten oder auswechselbar eingesetzten Vorratsbehälter mit einer bei am Halter angebrachtem Vorratsbehälter bodenseitig angeordnetem Auslaßöffnung.Dispensers of the type in question are known under the keyword "toilet bowl" in different versions. First, dispensing devices for a single active substance fluid are known. The drug fluid is there in a fixed in a holder or interchangeably inserted reservoir with a mounted on the holder reservoir bottom outlet opening arranged.
Bei einer ersten bekannten Abgabevorrichtung für ein einzelnes Wirkstofffluid wird das Wirkstofffluid über ein damit tränkbares, mit der Spülflüssigkeit beaufschlagbares Betätigungselement (z.B. aus einem offenporigen Schaumstoff) zugegeben (
Bei der Verwendung zuvor erläuterter Abgabevorrichtungen der in Rede stehenden Art müssen alle Komponenten, die in die Spülflüssigkeit des Toilettenbeckens gelangen, im Wirkstofffluid gemeinsam enthalten sein. Manche Wirkstoffkomponenten sind aber nicht gemeinsam lagerstabil zu realisieren. Deshalb hat man bereits eine Mehrkammer-Abgabevorrichtung vorgeschlagen (
Bei der zuvor erläuterten Abgabevorrichtung, wird das Funktionsprinzip bekannter "WC-Körbchen" genutzt, nach dem von oben her überströmendes Spülwasser in die das Wirkstofffluid enthaltenden Kammern einströmt, Teile der Wirkstoffsubstanz löst und unter Mitführung dieser aus den Kammern wieder abfließt. Dabei besteht das Problem darin, daß mit dem hier verwirklichten Siphoneffekt in den Kammern ein erheblicher Flüssigkeitsspiegel zurückbleibt. Die Einwirkung der Spülflüssigkeit auf das Wirkstofffluid in der jeweiligen Kammer geht also weiter, auch wenn der Spülvorgang lange abgeschlossen worden ist. Der Verbrauch von Wirkstofffluid ist praktisch nicht optimal zu steuern.In the previously described dispensing device, the principle of operation known "toilet bowl" is used, after flowing from above overflow rinse water flows into the fluid containing chambers, parts of the drug substance dissolves and flows with this entrainment from the chambers again. The problem is that with the siphon effect realized in the chambers, a considerable amount of liquid remains behind. The action of the rinsing liquid on the active substance fluid in the respective chamber therefore continues, even if the rinsing process has been completed for a long time. The consumption of active substance fluid is practically not optimal to control.
Es ist üblich, dass derartige Mehrkammersysteme jeweils eine Auslassöffnung für ein Wirkstofffluid aus einer der Kammern bereitstellen. Häufig werden daher entweder zwei separat ausgeformte Kammern mit jeweils einer Auslassöffnung miteinander gekuppelt im WC-Körbchen angeordnet. Alternativ kann ein einstückiger Vorratsbehälter mit zwei Kammern und zwei Auslassöffnungen vorgesehen sein.It is common that such multi-chamber systems each provide an outlet port for a drug fluid from one of the chambers. Often, therefore, either two separately formed chambers, each with an outlet opening are coupled together arranged in the toilet bowl. Alternatively, a one-piece reservoir with two chambers and two outlet openings may be provided.
Durch die Ausbildung von zwei separierten Auslassöffnungen ist es häufig notwendig, auch zwei Abgabevorrichtungen vorzusehen, die die Abgabe von Wirkstofffluid aus den Vorratsbehältern in die Spülflüssigkeit des Toilettenbeckens steuern. Hier sind beispielsweise Ventilanordnungen bekannt, bei denen ein mit Spülwasser beaufschlagter Hebel mit einem Ventil verbunden ist, dass beim Abspülen die Freisetzung einer Teilmenge an Wirkstofffluid aus einem der Vorratsbehälter bewirkt. Andere Abgabevorrichtungen sind beispielsweise durch Kapillarwirkungen realisiert, die sich zwischen den Wirkstofffluiden und entsprechend dimensionierten Abgabekanälen ausbilden und somit ein freies Fließen eines Wirkstofffluids aus dem Vorratsbehälter verhindern.With the formation of two separate outlet ports, it is often necessary to provide two dispensers which control the delivery of active fluid from the reservoirs into the flushing fluid of the toilet bowl. Here, for example, valve arrangements are known in which a flushing water acted upon lever is connected to a valve that causes the release of a subset of active fluid from one of the reservoir during rinsing. Other dispensing devices are realized, for example, by capillary action that forms between the drug fluids and appropriately sized dispensing channels, thus preventing free flow of active fluid from the reservoir.
Die Ausbildung von zwei separierten Abgabevorrichtungen für die jeweiligen Auslassöffnungen ist aufwendig und kostenintensiv.The formation of two separate dispensing devices for the respective outlet openings is complicated and costly.
Ferner ist häufig nicht gewährleistet, dass es zu einer gleichmäßigen Abgabe von Wirkstoffluiden aus den jeweiligen Behältern kommt, da die Abgabevorrichtungen beispielsweise ungleichmäßig öffnen und schließen. So kommt es häufig vor, dass bereits eine Kammer vollständig von Wirkstofffluid entleert ist, während in der anderen noch Wirkstofffluid ansteht, wodurch die Fehlfunktion eines derartigen WC-Körbchens für den Verbraucher sofort ersichtlich ist.Furthermore, it is often not ensured that there is a uniform delivery of active fluids from the respective containers, since the dispensing devices open and close, for example unevenly. Thus, it often happens that one chamber is already completely emptied of active substance fluid, while in the other still drug fluid is present, whereby the malfunction of such a toilet bowl for the consumer is immediately apparent.
Andere Abgabesysteme sind in
Aufgabe der Erfindung ist es daher die geschilderten, aus dem Stand der Technik bekannten Nachteile zu überwinden und ein Abgabesystem für wenigstens zwei Wirkstofffluide zu schaffen, das auf einfache und kostengünstige Weise herzustellen ist und das eine gleichzeitige und gleichmäßige Abgabe der Wirkstofffluide in die Spülflüssigkeit eines Toilettenbeckens gewährleistet.The object of the invention is therefore to overcome the described, known from the prior art disadvantages and to provide a delivery system for at least two active fluids, which is to produce in a simple and cost-effective manner and that a simultaneous and uniform delivery of the active fluids in the rinsing fluid of a toilet bowl guaranteed.
Die Aufgabe wird durch ein Abgabesystem gemäß Anspruch 1 und 5 sowie durch einen Vorratsbehälter gemäß Anspruch 7 zur Verwendung in einem Abgabesystem gelöst.The object is achieved by a dispensing system according to
Durch die Ausbildung einer einzigen Abgabeöffnung für eine Mehrzahl von Wirkstofffluiden ist sichergestellt, dass die Wirkstofffluide gleichmäßig in die Spülflüssigkeit abgegeben werden und eine ungleichmäßige Abgabe, wie sie beispielsweise bei einer ungleichmäßigen Beaufschlagung der Abspülplatte bei WC-Spülern mit wenigstens zwei Abgabeöffnungen vorkommen kann, verhindert wird.The formation of a single discharge opening for a plurality of active substance fluids ensures that the active substance fluids are dispensed uniformly into the rinsing fluid and prevents uneven delivery, as may occur, for example, in the case of uneven loading of the rinsing plate in toilet rinsers with at least two discharge openings ,
Ferner ist der fertigungstechnische Aufwand verglichen mit dem aus dem Stand der Technik bekannten WC-Spülern deutlich geringer, da nicht für jedes einzelne Fluid eine Ventil- oder sonstige Fließkontrollvorrichtung notwendig ist, sondern lediglich eine Ventil- oder sonstige Fließkontrollvorrichtung für alle Wirkstofffluide benötigt wird.Furthermore, the manufacturing effort compared to the known from the prior art toilet bowls significantly lower because not every single fluid valve or other flow control device is necessary, but only a valve or other flow control device is needed for all drug fluids.
Ein Vorratsbehälter im Sinne dieser Anmeldung ist ein Behälter, der zur Aufnahme eines fließ- oder streufähigen Produktes geeignet ist. Der Vorratsbehälter verfügt über eine bodenseitige Abgabeöffnung, aus der die Wirkstofffluide austreten.A storage container in the sense of this application is a container which is suitable for receiving a flowable or spreadable product. The storage container has a bottom-side discharge opening, from which the active substance fluids emerge.
Es ist besonders bevorzugt, die Vorratsbehälter einstückig auszuformen. Die Vorratsbehälter können durch eine Trennwand zumindest abschnittsweise voneinander separiert sein.It is particularly preferred to form the storage container in one piece. The storage containers can be separated from each other by a partition at least in sections.
Es ist jedoch auch denkbar dass die Vorratsbehälter mehrstückig ausgeformt sind. Die Vorratsbehälter verfügen über eine gemeinsame, bodenseitige Abgabeöffnung.However, it is also conceivable that the reservoir are formed in several pieces. The reservoirs have a common, bottom-side discharge opening.
Im Abgabesystem der vorliegenden Erfindung sind zwei Vorratsbehälter vorgesehen, die, bevorzug voneinander separiert sind, und jeweils ein Wirkstofffluid enthalten. Es kann aber auch mehrere Vorratsbehälter für mehrere Wirkstofffluide geben. Die Vorratsbehälter sind voneinander separiert, um eine vorzeitige Mischung der Wirkstofffluide zu unterbinden. Sie können körperlich separat oder als separate Abteile in einem zusammenhängenden Körper ausgebildet sein.In the delivery system of the present invention, two reservoirs are provided, which are preferably separated from each other and each contain a drug fluid. But there may also be several reservoirs for multiple drug fluids. The reservoirs are separated from each other to prevent premature mixing of the drug fluids. They may be physically separate or formed as separate compartments in a contiguous body.
In einer weiteren Ausführungsform ist vorgesehen, dass an dem WC-Spüler ein Vorratsbehälter mit einer bodenseitigen Öffnung ausgeformt ist, wobei die Wirkstofffluide im Vorratsbehälter im Wesentlichen nicht miteinander mischbare Phasen mit vertikal verlaufenden Phasengrenzen ausbilden und die Phasengrenze bevorzugt mittig über der Abgabeöffnung steht.In a further embodiment, provision is made for a storage container having a bottom-side opening to be formed on the toilet freshener, wherein the active-substance fluids form in the reservoir substantially immiscible phases with vertically extending phase boundaries and the phase boundary is preferably centrally above the discharge opening.
Die bodenseitige Abgabeöffnung kann mittig oder versetzt zur Mitte des WC-Spülers angeordnet sein.The bottom-side discharge opening may be arranged centrally or offset to the center of the toilet rinser.
Die Böden können insbesondere zur Öffnung hin abfallend ausgebildet sein, um eine vollständige Restentleerbarkeit der Wirkstofffluide aus den Vorratsbehältern zu gewährleisten.The floors may be sloping, in particular, towards the opening in order to ensure complete emptying of the active substance fluids from the storage containers.
Es ist insbesondere bevorzugt, den Vorratsbehälter transparent auszubilden, um eine Füllstandskontrolle bezüglich der bevorrateten Wirkstofffluide zu erlauben.It is particularly preferred to form the reservoir transparent to allow a level control with respect to the stored drug fluids.
Es ist ferner denkbar, dass der Vorratsbehälter gemeinsam mit einer Abgabevorrichtung konfektioniert angeboten wird. Es ist jedoch auch möglich, dass der Vorratsbehälter als Nachfüll- oder Austauscheinheit konfiguriert ist.It is also conceivable that the storage container is offered ready made together with a dispenser. However, it is also possible that the reservoir is configured as a refill or exchange unit.
Eine Abgabevorrichtung im Sinne dieser Anmeldung ist eine der Abgabeöffnung der Vorratsbehälter in Fließrichtung der Wirkstofffluide nachgeschaltete Anordnung, die die Abgabe der Wirkstofffluide in die Spülflüssigkeit steuert.For the purposes of this application, a dispensing device is an arrangement arranged downstream of the dispensing opening of the storage container in the direction of flow of the active substance fluids, which controls the dispensing of the active substance fluids into the rinsing liquid.
Steuern bedeutet in diesem Zusammenhang, dass ein freies Fließen der Wirkstofffluide durch die Abgabevorrichtung verhindert ist und eine Freisetzung von Produkt durch die Abgabevorrichtung insbesondere unmittelbar vor, während oder nach einem Spülvorgang der Toilette erfolgt.Control in this context means that a free flow of the active substance fluids is prevented by the dispensing device and a release of product by the dispensing device takes place in particular immediately before, during or after a rinsing process of the toilet.
Die Abgabe kann beispielsweise durch den Spülwasserschwall des Toilettenbeckens bewirkt sein, indem der Spülwasserschwall beispielsweise eine Ventilanordnung öffnet. Die Abgabevorrichtung kann auch durch eine Anordnung realisiert sein, die ein freies Fließen der Wirkstofffluide aus den Vorratsbehältern zum Beispiel durch Kapillarwirkungen verhindert. Es wird hierzu auf die Abgabevorrichtungen verwiesen, die aus der
Die fließfähigen Wirkstofffluide sind insbesondere durch ihre jeweilige Viskositäten in derart konfiguriert, dass sie im Wesentlichen nicht miteinander mischbare Phasen mit vertikal verlaufenden Phasengrenzen ausbilden können.The flowable drug fluids are particularly configured by their respective viscosities in such that they can form substantially immiscible phases with vertically extending phase boundaries.
Es ist besonders bevorzugt, dass genau zwei voneinander verschiedene Wirkstofffluide eine vertikal durch den Vorratsbehälter verlaufende Phasengrenze ausbilden, wobei die Phasengrenze in etwa mittig über der Abgabeöffnung verläuft.It is particularly preferred that exactly two different drug fluids form a vertically extending through the reservoir phase boundary, wherein the phase boundary extends approximately centrally above the discharge opening.
Voneinander verschieden bedeutet im Sinne dieser Anmeldung, dass sich die Wirkstofffluide beispielsweise aber nicht abschließend hinsichtlich ihrer chemischen Zusammensetzung, ihres pH-Wertes, Farbe, Duftes, Fließeigenschaften oder dergleichen unterscheiden.For the purposes of this application, different from one another means that the active substance fluids, for example, do not differ conclusively with respect to their chemical composition, their pH, color, fragrance, flow properties or the like.
Die Wirkstofffluide können im Wesentlichen identische oder voneinander verschiedene Fließeigenschaften aufweisen. Durch voneinander verschiedene Fließeigenschaften ist es möglich, unterschiedliche Mischungsverhältnisse der Wirkstofffluide zueinander bereitzustellen.The drug fluids may have substantially identical or different flow characteristics. By different flow properties, it is possible to provide different mixing ratios of the active fluids to each other.
Erfindungsgemäß geeignete Wirkstofffluide sind beispielsweise Duftphasen, insbesondere parfümierte Duftphasen. Solche Duftphasen enthalten üblicherweise mindestens einen Duftstoff, vorzugsweise Parfümöl, mindestens ein Tensid oder einen Emulgator und Wasser sowie ggf. weitere Inhaltsstoffe wie Konservierungsmittel, Verdickungsmittel, Komplexbildner, Farbstoffe, weitere Tenside oder Emulgatoren, Stabilisatoren, Kalklöser etc.Active substance fluids which are suitable according to the invention are, for example, fragrance phases, in particular perfumed fragrance phases. Such scent phases usually comprise at least one perfume, preferably perfume oil, at least one surfactant or an emulsifier and water and optionally further ingredients such as preservatives, thickeners, complexing agents, dyes, other surfactants or emulsifiers, stabilizers, lime solubilizer etc.
Erfindungsgemäß ebenso geeignet als Wirkstofffluide sind Bleichphasen, insbesondere chlorhaltige Bleichphasen, vorzugsweise Bleichphasen auf Basis von Hypochlorit, wobei die Bleichphasen üblicherweise neben dem eigentlichen Bleichmittel und Wasser ggf. weitere Inhaltsstoffe wie Verdickungsmittel, Tenside oder Emulgatoren, Neutralisierungsmittel, Farbstoffe, Duftstoffe etc. enthalten können.Likewise suitable as active substance fluids are bleaching phases, in particular chlorine-containing bleaching phases, preferably bleaching phases based on hypochlorite, wherein the bleaching phases may optionally contain, in addition to the actual bleaching agent and water, further ingredients such as thickeners, surfactants or emulsifiers, neutralizing agents, dyes, fragrances, etc.
Weitere erfindungsgemäß geeignete Wirkstofffluide sind kalklösende Wirkstoffphasen, vorzugsweise saure kalklösende Wirkstoffphasen. Solche kalklösende Wirkstoffphasen können neben dem eigentlichen Kalklöser-vorzugsweise handelt es sich hierbei um eine organische oder anorganische Säure-und Wasser ggf. weitere Inhaltsstoffe wie Tenside, Emulgatoren, Verdickungsmittel, Duftstoffe, oder Konservierungsmittel enthalten.Further active substance fluids suitable according to the invention are lime-dissolving active substance phases, preferably acidic lime-dissolving active substance phases. Such lime-solubilizing active ingredient phases may contain, in addition to the actual lime solubilizer-preferably an organic or inorganic acid and water-optionally further ingredients such as surfactants, emulsifiers, thickeners, fragrances, or preservatives.
Gleichermaßen ist es möglich, als Wirkstofffluide hochkonzentrierte Tensidphasen, sogenannte "Schaumbooster", einzusetzen. Solche hochkonzentrierten Tensidphasen können neben den Tensiden auch noch weitere, übliche Inhaltsstoffe enthalten.Likewise, it is possible to use highly concentrated surfactant phases, so-called "foam boosters", as active substance fluids. Such highly concentrated surfactant phases may also contain other conventional ingredients in addition to the surfactants.
Erfindungsgemäß ebenfalls geeignet sind Wirkstofffluide mit antibakterieller und/oder fungizider und/oder antiviraler Aktivstoffphase, wobei die Aktivstoffphase neben dem antibakteriell und/oder fungizid und/oder antiviral wirkenden Aktivstoff und Wasser ggf. weitere Inhaltsstoffe, wie zum Beispiel Tenside oder Emulgatoren, Verdickungsmittel, Duftstoffe, Konservierungsmittel, enthalten kann.Also suitable according to the invention are active-ingredient fluids having an antibacterial and / or fungicidal and / or antiviral active phase, wherein the active-substance phase, in addition to the antibacterial and / or fungicidal and / or antiviral active and water, optionally further ingredients, such as, for example, surfactants or emulsifiers, thickeners, fragrances , Preservative, may contain.
Weiter ist es möglich, daß es sich bei den Wirkstofffluiden um enzymhaltige Aktivstoffphasen handelt. Solche enzymhaltigen Aktivstoffphasen können neben Enzym(en) und Wasser ggf. weitere Inhaltsstoffe wie Tenside oder Emulgatoren, Verdickungsmittel, Duftstoffe, Konservierungsmitteln, enthalten.Furthermore, it is possible that the active substance fluids are enzyme-containing active substance phases. Such enzyme-containing active substance phases may, in addition to enzyme (s) and water, optionally contain further ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives.
Gleichermaßen ist es möglich, daß es sich bei den erfindungsgemäß eingesetzten Wirkstofffluiden um absorbierende, insbesondere geruchsabsorbierende Wirkstoffphasen handelt. Diese können neben dem Absorptionsmittel, insbesondere Geruchsabsorptionsmittel, und Wasser ggf. weitere Inhaltsstoffe wie Tenside oder Emulgatoren, Verdickungsmittel, Duftstoffe, Konservierungsmittel enthalten.Likewise, it is possible that the active substance fluids used according to the invention are absorbent, in particular odor-absorbing, active-substance phases. These may contain, in addition to the absorbent, in particular odor absorbent, and water, if appropriate, further ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives.
Die erfindungsgemäße Abgabevorrichtung bietet gemäß einer besonderen Ausführungsform die Möglichkeit, in den Vorratsbehältern Kombinationen unterschiedlicher Wirkstofffluide einzusetzen, wobei gemäß einer bevorzugten Ausführungsform einer der Vorratsbehälter eine Duftphase, insbesondere wie zuvor definiert, enthält.According to a particular embodiment, the dispensing device according to the invention offers the possibility of using combinations of different active substance fluids in the storage containers, wherein according to a preferred embodiment one of the storage containers contains a fragrance phase, in particular as defined above.
Beispiele für einzusetzende Wirkstofffluid-Kombinationen sind parfümierte Duftphase kombiniert mit Chlorbleiche (miteinander zusammen nicht lagerstabil), parfümierte Duftphase mit hochkonzentrierter Tensidphase (Schaum-booster), Duftphase mit kalklösender, saurer Wirkstoffphase, Duftphase mit antibakterieller Wirkstoffphase, unterschiedliche Säure-Systeme, Duftphase kombiniert mit enzymhaltiger Wirkstoffphase, parfümierte Säurephase kombiniert mit wasserfärbender Phase, Duftphase mit geruchsabsorbierender Phase, parfümierte Säurephase mit Aktivsauerstoff, parfümierte Säurephase mit Wirkstoffphase, mit Polyacrylat verdickt etc. Von besonderem Interesse sind dabei zähflüssige bis gelartige Wirkstofffluide mit Viskositäten im Bereich einiger tausend mPas, insbesondere von 2000 bis 5000 mPas, vorzugsweise 2500 bis 3500 mPas (gemessen mit Roto-Visko LVTV II, Spindel 31, 5 U/min, 20 °C).Examples of active substance fluid combinations to be used are perfumed fragrance phase combined with chlorine bleach (together not storage-stable), perfumed fragrance phase with highly concentrated surfactant phase (foam booster), fragrance phase with lime-dissolving, acidic active phase, fragrance phase with antibacterial active ingredient phase, different acid systems, fragrance phase combined with enzyme-containing active substance phase, perfumed acid phase combined with water-coloring phase, fragrance phase with odor-absorbing phase, perfumed acid phase with active oxygen, perfumed acid phase with active substance phase, thickened with polyacrylate etc. Of particular interest are viscous to gel-like active substance fluids with viscosities in the range of a few thousand mPas, in particular 2000 up to 5000 mPas, preferably 2500 to 3500 mPas (measured with Roto-Visko LVTV II,
Zum Zwecke der Offenbarung der vorliegenden Patentanmeldung wird in vollem Umfang auf den Inhalt der vorveröffentlichten Druckschrift
- 1.1.
- WC-SpülerToilet freshener
- 2.Second
- Vorratsbehälterreservoir
- 3.Third
- Vorratsbehälterreservoir
- 4.4th
- Wirkstofffluidactive fluid
- 5.5th
- Wirkstofffluidactive fluid
- 6.6th
- Trennwandpartition wall
- 7.7th
- Abgabeöffnungdischarge opening
- 8.8th.
- Behälterstutzencontainer connector
- 9.9th
- AbspülplatteAbspülplatte
- 10.10th
- Verbindungselementconnecting element
- 11.11th
- Bodenground
- 12.12th
- Bodenground
- 13.13th
- Abgabevorrichtung (Ventil, Kapillar etc.)Dispensing device (valve, capillary, etc.)
Die Vorratsbehälter 2,3 sind durch eine Trennwand 6 zumindest abschnittsweise voneinander separiert. Wie in
Die Trennwand 6 kann als eine geschlossene Fläche ausgeformt sein. Die Trennwand 6 kann auch Öffnungen aufweisen, wobei die Öffnungen in derart ausgeführt sind, dass eine Vermischung der Wirkstofffluide 4,5 verhindert ist. Die Trennwand kann demnach in einer weiteren Ausführungsform als engmaschiges Gitter ausgebildet sein. Die Trennwand 6 kann auch als Folie oder Film ausgebildet sein.The
Die Trennwand 6 ist mit einem oder beiden der Vorratsbehälter 2,3 fest verbunden. In einer weiteren Ausführungsform der Erfindung, die nicht in den Abbildungen gezeigt ist, ist es auch denkbar, dass die Trennwand 6 keine Verbindung mit dem Vorratsbehälter aufweist, also zwischen den Wirkstofffluiden 4,5 schwimmend gelagert ist.The
Wie in
Bei der dargestellten Abgabevorrichtung weist der Vorratsbehälter 2 einen Behälterstutzen 8 auf, bei dem sich im verschlossenen Zustand der Vorratsbehälters 2,3 ein Verschluss befindet.In the case of the dispensing device shown, the
Für die Abgabe der Wirkstofffluid 4,5 aus den Vorratsbehältern 2,3 sind Gravitation, Unterdruck oberhalb des Flüssigkeitsspiegels der Wirkstofffluid 4,5 in denFor the delivery of the
Vorratsbehältern 2,3, Verdünnung der Wirkstofffluide 4,5 an der Abgabestelle, ebenso von Bedeutung wie die räumliche Lage der Abgabevorrichtung im Toilettenbecken, die Intensität der Strömung der Spülflüssigkeit.
Die Vorratsbehälter 2,3 sind gegen den Eintritt von Spülflüssigkeit aus der WC-Spülung geschützt und verfügen jeweils über einen Boden 11,12, wobei die Böden 11,12 der Vorratsbehälter 2,3 eine gemeinsame bodenseitige Öffnung 7 aufweisen, aus der die Wirkstofffluide 4,5 austreten können. Das Mischungsverhältnis der Wirkstofffluide 4,5 kann durch die Größe und Lage der Öffnung 7 sowie durch Konfiguration der Fließeigenschaften der Wirkstofffluide beeinflusst werden.The
Von der Öffnung 7 erstreckt sich in bodenseitiger Richtung ein Behälterstutzen 8 an dem sich in Fließrichtung nachfolgend eine Abgabevorrichtung 13 befindet, die die Abgabe der Wirkstofffluide 4,5 in die Umgebung und/oder die Spülflüssigkeit steuert.Extending from the
Die Abgabevorrichtung kann beispielsweise ventilgesteuert sein oder durch eine Anordnung realisiert sein, die ein freies Fließen der Wirkstofffluide verhindert, zum Beispiel durch Kapillarwirkung.For example, the dispenser may be valve-controlled or may be implemented by an arrangement that prevents free flow of the active fluids, for example by capillary action.
Von der Abgabevorrichtung 13 gelangen die Wirkstofffluide 4,5 auf eine Abspülplatte 9, wo sich durch die Beaufschlagung mit Spülflüssigkeit aufgelöst und mitgeschwemmt werden.From the dispensing
Claims (7)
- A dispensing system for dispensing active ingredient fluids, in particular into the flushing liquid of a toilet bowl, comprising• a first reservoir (2) containing a first active ingredient fluid (4),• at least one second reservoir (3) containing a second active ingredient fluid (5) that is different from the first active ingredient fluid (4),• the reservoir (2, 3) being configured such that the active ingredient fluids (4, 5) are prevented from intermixing in the reservoirs and the flushing liquid is prevented from entering the reservoirs (2, 3),• the first reservoir (2) comprising a first dispensing orifice (7a) arranged on the bottom (12) and the second reservoir (3) comprising a second dispensing orifice (7b) arranged on the bottom (13),characterized in that• the first dispensing orifice (7a) and the second dispensing orifice (7b) form a common dispensing orifice (7) through which the first active ingredient fluid (4) and the second active ingredient fluid (5) leave the reservoirs (2, 3),• a dispensing device (13) connected downstream of the common dispensing orifice (7) of the reservoirs (2, 3) in the flow direction of the active ingredient fluids being provided, which device controls the dispensing of the active ingredient fluids (4, 5) into the flushing liquid.
- The dispensing system according to claim 1, characterized in that the reservoirs (2, 3) are formed in one piece.
- The dispensing system according to claim 2, characterized in that the reservoirs (2, 3) have a common partition wall (6).
- The dispensing system according to claim 3, characterized in that the partition wall (6) is flush with the bottom (12, 13).
- The dispensing system for dispensing active ingredient fluids, in particular into the flushing liquid of a toilet bowl, comprising• a first reservoir (2) containing a first active ingredient fluid (4) and at least one second reservoir (3) containing a second active ingredient fluid (5) that is different from the first active ingredient fluid (4),• the reservoirs being designed such that the flushing liquid is prevented from entering the reservoirs,• the first reservoir (2) comprising a first dispensing orifice (7a) arranged on the bottom (12) and the second reservoir (3) comprising a second dispensing orifice (7b) arranged on the bottom (13),• a dispensing device (13) connected downstream of the dispensing orifice (7) of the reservoirs (2, 3) in the flow direction of the active ingredient fluids being provided, which device controls the dispensing of the active ingredient fluids (4, 5) into the flushing liquid,characterized in that• the active ingredient fluids (4, 5) in the respective reservoirs form substantially horizontally oriented phases,• the first dispensing orifice (7a) and the second dispensing orifice (7b) form a common dispensing orifice (7) through which the first active ingredient fluid (4) and the second active ingredient fluid (5) leave the reservoirs (2, 3), and• the active ingredient fluids (4, 5) being configured such that the active ingredient fluids (4, 5) are prevented from intermixing.
- The dispensing system according to claim 5, characterized in that the phase boundary of the active ingredient fluids (4, 5) extends approximately centrally across the orifice (7).
- A reservoir for active ingredient fluids, in particular for use together with a system for dispensing active ingredient fluids into the flushing liquid of a toilet bowl, comprising• a first reservoir (2) containing a first active ingredient fluid (4),• at least one second reservoir (3) containing a second active ingredient fluid (5) that is different from the first active ingredient fluid (4),• the reservoirs (2, 3) being configured such that the active ingredient fluids (4, 5) are prevented from intermixing in the reservoirs and the flushing liquid is prevented from entering the reservoirs (4, 5),• the first reservoir (2) comprising a first dispensing orifice (7a) arranged on the bottom (12) and the second reservoir (3) comprising a second dispensing orifice (7b) arranged on the bottom (13),characterized in that• the first dispensing orifice (7a) and the second dispensing orifice (7b) form a common dispensing orifice (7) through which the first active ingredient fluid (4) and the second active ingredient fluid (5) leave the reservoirs (2, 3).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006062431 | 2006-12-27 | ||
PCT/EP2007/058504 WO2008080642A1 (en) | 2006-12-27 | 2007-08-16 | System for dispensing active ingredient fluids to the flushing liquid of a toilet bowl |
Publications (2)
Publication Number | Publication Date |
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EP2104773A1 EP2104773A1 (en) | 2009-09-30 |
EP2104773B1 true EP2104773B1 (en) | 2016-09-28 |
Family
ID=38802669
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP07819948.6A Active EP2104773B1 (en) | 2006-12-27 | 2007-08-16 | System for dispensing active ingredient fluids to the flushing liquid of a toilet bowl |
Country Status (3)
Country | Link |
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EP (1) | EP2104773B1 (en) |
PL (1) | PL2104773T3 (en) |
WO (1) | WO2008080642A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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DE102008037723A1 (en) | 2008-08-14 | 2010-02-25 | Henkel Ag & Co. Kgaa | Toilet basket with Spülwasserverteilelement |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4581777A (en) * | 1985-03-29 | 1986-04-15 | The Drackett Company | Sealable dispenser and hanger |
GB2194258B (en) * | 1986-08-15 | 1990-11-21 | Jeyes Group Ltd | Lavatory cleansing devices |
DE10113036B4 (en) * | 2000-11-17 | 2005-02-17 | Henkel Kgaa | Device for delivering fluids with active substances into flushing water in a toilet bowl, has storage containers with outlets arranged so that they deliver fluids only during each flushing operation |
JP4974477B2 (en) * | 2005-03-31 | 2012-07-11 | 小林製薬株式会社 | Chemical supply device |
-
2007
- 2007-08-16 WO PCT/EP2007/058504 patent/WO2008080642A1/en active Application Filing
- 2007-08-16 PL PL07819948T patent/PL2104773T3/en unknown
- 2007-08-16 EP EP07819948.6A patent/EP2104773B1/en active Active
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PL2104773T3 (en) | 2017-03-31 |
WO2008080642A1 (en) | 2008-07-10 |
EP2104773A1 (en) | 2009-09-30 |
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