PL108903B1 - Fungicide - Google Patents
Fungicide Download PDFInfo
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- PL108903B1 PL108903B1 PL1978205555A PL20555578A PL108903B1 PL 108903 B1 PL108903 B1 PL 108903B1 PL 1978205555 A PL1978205555 A PL 1978205555A PL 20555578 A PL20555578 A PL 20555578A PL 108903 B1 PL108903 B1 PL 108903B1
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- 230000000855 fungicidal effect Effects 0.000 title claims description 7
- 239000000417 fungicide Substances 0.000 title claims description 6
- 239000013543 active substance Substances 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 18
- TWFZGCMQGLPBSX-UHFFFAOYSA-N carbendazim Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 claims description 10
- 239000000969 carrier Substances 0.000 claims description 8
- 229910052801 chlorine Inorganic materials 0.000 claims description 6
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 6
- 231100001184 nonphytotoxic Toxicity 0.000 claims description 6
- 230000007935 neutral effect Effects 0.000 claims description 4
- 150000003230 pyrimidines Chemical class 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052731 fluorine Chemical group 0.000 claims description 2
- 125000001153 fluoro group Chemical group F* 0.000 claims description 2
- 239000000203 mixture Substances 0.000 description 10
- 239000004094 surface-active agent Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000007900 aqueous suspension Substances 0.000 description 6
- 235000013339 cereals Nutrition 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000002562 thickening agent Substances 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- 206010017533 Fungal infection Diseases 0.000 description 4
- 208000031888 Mycoses Diseases 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- -1 alkyl succinates Chemical class 0.000 description 3
- 230000002528 anti-freeze Effects 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000004182 2-chlorophenyl group Chemical group [H]C1=C([H])C(Cl)=C(*)C([H])=C1[H] 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 2
- 235000014787 Vitis vinifera Nutrition 0.000 description 2
- 240000006365 Vitis vinifera Species 0.000 description 2
- HVFLCNVBZFFHBT-ZKDACBOMSA-N cefepime Chemical compound S([C@@H]1[C@@H](C(N1C=1C([O-])=O)=O)NC(=O)\C(=N/OC)C=2N=C(N)SC=2)CC=1C[N+]1(C)CCCC1 HVFLCNVBZFFHBT-ZKDACBOMSA-N 0.000 description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052901 montmorillonite Inorganic materials 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- NHOWDZOIZKMVAI-UHFFFAOYSA-N (2-chlorophenyl)(4-chlorophenyl)pyrimidin-5-ylmethanol Chemical compound C=1N=CN=CC=1C(C=1C(=CC=CC=1)Cl)(O)C1=CC=C(Cl)C=C1 NHOWDZOIZKMVAI-UHFFFAOYSA-N 0.000 description 1
- SAPGTCDSBGMXCD-UHFFFAOYSA-N (2-chlorophenyl)-(4-fluorophenyl)-pyrimidin-5-ylmethanol Chemical compound C=1N=CN=CC=1C(C=1C(=CC=CC=1)Cl)(O)C1=CC=C(F)C=C1 SAPGTCDSBGMXCD-UHFFFAOYSA-N 0.000 description 1
- WPRAXAOJIODQJR-UHFFFAOYSA-N 1-(3,4-dimethylphenyl)ethanone Chemical compound CC(=O)C1=CC=C(C)C(C)=C1 WPRAXAOJIODQJR-UHFFFAOYSA-N 0.000 description 1
- 125000001255 4-fluorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1F 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- QLAKAJLYYGOZQL-UHFFFAOYSA-N Carboxyphosphamide Chemical compound ClCCN(CCCl)P(=O)(N)OCCC(O)=O QLAKAJLYYGOZQL-UHFFFAOYSA-N 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229960002242 chlorocresol Drugs 0.000 description 1
- CRPOUZQWHJYTMS-UHFFFAOYSA-N dialuminum;magnesium;disilicate Chemical compound [Mg+2].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] CRPOUZQWHJYTMS-UHFFFAOYSA-N 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- 208000032625 disorder of ear Diseases 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- VSXGXPNADZQTGQ-UHFFFAOYSA-N oxirane;phenol Chemical class C1CO1.OC1=CC=CC=C1 VSXGXPNADZQTGQ-UHFFFAOYSA-N 0.000 description 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Description
Przedmiotem wynalazku jest srodek grzybobój¬ czy do ochrony upraw przed zakazeniem grzy¬ bowym.Srodek grzybobójczy wedlug wynalazku zawie¬ ra substancje czynne w polaczeniu z jednym lub kilkoma obojetnymi i niefitotoksycznymi nosnika¬ mi. Srodek zawiera jako jedna substancje czyn¬ na grzybobójczo pochodna pirymidyny o wzorze 1, w którym X oznacza atom chlorku lub fluoru a jako druga substancje czynna grzybobójczo za¬ wiera ester metylowy kwasu benzimidazolo-2-kar- baminowego o wzorze 2.Oba wymienione zwiazki sa znane i mozna je otrzymac metodami opisanymi w literaturze. O- kreslone polaczenie substancji czynnych wchodza¬ cych w sklad srodka wedlug wynalazku jest no¬ we i, jak stwierdzono, dziala niespodziewanie sku¬ tecznie przy ograniczeniu lub zwalczaniu zaka¬ zen upraw grzybami. Srodek zawierajacy jako substancje czynna zwiazek o wzorze 1 i zwiazek o wzorze 2 jest szczególnie uzyteczny przy zwal¬ czaniu chorób zbóz, takich jak plesn proszkowa, zgnilizna korzeniowa i inne choroby lisci i klo¬ sów atakujace rosliny zbozowe w stadium dojrze¬ wania.Srodek wedlug wynalazku stosuje sie przeciw zakazeniom grzybowym na rosliny, zwlaszcza na zboza i winorosle, w ilosci skutecznej grzybobój¬ czo. Srodek stosuje sie korzystnie na liscie w do¬ wolnym czasie, poczawszy od wykielkowania ros¬ liny do czasu zbioru. Ilosc i czestotliwosc stoso¬ wania srodka zalezy od stwierdzonego lub spo¬ dziewanego stopnia zaatakowania roslin zakaze¬ niem grzybowym. Jednakze cecha srodka wedlug , wynalazku jest to, ze szczególnie dobre dzialanie wykazuje on przy ograniczonej czestotliwosci sto¬ sowania. Przykladowo, w celu panowania nad za¬ kazeniami winorosli plesnia, srodek stosuje sie skutecznie tylko raz na 2—3 tygodni, dzieki cze- lf mu ogranicza sie koszty robocizny.Korzystna substancja czynna srodka wedlug wy¬ nalazku przeznaczonego do stosowania na wino¬ rosle jest pirymidyna o wzorze 1, w którym X oznacza atom chloru, natomiast korzystna sub- u stancja srodka przeznaczonego do stosowania na zboza jest pirymidyna o wzorze 1, w którym X oznacza atom fluoru.Skladniki srodka wedlug wynalazku mozna sto¬ sowac na rosliny kolejno lub jednoczesnie, przy n czym bardziej zalecane jest stosowanie ich razem.Zwiazek o wzorze 1 stosuje sie korzystnie w iles* ci 10—100 g/ha, a najkorzystniej, przy stosowa¬ niu na winorosle, w ilosci 10—30 g/ha. Zwiazki o wzorze 2 stosuje sie korzystnie w ilosci 100—3000 21 g/ha. Tak wiec stosunek wagowy zwiazków o wzorze 1 do zwiazków o wzorze 2 wchodzacych w sklad srodka zawiera sie w zakresie 5:1 do 1:300.Korzystny stosunek wagowy zwiazku o wzorze 1 do zwiazku o wzorze 2 wynosi 1:1 do 1:25. W M przeliczeniu na jedna substancje czynna, zwiazek 108 903108 903 o wzorze 1 stosuje sie w ilosci 20—100 g/ha, a zwiazek o wzorze 2 w ilosci 100—500 g/ha.W celu uproszczenia produkcji, magazynowania i transportu srodek przygotowuje sie zwykle w postaci koncentratu przeznaczonego do rozciencza¬ nia woda w takim stopniu, -który pozwala na lat¬ we stosowanie omawianych poprzednio dawek sub- staeji czynnych. Koncentraty takie moga zawie¬ rac 6,5—90°/o, a korzystnie 5—90*/o wagowych sub¬ stancji czynnych w polaczeniu z jednym lub kil¬ koma obojetnymi, niefitotoksycznymi nosnikami.Srodek taki ma zwykle postac zwilzalnego prosz¬ ku, pylu lub zawiesiny wodnej. Srodek w postaci koncentratów przeznaczony jest do rozcienczania woda przed uzyciem. Zawiesiny wodne przygoto¬ wuje sie z koncentratów w zwyklych, nadajacych sie do tego celu zbiornikach.Zwilzalne proszki lub pyly zawieraja doklad¬ nie zmieszane substancje czynne i jeden lub kil¬ ka obojetnych nosników oraz odpowiednie srod¬ ki powierzchniowo czynne. Obojetny nosnik moze byc dobrany z glin atapulgitowych, glin montmo- rylonitowych, ziem okrzemkowych, kaolinów, miki, talków i oczyszczanych krzemianów. Odpowiednie srodki powierzchniowe czynne wybiera sie sposród sulfonowych lignin, naftalenosulfonianów i kon- densowanych naftalenosulfonianów, bursztynianów alkilowych, sulfonianów alkilobenzenu, sulfonia¬ nów alkilowych i niejonowych srodków powierz¬ chniowo czynnych, takich jak addukty tlenku ety¬ lenu i fenolu. Przykladowymi zwilzalnymi prosz¬ kami wedlug wynalazku sa preparaty o nastepu¬ jacym skladzie: Zwilzalneproszki °/l wagowy Zwiazek o wzorze 1 0,25—10 Zwiazek o wzorze2 10—80 Srodek lub srodki powierzchniowo czynne 0—10 Srodek dyspergujacy 0—10 Srodek zapobiegajacy zbrylaniu 0—10 Obojetny nosnik lub nosniki do 100 Zawiesiny wodne i roztwory zawieraja substan¬ cje czynne zawieszone lub rozpuszczone w wodzie lub odpowiednich rozpuszczalnikach oraz dowol¬ ne srodki powierzchniowo czynne, srodki zgeszcza- jace, srodki przeciw zamarzaniu lub srodki kon¬ serwujace. Odpowiednie srodki powierzchniowo czynne mozna wybrac sposród wymienionych po¬ przednio w odniesieniu do zwilzalnych proszków.Srodki zgeszczajace, jezeli sie je stosuje, wybie¬ ra sie z nadajacych sie do tego celu materialów celulozowych i zywic naturalnych. Glikole sto¬ suje sie zwykle jako srodek przeciw zamarzaniu o ile jest potrzebny. Srodki konserwujace mozna wybrac z wielu róznych substancji tego typu, ta¬ kich jak rózne parabenowe substancje przeciwbak- teryjne fenol, 0-chlorokrezol, azotan fenylorteci i formaldehyd. Typowymi zawiesinami wodnymi sa wedlug wynalazku preparaty o nastepujacym skla¬ dzie: Zawiesiny wodne /plynne/ % wagowy Zwiazek o wzorze 1 0,1—8 Zwiazek o wzorze 2 20—52 Srodek lub srodki powierzchniowo czynne 0—15 Srodek zgeszczajacy 0—3 lt 15 25 15 Srodek przeciw zamarzaniu 0—20 Srodek konserwujacy 0—1 Srodek przeciwpienny 0—0,5 Woda do 100 Mimo, ze podane wyzej ogólne sklady prepara¬ tów srodka odpowiednio ilustruja fachowcom ty¬ py stosowanych zestawów, w celu dokladniejsze¬ go zilustrowania wynalazku we wszystkich jego aspektach przytoczone sa nastepujace przyklady: W przykladach a^/2-chlorofenylo/-a-/4-chlorofe- nylo/-5-pirymidynometanol /„CCPM"/ oznacza zwiazek o wzorze 1, w którym X oznacza atom chloru, a a-/2-chlorofenylo/- -pirymidynometanol /„CFPM"/ oznacza zwiazek o wzorze 1, w którym X oznacza atom fluoru, a ester metylowy kwasu 2-benzimidazolokarbomino- wego zwiazek o wzorze 2 oznaczony jest symbo¬ lem literowym „MBC".Przyklad I i II. Przygotowano zwilzalne proszki o nastepujacym skladzie: I •/• wagowy a-/2-chlorofenylo/-a-/4-chlorofenylo/-5- -pirymidynometanol /CCPM/ 5,0 ester metylowy kwasu 2-benzimidazolo- karbaminowego /MBC/ 50,0 Dwuoktylosulfobursztynian sodu 4,0 Ligninosulfoniansodu 1,5 Stracana krzemionka 2,5 Atapulgit do 100,0 II c/.-/2-chlorofenylo/-a-/4-fluorofenylo/- -5-pirymidynometanol /CEPM/ 3,0 ester metylowy kwasu 2-benzimidazolo- karbaminowego /MBC/ 45,0 Alkilonaftalenosulfonian sodu 8,0 ziemia okrzemkowa 6,0 Montmorylonit do 100,0 W obu przykladach substancje czynne staran¬ nie mieszane z odpowiednimi rozczynnikami w zwyklym mieszalniku. Mieszanke mielono nastep¬ nie w mlynie hydraulicznym do uziarnienia rzedu 1—10 mikronów, korygowano sklad mieszanki i odpowietrzono ja przed zapakowaniem.Przykladylll i IV. Przygotowano zawie¬ siny wodne o nastepujacym skladzie: III °/t wagowy a-/2-chlorofenylo/-a-/4-fluorofenylo/- -5-pirymidynometanol /CFPM/ 4,0 ester metylowy kwasu 2-benzimidazolo- karbaminowego /MBC/ 40,0 Polioksyetylenowo-polioksypropylenowy kopolimer blokowy 2,0 Zywica ksantanowa 0,4 Silikonowy srodek przeciwpienny 0,1 Woda do 100,0 IV •/• wagowy 0H/2-chlorofenylo/-a-/4-chlorofenylo/- -5-pirymidynometanol /CCPM/ 5,0 ester metylowy kwasu 2-benzimidazolo- karbaminowego /MBC/ 40,0 Etoksylowany nonylofenol 4,0 Hydroksymetyloceluloza 2,0 Silikonowy srodek przeciwpienny 0,15 Glikol propylenowy 6,0 woda do 100,05 108 903 S Oba skladniki czynne zmielone w zwykly spo¬ sób w razie potrzeby dyspergowano w wodzie za¬ wierajacej srodki powierzchniowo czynne, konser¬ wujace i czesc srodka zgeszczajacego. Uziarnienie obu substancji czynnych zmniejszono dalej przez mielenie cieczy i dodawano pozostala ilosc srodka zgeszczajacego. Pozostawiono zawiesine do uwod¬ nienia i produkt rozcienczano woda do odpowied¬ niej objetosci.Zastrzezenia patentowe 1. Srodek grzybobójczy zawierajacy substancje czynne i jeden lub kilka obojetnych, niefitotok- 10 1S sycznych nosników, znamienny tym, ze jako jed¬ na substancje czynna grzybobójczo zawiera po¬ chodna pirymidyny o wzorze 1, w którym X ozna¬ cza atom chloru lub fluoru, a jako druga sub¬ stancje czynna grzybobójczo zawiera ester mety¬ lowy kwasu 2-benzimidazolokarbaminowego o wzo¬ rze 2. 2. Srodek wedlug zastrz. 1, znamienny tym* ze zawiera 0,5—90V« wagowych substancji czynnych, a reszte stanowi jeden lub kilka obojetnych, nie- fitotoksycznych nosników. 3. Srodek wedlug zastrz. 1 albo 2, znamienny tym, ze jako jedna z substancji czynnych zawiera zwiazek o wzorze 1, w którym X oznacza atom chloru. o t-NH-C-OCH Wtór 2 PL PL PL The subject of the invention is a fungicide for protecting crops against fungal infections. The fungicide according to the invention contains active substances in combination with one or more neutral and non-phytotoxic carriers. The agent contains as one fungicidally active substance a pyrimidine derivative of the formula 1, in which known and can be obtained by methods described in the literature. The specific combination of active substances included in the composition according to the invention is new and has been found to be surprisingly effective in limiting or combating fungal infections of crops. The agent containing as active substances a compound of the formula 1 and a compound of the formula 2 is particularly useful in combating cereal diseases such as powdery mildew, root rot and other leaf and ear diseases attacking cereal plants in the ripening stage. The agent according to The invention is used against fungal infections of plants, especially cereals and vines, in a fungicidally effective amount. The agent is preferably applied to the foliage at any time, from the time of plant germination until harvest. The amount and frequency of application of the agent depend on the observed or expected degree of fungal infection of the plants. However, the feature of the agent according to the invention is that it works particularly well with a limited frequency of use. For example, in order to control mold infections in grapevines, the agent is effectively applied only once every 2-3 weeks, thereby reducing labor costs. The preferred active substance of the agent according to the invention intended for use on grapevines is pyrimidine of formula 1, in which X is a chlorine atom, while the preferred substance of the agent intended for use on cereals is pyrimidine of formula 1, in which , and it is more recommended to use them together. The compound of formula 1 is preferably used in an amount of 10-100 g/ha, and most preferably, when applied to vines, in an amount of 10-30 g/ha. Compounds of formula 2 are preferably used in amounts of 100-3000 g/ha. Thus, the weight ratio of the compounds of formula 1 to the compounds of formula 2 contained in the composition is in the range of 5:1 to 1:300. A preferred weight ratio of the compound of formula 1 to the compound of formula 2 is 1:1 to 1:25. In M terms per one active substance, the compound 108 903108 903 of formula 1 is used in an amount of 20-100 g/ha, and the compound of formula 2 in an amount of 100-500 g/ha. In order to simplify production, storage and transport, the agent is prepared usually in the form of a concentrate intended to be diluted with water to an extent that allows easy use of the previously discussed doses of active substances. Such concentrates may contain 6.5-90%, and preferably 5-90% by weight of active substances in combination with one or more inert, non-phytotoxic carriers. Such an agent is usually in the form of a wettable powder. , dust or water suspension. The product in the form of concentrates is intended to be diluted with water before use. Aqueous suspensions are prepared from concentrates in ordinary tanks suitable for this purpose. Wettable powders or dusts contain thoroughly mixed active substances and one or more inert carriers and appropriate surfactants. The inert carrier may be selected from attapulgite clays, montmorillonite clays, diatomaceous earths, kaolins, mica, talcs and purified silicates. Suitable surfactants are selected from sulfonate lignins, naphthalene sulfonates and condensed naphthalene sulfonates, alkyl succinates, alkylbenzene sulfonates, alkyl sulfonates and non-ionic surfactants such as ethylene oxide-phenol adducts. Examples of wettable powders according to the invention are preparations with the following composition: Wettable powders °/l by weight Compound of formula 1 0.25-10 Compound of formula 2 10-80 Surfactant or surfactants 0-10 Dispersant 0-10 Preventive agent caking 0-10 Inert carrier or carriers up to 100 Aqueous suspensions and solutions contain active substances suspended or dissolved in water or appropriate solvents and any surfactants, thickeners, antifreezes or preservatives. Suitable surfactants may be selected from those previously mentioned for wettable powders. Thickening agents, if used, are selected from suitable cellulosic materials and natural gums. Glycol is usually used as an antifreeze when needed. Preservatives can be selected from a wide variety of substances of this type, such as the various paraben antibacterial substances phenol, 0-chlorocresol, phenylmercury nitrate and formaldehyde. Typical aqueous suspensions according to the invention are preparations with the following composition: Aqueous suspensions (liquid) % by weight Compound of formula 1 0.1-8 Compound of formula 2 20-52 Surface-active agent or agents 0-15 Thickening agent 0-3 lt 15 25 15 Antifreeze 0-20 Preservative 0-1 Antifoam 0-0.5 Water to 100 Although the general compositions of the agent preparations given above adequately illustrate to those skilled in the art the types of kits used, in order to illustrate more precisely the invention in all its aspects, the following examples are set forth: In the examples, α-(2-chlorophenyl)-α-(4-chlorophenyl)-5-pyrimidinemethanol ("CCPM") means a compound of formula 1, wherein X is a chlorine atom , and α-(2-chlorophenyl)-pyrimidinomethanol ("CFPM"/) means a compound of formula 1, in which MBC".Example I and II. Wettable powders with the following composition were prepared: -benzimidazole-carbamic acid /MBC/ 50.0 Sodium dioctylsulfosuccinate 4.0 Sodium lignin sulfonates 1.5 Lost silica 2.5 Attapulgite up to 100.0 II c/.-/2-chlorophenyl/-a-/4-fluorophenyl/- -5 -pyrimidinomethanol /CEPM/ 3.0 2-benzimidazole-carbamic acid methyl ester /MBC/ 45.0 Sodium alkylnaphthalenesulfonate 8.0 diatomaceous earth 6.0 Montmorillonite up to 100.0 In both examples, the active substances were carefully mixed with the appropriate excipients in a regular mixer. The mixture was then ground in a hydraulic mill to a grain size of 1-10 microns, the composition of the mixture was adjusted and it was deaerated before packaging. Examples III and IV. Aqueous suspensions with the following composition were prepared: III°/t by weight α-(2-chlorophenyl)-α-(4-fluorophenyl)-5-pyrimidinemethanol (CFPM) 2-benzimidazole-carbamic acid methyl ester 4.0 (MBC) / 40.0 Polyoxyethylene-polyoxypropylene block copolymer 2.0 Xanthan gum 0.4 Silicone antifoam 0.1 Water to 100.0 IV •/• by weight 0H/2-chlorophenyl/-a-/4-chlorophenyl/- -5 -pyrimidinomethanol /CCPM/ 5.0 2-benzimidazole-carbamic acid methyl ester /MBC/ 40.0 Ethoxylated nonylphenol 4.0 Hydroxymethylcellulose 2.0 Silicone antifoam agent 0.15 Propylene glycol 6.0 water to 100.05 108 903 S Both active ingredients, ground in a conventional manner, were, if necessary, dispersed in water containing surfactants, preservatives and part of the thickener. The particle size of both active substances was further reduced by grinding the liquid and the remaining amount of thickening agent was added. The suspension was left to hydrate and the product was diluted with water to the appropriate volume. Patent claims 1. A fungicide containing active substances and one or more inert, non-phytotoxic carriers, characterized in that it contains as one fungicide active substance a pyrimidine derivative of formula 1, in which X is a chlorine or fluorine atom, and the second fungicidal active substance contains 2-benzimidazolecarbamic acid methyl ester of formula 2. 2. The agent according to claim 1. 1, characterized in that it contains 0.5 - 90 V of active substances by weight, and the rest is one or several neutral, non-phytotoxic carriers. 3. The agent according to claim 1 or 2, characterized in that as one of the active substances it contains a compound of formula 1, in which X is a chlorine atom. o t-NH-C-OCH Repeat 2 PL PL PL
Claims (3)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB12972/77A GB1596380A (en) | 1977-03-28 | 1977-03-28 | Fungicidal combinations |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL205555A1 PL205555A1 (en) | 1978-12-04 |
| PL108903B1 true PL108903B1 (en) | 1980-05-31 |
Family
ID=10014480
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1978205555A PL108903B1 (en) | 1977-03-28 | 1978-03-24 | Fungicide |
| PL1978216610A PL112146B1 (en) | 1977-03-28 | 1978-03-24 | Fungicide |
| PL1978216611A PL112622B1 (en) | 1977-03-28 | 1978-03-24 | Fungicide |
| PL1978216612A PL112286B1 (en) | 1977-03-28 | 1978-03-24 | Fungicide |
Family Applications After (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1978216610A PL112146B1 (en) | 1977-03-28 | 1978-03-24 | Fungicide |
| PL1978216611A PL112622B1 (en) | 1977-03-28 | 1978-03-24 | Fungicide |
| PL1978216612A PL112286B1 (en) | 1977-03-28 | 1978-03-24 | Fungicide |
Country Status (34)
| Country | Link |
|---|---|
| JP (1) | JPS53121932A (en) |
| AR (2) | AR227124A1 (en) |
| AT (1) | AT362195B (en) |
| AU (1) | AU515204B2 (en) |
| BE (1) | BE865215A (en) |
| BG (4) | BG30167A4 (en) |
| BR (1) | BR7801746A (en) |
| CA (1) | CA1108046A (en) |
| CH (1) | CH629363A5 (en) |
| CS (4) | CS198289B2 (en) |
| DD (1) | DD135031A5 (en) |
| DE (2) | DE2858350C2 (en) |
| DK (1) | DK149442C (en) |
| ES (1) | ES468098A1 (en) |
| FR (4) | FR2390096A1 (en) |
| GB (1) | GB1596380A (en) |
| GR (1) | GR64791B (en) |
| HU (2) | HU179506B (en) |
| IE (1) | IE46690B1 (en) |
| IL (1) | IL54318A (en) |
| IN (1) | IN147690B (en) |
| IT (1) | IT1105157B (en) |
| LU (1) | LU79285A1 (en) |
| MX (1) | MX5640E (en) |
| NL (1) | NL7803064A (en) |
| NO (4) | NO147260C (en) |
| NZ (1) | NZ186757A (en) |
| PL (4) | PL108903B1 (en) |
| PT (1) | PT67801A (en) |
| RO (4) | RO78274A (en) |
| SE (5) | SE447783B (en) |
| SU (1) | SU1409119A3 (en) |
| TR (1) | TR20072A (en) |
| ZA (1) | ZA781700B (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2560510C2 (en) * | 1975-11-26 | 1989-02-16 | Bayer Ag, 5090 Leverkusen, De | |
| IT1143721B (en) * | 1977-12-01 | 1986-10-22 | Sipcam Spa | FUNGICIDAL COMPOSITION FOR THE FIGHT AGAINST PLANT DISEASES |
| DE2846038A1 (en) * | 1978-10-23 | 1980-05-08 | Basf Ag | 1,2,4-TRIAZOLE DERIVATIVES, THEIR PRODUCTION AND USE |
| DE3208142A1 (en) * | 1982-03-06 | 1983-09-08 | Bayer Ag, 5090 Leverkusen | FUNGICIDAL AGENT |
| FR2524261A1 (en) * | 1982-04-01 | 1983-10-07 | Rhone Poulenc Agrochimie | FENARIMOL FUNGICIDE POWDER COMPOSITION |
| GB8629360D0 (en) * | 1986-12-09 | 1987-01-21 | Sandoz Ltd | Fungicides |
| JPH01167287U (en) * | 1988-05-16 | 1989-11-24 | ||
| DE3818903A1 (en) * | 1988-06-03 | 1989-12-14 | Stama Maschinenfabrik Gmbh | DRILLING AND MILLING PLANT |
| JPH0274094U (en) * | 1988-11-28 | 1990-06-06 | ||
| JPH071190Y2 (en) * | 1989-03-01 | 1995-01-18 | 狭山精密工業株式会社 | Spiral control mechanism in pachinko ball lifting device |
| NZ260462A (en) * | 1994-05-05 | 1996-04-26 | Horticulture & Food Res Inst | Tree treatment and composition comprising phosphorous acid, a bioprecursor or a salt thereof and a triazole |
| FR2732191B1 (en) * | 1995-03-30 | 2000-12-29 | Rhone Poulenc Agrochimie | ANTIFUNGAL TREATMENT OF BANANA TREES |
| GB0811079D0 (en) * | 2008-06-17 | 2008-07-23 | Syngenta Participations Ag | Herbicide formulation |
| CN105028419B (en) * | 2012-08-17 | 2017-06-16 | 陕西美邦农药有限公司 | A kind of bactericidal composition containing Fenarimol |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1569940A (en) * | 1967-04-27 | 1969-06-06 | ||
| FR2140205B1 (en) | 1971-06-04 | 1977-12-23 | Oreal | |
| US3912752A (en) * | 1972-01-11 | 1975-10-14 | Bayer Ag | 1-Substituted-1,2,4-triazoles |
| US3868244A (en) | 1972-03-13 | 1975-02-25 | Lilly Co Eli | Plant growth regulation |
| US3869456A (en) | 1972-03-13 | 1975-03-04 | Lilly Co Eli | Synthesis of 5-pyrimidinecarbinols |
| DE2303757A1 (en) * | 1973-01-26 | 1974-08-15 | Hoechst Ag | Fungicidal wettable powders contg. benzimidazole carbamates - mixed with powdered carrier, penetrating agent, but without emulsifying agents |
| DE2354467C3 (en) * | 1973-10-31 | 1981-07-30 | Hoechst Ag, 6000 Frankfurt | Fungicidal dispersions based on benzimidazole methyl carbamate |
| DE2456627C2 (en) * | 1973-12-14 | 1984-05-10 | PEPRO - Société pour le Développement et la Vente de Spécialités Chimiques, Lyon | Fungicidal agents based on phosphonic acid esters |
| FR2254276B1 (en) * | 1973-12-14 | 1977-03-04 | Philagro Sa | |
| FR2279331A1 (en) * | 1974-07-24 | 1976-02-20 | Hoechst Ag | Fungicidal wettable powders contg. benzimidazole carbamates - mixed with powdered carrier, penetrating agent, but without emulsifying agents |
| DE2560510C2 (en) * | 1975-11-26 | 1989-02-16 | Bayer Ag, 5090 Leverkusen, De |
-
1977
- 1977-03-28 GB GB12972/77A patent/GB1596380A/en not_active Expired
-
1978
- 1978-03-15 IT IT48444/78A patent/IT1105157B/en active
- 1978-03-20 MX MX786944U patent/MX5640E/en unknown
- 1978-03-20 SE SE7803184A patent/SE447783B/en not_active IP Right Cessation
- 1978-03-20 FR FR7807978A patent/FR2390096A1/en active Granted
- 1978-03-20 CA CA299,331A patent/CA1108046A/en not_active Expired
- 1978-03-20 IN IN295/CAL/78A patent/IN147690B/en unknown
- 1978-03-20 PT PT67801A patent/PT67801A/en unknown
- 1978-03-21 GR GR55758A patent/GR64791B/en unknown
- 1978-03-21 ES ES468098A patent/ES468098A1/en not_active Expired
- 1978-03-21 DK DK127978A patent/DK149442C/en not_active IP Right Cessation
- 1978-03-21 IL IL54318A patent/IL54318A/en unknown
- 1978-03-21 AR AR271494A patent/AR227124A1/en active
- 1978-03-21 BR BR7801746A patent/BR7801746A/en unknown
- 1978-03-21 CH CH306178A patent/CH629363A5/en not_active IP Right Cessation
- 1978-03-21 DE DE2858350A patent/DE2858350C2/de not_active Expired
- 1978-03-21 RO RO7899324A patent/RO78274A/en unknown
- 1978-03-21 DE DE2812287A patent/DE2812287C2/en not_active Expired
- 1978-03-21 RO RO7893574A patent/RO73042A/en unknown
- 1978-03-21 RO RO7899325A patent/RO78260A/en unknown
- 1978-03-21 RO RO7899323A patent/RO78273A/en unknown
- 1978-03-22 NL NL7803064A patent/NL7803064A/en not_active Application Discontinuation
- 1978-03-22 BG BG041508A patent/BG30167A4/en unknown
- 1978-03-22 NO NO781040A patent/NO147260C/en unknown
- 1978-03-22 LU LU79285A patent/LU79285A1/en unknown
- 1978-03-22 AT AT203678A patent/AT362195B/en not_active IP Right Cessation
- 1978-03-22 BG BG041507A patent/BG30166A4/en unknown
- 1978-03-22 BG BG039128A patent/BG29863A3/en unknown
- 1978-03-22 AU AU34430/78A patent/AU515204B2/en not_active Expired
- 1978-03-22 BE BE6046404A patent/BE865215A/en not_active IP Right Cessation
- 1978-03-22 BG BG041506A patent/BG30165A4/en unknown
- 1978-03-22 NZ NZ186757A patent/NZ186757A/en unknown
- 1978-03-22 DD DD78204345A patent/DD135031A5/en unknown
- 1978-03-23 HU HU78LI322A patent/HU179506B/en unknown
- 1978-03-23 ZA ZA00781700A patent/ZA781700B/en unknown
- 1978-03-23 TR TR20072A patent/TR20072A/en unknown
- 1978-03-23 HU HU812978A patent/HU188701B/en unknown
- 1978-03-23 IE IE588/78A patent/IE46690B1/en unknown
- 1978-03-24 PL PL1978205555A patent/PL108903B1/en unknown
- 1978-03-24 SU SU782594402A patent/SU1409119A3/en active
- 1978-03-24 CS CS781922A patent/CS198289B2/en unknown
- 1978-03-24 CS CS789184A patent/CS198291B2/en unknown
- 1978-03-24 CS CS789185A patent/CS198292B2/en unknown
- 1978-03-24 CS CS789183A patent/CS198290B2/en unknown
- 1978-03-24 PL PL1978216610A patent/PL112146B1/en unknown
- 1978-03-24 PL PL1978216611A patent/PL112622B1/en unknown
- 1978-03-24 JP JP3402678A patent/JPS53121932A/en active Granted
- 1978-03-24 PL PL1978216612A patent/PL112286B1/en unknown
- 1978-09-08 FR FR7825894A patent/FR2390098A1/en active Granted
- 1978-09-08 FR FR7825893A patent/FR2390097A1/en active Granted
- 1978-09-08 FR FR7825895A patent/FR2390099B1/fr not_active Expired
-
1981
- 1981-02-02 AR AR284171A patent/AR225793A1/en active
-
1982
- 1982-05-07 NO NO821512A patent/NO148622C/en unknown
- 1982-05-07 NO NO821514A patent/NO148621C/en unknown
- 1982-05-07 NO NO821513A patent/NO148241C/en unknown
-
1983
- 1983-03-23 SE SE8301606A patent/SE454398B/en not_active IP Right Cessation
-
1986
- 1986-05-30 SE SE8602470A patent/SE8602470L/en not_active Application Discontinuation
-
1987
- 1987-08-19 SE SE8703223A patent/SE8703223D0/en not_active Application Discontinuation
- 1987-08-19 SE SE8703224A patent/SE8703224D0/en not_active Application Discontinuation
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