GB1561636A - Herbicidal combinations - Google Patents

Herbicidal combinations Download PDF

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Publication number
GB1561636A
GB1561636A GB45160/75A GB4616075A GB1561636A GB 1561636 A GB1561636 A GB 1561636A GB 45160/75 A GB45160/75 A GB 45160/75A GB 4616075 A GB4616075 A GB 4616075A GB 1561636 A GB1561636 A GB 1561636A
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United Kingdom
Prior art keywords
composition according
urea
weight
triazine
active ingredients
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
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GB45160/75A
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Lilly Industries Ltd
Original Assignee
Lilly Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lilly Industries Ltd filed Critical Lilly Industries Ltd
Priority to GB45160/75A priority Critical patent/GB1561636A/en
Priority to CA000264102A priority patent/CA1156851A/en
Priority to IT51972/76A priority patent/IT1080520B/en
Priority to RO7688275A priority patent/RO70593A/en
Priority to NZ182485A priority patent/NZ182485A/en
Priority to SE7612198A priority patent/SE7612198L/en
Priority to NL7612126A priority patent/NL7612126A/en
Priority to AR265311A priority patent/AR218231A1/en
Priority to DD7600195559A priority patent/DD127723A5/en
Priority to IL50818A priority patent/IL50818A/en
Priority to GR52065A priority patent/GR61714B/en
Priority to CH1377376A priority patent/CH601989A5/xx
Priority to IE2446/76A priority patent/IE44547B1/en
Priority to DE19762650362 priority patent/DE2650362A1/en
Priority to PT65792A priority patent/PT65792B/en
Priority to BR7607372A priority patent/BR7607372A/en
Priority to ZA766626A priority patent/ZA766626B/en
Priority to MX765049U priority patent/MX4486E/en
Priority to CS767122A priority patent/CS188295B2/en
Priority to SU762416205A priority patent/SU694046A3/en
Priority to HU76LI301A priority patent/HU176128B/en
Priority to FR7633228A priority patent/FR2330320A1/en
Priority to DK498876A priority patent/DK498876A/en
Priority to BG7634618A priority patent/BG27529A3/en
Priority to AT823576A priority patent/AT353545B/en
Priority to ES453080A priority patent/ES453080A1/en
Priority to BE6045751A priority patent/BE848080A/en
Priority to AU19365/76A priority patent/AU506364B2/en
Priority to OA55973A priority patent/OA05472A/en
Priority to PL1976193491A priority patent/PL101274B1/en
Priority to JP51133120A priority patent/JPS5261228A/en
Priority to EG684/76A priority patent/EG12382A/en
Publication of GB1561636A publication Critical patent/GB1561636A/en
Expired legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • A01N25/14—Powders or granules wettable
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Toxicology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)

Description

(54) HERBICIDAL COMBINATIONS (71) We, LILLY INDUSTRIES LIMITED, a British company of Henrietta House, Henrietta Place, London, W.1., do hereby declare the invention, for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement: The present invention relates to novel herbicidal combinations, to herbicidal formulations containing the novel combinations and to methods of controlling weeds in areas of sugar cane growth with said combinations and formulations or by treatment of said weeds separately with the components of said com- bination.
According to the present invention there is provided a herbicidal composition which com- prises, as active ingredients, a thiadiazolyl urea of formula Q:
wherein R is trifluoromethyl, t - butyl or ethylsulphonyl; and 2 - chloro - 4 - ethylamino - 6 - isopropylamino - 1,3,5 - triazine.
The thiadiazolyl ureas of formula {I) are known compounds which may, for example, be prepared by processes as described in U.K.
Patent Specification No. 1,266,172. The com- pound 2 - chloro - 4 - ethylamino - 6 - iso propylarnino - 1,3,5 - triazine is also a known compound and has been given the non-proprietary name "Atrazine".
At this point it should be noted that the compound of formula (I) where R is t - butyl, i.e. 1- (5 - tert - butyl - 1,3,4 - thiadiazol 2 - yl) - 1,3 - dimethylurea, is the compound of choice for use in the combinations, formulations and methods of the present invention.
The ratio of the amount of the thiadiazolyl urea to the 2 - chloro - 4 - ethylamino - 6 isopropylamino - 1,3,5 - triazine is not critical; however, it is preferred to combine the com- pounds at weight ratios in the range of from 1:10 to 10:1, more preferably from 1:5 to 5:1 and most preferably from 1:3 to 3:1.
As indicated above, it has surprisingly been found that the combinations of the invention are particularly effective in the control of weeds in land where sugar cane is growing. The thiadiazolyl urea and the triazine are preferably applied simultaneously in the form ot a com- bination but in some cases sequential application of the components of the combination may be effected. Such sequential application should be effected within a short period of time.
Whether sequential or simultaneous application is carried out, from 0.5 to 2.5, preferably 0.75 to 1.5, kg/hectare of the urea and from 0.5 to 5, preferably from 1 to 2, kg/hectare of the triazine are generally applied to the land to be treated.
The compositions of the invention will normally be utilised in the form of a herbicidal formulation, the active ingredients being associated with one or more non-phytotoxic carrivers. Such formulations, as well as methods of preparing the compositions and formulations comprising admixing the ingredients, form further aspects of the invention.
One formulation according to the present invention which may be mentioned is an aqueous suspension which can be sprayed onto the area to be treated. Such a formulation may be prepared by mixing the active ingredients in a spray tank just prior to use or more preferably the two active ingredients are formulated together in the desired proportions and this formulation may then merely be diluted prior to use. Such an aqueous formulation will generally comprise from 0.005 to 2.5%, preferably from 0.1 to 1%, by weight of the urea and from 0.005 to 5, preferably from 0.1 to 2% by weight of the triazine.
As stated above, the diluted formulations of the present invention may be produced by mixing the active ingredients just prior to use or by diluting a ready-prepared co-formulation of the two active ingredients. In the former case, the active ingredients will usually be in the form of concentrate compositions so formulated as to be capable of ready dispersion in water. Generally, any appropriate concentrate compositions may be used and will contain from about 1 to 90% by weight of the individual active ingredients.
In the case where the active ingredients are formulated together in concentrate compositions, the latter are novel and form a part of this invention. Such concentrates will normally contain from 5 to 90% total weight of the active ingredients.
The concentrate compositions of the present invention normally comprise the active ingredients in the above stated amounts, one or more non-phytotoxic carriers and optionally one or more surfactants, thickening agents, antifreezing agents and preservatives. The concentrates may be solids usually known as wettable powders, or liquids which may be aqueous suspensions.
Wettable powders comprise an intimate mixture of the active ingredients, one or more non-phytotoxic carriers and appropriate surfactants. The carrier may be chosen from the attapulgite clays, the montmorillonite clays, The diatomaceous earths, kaolins, micas, talcs and purified silicates. Effective surfactants may be found among the sulfonated lignins, the naphthalene sulfonates and condensed naphthalene sulfonates, the alkyl succinates, the alkylbenzene sulfonates, the alkyl sulfates and nonionic surfactants such as ethylene oxide adducts of phenol. Wettable powder formulations falling within the scope of the invention typically contain: % by weight Thiadiazolyl urea 10160 Atrazine 20--60 Surfactant(s) 1-7 Dispersing agent 1-7 Anti-caking agent 0-10 Solid Carrier to 100 The total amount of active ingredients, i.e.
urea and atrazine, should not exceed 90%.
Aqueous suspensions comprise the active ingredients suspended in water together with any desired surfactants, thickening agents, antifreezing agents or preservatives. Suitable surfactants may be chosen from those mentioned above in connection with wettable powders.
Thickening agents, if used, are normally chosen from appropriate cellulose materials and natural gums whilst glycols will generally be used when an antifreezing agent is required.
Preservatives may be chosen from a wide range of materials such as the various paraben antibacterials, phenol, o-chlorocresol, phenyl mercuric nitrate and formaldehyde. Aqueous suspensions falling within the scope of the invention typically contain: % weight/ volume: Thiadiazoylyl urea 5-30 Atrazine 10-30 Surfactant(s) 1-5 Thickening agent 0-2 Antifreezing agent 0-10 Preservative 0-2 Water (Carrier) to 100 Alternatively, it may be desired to apply the novel combination of the invention in the form of a granular formulation. Such a formulation typically comprises the active ingredients dispersed on a granular carrier such as coarsely ground clay. The particle size of granules usually ranges from about 0.1 to about 3 mm.
The usual formulation process for granules comprises dissolving the compound in an inexpensive solvent and applying the solution to the carrier in an appropriate solids mixer.
Somewhat less economically, the compound may be dispersed in a dough composed of damp clay or other carrier, which is then dried and coarsely ground to produce the desired granular product.
Although of much less importance, the coformulations of the present invention may also take the form of emulsifiable concentrates.
The following non-limitative examples will further illustrate the invention. In each case the urea which was utilised was 1 - (5 - tert butyl - 1,3,4 - thiadiazol - 2 - yl) - ],3 -di- methylurea; however, it will be appreciated that this urea may be replaced by its 5 - trifluoromethyl and 5 - ethylsulphonyl analogues without detriment EXAMPLE 1 This is an example of a wettable powder according to the invention: % by weight Urea 30 Atrazine 45 Sodium lauryl sulphate 5 Sodium lignin sulfonate 3 Silica 8 China clay to 100 The active ingredients were milled and then blended with the other ingredients in conventional mixing equipment. The blend was then milled in a fluid energy mill to a size range of from 1 to 10 microns and finally the mixture reblended and deaerated prior to being packaged.
Similarly, the following wettable powders were prepared: EXAMPLE 2 % by weight Urea 10 Atrazine 20 Sodium lauryl sulfate 4 Sodium lignin sulfonate 2 Kaolin to 100 EXAMPLE 3 % by weight Urea 30 Atrazine 30 Sodium alkyl succinate 6 Mica 5 China clay to 100 EXAMPLE 4 % by weight Urea 30 Atrazine 55 Sodium lignin sulfonate 4 Sodium succinate 2 Silica 2 China clay to 100 EXAMPLE 5 /O by weight Urea 30 Atrazine 40 Sodium lauryl sulfate 7 Silica 8 China clay to 100 EXAMPLE 6 The following is an example of an aqueous suspension according to the invention.
% by weight/ volume Urea 15 Atrazine 25 Sodium naphthalene sulfonate 4 Sodium lauryl sulfate 1 Xanthangum 0.2 Phenol 0.5 Water to 100 Both active ingredients, size reduced by conventional means, if necessary, were dispersed in water containing the surfactant system, preservative and part of the thickening agent Particle size was further reduced by liquid milling, the balance of the thickening agent added, allowed to hydrate and the product diluted to volume with water.
Similarly, the following aqueous concentrates were prepared: EXAMPLE 7 % weight/ volume Urea 20 Atriazine 30 Non-ionic surfactant 2 Xanthan gum 0.2 Ethylene glycol 8 Phenol 0.5 Water to 100 EXAMPLE 8 O/o weighty volurne Urea 5 Atrazine 10 Sodium naphthalene sulfonate 3 Sodium lignin sulfonate 2 Ethylene glycol 4 Phenol 0.5 Gum Arabic Water to 100 EXAMPLE 9 A wettable powder having the following ingredients was prepared using a similar method to that described in Example 1.
% weight/ volume Urea 25 Atrazine 50 "Micronised" (Registered Trade Mark) Silica gel 7.5 Alkyl polyethoxyethanol 5 Sodium alkylnaphthalene sulphonateformaldehyde condensate 2.0 Talc to 100 As can be seen from the above description, the concentrate formulations of the present invention are prepared by the conventional method of mixing the active ingredients in the desired proportions with an appropriate inert carrier and such a method. forms a part of this invention.
WHAT WE CLAIM IS: 1. A herbicidal composition which com- prises, as active ingredients, a thiadiazolyl urea of formula (I)
wherein R is trifluoromethyl, t - butyl or ethylsulphonyl, and 2 - chloro - 4 - ethylamino 6 - isopropylamino, 1,3,5 - triazine.
2. A composition according to Claim 1, wherein, in the compound of formula (I), R is t - butyl.
3. A composition according to Claim 1 or Claim 2, in the form of a herbicidal formulation, the active ingredients being associated with one or more non-phytotoxic carriers.
4. A composition according to any preceding claim, wherein the weight ratio of the urea to the triazine is in the range of from 1:10 to 10:1.
5. A composition according to Claim 4, wherein said weight ratio is in the range of from 1:5 to 5:1.
6. A composition according to Claim 5, wherein said weight ratio is in the range of from 1:3 to 3:1.
7. A composition according to any preceding claim in the form of a concentrate composition and containing from 1 to 90% by weight of the active ingredients.
**WARNING** end of DESC field may overlap start of CLMS **.

Claims (27)

**WARNING** start of CLMS field may overlap end of DESC **. EXAMPLE 3 % by weight Urea 30 Atrazine 30 Sodium alkyl succinate 6 Mica 5 China clay to 100 EXAMPLE 4 % by weight Urea 30 Atrazine 55 Sodium lignin sulfonate 4 Sodium succinate 2 Silica 2 China clay to 100 EXAMPLE 5 /O by weight Urea 30 Atrazine 40 Sodium lauryl sulfate 7 Silica 8 China clay to 100 EXAMPLE 6 The following is an example of an aqueous suspension according to the invention. % by weight/ volume Urea 15 Atrazine 25 Sodium naphthalene sulfonate 4 Sodium lauryl sulfate 1 Xanthangum 0.2 Phenol 0.5 Water to 100 Both active ingredients, size reduced by conventional means, if necessary, were dispersed in water containing the surfactant system, preservative and part of the thickening agent Particle size was further reduced by liquid milling, the balance of the thickening agent added, allowed to hydrate and the product diluted to volume with water. Similarly, the following aqueous concentrates were prepared: EXAMPLE 7 % weight/ volume Urea 20 Atriazine 30 Non-ionic surfactant 2 Xanthan gum 0.2 Ethylene glycol 8 Phenol 0.5 Water to 100 EXAMPLE 8 O/o weighty volurne Urea 5 Atrazine 10 Sodium naphthalene sulfonate 3 Sodium lignin sulfonate 2 Ethylene glycol 4 Phenol 0.5 Gum Arabic Water to 100 EXAMPLE 9 A wettable powder having the following ingredients was prepared using a similar method to that described in Example 1. % weight/ volume Urea 25 Atrazine 50 "Micronised" (Registered Trade Mark) Silica gel 7.5 Alkyl polyethoxyethanol 5 Sodium alkylnaphthalene sulphonateformaldehyde condensate 2.0 Talc to 100 As can be seen from the above description, the concentrate formulations of the present invention are prepared by the conventional method of mixing the active ingredients in the desired proportions with an appropriate inert carrier and such a method. forms a part of this invention. WHAT WE CLAIM IS:
1. A herbicidal composition which com- prises, as active ingredients, a thiadiazolyl urea of formula (I)
wherein R is trifluoromethyl, t - butyl or ethylsulphonyl, and 2 - chloro - 4 - ethylamino 6 - isopropylamino, 1,3,5 - triazine.
2. A composition according to Claim 1, wherein, in the compound of formula (I), R is t - butyl.
3. A composition according to Claim 1 or Claim 2, in the form of a herbicidal formulation, the active ingredients being associated with one or more non-phytotoxic carriers.
4. A composition according to any preceding claim, wherein the weight ratio of the urea to the triazine is in the range of from 1:10 to 10:1.
5. A composition according to Claim 4, wherein said weight ratio is in the range of from 1:5 to 5:1.
6. A composition according to Claim 5, wherein said weight ratio is in the range of from 1:3 to 3:1.
7. A composition according to any preceding claim in the form of a concentrate composition and containing from 1 to 90% by weight of the active ingredients.
8. A composition according to Claim 7, con
taining from 5 to 90% by weight of the active ingredients.
9. A composition according to any one of Claims 1 to 6 in the form of an aqueous formulation and comprising from 0.005 to 2.50,; by weight of the urea and from 0.005 to 5% by weight of the triazine.
10. A composition according to Claim 9 and comprising from 0.1 to 1% by weight of the urea and from 0.1 to 2% by weight of the triazine.
11. A composition according to any one of Claims 1 to 8 in the form of a wettable powder.
12. A composition according to Claim 11 and containing 10-60% of the urea, 20 60 /O of the triazine, 17% surfactant, 17% dispersing agent, 010% anti-caking agent, the balance being carrier, the total amount of the urea and triazine not exceeding 90% and the percentages being by weight
13. A composition according to any one of claims 1 to 8 in the form of an aqueous suspension.
14. A composition according to Claim 13 and containing 5-30% of the urea, 1030% of the triazine, 15% surfactant, 0 > 2% thickening agent, 0-10% antifreezing agent, 0--2% preservative, the balance being water, the percentages being weight/volume.
15. A composition according to any one of claims 1 to 8, in the form of a granular formulation.
16. A composition according to Claim 15, wherein the active ingredients are dispersed on or in a granular inert carrier.
17. A composition according to Claim 16 having a particle size in the range of from 0.1 to 3 mm.
18. A composition according to any one of claims 1 to 8, in the form of an emulsifiable concentrate.
19. A composition according to Claim 1, substantially as hereinbefore described with reference to any one of the foregoing Examples 1 to 9.
20. A method of preparing a herbicidal composition according to any one of the proceding claims which comprises admixing the ingredients.
21. A method according to Claim 20, substantially as hereinbefore described, with reference to any one of the foregoing Examples 1 to 9.
22. A composition according to Claim 1, whenever prepared by a method according to Claim 20 or 21.
23. A method of controlling weeds in an area of land where sugar cane is growing which comprises applying to said area a urea of formula (I), stated in Claim 1, and 2 chloro - 4 - ethylamino - 6 - isopropylamino 1,3,5 - triazine, the compounds being applied simultaneously or sequentially.
24. A method according to Claim 23, wherein the urea is applied at a rate of from 0.5 to 2.5 kg/hectare and the triazine at a rate of from 0.5 to 5 kg/hectare.
25. A method according to Claim 24, wherein the urea is applied at a rate of from 0.75 to 1.5 kg/hectare and the triazine at a rate of from 1 to 2 kg/hectare.
26. A method according to any one of Claims 23 to 25 wherein there is applied to the area a composition according to any of claims 1 to 19 or 22 or a diluted form of a composition according to said claims, as appropriate.
27. A method according to Claim 23 substantially as hereinbefore described.
GB45160/75A 1975-11-07 1975-11-07 Herbicidal combinations Expired GB1561636A (en)

Priority Applications (32)

Application Number Priority Date Filing Date Title
GB45160/75A GB1561636A (en) 1975-11-07 1975-11-07 Herbicidal combinations
CA000264102A CA1156851A (en) 1975-11-07 1976-10-25 Herbicidal combinations
IT51972/76A IT1080520B (en) 1975-11-07 1976-10-29 TANK COMPOSITION USEFUL IN PARTICULAR TO PROTECT SUGAR CANE PLANTS FROM WEEDS
RO7688275A RO70593A (en) 1975-11-07 1976-11-01 SINERGETIC HERBICIDE COMPOSITION
NZ182485A NZ182485A (en) 1975-11-07 1976-11-01 Herbicidal composition comprising 1-(5-t-butyl-1,3,4-thiadiazol-2-yl)-1,3-dimethylurea and 2-chloro-4-ethylamino-6 isopropylamino-1,3,5-triazine
SE7612198A SE7612198L (en) 1975-11-07 1976-11-02 HERBICIDE
NL7612126A NL7612126A (en) 1975-11-07 1976-11-02 PROCESS FOR THE PREPARATION OF A HERBICIDE AND HERBICIDE.
AR265311A AR218231A1 (en) 1975-11-07 1976-11-02 HERBICIDE COMPOSITION BASED ON 2-CHLORINE-4-ETHYLAMINE-6-ISOPROPYLAMINE-1,3,5, -TRIAZINE AND TIADIAZOLILUREA, EFFECTED BY SYNERGISM
DD7600195559A DD127723A5 (en) 1975-11-07 1976-11-02 HERBICIDES AND METHOD FOR THE PRODUCTION THEREOF
IL50818A IL50818A (en) 1975-11-07 1976-11-02 Synergistic herbicidal compositions comprising tebuthiuron and atrazine
GR52065A GR61714B (en) 1975-11-07 1976-11-02 Herbicidal combinations
CH1377376A CH601989A5 (en) 1975-11-07 1976-11-02
IE2446/76A IE44547B1 (en) 1975-11-07 1976-11-03 Herbicidal combinations
DE19762650362 DE2650362A1 (en) 1975-11-07 1976-11-03 HERBICIDAL AGENTS AND METHOD FOR ITS MANUFACTURING
PT65792A PT65792B (en) 1975-11-07 1976-11-03 Process for preparing herbicidal combinations
BR7607372A BR7607372A (en) 1975-11-07 1976-11-04 SYNERGIC HERBICIDE COMPOSITES
ZA766626A ZA766626B (en) 1975-11-07 1976-11-04 Herbicidal combinations
MX765049U MX4486E (en) 1975-11-07 1976-11-04 PROCEDURE FOR THE PREPARATION OF HERBICIDE COMPOSITIONS
CS767122A CS188295B2 (en) 1975-11-07 1976-11-04 Herbicide composition
SU762416205A SU694046A3 (en) 1975-11-07 1976-11-04 Herbicide
HU76LI301A HU176128B (en) 1975-11-07 1976-11-04 Herbicide compositions containing synergetic combinations of 1-bracket-5-terc-butyl-1,2,3-thiadiasol-2-yl-bracket closed-1,3-dimethyl-urea and 2-chloro-4-ethyl-amino-6-isopropyl-amino-1,3,5-triasine as active agents
FR7633228A FR2330320A1 (en) 1975-11-07 1976-11-04 NEW THIADIAZOLYL-UREE-BASED COMPOSITION AND ITS USE AS HERBICIDES
DK498876A DK498876A (en) 1975-11-07 1976-11-04 HERBICIDES
BG7634618A BG27529A3 (en) 1975-11-07 1976-11-05 Herbicide composition
AT823576A AT353545B (en) 1975-11-07 1976-11-05 AGENT TO CONTROL WEED
ES453080A ES453080A1 (en) 1975-11-07 1976-11-05 Herbicidal combinations
BE6045751A BE848080A (en) 1975-11-07 1976-11-05 HERBICIDE COMPOSITIONS,
AU19365/76A AU506364B2 (en) 1975-11-07 1976-11-05 Herbicidal compositions
OA55973A OA05472A (en) 1975-11-07 1976-11-05 Herbicidal compositions.
PL1976193491A PL101274B1 (en) 1975-11-07 1976-11-05 A WORMHOUSE
JP51133120A JPS5261228A (en) 1975-11-07 1976-11-05 Weed killer mixture
EG684/76A EG12382A (en) 1975-11-07 1976-11-06 Herbicidal combinations

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB45160/75A GB1561636A (en) 1975-11-07 1975-11-07 Herbicidal combinations

Publications (1)

Publication Number Publication Date
GB1561636A true GB1561636A (en) 1980-02-27

Family

ID=10440106

Family Applications (1)

Application Number Title Priority Date Filing Date
GB45160/75A Expired GB1561636A (en) 1975-11-07 1975-11-07 Herbicidal combinations

Country Status (32)

Country Link
JP (1) JPS5261228A (en)
AR (1) AR218231A1 (en)
AT (1) AT353545B (en)
AU (1) AU506364B2 (en)
BE (1) BE848080A (en)
BG (1) BG27529A3 (en)
BR (1) BR7607372A (en)
CA (1) CA1156851A (en)
CH (1) CH601989A5 (en)
CS (1) CS188295B2 (en)
DD (1) DD127723A5 (en)
DE (1) DE2650362A1 (en)
DK (1) DK498876A (en)
EG (1) EG12382A (en)
ES (1) ES453080A1 (en)
FR (1) FR2330320A1 (en)
GB (1) GB1561636A (en)
GR (1) GR61714B (en)
HU (1) HU176128B (en)
IE (1) IE44547B1 (en)
IL (1) IL50818A (en)
IT (1) IT1080520B (en)
MX (1) MX4486E (en)
NL (1) NL7612126A (en)
NZ (1) NZ182485A (en)
OA (1) OA05472A (en)
PL (1) PL101274B1 (en)
PT (1) PT65792B (en)
RO (1) RO70593A (en)
SE (1) SE7612198L (en)
SU (1) SU694046A3 (en)
ZA (1) ZA766626B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA775225B (en) * 1977-08-29 1978-03-29 Lilly Co Eli Herbicidal combinations
JPS5995208A (en) * 1982-11-25 1984-06-01 Japan Carlit Co Ltd:The Herbicide composition

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH488723A (en) * 1967-12-27 1970-04-15 Agripat Sa Process for the production of thiadiazolyl ureas
GB1266172A (en) * 1968-03-13 1972-03-08
DE1770467A1 (en) * 1968-05-22 1971-11-04 Bayer Ag 1,3,4-thiadiazolyl ureas
CH513585A (en) * 1969-07-18 1971-10-15 Agripat Sa Thiadiazolyl (2)- ureas prodn
CA931961A (en) * 1970-04-17 1973-08-14 Gulf Research And Development Company Combating unwanted vegetation with 1,3,4-thiadiazolylureas
DE2028778A1 (en) * 1970-06-06 1971-12-23 Thiadiazolyl-urea herbicides - 5 - substd by sulphinyl or sulphonyl
DE2044442C2 (en) * 1970-09-03 1983-11-03 Schering AG, 1000 Berlin und 4709 Bergkamen 1,1,3-Trimethyl-3 - (- 5-Ethylsulfonyl-1,3,4-Thiadiazol-2-yl) -urea with herbicidal action
GB1439501A (en) * 1972-08-14 1976-06-16 Air Prod & Chem Herbicidal compositions and method of use
LU66864A1 (en) * 1973-01-19 1974-08-19

Also Published As

Publication number Publication date
JPS5261228A (en) 1977-05-20
BE848080A (en) 1977-05-05
PT65792A (en) 1976-12-01
BG27529A3 (en) 1979-11-12
DE2650362A1 (en) 1977-05-26
IT1080520B (en) 1985-05-16
IL50818A (en) 1980-11-30
OA05472A (en) 1981-03-31
GR61714B (en) 1978-12-28
IE44547B1 (en) 1981-12-30
HU176128B (en) 1980-12-28
NZ182485A (en) 1980-03-05
RO70593A (en) 1980-08-15
EG12382A (en) 1979-03-31
ATA823576A (en) 1979-04-15
CA1156851A (en) 1983-11-15
IL50818A0 (en) 1977-01-31
SE7612198L (en) 1977-05-08
FR2330320A1 (en) 1977-06-03
FR2330320B1 (en) 1980-09-12
CH601989A5 (en) 1978-07-14
PT65792B (en) 1977-04-26
NL7612126A (en) 1977-05-10
MX4486E (en) 1982-05-21
ES453080A1 (en) 1978-03-01
AU506364B2 (en) 1979-12-20
DD127723A5 (en) 1977-10-12
IE44547L (en) 1977-05-07
PL101274B1 (en) 1978-12-30
BR7607372A (en) 1977-09-20
SU694046A3 (en) 1979-10-25
AR218231A1 (en) 1980-05-30
CS188295B2 (en) 1979-02-28
AT353545B (en) 1979-11-26
DK498876A (en) 1977-05-08
ZA766626B (en) 1977-10-26
AU1936576A (en) 1978-05-11

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
704A Declaration that licence is not available as of right for an excepted use (par. 4a/1977)
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19941108