CS198289B2 - Fungicide - Google Patents
Fungicide Download PDFInfo
- Publication number
- CS198289B2 CS198289B2 CS781922A CS192278A CS198289B2 CS 198289 B2 CS198289 B2 CS 198289B2 CS 781922 A CS781922 A CS 781922A CS 192278 A CS192278 A CS 192278A CS 198289 B2 CS198289 B2 CS 198289B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- formula
- compound
- compounds
- fungicidal composition
- active ingredients
- Prior art date
Links
- 230000000855 fungicidal effect Effects 0.000 title claims abstract description 8
- 239000000417 fungicide Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 17
- -1 pyrimidine compound Chemical class 0.000 claims abstract description 4
- 239000004480 active ingredient Substances 0.000 claims description 12
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 229910052731 fluorine Chemical group 0.000 claims description 4
- 125000001153 fluoro group Chemical group F* 0.000 claims description 4
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 3
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 claims description 2
- 231100001184 nonphytotoxic Toxicity 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 16
- 235000013339 cereals Nutrition 0.000 abstract description 5
- 239000000969 carrier Substances 0.000 abstract description 3
- 239000000546 pharmaceutical excipient Substances 0.000 abstract description 2
- 241000221785 Erysiphales Species 0.000 abstract 1
- 241000233679 Peronosporaceae Species 0.000 abstract 1
- 159000000013 aluminium salts Chemical class 0.000 abstract 1
- 229910000329 aluminium sulfate Inorganic materials 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- ZUNGGJHBMLMRFJ-UHFFFAOYSA-O ethoxy-hydroxy-oxophosphanium Chemical compound CCO[P+](O)=O ZUNGGJHBMLMRFJ-UHFFFAOYSA-O 0.000 abstract 1
- 230000003449 preventive effect Effects 0.000 abstract 1
- 150000003852 triazoles Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000007900 aqueous suspension Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 208000031888 Mycoses Diseases 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 206010017533 Fungal infection Diseases 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000007798 antifreeze agent Substances 0.000 description 2
- HVFLCNVBZFFHBT-ZKDACBOMSA-N cefepime Chemical compound S([C@@H]1[C@@H](C(N1C=1C([O-])=O)=O)NC(=O)\C(=N/OC)C=2N=C(N)SC=2)CC=1C[N+]1(C)CCCC1 HVFLCNVBZFFHBT-ZKDACBOMSA-N 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 108010053481 Antifreeze Proteins Proteins 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 244000309466 calf Species 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 208000032625 disorder of ear Diseases 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 235000019357 lignosulphonate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- FPJQWFBQXIKMMP-UHFFFAOYSA-N phenyl nitrate Chemical compound [O-][N+](=O)OC1=CC=CC=C1 FPJQWFBQXIKMMP-UHFFFAOYSA-N 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Abstract
Description
Vynález se týká fungicidního prostředku.The invention relates to a fungicidal composition.
Podstata fungicidního prostředku podle vynálezu je v tom, že jako jednu fungicídně účinnou složku obsahuje pyrimidinovou sloučeninu obecného vzorce IThe fungicidal composition according to the invention is characterized in that it contains as a fungicidally active ingredient a pyrimidine compound of the formula I
/I/, kde X značí atom chloru nebo atom fluoru, a jako druhou fungicídně účinnou složku obsahuje benzimidazol vzorce II(I) wherein X represents a chlorine atom or a fluorine atom and contains, as a second fungicidally active ingredient, a benzimidazole of the formula II
OO
C-NH-é-OCHj /II/, v kombinaci tvoří 0,5 až 90 % 1:1 až 1:25.C-NH-6-OCH3 (II), in combination, 0.5 to 90% 1: 1 to 1:25.
Výše uvedené ratury. Kombinace zjištěno, že jsou s alespoň jedním netečným nefуtotoxickým nosičem, hmotnostních fungicidního prostředku a jsou přičemž účinné látky I а II přítomny v hmotnostním poměru sloučeniny jsou známé a lze je připravovat metodami dobře známými z liteúčinných složek, vymezených ve výše uvedeném prostředku , jsou nové a bylo překvapivě účinné při potlačování nebo při boji protí houbovým infekcímThe above-mentioned ratures. The combinations have been found to be with at least one inert non-fungotoxic carrier, the weight of the fungicidal composition and wherein the active ingredients I and II present in the weight ratio of the compound are known and can be prepared by methods well known from the active ingredients defined in the above composition. surprisingly, it was effective in suppressing or fighting fungal infections
28 9 pěstovaných rostlin, přičemž kombinace sloučeniny vzorce I a sloučeniny vzorce II jsou obzvláště cenné při léčeni chorob obilí, jako je prašná plíseň, hniloba patky a jiné choroby listů a klasů, pootihující obilniny ve Btadiu- zrání.The combination of a compound of formula I and a compound of formula II are of particular value in the treatment of cereal diseases such as dusty fungus, heel rot, and other leaf and ear diseases affecting cereals in the Badadia maturation.
Prostředek podle vynálezu se výhodně aplikuje na listy v období po vzejjtí obblí až do sklizně, přičemž mnnžství a četnost aplikace je dána závažnooti nebo očekávanou závažnnotí plíeňové choroby. Chharateeistcekým znakem vynálezu a zvláštní .výhodou vyppývající z používání výše uvedených ^тЬ^ес! je snížená četnost ošetření, postačuuící k dosaženi. účinku, čímž se dosáhne značného snížení pracovních nákladů.The composition of the invention is preferably applied to the leaves in the post-harvest period until harvest, the amount and frequency of application being determined by the severity or expected severity of the fungal disease. The characteristic feature of the invention and the particular advantage resulting from the use of the above-mentioned features. is the reduced frequency of treatment sufficient to achieve. effect, resulting in a significant reduction in labor costs.
Výhodný pyrimidin pro ošetřování obilnin je ten, kde X značí atom fluoruj má přednost pro pouužtí ve tpojjtoati s plísňovýoi infekcemi obilnin.A preferred pyrimidine for the treatment of cereals is that wherein X is a fluorine atom is preferred for use in fungal infections of cereal.
Složky prostředku podle vynálezu lze aplikovat na ošetřovanou rostlinu po sobě nebo současné, přičemž poslednímu způsobu se dává přednoot. Sloučeniny obecného vzorce I se aplikují s výhodou v mnoUství 10 až 100 g, nejvýhodnOji .10 až 30 g na hektar, zatímco sloučeniny vzorce II se aplikují s výhodou v mnnUství od 100 do 3 000 g na hektar. Poměr sloučenin vzorce I ke sloučeninám vzorce II v ^ιΟΐηηεί^ podle vynálezu se tedy může pohybovat od 5:1 do 1:300, vyjádřeno ^©ono^né. Výhodný ^©onno^! poměr sloučeniny vzorce I ke sloučenině vzorce II je mezi 1:1 a 1:25 při pouUžtí 20 až 100 g na hektar sloučeniny, přičemž lze pouUít 100 až 500 g na hektar sloučeniny vzorce II.The components of the composition of the invention can be applied to the plant to be treated sequentially or concurrently, with the last method giving a pre-root. The compounds of the formula I are preferably applied in an amount of 10 to 100 g, most preferably 10 to 30 g per hectare, whereas the compounds of the formula II are preferably applied in a quantity of 100 to 3000 g per hectare. Accordingly, the ratio of the compounds of formula I to the compounds of formula II in the present invention may range from 5: 1 to 1: 300, expressed as a result. Preferred? the ratio of the compound of formula I to the compound of formula II is between 1: 1 and 1:25 using 20 to 100 g per hectare of compound, whereby 100 to 500 g per hectare of compound of formula II can be used.
Za účelem zjednodušení výroby, skladování a transportu se kombinace sloučenin vzorce I a sloučenin . vzorce II obvykle vyráb^í ve formě koncentrátu určeného k ředění vodou na požadovanou koncceOtacc. Takové koncentrované prostředky mohou obsahovat 0,5 až 90 Z, s výhodou 5 až 90 Z hmoo, aktivních složek, doplněných jedním nebo více netečnými oefytotoxickými nosiči. Takové prostředky budou obvykle ve formě smádčtelného prášku, popraše nebo vodné suspenze .Končentráty jsou určeny pro přiměřené ředěni vodou před použitím. Vodné disperze lze připravovat v obvyklých rozprašovacích tancích vhodných k tomuto účelu.In order to simplify production, storage and transport, a combination of compounds of formula I and compounds is used. of formula (II) is usually prepared in the form of a concentrate to be diluted with water at the desired end. Such concentrated formulations may contain from 0.5 to 90 Z, preferably 5 to 90 Z, of the active ingredients, supplemented with one or more inert, ophytotoxic carriers. Such compositions will generally be in the form of a wettable powder, dust, or aqueous suspension. The concentrates are intended to be appropriately diluted with water prior to use. Aqueous dispersions can be prepared in conventional spray tanks suitable for this purpose.
Smááčtelné prášky nebo popraše obsahnuí dokonalou směs aktivních . složek, jeden nebo více netečných nosičů a vhodné povrchově aktivní látky. Netečný nosič lze voUt z cttcpulgttoaých hlinek, moontori lionitových hlinek, infusoriových hlinek, kaolinů, . slíd, telků a čištěných silikátů. Účinné povrchově aktivní látky lze nalézt mozi sulfonoaanými ligniny, oajtdlrotulfooáty a kondenzovanými nadtaleosulfooáty, cltylsutcioáty, cltylirneennuUfooáty, ty a neiionogenníoi povrchově aktivními látkami, například ethylenoxddovýoi adukty fenolu. Pro názornost jsou dále uvedeny soááčteloé prášky speddajcí do rozsahu vynálezu, oscící náslLeduuící složení:Wettable powders or dusts contain a perfect blend of active. components, one or more inert carriers and suitable surfactants. The inert carrier can be selected from carbonaceous earths, lionite earths, diatomaceous earths, diatomaceous earths, kaolins, and the like. mica, calves and purified silicates. The active surfactants can be found by sulfonated lignins, oxotrotulfoates and condensed superthalosulfoates, clthyl sulfonates, clthylinene surfactants, and nonionic surfactants such as ethylene oxide adducts of phenol. For the sake of clarity, the following powders are included within the scope of the invention and are as follows:
STnOččieloé práškySTnOčceloé powders
Z hmoUnoutních sloučenina vzorce I sloučenina vzorce II sošáčedo/c/ disperzní čiotdlu protispékcvé činidlo oetečoý/é/oo8sč/e/Of the compounds of formula (I), the compound of formula (II) is a drying agent (c) a dispersing agent and an anti-caking agent (s).
0,25 až 10,00.25 to 10.0
10,00 až 80,010.00 to 80.0
0,00 až 10,00.00 to 10.0
0,00 až 10,0 ,00 až 10,0 do 1000.00 to 10.0, 00 to 10.0 to 100
Vodné suspenze a roztoky obsáhlí aktivní složky suspendované nebo rozpuštěné ve vodě nebo ve vhodných rozpouštědlech spolu s kterými^H požadovanými povrchově aktivními látkami, zchuUtoaaddy, příaadcmi proti zamrzání nebo konzervačními prostředky. Vhodné povrchově aktivní látky mohou být voleny z těch, které byly uvedeny výše v souuvilosti se snááčtelnými prášky. P^užívi-í . se zchuutovadee, volí se obvykle z vhodných celulózových oadeeiálů a přirozených gum, zatímco glykolů se používá obecně jako přísad proti zamrzánO. Koonervační prostředky mohou být vybírány ze široké palety oadtrrálů, například z анГ^ске: er iáloích látek na bázi parabenu, fenolu, o-chlork^i^i^i^lu, dusičnanu fenylTtutnctého a formaldehydu. Typickými příklady vodných suspenzí speddjících do rozsahu vynálezu jsou:Aqueous suspensions and solutions contain the active ingredients suspended or dissolved in water or in suitable solvents together with which of the desired surfactants, flavorants, antifreeze agents or preservatives. Suitable surfactants may be selected from those listed above in conjunction with wettable powders. It is used. with a flavoring agent, it is usually selected from suitable cellulosic oils and natural gums, while glycols are generally used as antifreeze agents. The coonervatives may be selected from a wide variety of oadtrals, for example, from paraben, phenol, o-chlorine, phenyl nitrate and formaldehyde. Typical examples of aqueous suspensions falling within the scope of the invention are:
Vodné suspense /tekuté/Aqueous suspensions (liquid)
............Z, .hmo.t.nn.s.t.ní.ch *............ Z, .hmo.t.nn.s.t.ní.ch *
Zatímco předchozí obecné příklady dostatečně ilustrují odborníkům typy koncentrovaných přípravků používaných v tomto vynálezu, následující neomeeuúící příklady slouží k další ilustraci prostředků podle toho to-.vyná lezu.While the foregoing general examples sufficiently illustrate to those skilled in the art the types of concentrated formulations used in the present invention, the following non-limiting examples serve to further illustrate the compositions accordingly.
Název CCPM” v těchto příkladech značí sloučeninu obecného vzorce I, ve' kterém X značí atom chloru, zatímco příbuzná sloučenina, ve které X značí atom fluoru, je označena písmeny CFPM. Podobně sloučenina vzorce II je označena symbolemIn these examples, the name CCPM refers to a compound of formula I in which X represents a chlorine atom, while a related compound in which X represents a fluorine atom is designated by the letters CFPM. Similarly, the compound of formula II is indicated by the symbol
Příklady provedeníExamples
Byly připraveny nás ledu uící smááitelné prášky:We have prepared ice-cold wettable powders:
Z hmoonootníchFrom hmoonoot
CCPM5,0CCPM5.0
MBC50,0 dioktylsulfosukcinát sodný4,0 ligoiosulfooát sodný1 ,5.MBC50,0 sodium dioctylsulfosuccinate4,0 sodium ligoiosulfooate1,5.
srážený kysličník křemičitý2,5 attapulgit do100,0precipitated silica2,5 attapulgite to100,0
Z hrnoonnotníchZ hrnoonnotních
CFPM3,0CFPM3.0
MBC45,0 alkyloaftaleosulfooát sodný8,0 infuzoriová hlinka6,0 moonomróllonót do100,0MBC45,0 sodium alkyloaphthalosulfooate8,0 diatomaceous earth6,0 moonomrollonot up to100,0
Aktivní složky v každém příkladu byly pečlivě smíchány se specifckkými pomocnými látkami v obvyklém míchacím zařízeni. Směs byla potom dále mleta ve fluidním mlýnu na velikost částic řádu od 1 do 10 a nakonec byla směs znovu promíchána a před balením byla odvzdušněna.The active ingredients in each example were carefully mixed with the specific excipients in a conventional mixer. The mixture was then further milled in a fluid mill to a particle size of the order of 1 to 10 and finally mixed again and vented before packing.
Byly připraveny nás led иuicí vodné suspenze:We prepared ice-cold aqueous suspensions:
> % hmoonn>otních>% hmoonn>
Z hmotnostních propylenglykol 0,15 * voda do 100,0 л Obě aktivní složky s velikosti částic redukovanou obvyklými prostředky, kde to bylo vhodné, byly dispergovány ve vodě obsahující smáčedlo, konzervační prostředek a část zahuŠtovadla. Velikost částic obou aktivních složek byla dále redukována mletím v kapalném stavu, byl přidán zbytek zahuŠtovadla, směs ponechána hydratovat a produkt zředěn vodou na žádaný objem.By weight propylene glycol 0.15 * water to 100.0 [ mu] l Both active ingredients with particle size reduced by conventional means, where appropriate, were dispersed in water containing a wetting agent, preservative and part of the thickener. The particle size of both active ingredients was further reduced by liquid milling, the remainder of the thickener was added, the mixture allowed to hydrate and the product diluted with water to the desired volume.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB12972/77A GB1596380A (en) | 1977-03-28 | 1977-03-28 | Fungicidal combinations |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS198289B2 true CS198289B2 (en) | 1980-05-30 |
Family
ID=10014480
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS789184A CS198291B2 (en) | 1977-03-28 | 1978-03-24 | Fungicide |
| CS789183A CS198290B2 (en) | 1977-03-28 | 1978-03-24 | Fungicide |
| CS781922A CS198289B2 (en) | 1977-03-28 | 1978-03-24 | Fungicide |
| CS789185A CS198292B2 (en) | 1977-03-28 | 1978-03-24 | Fungicide |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS789184A CS198291B2 (en) | 1977-03-28 | 1978-03-24 | Fungicide |
| CS789183A CS198290B2 (en) | 1977-03-28 | 1978-03-24 | Fungicide |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS789185A CS198292B2 (en) | 1977-03-28 | 1978-03-24 | Fungicide |
Country Status (34)
| Country | Link |
|---|---|
| JP (1) | JPS53121932A (en) |
| AR (2) | AR227124A1 (en) |
| AT (1) | AT362195B (en) |
| AU (1) | AU515204B2 (en) |
| BE (1) | BE865215A (en) |
| BG (4) | BG30167A4 (en) |
| BR (1) | BR7801746A (en) |
| CA (1) | CA1108046A (en) |
| CH (1) | CH629363A5 (en) |
| CS (4) | CS198291B2 (en) |
| DD (1) | DD135031A5 (en) |
| DE (2) | DE2812287C2 (en) |
| DK (1) | DK149442C (en) |
| ES (1) | ES468098A1 (en) |
| FR (4) | FR2390096A1 (en) |
| GB (1) | GB1596380A (en) |
| GR (1) | GR64791B (en) |
| HU (2) | HU188701B (en) |
| IE (1) | IE46690B1 (en) |
| IL (1) | IL54318A (en) |
| IN (1) | IN147690B (en) |
| IT (1) | IT1105157B (en) |
| LU (1) | LU79285A1 (en) |
| MX (1) | MX5640E (en) |
| NL (1) | NL7803064A (en) |
| NO (4) | NO147260C (en) |
| NZ (1) | NZ186757A (en) |
| PL (4) | PL112286B1 (en) |
| PT (1) | PT67801A (en) |
| RO (4) | RO73042A (en) |
| SE (5) | SE447783B (en) |
| SU (1) | SU1409119A3 (en) |
| TR (1) | TR20072A (en) |
| ZA (1) | ZA781700B (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2552967A1 (en) * | 1975-11-26 | 1977-06-08 | Bayer Ag | FUNGICIDALS |
| IT1143721B (en) * | 1977-12-01 | 1986-10-22 | Sipcam Spa | FUNGICIDAL COMPOSITION FOR THE FIGHT AGAINST PLANT DISEASES |
| DE2846038A1 (en) * | 1978-10-23 | 1980-05-08 | Basf Ag | 1,2,4-TRIAZOLE DERIVATIVES, THEIR PRODUCTION AND USE |
| DE3208142A1 (en) * | 1982-03-06 | 1983-09-08 | Bayer Ag, 5090 Leverkusen | FUNGICIDAL AGENT |
| FR2524261A1 (en) * | 1982-04-01 | 1983-10-07 | Rhone Poulenc Agrochimie | FENARIMOL FUNGICIDE POWDER COMPOSITION |
| GB8629360D0 (en) * | 1986-12-09 | 1987-01-21 | Sandoz Ltd | Fungicides |
| JPH01167287U (en) * | 1988-05-16 | 1989-11-24 | ||
| DE3818903A1 (en) * | 1988-06-03 | 1989-12-14 | Stama Maschinenfabrik Gmbh | DRILLING AND MILLING PLANT |
| JPH0274094U (en) * | 1988-11-28 | 1990-06-06 | ||
| NZ260462A (en) * | 1994-05-05 | 1996-04-26 | Horticulture & Food Res Inst | Tree treatment and composition comprising phosphorous acid, a bioprecursor or a salt thereof and a triazole |
| FR2732191B1 (en) * | 1995-03-30 | 2000-12-29 | Rhone Poulenc Agrochimie | ANTIFUNGAL TREATMENT OF BANANA TREES |
| GB0811079D0 (en) * | 2008-06-17 | 2008-07-23 | Syngenta Participations Ag | Herbicide formulation |
| CN103583541B (en) * | 2012-08-17 | 2015-11-11 | 陕西美邦农药有限公司 | A kind of bactericidal composition containing pyrimidine alcohol |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1569940A (en) * | 1967-04-27 | 1969-06-06 | ||
| CA1021324A (en) | 1971-06-04 | 1977-11-22 | Gerard Lang | Tinctorial compositions for keratinic fibres and new diaza-merocyanines entering these compositions |
| US3912752A (en) * | 1972-01-11 | 1975-10-14 | Bayer Ag | 1-Substituted-1,2,4-triazoles |
| US3868244A (en) | 1972-03-13 | 1975-02-25 | Lilly Co Eli | Plant growth regulation |
| US3869456A (en) | 1972-03-13 | 1975-03-04 | Lilly Co Eli | Synthesis of 5-pyrimidinecarbinols |
| DE2303757A1 (en) * | 1973-01-26 | 1974-08-15 | Hoechst Ag | Fungicidal wettable powders contg. benzimidazole carbamates - mixed with powdered carrier, penetrating agent, but without emulsifying agents |
| DE2354467C3 (en) * | 1973-10-31 | 1981-07-30 | Hoechst Ag, 6000 Frankfurt | Fungicidal dispersions based on benzimidazole methyl carbamate |
| DE2456627C2 (en) * | 1973-12-14 | 1984-05-10 | PEPRO - Société pour le Développement et la Vente de Spécialités Chimiques, Lyon | Fungicidal agents based on phosphonic acid esters |
| FR2254276B1 (en) * | 1973-12-14 | 1977-03-04 | Philagro Sa | |
| FR2279331A1 (en) * | 1974-07-24 | 1976-02-20 | Hoechst Ag | Fungicidal wettable powders contg. benzimidazole carbamates - mixed with powdered carrier, penetrating agent, but without emulsifying agents |
| DE2552967A1 (en) * | 1975-11-26 | 1977-06-08 | Bayer Ag | FUNGICIDALS |
-
1977
- 1977-03-28 GB GB12972/77A patent/GB1596380A/en not_active Expired
-
1978
- 1978-03-15 IT IT48444/78A patent/IT1105157B/en active
- 1978-03-20 FR FR7807978A patent/FR2390096A1/en active Granted
- 1978-03-20 CA CA299,331A patent/CA1108046A/en not_active Expired
- 1978-03-20 SE SE7803184A patent/SE447783B/en not_active IP Right Cessation
- 1978-03-20 IN IN295/CAL/78A patent/IN147690B/en unknown
- 1978-03-20 MX MX786944U patent/MX5640E/en unknown
- 1978-03-20 PT PT67801A patent/PT67801A/en unknown
- 1978-03-21 BR BR7801746A patent/BR7801746A/en unknown
- 1978-03-21 CH CH306178A patent/CH629363A5/en not_active IP Right Cessation
- 1978-03-21 RO RO7893574A patent/RO73042A/en unknown
- 1978-03-21 DE DE2812287A patent/DE2812287C2/en not_active Expired
- 1978-03-21 DE DE2858350A patent/DE2858350C2/de not_active Expired
- 1978-03-21 DK DK127978A patent/DK149442C/en not_active IP Right Cessation
- 1978-03-21 GR GR55758A patent/GR64791B/en unknown
- 1978-03-21 AR AR271494A patent/AR227124A1/en active
- 1978-03-21 RO RO7899323A patent/RO78273A/en unknown
- 1978-03-21 IL IL54318A patent/IL54318A/en unknown
- 1978-03-21 ES ES468098A patent/ES468098A1/en not_active Expired
- 1978-03-21 RO RO7899325A patent/RO78260A/en unknown
- 1978-03-21 RO RO7899324A patent/RO78274A/en unknown
- 1978-03-22 BG BG041508A patent/BG30167A4/en unknown
- 1978-03-22 LU LU79285A patent/LU79285A1/en unknown
- 1978-03-22 AT AT203678A patent/AT362195B/en not_active IP Right Cessation
- 1978-03-22 BG BG039128A patent/BG29863A3/en unknown
- 1978-03-22 BG BG041506A patent/BG30165A4/en unknown
- 1978-03-22 DD DD78204345A patent/DD135031A5/en unknown
- 1978-03-22 NL NL7803064A patent/NL7803064A/en not_active Application Discontinuation
- 1978-03-22 NO NO781040A patent/NO147260C/en unknown
- 1978-03-22 NZ NZ186757A patent/NZ186757A/en unknown
- 1978-03-22 BE BE6046404A patent/BE865215A/en not_active IP Right Cessation
- 1978-03-22 BG BG041507A patent/BG30166A4/en unknown
- 1978-03-22 AU AU34430/78A patent/AU515204B2/en not_active Expired
- 1978-03-23 IE IE588/78A patent/IE46690B1/en unknown
- 1978-03-23 TR TR20072A patent/TR20072A/en unknown
- 1978-03-23 ZA ZA00781700A patent/ZA781700B/en unknown
- 1978-03-23 HU HU812978A patent/HU188701B/en unknown
- 1978-03-23 HU HU78LI322A patent/HU179506B/en unknown
- 1978-03-24 JP JP3402678A patent/JPS53121932A/en active Granted
- 1978-03-24 PL PL1978216612A patent/PL112286B1/en unknown
- 1978-03-24 SU SU782594402A patent/SU1409119A3/en active
- 1978-03-24 CS CS789184A patent/CS198291B2/en unknown
- 1978-03-24 CS CS789183A patent/CS198290B2/en unknown
- 1978-03-24 PL PL1978216610A patent/PL112146B1/en unknown
- 1978-03-24 CS CS781922A patent/CS198289B2/en unknown
- 1978-03-24 PL PL1978205555A patent/PL108903B1/en unknown
- 1978-03-24 PL PL1978216611A patent/PL112622B1/en unknown
- 1978-03-24 CS CS789185A patent/CS198292B2/en unknown
- 1978-09-08 FR FR7825894A patent/FR2390098A1/en active Granted
- 1978-09-08 FR FR7825895A patent/FR2390099B1/fr not_active Expired
- 1978-09-08 FR FR7825893A patent/FR2390097A1/en active Granted
-
1981
- 1981-02-02 AR AR284171A patent/AR225793A1/en active
-
1982
- 1982-05-07 NO NO821514A patent/NO148621C/en unknown
- 1982-05-07 NO NO821512A patent/NO148622C/en unknown
- 1982-05-07 NO NO821513A patent/NO148241C/en unknown
-
1983
- 1983-03-23 SE SE8301606A patent/SE454398B/en not_active IP Right Cessation
-
1986
- 1986-05-30 SE SE8602470A patent/SE8602470L/en not_active Application Discontinuation
-
1987
- 1987-08-19 SE SE8703224A patent/SE8703224L/en not_active Application Discontinuation
- 1987-08-19 SE SE8703223A patent/SE8703223L/en not_active Application Discontinuation
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CS198289B2 (en) | Fungicide | |
| EP1891856B1 (en) | Herbicidal composition | |
| HUT62756A (en) | Fungicidal and insecticidal composition comprising several active ingredients | |
| JPS62267211A (en) | Herbicidal composition | |
| CS264347B2 (en) | Fungicide | |
| HU194697B (en) | Fungicides comprsing synergistic active substance combination | |
| US20020045631A1 (en) | Enhancement of the efficacy of triazolopyrimidines | |
| HU182868B (en) | Fungicide compositions containing synergistic mixture of triadimefon and chlortalonyl | |
| JP3849040B2 (en) | Plant protectant | |
| JPH04295405A (en) | Acaricede composition | |
| JPS60233005A (en) | Herbicide | |
| CA1089357A (en) | Fungicidal formulations | |
| KR820000731B1 (en) | Fungicidal composition | |
| CS241143B2 (en) | Fungicide | |
| CA1075599A (en) | Fungicidal composition containing pyrimidine methanol | |
| CA1076024A (en) | Fungicidal compositions | |
| EP0443980A1 (en) | Microbicidal agents | |
| US3355352A (en) | Fungicidal composition | |
| IE55535B1 (en) | Fungicidal formulations | |
| CA1178197A (en) | Fungicidal formulations | |
| CS274430B2 (en) | Herbicide | |
| GB2159057A (en) | Horticultural fungicidal formulations | |
| GB2124083A (en) | Fungicidal formulations | |
| PT96171A (en) | PROCESS FOR THE PREPARATION OF A SYNERGIC FUNGICIDE ASSOCIATION BASED ON A MORPHOLIN AND A TRIAZOL | |
| DE2617163A1 (en) | PROCESS FOR THE PREPARATION OF IMINOPYRROLINONES |