NZ501791A - Method for coating fabric, paper or other surface using pulsed plasma polymerisation - Google Patents
Method for coating fabric, paper or other surface using pulsed plasma polymerisationInfo
- Publication number
- NZ501791A NZ501791A NZ501791A NZ50179198A NZ501791A NZ 501791 A NZ501791 A NZ 501791A NZ 501791 A NZ501791 A NZ 501791A NZ 50179198 A NZ50179198 A NZ 50179198A NZ 501791 A NZ501791 A NZ 501791A
- Authority
- NZ
- New Zealand
- Prior art keywords
- formula
- group
- plasma
- compound
- hydrogen
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 49
- 238000000576 coating method Methods 0.000 title claims abstract description 30
- 239000004744 fabric Substances 0.000 title claims abstract description 30
- 239000011248 coating agent Substances 0.000 title claims abstract description 16
- 150000001875 compounds Chemical class 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 20
- 239000005871 repellent Substances 0.000 claims abstract description 14
- 125000001188 haloalkyl group Chemical group 0.000 claims abstract description 12
- 230000002940 repellent Effects 0.000 claims abstract description 10
- 125000003118 aryl group Chemical group 0.000 claims abstract description 9
- 239000011521 glass Substances 0.000 claims abstract description 9
- 125000000565 sulfonamide group Chemical group 0.000 claims abstract description 6
- 239000000123 paper Substances 0.000 claims abstract description 5
- 239000000919 ceramic Substances 0.000 claims abstract description 4
- 239000002184 metal Substances 0.000 claims abstract description 4
- 229910052751 metal Inorganic materials 0.000 claims abstract description 4
- 125000001475 halogen functional group Chemical group 0.000 claims abstract 4
- 229920000307 polymer substrate Polymers 0.000 claims abstract 2
- 239000000758 substrate Substances 0.000 claims description 25
- 229920000642 polymer Polymers 0.000 claims description 23
- 239000001257 hydrogen Substances 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 6
- 230000002209 hydrophobic effect Effects 0.000 claims description 6
- 150000002894 organic compounds Chemical class 0.000 claims description 5
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 210000002381 plasma Anatomy 0.000 description 61
- 238000012360 testing method Methods 0.000 description 19
- 235000011468 Albizia julibrissin Nutrition 0.000 description 16
- 241001070944 Mimosa Species 0.000 description 16
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 15
- 238000000151 deposition Methods 0.000 description 14
- 230000008021 deposition Effects 0.000 description 13
- 239000000178 monomer Substances 0.000 description 12
- 238000011282 treatment Methods 0.000 description 11
- 239000007788 liquid Substances 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 7
- 150000002430 hydrocarbons Chemical group 0.000 description 7
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 125000005843 halogen group Chemical group 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 4
- 238000013467 fragmentation Methods 0.000 description 4
- 238000006062 fragmentation reaction Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- ZLQGITSKRNWIOT-UHFFFAOYSA-N 5-(dimethylamino)furan-2-carbaldehyde Chemical compound CN(C)C1=CC=C(C=O)O1 ZLQGITSKRNWIOT-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229940069096 dodecene Drugs 0.000 description 3
- 229920002313 fluoropolymer Polymers 0.000 description 3
- 239000004811 fluoropolymer Substances 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 238000000944 Soxhlet extraction Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- ODIGIKRIUKFKHP-UHFFFAOYSA-N (n-propan-2-yloxycarbonylanilino) acetate Chemical compound CC(C)OC(=O)N(OC(C)=O)C1=CC=CC=C1 ODIGIKRIUKFKHP-UHFFFAOYSA-N 0.000 description 1
- GETTZEONDQJALK-UHFFFAOYSA-N (trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=CC=C1 GETTZEONDQJALK-UHFFFAOYSA-N 0.000 description 1
- MHQSODYIEVVICX-UHFFFAOYSA-N 1,1,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-tetracosafluorododec-1-ene Chemical compound FC(F)=C(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F MHQSODYIEVVICX-UHFFFAOYSA-N 0.000 description 1
- CONKBQPVFMXDOV-QHCPKHFHSA-N 6-[(5S)-5-[[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]methyl]-2-oxo-1,3-oxazolidin-3-yl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C[C@H]1CN(C(O1)=O)C1=CC2=C(NC(O2)=O)C=C1 CONKBQPVFMXDOV-QHCPKHFHSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920002449 FKM Polymers 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005108 dry cleaning Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical group FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 125000000262 haloalkenyl group Chemical group 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- 208000006278 hypochromic anemia Diseases 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- -1 maleic anhydride Chemical class 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QLOAVXSYZAJECW-UHFFFAOYSA-N methane;molecular fluorine Chemical compound C.FF QLOAVXSYZAJECW-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000004447 silicone coating Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
- D06M14/20—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/62—Plasma-deposition of organic layers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/16—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising curable or polymerisable compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/11—Oleophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/32—Addition to the formed paper by contacting paper with an excess of material, e.g. from a reservoir or in a manner necessitating removal of applied excess material from the paper
- D21H23/42—Paper being at least partly surrounded by the material on both sides
- D21H23/44—Treatment with a gas or vapour
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24033—Structurally defined web or sheet [e.g., overall dimension, etc.] including stitching and discrete fastener[s], coating or bond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/102—Woven scrim
- Y10T442/172—Coated or impregnated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2033—Coating or impregnation formed in situ [e.g., by interfacial condensation, coagulation, precipitation, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2164—Coating or impregnation specified as water repellent
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Materials For Medical Uses (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Wrappers (AREA)
- Physical Vapour Deposition (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Paper (AREA)
- Laminated Bodies (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Polishing Bodies And Polishing Tools (AREA)
- Organic Insulating Materials (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9712338.4A GB9712338D0 (en) | 1997-06-14 | 1997-06-14 | Surface coatings |
| GBGB9720078.6A GB9720078D0 (en) | 1997-06-14 | 1997-09-23 | Surface coatings |
| PCT/GB1998/001702 WO1998058117A1 (en) | 1997-06-14 | 1998-06-11 | Surface coatings |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NZ501791A true NZ501791A (en) | 2001-09-28 |
Family
ID=26311714
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NZ501791A NZ501791A (en) | 1997-06-14 | 1998-06-11 | Method for coating fabric, paper or other surface using pulsed plasma polymerisation |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6551950B1 (enExample) |
| EP (1) | EP0988412B1 (enExample) |
| JP (2) | JP4527206B2 (enExample) |
| CN (1) | CN1190545C (enExample) |
| AT (1) | ATE316593T1 (enExample) |
| AU (1) | AU738802B2 (enExample) |
| CA (1) | CA2294644C (enExample) |
| DE (1) | DE69833321T2 (enExample) |
| DK (1) | DK0988412T3 (enExample) |
| ES (1) | ES2252840T3 (enExample) |
| GB (1) | GB2341864B (enExample) |
| NZ (1) | NZ501791A (enExample) |
| PT (1) | PT988412E (enExample) |
| WO (1) | WO1998058117A1 (enExample) |
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| GB9712338D0 (en) | 1997-06-14 | 1997-08-13 | Secr Defence | Surface coatings |
| US6432175B1 (en) | 1998-07-02 | 2002-08-13 | 3M Innovative Properties Company | Fluorinated electret |
| US6649138B2 (en) | 2000-10-13 | 2003-11-18 | Quantum Dot Corporation | Surface-modified semiconductive and metallic nanoparticles having enhanced dispersibility in aqueous media |
| GB0200957D0 (en) * | 2002-01-17 | 2002-03-06 | Secr Defence | Novel polymer and uses thereof |
| SE0200313D0 (sv) * | 2002-02-01 | 2002-02-01 | Astrazeneca Ab | Novel process |
| GB0206932D0 (en) * | 2002-03-23 | 2002-05-08 | Univ Durham | Preparation of superabsorbent materials by plasma modification |
| GB0211354D0 (en) | 2002-05-17 | 2002-06-26 | Surface Innovations Ltd | Atomisation of a precursor into an excitation medium for coating a remote substrate |
| GB0212848D0 (en) | 2002-06-01 | 2002-07-17 | Surface Innovations Ltd | Introduction of liquid/solid slurry into an exciting medium |
| WO2004065684A2 (en) * | 2003-01-22 | 2004-08-05 | The Procter & Gamble Company | Fibrous products and methods of making and using them |
| JP4150001B2 (ja) * | 2003-01-30 | 2008-09-17 | ユーロプラズマ | 開放気泡構造を有する製品の表面にその構造全体にわたってコーティングを提供する方法およびその方法の使用方法 |
| WO2005010271A1 (en) * | 2003-07-25 | 2005-02-03 | Universita' Degli Studi Di Milano-Bicocca | Method for working polymeric and inorganic materials with plasma |
| GB2421960A (en) * | 2003-09-18 | 2006-07-12 | Surface Innovations Ltd | Fibrous products and methods of making and using them |
| MXPA06006916A (es) * | 2003-12-16 | 2006-12-19 | Sun Chemical Corp | Metodo para formar una cubierta curable por radiacion y articulo cubierto. |
| GB0406049D0 (en) * | 2004-03-18 | 2004-04-21 | Secr Defence | Surface coatings |
| WO2005111189A1 (en) * | 2004-05-14 | 2005-11-24 | Reckitt Benckiser (Uk) Limited | Cleaning wipes having a covalently bound oleophilic coating their use and processes for their manufacture |
| KR20070102482A (ko) * | 2004-11-02 | 2007-10-18 | 아사히 가라스 가부시키가이샤 | 플루오로카본막 및 그 제조 방법 |
| GB2434368B (en) | 2006-01-20 | 2010-08-25 | P2I Ltd | Plasma coated laboratory consumables |
| GB2434369B (en) * | 2006-01-20 | 2010-08-25 | P2I Ltd | Plasma coated electrical or electronic devices |
| GB2434379A (en) * | 2006-01-20 | 2007-07-25 | P2I Ltd | Coated fabrics |
| MX2008009092A (es) * | 2006-01-20 | 2008-10-02 | P2I Ltd | Productos novedosos. |
| GB2438195A (en) * | 2006-05-20 | 2007-11-21 | P2I Ltd | Coated ink jet nozzle plate |
| GB0614621D0 (en) | 2006-07-24 | 2006-08-30 | 3M Innovative Properties Co | Metered dose dispensers |
| GB0620700D0 (en) | 2006-10-19 | 2006-11-29 | 3M Innovative Properties Co | Metered dose valves and dispensers |
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| GB2443322B (en) * | 2006-10-28 | 2010-09-08 | P2I Ltd | Plasma coated microfabricated device or component thereof |
| US9157191B2 (en) | 2006-11-02 | 2015-10-13 | Apjet, Inc. | Treatment of fibrous materials using atmospheric pressure plasma polymerization |
| DE102006060932A1 (de) * | 2006-12-20 | 2008-07-03 | Carl Freudenberg Kg | Temperaturstabile plasmabehandelte Gebilde und Verfahren zu deren Herstellung |
| GB0703172D0 (en) | 2007-02-19 | 2007-03-28 | Pa Knowledge Ltd | Printed circuit boards |
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| EP2167724B1 (en) * | 2007-07-17 | 2012-09-12 | P2I Ltd | Method for liquid proofing an item of footwear by plasma graft polymerisation |
| US20090263581A1 (en) * | 2008-04-16 | 2009-10-22 | Northeast Maritime Institute, Inc. | Method and apparatus to coat objects with parylene and boron nitride |
| US20090263641A1 (en) * | 2008-04-16 | 2009-10-22 | Northeast Maritime Institute, Inc. | Method and apparatus to coat objects with parylene |
| GB0721527D0 (en) * | 2007-11-02 | 2007-12-12 | P2I Ltd | Filtration Membranes |
| FR2923494B1 (fr) * | 2007-11-09 | 2010-01-15 | Hutchinson | Membranes imper-respirantes et leur procede de fabrication |
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| US20110078848A1 (en) * | 2009-10-05 | 2011-04-07 | Mathis Michael P | Treatment of Folded Articles |
| GB2475685A (en) | 2009-11-25 | 2011-06-01 | P2I Ltd | Plasma polymerization for coating wool |
| GB201000538D0 (en) | 2010-01-14 | 2010-03-03 | P2I Ltd | Liquid repellent surfaces |
| GB2477763A (en) | 2010-02-11 | 2011-08-17 | Thorn Security | Fire detector with a component including a contaminant-resistant surface |
| US8995146B2 (en) | 2010-02-23 | 2015-03-31 | Semblant Limited | Electrical assembly and method |
| AU2011252996B2 (en) * | 2010-05-12 | 2014-06-26 | Duncan C. Ferguson | Method for producing improved feathers and improved feathers thereto |
| EP2422887A1 (en) | 2010-08-27 | 2012-02-29 | Oticon A/S | A method of coating a surface with a water and oil repellant polymer layer |
| EP2457670B1 (en) * | 2010-11-30 | 2017-06-21 | Oticon A/S | Method and apparatus for plasma induced coating at low pressure |
| US20120164901A1 (en) * | 2010-12-22 | 2012-06-28 | Kimberly-Clark Worldwide, Inc. | Nonwoven webs having improved barrier properties |
| US8551895B2 (en) * | 2010-12-22 | 2013-10-08 | Kimberly-Clark Worldwide, Inc. | Nonwoven webs having improved barrier properties |
| US8852693B2 (en) | 2011-05-19 | 2014-10-07 | Liquipel Ip Llc | Coated electronic devices and associated methods |
| EP2532716A1 (en) | 2011-06-10 | 2012-12-12 | Eppendorf AG | A substrate having hydrophobic moiety-repelling surface characteristics and process for preparing the same |
| WO2013009684A1 (en) * | 2011-07-08 | 2013-01-17 | The University Of Akron | Carbon nanotube-based robust steamphobic surfaces |
| GB201112369D0 (en) | 2011-07-19 | 2011-08-31 | Surface Innovations Ltd | Polymeric structure |
| GB201112516D0 (en) | 2011-07-21 | 2011-08-31 | P2I Ltd | Surface coatings |
| GB2489761B (en) * | 2011-09-07 | 2015-03-04 | Europlasma Nv | Surface coatings |
| KR102107997B1 (ko) * | 2011-12-14 | 2020-05-11 | 엘지디스플레이 주식회사 | 투명필름의 표면처리 방법, 그 방법을 이용하여 제조된 유기발광장치, 및 유기발광장치의 제조방법 |
| GB2510213A (en) * | 2012-08-13 | 2014-07-30 | Europlasma Nv | Forming a protective polymer coating on a component |
| EP2906746B1 (en) * | 2012-10-09 | 2019-06-12 | Europlasma Nv | Surface coatings |
| US9988536B2 (en) | 2013-11-05 | 2018-06-05 | E I Du Pont De Nemours And Company | Compositions for surface treatments |
| GB201403558D0 (en) | 2014-02-28 | 2014-04-16 | P2I Ltd | Coating |
| EP3101170B1 (en) | 2015-06-03 | 2018-08-22 | Europlasma NV | Surface coatings |
| BE1023998B1 (nl) | 2015-06-09 | 2017-10-26 | P2I Ltd | Coatings |
| CN105648770B (zh) * | 2016-03-25 | 2018-04-13 | 广州拜费尔空气净化材料有限公司 | 一种超疏水表面的制备方法 |
| US11154903B2 (en) | 2016-05-13 | 2021-10-26 | Jiangsu Favored Nanotechnology Co., Ltd. | Apparatus and method for surface coating by means of grid control and plasma-initiated gas-phase polymerization |
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| CN107177835B (zh) * | 2017-05-21 | 2018-06-19 | 江苏菲沃泰纳米科技有限公司 | 一种循环大占空比脉冲放电制备多功能性纳米防护涂层的方法 |
| US11270871B2 (en) | 2017-05-21 | 2022-03-08 | Jiangsu Favored Nanotechnology Co., LTD | Multi-layer protective coating |
| WO2019106334A1 (en) | 2017-11-28 | 2019-06-06 | P2I Ltd | Electrical or electronic device with a screen having an air vent |
| GB201804277D0 (en) * | 2018-03-16 | 2018-05-02 | P2I Ltd | Method |
| CN109354903B (zh) * | 2018-10-24 | 2020-01-17 | 江苏菲沃泰纳米科技有限公司 | 一种高透明低色差纳米涂层及其制备方法 |
| CN109402611B (zh) * | 2018-10-24 | 2020-03-31 | 江苏菲沃泰纳米科技有限公司 | 一种含硅共聚物纳米涂层及其制备方法 |
| CN109354941B (zh) * | 2018-10-24 | 2020-01-24 | 江苏菲沃泰纳米科技有限公司 | 一种高粘附性耐老化纳米涂层及其制备方法 |
| GB2579871B (en) | 2019-02-22 | 2021-07-14 | P2I Ltd | Coatings |
| US11898248B2 (en) | 2019-12-18 | 2024-02-13 | Jiangsu Favored Nanotechnology Co., Ltd. | Coating apparatus and coating method |
| GB202000732D0 (en) * | 2020-01-17 | 2020-03-04 | Univ Oxford Innovation Ltd | Polymer coatings |
| CN111690306B (zh) * | 2020-05-18 | 2021-08-17 | 江苏菲沃泰纳米科技股份有限公司 | 防水膜层及其制备方法和产品 |
| EP3913110A1 (de) | 2020-05-20 | 2021-11-24 | Eppendorf AG | Laborverbrauchsartikel und verfahren zur herstellung eines solchen laborverbrauchsartikels |
| CN113774363A (zh) | 2020-06-09 | 2021-12-10 | 江苏菲沃泰纳米科技股份有限公司 | 镀膜设备及其镀膜方法 |
| CN115074989B (zh) * | 2022-08-01 | 2023-11-24 | 武汉纺织大学 | 一种超疏水的莱赛尔面料及其制备方法 |
| CN118240436A (zh) * | 2022-12-22 | 2024-06-25 | 江苏菲沃泰纳米科技股份有限公司 | 一种涂层、制备方法及器件 |
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-
1998
- 1998-06-11 CA CA 2294644 patent/CA2294644C/en not_active Expired - Lifetime
- 1998-06-11 DK DK98928453T patent/DK0988412T3/da active
- 1998-06-11 NZ NZ501791A patent/NZ501791A/en not_active IP Right Cessation
- 1998-06-11 PT PT98928453T patent/PT988412E/pt unknown
- 1998-06-11 CN CNB988079453A patent/CN1190545C/zh not_active Expired - Lifetime
- 1998-06-11 AT AT98928453T patent/ATE316593T1/de active
- 1998-06-11 GB GB9929106A patent/GB2341864B/en not_active Expired - Lifetime
- 1998-06-11 EP EP19980928453 patent/EP0988412B1/en not_active Expired - Lifetime
- 1998-06-11 AU AU80284/98A patent/AU738802B2/en not_active Expired
- 1998-06-11 ES ES98928453T patent/ES2252840T3/es not_active Expired - Lifetime
- 1998-06-11 DE DE1998633321 patent/DE69833321T2/de not_active Expired - Lifetime
- 1998-06-11 JP JP50394899A patent/JP4527206B2/ja not_active Expired - Lifetime
- 1998-06-11 WO PCT/GB1998/001702 patent/WO1998058117A1/en not_active Ceased
- 1998-06-11 US US09/445,800 patent/US6551950B1/en not_active Ceased
-
2009
- 2009-12-16 JP JP2009284898A patent/JP5320276B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DK0988412T3 (da) | 2006-05-15 |
| JP2010058523A (ja) | 2010-03-18 |
| DE69833321T2 (de) | 2006-09-14 |
| GB2341864A (en) | 2000-03-29 |
| AU738802B2 (en) | 2001-09-27 |
| AU8028498A (en) | 1999-01-04 |
| JP5320276B2 (ja) | 2013-10-23 |
| HK1030030A1 (en) | 2001-04-20 |
| JP2002510363A (ja) | 2002-04-02 |
| ATE316593T1 (de) | 2006-02-15 |
| US6551950B1 (en) | 2003-04-22 |
| GB9929106D0 (en) | 2000-02-02 |
| WO1998058117A1 (en) | 1998-12-23 |
| PT988412E (pt) | 2006-05-31 |
| CN1265714A (zh) | 2000-09-06 |
| EP0988412A1 (en) | 2000-03-29 |
| GB2341864B (en) | 2001-11-07 |
| CN1190545C (zh) | 2005-02-23 |
| CA2294644C (en) | 2009-12-22 |
| EP0988412B1 (en) | 2006-01-25 |
| ES2252840T3 (es) | 2006-05-16 |
| CA2294644A1 (en) | 1998-12-23 |
| DE69833321D1 (de) | 2006-04-13 |
| JP4527206B2 (ja) | 2010-08-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PSEA | Patent sealed | ||
| RENW | Renewal (renewal fees accepted) | ||
| RENW | Renewal (renewal fees accepted) | ||
| RENW | Renewal (renewal fees accepted) | ||
| RENW | Renewal (renewal fees accepted) | ||
| ASS | Change of ownership |
Owner name: P2I LTD, GB Effective date: 20140130 |
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| EXPY | Patent expired |