NO842757L - DISHWASH DETERGENTS, CONTAINING A CHLORISOCYANURATE DERIVATIVE, AND PROCEDURE IN ITS PREPARATION - Google Patents
DISHWASH DETERGENTS, CONTAINING A CHLORISOCYANURATE DERIVATIVE, AND PROCEDURE IN ITS PREPARATIONInfo
- Publication number
- NO842757L NO842757L NO842757A NO842757A NO842757L NO 842757 L NO842757 L NO 842757L NO 842757 A NO842757 A NO 842757A NO 842757 A NO842757 A NO 842757A NO 842757 L NO842757 L NO 842757L
- Authority
- NO
- Norway
- Prior art keywords
- weight
- trichloroisocyanuric acid
- detergent
- derivative
- acid
- Prior art date
Links
- 239000003599 detergent Substances 0.000 title claims description 26
- 238000000034 method Methods 0.000 title claims description 4
- 238000002360 preparation method Methods 0.000 title description 3
- 239000000203 mixture Substances 0.000 claims description 30
- 229950009390 symclosene Drugs 0.000 claims description 18
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 claims description 17
- 239000012188 paraffin wax Substances 0.000 claims description 16
- 239000004115 Sodium Silicate Substances 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 6
- 239000001993 wax Substances 0.000 claims description 6
- 229920000388 Polyphosphate Polymers 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000001205 polyphosphate Substances 0.000 claims description 5
- 235000011176 polyphosphates Nutrition 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 239000004902 Softening Agent Substances 0.000 claims description 4
- 230000003113 alkalizing effect Effects 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 235000019351 sodium silicates Nutrition 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 description 23
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 19
- 229910052801 chlorine Inorganic materials 0.000 description 19
- 235000019809 paraffin wax Nutrition 0.000 description 12
- 235000019271 petrolatum Nutrition 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 229910052911 sodium silicate Inorganic materials 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- 238000004448 titration Methods 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 235000019795 sodium metasilicate Nutrition 0.000 description 4
- 239000000645 desinfectant Substances 0.000 description 3
- 235000019832 sodium triphosphate Nutrition 0.000 description 3
- KEZYHIPQRGTUDU-UHFFFAOYSA-N 2-[dithiocarboxy(methyl)amino]acetic acid Chemical compound SC(=S)N(C)CC(O)=O KEZYHIPQRGTUDU-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- -1 calcium dichloroisocyanurate tetrahydrate Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- IFIDXBCRSWOUSB-UHFFFAOYSA-N potassium;1,3-dichloro-1,3,5-triazinane-2,4,6-trione Chemical compound [K+].ClN1C(=O)NC(=O)N(Cl)C1=O IFIDXBCRSWOUSB-UHFFFAOYSA-N 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920002257 Plurafac® Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000005262 alkoxyamine group Chemical group 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000004686 pentahydrates Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 235000019828 potassium polyphosphate Nutrition 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- PYILKOIEIHHYGD-UHFFFAOYSA-M sodium;1,5-dichloro-4,6-dioxo-1,3,5-triazin-2-olate;dihydrate Chemical compound O.O.[Na+].[O-]C1=NC(=O)N(Cl)C(=O)N1Cl PYILKOIEIHHYGD-UHFFFAOYSA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3958—Bleaching agents combined with phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3955—Organic bleaching agents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
Denne oppfinnelse angår nye vaskemiddelblandinger som egner seg for anvendelse i oppvaskmaskiner, og en fremgangsmåte for fremstilling av disse. This invention relates to new detergent mixtures which are suitable for use in dishwashers, and a method for their production.
Vaskeoperasjonen i en vaskemaskin involverer både den rensende virkning av vaskemidlet og den mekaniske virkning av vannet. I tillegg til vaskeevne må vaskemidlet ha desin-fiserende evne og vannbløtgjørende egenskaper. Vaskemidlet må derfor ha en sterk renseevne, men dets sammensetning må også være slik at det ikke forårsaker dannelse av skum som vil ha uhelding innvirkning på den mekaniske virkning av vaskevannet. Dette er årsakene til at vaskemiddelblandinger som i og for The washing operation in a washing machine involves both the cleaning effect of the detergent and the mechanical effect of the water. In addition to washing ability, the detergent must have disinfecting ability and water-softening properties. The detergent must therefore have a strong cleaning ability, but its composition must also be such that it does not cause the formation of foam which will have an adverse effect on the mechanical effect of the washing water. These are the reasons why detergent mixtures such as in and for
seg kjent utgjøres av:is known to consist of:
- Et bløtgjørende middel, som vanligvis velges blant polyfosfatér. (Blant de polyfosfater som benyttes, kan nevnes natriumtripolyfosfat, natriumhexametafosfat og natriumpyrofos-fat samt de tilsvarende kaliumpolyfosfater.) - Et alkaliserende middel bestående av et natriummetasilicat i vannfri form eller i form av pentahydratet. (Som i og for seg kjent kan natriumsilicat erstattes delvis med natriumcarbonat, natriumsulfat eller natriumhydroxyd.) - Et ikke-skummende overflateaktivt middel av ikke-ionisk type, valgt blant de følgende materialer: ethoxylérte lineære alkoholer, kondensater av ethylenoxyd og propylenoxyd, alkoxyaminer, polyethoxyetere av fettalkoholer, ethoxylérte alkylfenoler og fosforsyreestere av fettalkoholer. Med tanke på effektivitet, biologisk nedbrytbarhet og kostnadsnivå fore-trekkes det å benytte et overflateaktivt middel valgt blant ethoxylérte lineære alkoholer. - A softening agent, which is usually chosen from among polyphosphates. (Among the polyphosphates used, mention may be made of sodium tripolyphosphate, sodium hexametaphosphate and sodium pyrophosphate as well as the corresponding potassium polyphosphates.) - An alkalizing agent consisting of sodium metasilicate in anhydrous form or in the form of the pentahydrate. (As is known in and of itself, sodium silicate can be partially replaced by sodium carbonate, sodium sulfate or sodium hydroxide.) - A non-foaming surfactant of a non-ionic type, selected from the following materials: ethoxylated linear alcohols, condensates of ethylene oxide and propylene oxide, alkoxyamines, polyethoxyethers of fatty alcohols, ethoxylated alkylphenols and phosphoric acid esters of fatty alcohols. In view of efficiency, biodegradability and cost level, it is preferred to use a surface-active agent selected from among ethoxylated linear alcohols.
- Et desinfeksjonsmiddel.- A disinfectant.
Desinfeksjonsmidlet som benyttes, og som frigjør aktivt klor, er vanligvis et fast materiale på klorbasis av klorisocyanuratderivat-typen. Dette er som oftest et natrium- eller kalium-salt av diklorisocyanursyre. The disinfectant used, which releases active chlorine, is usually a solid chlorine-based material of the chloroisocyanurate derivative type. This is usually a sodium or potassium salt of dichloroisocyanuric acid.
Hittil er de følgende blitt benyttet i praksis: vannfritt natriumdiklorisocyanurat som ved titrering gir -63% aktivt klor, et natriumdiklorisocyanurat-dihydrat som ved . titrering gir 56% aktivt klor, vannfritt kaliumdiklorisocyanu-rat som ved titrering gir 59% aktivt klor, kaliumdiklorisocya- So far, the following have been used in practice: anhydrous sodium dichloroisocyanurate, which on titration gives -63% active chlorine, a sodium dichloroisocyanurate dihydrate which at . titration gives 56% active chlorine, anhydrous potassium dichloroisocyanurate which on titration gives 59% active chlorine, potassium dichloroisocyanurate
nurat-monohydrat som ved titrering gir 56% aktivt klor eller kalsiumdiklorisocyanurat-tetrahydrat som ved titrering gir 56% aktivt klor. Det aktive klor defineres som den oxyderende evne, fordi kloret er positivt. Kloret som er tilstede i de ovenfor omtalte klorerte derivater, er bundet til et nitrogen-atom og er således tilstede i derivatene i oxydasjonstilstanden +1, det vil si som Cl<+>. Under oxydasjonsprosessen binder et Cl<+>—ion til seg to elektroner, slik at det overføres til Cl" nurate monohydrate which on titration gives 56% active chlorine or calcium dichloroisocyanurate tetrahydrate which on titration gives 56% active chlorine. Active chlorine is defined as the oxidizing ability, because chlorine is positive. The chlorine that is present in the above-mentioned chlorinated derivatives is bound to a nitrogen atom and is thus present in the derivatives in the oxidation state +1, that is as Cl<+>. During the oxidation process, a Cl<+> ion binds to itself two electrons, so that it is transferred to Cl"
(klorid). To ekvivalenter av et oxydasjonsmiddel frigjøres, hvilket svarer til 71 g elementært klor, selv om atomveksten bare er 35,5. Dette innebærer også at et atom Cl<+>har samme oxyderende evne som et molekyl elementært klor Cl^'(chloride). Two equivalents of an oxidizing agent are liberated, corresponding to 71 g of elemental chlorine, although the atomic growth is only 35.5. This also implies that an atom of Cl<+> has the same oxidising ability as a molecule of elemental chlorine Cl^'
Blant de øvrige klorerte desinfeksjonsmidler av kloriso-cyanuratgruppen finnes der ett som ved titrering gir ca. 91% aktivt klor, nemlig triklorisocyanursyre. Det ville derfor være fordelaktig å kunne benytte denne, tatt i betraktning det høye prosentvise innhold av aktivt klor. Dessverre har den hittil ikke kunnet benyttes, da den har vært for reaktivt overfor de øvrige komponenter av vaskemiddelblandingene, spesielt overfor de overflateaktive midler. Vaskemiddelblandinger som inneholder triklorisocyanursyre, er lagringsustabile, og de taper betydelige mengder både av klor og av overflateaktive midler som følge av gjensidig ødeleggelse. Among the other chlorinated disinfectants of the chlorisocyanurate group, there is one which, by titration, gives approx. 91% active chlorine, namely trichloroisocyanuric acid. It would therefore be advantageous to be able to use this, considering the high percentage content of active chlorine. Unfortunately, it has so far not been able to be used, as it has been too reactive towards the other components of the detergent mixtures, especially towards the surfactants. Detergent compositions containing trichloroisocyanuric acid are storage unstable, and they lose significant amounts of both chlorine and surfactants as a result of mutual destruction.
En måte å stabilisere triklorisocyanursyre på er nu blitt funnet, spesielt for stabilisering av denne for fremstilling av vaskemiddelblandinger som er lagringsstabile og egnede for anvendelse i oppvaskmaskiner. A way of stabilizing trichloroisocyanuric acid has now been found, especially for stabilizing this for the production of detergent mixtures which are storage stable and suitable for use in dishwashers.
I henhold til oppfinnelsen tilveiebringes det således en ny vaskemiddelblanding som er anvendelig i oppvaskmaskiner, og som inneholder et bløtgjøringsmiddel valgt blant polyfosfatene, et alkaliserende middel valgt blant natriumsilicatene, et ikke-ionisk overflateaktivt middel og et klorisocyanuratderivat. Den nye vaskemiddelblanding utmerker seg ved at den benyttede triklorisocyanursyre er overtrukket med en parafinvoks anvendt i en konsentrasjon av fra 1 til 10 vekt% beregnet på vekten av syren. According to the invention, a new detergent mixture is thus provided which can be used in dishwashers, and which contains a softening agent selected from the polyphosphates, an alkalizing agent selected from the sodium silicates, a non-ionic surfactant and a chloroisocyanurate derivative. The new detergent mixture is distinguished by the fact that the trichloroisocyanuric acid used is coated with a paraffin wax used in a concentration of from 1 to 10% by weight calculated on the weight of the acid.
Det har vist seg at parafinvokser er forlikelige med triklorisocyanursyre. Dessuten gjør disse det mulig, selv når de anvendes i relativt små mengder, å oppnå en god stabilisering av syren. Videre er de dispergerbare under vaskebetingelsene, det vil si i vandige medier ved temperaturer på 50-60°C. Paraffin waxes have been found to be compatible with trichloroisocyanuric acid. Moreover, these make it possible, even when used in relatively small amounts, to achieve a good stabilization of the acid. Furthermore, they are dispersible under washing conditions, that is to say in aqueous media at temperatures of 50-60°C.
Parafinvoksene består av en blanding av faste hydrocar-boner som har høy molekylvekt (f.eks. C^gH-^) , som har et smeltepunkt som er lavere enn 60°C og høyere enn 4 0°C, og som har en viskositet ved 100°C som er lavere enn 6 eps. De benyttes i en konsentrasjon av fra 1 til 10 vekt%, beregnet på triklorisocyanursyren, fortrinnsvis i en konsentrasjon iav fra 3 til 5 vekt%. Ved bruk av mer enn 5 vekt% kan det oppstå van-skeligheter ved utførelsen av overtrekkingsoperasjonen, og det vil være nødvendig å modifisere overtrekkingsbetingelsene for å oppnå et ønsket overtrekk. Anvendelse av mengder utover 10 vekt% gir ingen nevneverdig forbedring av lagringsstabiliteten av vaskemiddelblandingene, og bruk av mengder under 1 vekt% resulterer i ubetydelig stabilisering. The paraffin waxes consist of a mixture of solid hydrocarbons which have a high molecular weight (e.g. C^gH-^), which have a melting point lower than 60°C and higher than 40°C, and which have a viscosity at 100°C which is lower than 6 eps. They are used in a concentration of from 1 to 10% by weight, calculated on the trichloroisocyanuric acid, preferably in a concentration of from 3 to 5% by weight. If more than 5% by weight is used, difficulties may arise when carrying out the coating operation, and it will be necessary to modify the coating conditions in order to achieve a desired coating. Use of amounts in excess of 10% by weight does not provide any appreciable improvement in the storage stability of the detergent mixtures, and use of amounts below 1% by weight results in negligible stabilization.
Ved fremstillingen av vaskemiddelblandingene ifølge oppfinnelsen foretas først overtrekkingen av triklorisocyanursyren med parafinvoksene. Denne overtrekkingsoperasjon ut-føres i en hvilken som helst type industriell blander, såsom i en trommelblander, fortrinnsvis en blander som er utstyrt med en oppvarmningsinnretning. Det er likeledes mulig å benytte en roterende blander av betongblandertypen, i hvilken den smeltede voks sprøytes på syren mens denne holdes oppvarmet ved en temperatur på rundt 50°C. En slik temperatur muliggjør god -fordeling av parafinvoksen, som størkner ved avkjøling. In the preparation of the detergent mixtures according to the invention, the trichloroisocyanuric acid is first coated with the paraffin waxes. This coating operation is carried out in any type of industrial mixer, such as in a drum mixer, preferably a mixer equipped with a heating device. It is also possible to use a rotary mixer of the concrete mixer type, in which the melted wax is sprayed onto the acid while it is kept heated at a temperature of around 50°C. Such a temperature enables good distribution of the paraffin wax, which solidifies on cooling.
Den voksbelagte triklorisocyanursyre blandes så i en annen blander med de øvrige bestanddeler av vaskemiddelblandingen. The wax-coated trichloroisocyanuric acid is then mixed in another mixer with the other components of the detergent mixture.
Mengdene av de forskjellige bestanddeler som i tillegg til parafinet benyttes for fremstilling av de nye vaskemiddelblandinger ifølge oppfinnelsen, er i og for seg konvensjonelle. Det bløtgjørende middel valgt blant polyfosfater benyttes i en mengde av fra 25 til 60 vekt%, fortrinnsvis i en mengde av fra 40 til 50 vekt%, beregnet på vekten av blandingen. The quantities of the various components which, in addition to the paraffin, are used for the production of the new detergent mixtures according to the invention, are in and of themselves conventional. The softening agent selected from polyphosphates is used in an amount of from 25 to 60% by weight, preferably in an amount of from 40 to 50% by weight, calculated on the weight of the mixture.
Det alkaliserende middel valgt blant natriumsilicater benyttes i en mengde av fra 30 til 70 vekt%, fortrinnsvis i en mengde av fra 40 til 60 vekt%, beregnet på vekten av blandingen. Som i og for seg kjent kan natriumsilicat delvis erstattes med natriumcarbonat, natriumsulfat eller natriumhydroxyd. Det ikke-ioniske overflateaktive middel benyttes i en mengde av^fra 0,5 til 4 vekt%, fortrinnsvis i en mengde av fra 1 til 3 vekt%, beregnet på vekten av blandingen. Triklorisocyanursyren overtrukket med parafin^roksen benyttes i en mengde av fra 0,5 til 5 vekt%, fortrinnsvis i en mendge av fra 1 til 3 vekt%, beregnet på vekten av blandingen. The alkalizing agent selected from sodium silicates is used in an amount of from 30 to 70% by weight, preferably in an amount of from 40 to 60% by weight, calculated on the weight of the mixture. As is known in and of itself, sodium silicate can be partially replaced with sodium carbonate, sodium sulfate or sodium hydroxide. The nonionic surfactant is used in an amount of from 0.5 to 4% by weight, preferably in an amount of from 1 to 3% by weight, calculated on the weight of the mixture. The trichloroisocyanuric acid coated with paraffin wax is used in an amount of from 0.5 to 5% by weight, preferably in an amount of from 1 to 3% by weight, calculated on the weight of the mixture.
De følgende eksempler illustrerer oppfinnelsen. The following examples illustrate the invention.
Eksempel 1Example 1
Triklorisocyanursyre blir først stabilisert med parafinvoksen på følgende måte: Syren oppvarmes til en temperatur på 50°C og anbringes så i én roterende blander (drageringsapparat). Mens blanderen roterer, påsprøytes parafinvoks ovenfra ved hjelp av en sprøyte-pistol. Den benyttede temperatur muliggjør en god fordeling av voksen, som størkner ved avkjøling. Den benyttede parafinvoks har et smeltepunkt som er lavere enn 6 0°C og en viskositet ved 100°C som er mindre enn 6 eps. Forskjellige blan- Trichloroisocyanuric acid is first stabilized with paraffin wax in the following way: The acid is heated to a temperature of 50°C and then placed in a rotating mixer (coating apparatus). While the mixer is rotating, paraffin wax is sprayed on from above using a spray gun. The temperature used enables a good distribution of the wax, which solidifies on cooling. The paraffin wax used has a melting point that is lower than 60°C and a viscosity at 100°C that is less than 6 eps. Different mix-
dinger av syre og voks tilberedes ved at det benyttes varierende presentmengder polyethylenvoks. De således erholdte blandinger benyttes for fremstilling av vaskemiddelblandinger. products of acid and wax are prepared by using varying amounts of polyethylene wax. The mixtures thus obtained are used for the production of detergent mixtures.
Vaskemidler av følgende sammensetning fremstilles:Detergents of the following composition are produced:
- Natriumtripolyfosfat: 50 vektdeler.- Sodium tripolyphosphate: 50 parts by weight.
- Natriummetasilicat (vannfritt eller 5^0-hydrat): 50 vektdeler. - "Plurafac" RA 43 (ethoxylert ikke-ionisk overflateaktivt middel fremstilt av firmaet PCUK): 2 vektdeler, - Sodium metasilicate (anhydrous or 5^0-hydrate): 50 parts by weight. - "Plurafac" RA 43 (ethoxylated non-ionic surfactant produced by the company PCUK): 2 parts by weight,
- Triklorisocyanursyre overtrukket med parafinvoks:- Trichloroisocyanuric acid coated with paraffin wax:
2 vektdeler.2 parts by weight.
En forhåndsblanding av natriumtripolyfosfat med ikke-ionisk overflateaktivt middel blir først tilberedt i en blander av roterende type. Etter 20 minutter oppnås en homogen blanding. Metasilicatet blir så tilsatt blanderen,og etter 2 0 minutter tilsettes den overtrukkede triklorisocyanursyre. Hele blandingen blandes så i den roterende blander i 20 minutter. Mengden av klor i vaskemiddelblåndingen, bestemt jodometrisk, er da 1,65%. A premix of sodium tripolyphosphate with nonionic surfactant is first prepared in a rotary type mixer. After 20 minutes, a homogeneous mixture is obtained. The metasilicate is then added to the mixer, and after 20 minutes the coated trichloroisocyanuric acid is added. The whole mixture is then mixed in the rotary mixer for 20 minutes. The amount of chlorine in the detergent mixture, determined iodometrically, is then 1.65%.
Den på denne måte fremstilte vaskemiddelblanding anbringes i plastposer sont lukkes med en lukkeinnretning som ikke gir hermetisk lukking. Posene lagres i en ovn ved de følgende re-gulerte betingelser: The detergent mixture produced in this way is placed in plastic bags and closed with a closing device that does not provide a hermetic seal. The bags are stored in an oven under the following regulated conditions:
- Temperatur 4(Pc,- Temperature 4(Pc,
- Relativ fuktighet 80%.- Relative humidity 80%.
Etter mellom 1 og 3 måneders lagring taes det ut prøver, og restklorinnholdet bestemmes jodometrisk. After between 1 and 3 months of storage, samples are taken, and the residual chlorine content is determined iodometrically.
Tabell 1 viser resultatene oppnådd etter 50 dagers lagring for vaskemiddelblandinger fremstilt ut fra vannfritt natriummetasilicat og ut fra triklorisocyanursyre overtrukket med parafinvoks benyttet i varierende prosentmengder (på vekt-basis). Restklormengdene er uttrykt i prosent av det opprinne-lige klorinnhold. Table 1 shows the results obtained after 50 days of storage for detergent mixtures prepared from anhydrous sodium metasilicate and from trichloroisocyanuric acid coated with paraffin wax used in varying percentage amounts (on a weight basis). The residual chlorine amounts are expressed as a percentage of the original chlorine content.
Eksempel 2 Example 2
Eksempel 1 gjentas, bortsett fra at det for fremstilling av vaskemiddelblandingene benyttes natriummetasilicat-pentahyd- rat istedenfor det vannfrie metasilicat som ble benyttet i Eksempel 1. Resultatene er oppsummert i Tabell 2. Example 1 is repeated, except that for the preparation of the detergent mixtures, sodium metasilicate pentahydrate is used instead of the anhydrous metasilicate that was used in Example 1. The results are summarized in Table 2.
Eksempel 3 Example 3
Eksempler 1 og 2 gjentas, idet det benyttes parafinvoks med smeltepunkt 4 0-42°C. Prøver tas ut etter 80 dagers lagring. Tabell 3 viser de resultater som ble oppnådd for vaskemiddelblandinger fremstilt enten ved anvendelse av vannfritt natriummetasilicat eller ved anvendelse av natriummetasilicat-péntahydrat. Examples 1 and 2 are repeated, using paraffin wax with melting point 4 0-42°C. Samples are taken out after 80 days of storage. Table 3 shows the results obtained for detergent compositions prepared either using anhydrous sodium metasilicate or using sodium metasilicate pentahydrate.
Claims (4)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8311427A FR2548684B1 (en) | 1983-07-08 | 1983-07-08 | DETERGENT COMPOSITIONS CONTAINING A CHLOROISOCYANURIC DERIVATIVE SUITABLE FOR WASHING DISHWASHER IN A WASHING MACHINE AND THEIR PREPARATION METHOD |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO842757L true NO842757L (en) | 1985-01-09 |
Family
ID=9290659
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO842757A NO842757L (en) | 1983-07-08 | 1984-07-06 | DISHWASH DETERGENTS, CONTAINING A CHLORISOCYANURATE DERIVATIVE, AND PROCEDURE IN ITS PREPARATION |
Country Status (16)
| Country | Link |
|---|---|
| JP (1) | JPS6036599A (en) |
| BE (1) | BE900109A (en) |
| BR (1) | BR8403373A (en) |
| CA (1) | CA1230796A (en) |
| CH (1) | CH660024A5 (en) |
| DE (1) | DE3424764A1 (en) |
| DK (1) | DK164288C (en) |
| ES (1) | ES534087A0 (en) |
| FR (1) | FR2548684B1 (en) |
| GB (1) | GB2143251B (en) |
| IT (1) | IT1177864B (en) |
| LU (1) | LU85433A1 (en) |
| NL (1) | NL8402153A (en) |
| NO (1) | NO842757L (en) |
| SE (1) | SE8403600L (en) |
| ZA (1) | ZA845007B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69031824T2 (en) * | 1989-11-15 | 1998-04-30 | Unilever Nv | Bleach particles encapsulated with wax and manufacturing process |
| EP0679178A1 (en) * | 1993-01-18 | 1995-11-02 | The Procter & Gamble Company | Machine dishwashing detergent compositions |
| EP0679177A1 (en) * | 1993-01-18 | 1995-11-02 | The Procter & Gamble Company | Detergent compositions |
| US5776874A (en) * | 1993-01-18 | 1998-07-07 | The Procter & Gamble Company | Anti-tarnishing machine dishwashing detergent compositions containing a paraffin oil |
| EP0706559B1 (en) * | 1993-07-01 | 2001-08-08 | The Procter & Gamble Company | Machine dishwashing composition containing oxygen bleach and paraffin oil and benzotriazole compound silver tarnishing inhibitors |
| DE69328679T2 (en) * | 1993-07-16 | 2001-01-11 | The Procter & Gamble Company, Cincinnati | Detergent compositions for dishwashers |
| KR100892551B1 (en) | 2006-02-15 | 2009-04-09 | 신명곤 | The method of preparing for microencapsulated acids to control of the carbon dioxide release and the pH values in model packs |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB911410A (en) * | 1958-08-18 | 1962-11-28 | Procter & Gamble Ltd | Detergent compositions |
| GB1044314A (en) * | 1963-12-24 | 1966-09-28 | Unilever Ltd | Abrasive compositions |
| FR1472680A (en) * | 1965-03-30 | 1967-03-10 | Fmc Corp | Detergent for dishwashing machines based on chlorinated isocyanurates |
| GB1395010A (en) * | 1971-05-28 | 1975-05-21 | Unilever Ltd | Coated alkaline earth metal hypochorites |
| GB1509797A (en) * | 1975-04-24 | 1978-05-04 | Unilever Ltd | Encapsulation process |
| US4327151A (en) * | 1976-08-25 | 1982-04-27 | Lever Brothers Company | Encapsulated bleaches and methods for their preparation |
| US4078099A (en) * | 1976-08-25 | 1978-03-07 | Lever Brothers Company | Encapsulated bleaches and methods for their preparation |
| EP0054094B1 (en) * | 1980-12-11 | 1985-07-24 | Eka Ab | Detergent compositions stable to chlorine separation, and agents for producing same |
| CA1182371A (en) * | 1980-12-18 | 1985-02-12 | Jeyes Group Limited | Lavatory cleansing blocks |
-
1983
- 1983-07-08 FR FR8311427A patent/FR2548684B1/en not_active Expired
-
1984
- 1984-06-27 LU LU85433A patent/LU85433A1/en unknown
- 1984-06-29 ZA ZA845007A patent/ZA845007B/en unknown
- 1984-07-04 IT IT48493/84A patent/IT1177864B/en active
- 1984-07-05 DE DE19843424764 patent/DE3424764A1/en not_active Ceased
- 1984-07-06 NO NO842757A patent/NO842757L/en unknown
- 1984-07-06 CH CH3294/84A patent/CH660024A5/en not_active IP Right Cessation
- 1984-07-06 SE SE8403600A patent/SE8403600L/en unknown
- 1984-07-06 BR BR8403373A patent/BR8403373A/en not_active IP Right Cessation
- 1984-07-06 DK DK332384A patent/DK164288C/en active
- 1984-07-06 ES ES534087A patent/ES534087A0/en active Granted
- 1984-07-06 JP JP59139204A patent/JPS6036599A/en active Pending
- 1984-07-06 BE BE0/213296A patent/BE900109A/en not_active IP Right Cessation
- 1984-07-06 NL NL8402153A patent/NL8402153A/en not_active Application Discontinuation
- 1984-07-06 CA CA000458375A patent/CA1230796A/en not_active Expired
- 1984-07-09 GB GB08417503A patent/GB2143251B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6036599A (en) | 1985-02-25 |
| IT8448493A0 (en) | 1984-07-04 |
| ES8603724A1 (en) | 1986-01-01 |
| SE8403600D0 (en) | 1984-07-06 |
| SE8403600L (en) | 1985-01-09 |
| GB2143251B (en) | 1987-08-05 |
| IT1177864B (en) | 1987-08-26 |
| NL8402153A (en) | 1985-02-01 |
| ZA845007B (en) | 1985-10-30 |
| GB2143251A (en) | 1985-02-06 |
| CA1230796A (en) | 1987-12-29 |
| BE900109A (en) | 1985-01-07 |
| BR8403373A (en) | 1985-06-18 |
| DK332384A (en) | 1985-01-09 |
| ES534087A0 (en) | 1986-01-01 |
| LU85433A1 (en) | 1984-11-30 |
| CH660024A5 (en) | 1987-03-13 |
| DK332384D0 (en) | 1984-07-06 |
| FR2548684A1 (en) | 1985-01-11 |
| DK164288B (en) | 1992-06-01 |
| GB8417503D0 (en) | 1984-08-15 |
| DK164288C (en) | 1992-12-28 |
| FR2548684B1 (en) | 1986-08-22 |
| DE3424764A1 (en) | 1985-01-17 |
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