NO810527L - Pyrrolidinderivater for stabilisering av polymermaterialer - Google Patents
Pyrrolidinderivater for stabilisering av polymermaterialerInfo
- Publication number
- NO810527L NO810527L NO810527A NO810527A NO810527L NO 810527 L NO810527 L NO 810527L NO 810527 A NO810527 A NO 810527A NO 810527 A NO810527 A NO 810527A NO 810527 L NO810527 L NO 810527L
- Authority
- NO
- Norway
- Prior art keywords
- stabilizers
- ingrediates
- pyrrolide
- acid ester
- polymer materials
- Prior art date
Links
- 230000000087 stabilizing effect Effects 0.000 title claims description 6
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 title 1
- 239000002861 polymer material Substances 0.000 title 1
- -1 straight-chain fatty acid ester Chemical class 0.000 claims description 20
- 229920000642 polymer Polymers 0.000 claims description 11
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical group C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 7
- 229920000098 polyolefin Polymers 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 230000005855 radiation Effects 0.000 claims description 5
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 230000009931 harmful effect Effects 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 229940070765 laurate Drugs 0.000 claims 1
- 125000005480 straight-chain fatty acid group Chemical group 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 description 9
- 239000004743 Polypropylene Substances 0.000 description 8
- 229920001155 polypropylene Polymers 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000012963 UV stabilizer Substances 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 3
- 235000021314 Palmitic acid Nutrition 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 238000004566 IR spectroscopy Methods 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- AAEJQHLAJICLHR-UHFFFAOYSA-N 1,2,2,3,3,4-hexamethylpyrrolidine Chemical compound CC1CN(C)C(C)(C)C1(C)C AAEJQHLAJICLHR-UHFFFAOYSA-N 0.000 description 1
- YAYNEUUHHLGGAH-UHFFFAOYSA-N 1-chlorododecane Chemical compound CCCCCCCCCCCCCl YAYNEUUHHLGGAH-UHFFFAOYSA-N 0.000 description 1
- CLWAXFZCVYJLLM-UHFFFAOYSA-N 1-chlorohexadecane Chemical compound CCCCCCCCCCCCCCCCCl CLWAXFZCVYJLLM-UHFFFAOYSA-N 0.000 description 1
- NOXHNAYUTJEYNN-UHFFFAOYSA-N 2,2,3,4,5,5-hexamethylpyrrolidine Chemical compound CC1C(C)C(C)(C)NC1(C)C NOXHNAYUTJEYNN-UHFFFAOYSA-N 0.000 description 1
- OCAQNEYBPDEIGD-UHFFFAOYSA-N C(CCCCCCCCCCC)(=O)OCC.CC1C(C(N(C1)C)(C)C)(C)C Chemical compound C(CCCCCCCCCCC)(=O)OCC.CC1C(C(N(C1)C)(C)C)(C)C OCAQNEYBPDEIGD-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012259 ether extract Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- JKANAVGODYYCQF-UHFFFAOYSA-N prop-2-yn-1-amine Chemical compound NCC#C JKANAVGODYYCQF-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/08—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms
- C07D295/084—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
- C07D295/088—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3415—Five-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Hydrogenated Pyridines (AREA)
- Cosmetics (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT20001/80A IT1174663B (it) | 1980-02-19 | 1980-02-19 | Composizioni pirrolidiniche e loro uso quali stabilizzanti uv per materie plastiche |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO810527L true NO810527L (no) | 1981-08-20 |
Family
ID=11162984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO810527A NO810527L (no) | 1980-02-19 | 1981-02-17 | Pyrrolidinderivater for stabilisering av polymermaterialer |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US4325864A (it) |
| JP (1) | JPS56131644A (it) |
| BE (1) | BE887565A (it) |
| CH (1) | CH652730A5 (it) |
| DE (1) | DE3106217C2 (it) |
| DK (1) | DK56081A (it) |
| FR (1) | FR2476105A1 (it) |
| GB (2) | GB2069507B (it) |
| IE (1) | IE50926B1 (it) |
| IT (1) | IT1174663B (it) |
| LU (1) | LU83146A1 (it) |
| NL (1) | NL8100835A (it) |
| NO (1) | NO810527L (it) |
| SE (1) | SE8100746L (it) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1196327B (it) * | 1984-11-16 | 1988-11-16 | Consiglio Nazionale Ricerche | 3-aza-7-idrossi-2,2,4,4-tetraalchilbiciclo (3.3.0) ottani,procedimento per la loro preparazione,intermedi adatti allo scopo e procedimento per l'ottenimento di questi ultimi |
| US5350786A (en) * | 1986-06-30 | 1994-09-27 | Enichem Synthesis S.P.A. | Process of (co)polymerization of α-olefins in the presence of stabilizers |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE923915C (de) * | 1951-05-05 | 1955-02-24 | Upjohn Co | Verfahren zur Herstellung von spasmolytisch wirksamen Pyrrolidinverbindungen |
| GB1398414A (en) * | 1972-07-28 | 1975-06-18 | Ciba Geigy Ag | Piperidine derivatives |
| GB1437002A (en) * | 1972-09-13 | 1976-05-26 | Ici Ltd | Cyclic amines |
| DE2459331A1 (de) * | 1973-12-28 | 1975-07-10 | Ciba Geigy Ag | Pyrrolidin-dicarbonsaeuren und ihre ester als lichtstabilisatoren |
| GB1467672A (en) * | 1974-04-11 | 1977-03-16 | Ciba Geigy Ag | Stabilised epoxy resin |
| US4093586A (en) * | 1975-01-15 | 1978-06-06 | Ciba-Geigy Corporation | Pyrrolidine dicarboxylic acids and esters and stabilized compositions |
| US4111901A (en) * | 1977-06-06 | 1978-09-05 | Borg-Warner Corporation | Hindered five-membered nitrogen rings as polyolefin stabilizers |
| IT1160064B (it) * | 1978-11-10 | 1987-03-04 | Anic Spa | Procedimento per la stabilizzazione di polimeri mediante impiego di sali di nichel di pirrolidinditiocarbammati sostituiti |
-
1980
- 1980-02-19 IT IT20001/80A patent/IT1174663B/it active
- 1980-12-05 US US06/213,653 patent/US4325864A/en not_active Expired - Lifetime
-
1981
- 1981-01-30 SE SE8100746A patent/SE8100746L/xx not_active Application Discontinuation
- 1981-02-04 GB GB8103466A patent/GB2069507B/en not_active Expired
- 1981-02-10 DK DK56081A patent/DK56081A/da not_active Application Discontinuation
- 1981-02-16 CH CH1015/81A patent/CH652730A5/it not_active IP Right Cessation
- 1981-02-17 FR FR8103117A patent/FR2476105A1/fr active Granted
- 1981-02-17 NO NO810527A patent/NO810527L/no unknown
- 1981-02-18 IE IE322/81A patent/IE50926B1/en unknown
- 1981-02-18 BE BE0/203829A patent/BE887565A/fr not_active IP Right Cessation
- 1981-02-18 LU LU83146A patent/LU83146A1/fr unknown
- 1981-02-18 JP JP2162481A patent/JPS56131644A/ja active Pending
- 1981-02-19 DE DE3106217A patent/DE3106217C2/de not_active Expired
- 1981-02-19 NL NL8100835A patent/NL8100835A/nl not_active Application Discontinuation
-
1983
- 1983-06-20 GB GB08316728A patent/GB2129813B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB2129813B (en) | 1984-11-21 |
| GB2129813A (en) | 1984-05-23 |
| FR2476105A1 (fr) | 1981-08-21 |
| DK56081A (da) | 1981-08-20 |
| LU83146A1 (fr) | 1981-09-11 |
| GB8316728D0 (en) | 1983-07-20 |
| DE3106217A1 (de) | 1982-01-21 |
| CH652730A5 (it) | 1985-11-29 |
| IT1174663B (it) | 1987-07-01 |
| NL8100835A (nl) | 1981-09-16 |
| JPS56131644A (en) | 1981-10-15 |
| IE810322L (en) | 1981-08-19 |
| GB2069507B (en) | 1984-02-08 |
| FR2476105B1 (it) | 1984-02-24 |
| US4325864A (en) | 1982-04-20 |
| BE887565A (fr) | 1981-08-18 |
| IT8020001A0 (it) | 1980-02-19 |
| IE50926B1 (en) | 1986-08-20 |
| GB2069507A (en) | 1981-08-26 |
| SE8100746L (sv) | 1981-08-20 |
| DE3106217C2 (de) | 1985-03-28 |
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