NO744372L - - Google Patents
Info
- Publication number
- NO744372L NO744372L NO744372A NO744372A NO744372L NO 744372 L NO744372 L NO 744372L NO 744372 A NO744372 A NO 744372A NO 744372 A NO744372 A NO 744372A NO 744372 L NO744372 L NO 744372L
- Authority
- NO
- Norway
- Prior art keywords
- component
- catalyst
- catalyst according
- compound
- group
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 claims description 84
- 239000003054 catalyst Substances 0.000 claims description 82
- 238000006116 polymerization reaction Methods 0.000 claims description 55
- 239000007787 solid Substances 0.000 claims description 42
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 39
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 39
- -1 aluminum compound Chemical class 0.000 claims description 37
- 150000001875 compounds Chemical class 0.000 claims description 33
- 229910052782 aluminium Inorganic materials 0.000 claims description 32
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 28
- 239000001257 hydrogen Substances 0.000 claims description 28
- 229910052739 hydrogen Inorganic materials 0.000 claims description 28
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 25
- 239000002879 Lewis base Substances 0.000 claims description 24
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 24
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 19
- 150000007527 lewis bases Chemical class 0.000 claims description 18
- 229910052757 nitrogen Inorganic materials 0.000 claims description 18
- 229910010062 TiCl3 Inorganic materials 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 16
- 239000008139 complexing agent Substances 0.000 claims description 16
- 239000003085 diluting agent Substances 0.000 claims description 16
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 16
- 239000002245 particle Substances 0.000 claims description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- CHVJITGCYZJHLR-UHFFFAOYSA-N cyclohepta-1,3,5-triene Chemical compound C1C=CC=CC=C1 CHVJITGCYZJHLR-UHFFFAOYSA-N 0.000 claims description 14
- 239000000178 monomer Substances 0.000 claims description 14
- 229920001155 polypropylene Polymers 0.000 claims description 14
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- 229910052698 phosphorus Inorganic materials 0.000 claims description 12
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims description 11
- 229910003074 TiCl4 Inorganic materials 0.000 claims description 11
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims description 11
- 229930195733 hydrocarbon Natural products 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 150000004291 polyenes Chemical class 0.000 claims description 11
- 239000010936 titanium Substances 0.000 claims description 11
- 229910052719 titanium Inorganic materials 0.000 claims description 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 10
- 229910052736 halogen Chemical group 0.000 claims description 10
- 150000002367 halogens Chemical group 0.000 claims description 9
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 8
- AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical compound C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 claims description 8
- 150000002902 organometallic compounds Chemical class 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 125000004437 phosphorous atom Chemical group 0.000 claims description 8
- 150000004985 diamines Chemical class 0.000 claims description 7
- 150000002170 ethers Chemical class 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 150000002903 organophosphorus compounds Chemical class 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 6
- 125000005843 halogen group Chemical group 0.000 claims description 6
- 125000000623 heterocyclic group Chemical group 0.000 claims description 6
- 239000000155 melt Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- 239000012429 reaction media Substances 0.000 claims description 5
- 239000011541 reaction mixture Substances 0.000 claims description 5
- 239000004711 α-olefin Substances 0.000 claims description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 150000002576 ketones Chemical class 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000002685 polymerization catalyst Substances 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 125000004429 atom Chemical group 0.000 claims description 3
- 125000005842 heteroatom Chemical group 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 150000002894 organic compounds Chemical group 0.000 claims description 3
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 3
- 230000009467 reduction Effects 0.000 claims description 3
- FIQMHBFVRAXMOP-UHFFFAOYSA-N triphenylphosphane oxide Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=O)C1=CC=CC=C1 FIQMHBFVRAXMOP-UHFFFAOYSA-N 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- SZKKRCSOSQAJDE-UHFFFAOYSA-N Schradan Chemical compound CN(C)P(=O)(N(C)C)OP(=O)(N(C)C)N(C)C SZKKRCSOSQAJDE-UHFFFAOYSA-N 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 125000003282 alkyl amino group Chemical group 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 239000012986 chain transfer agent Substances 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 239000003701 inert diluent Substances 0.000 claims description 2
- 150000003961 organosilicon compounds Chemical class 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- 125000004434 sulfur atom Chemical group 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims description 2
- 150000003624 transition metals Chemical class 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 1
- KDUIUFJBNGTBMD-VXMYFEMYSA-N cyclooctatetraene Chemical compound C1=C\C=C/C=C\C=C1 KDUIUFJBNGTBMD-VXMYFEMYSA-N 0.000 claims 1
- 125000001033 ether group Chemical group 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 238000002955 isolation Methods 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 claims 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 150000005671 trienes Chemical class 0.000 claims 1
- 150000003672 ureas Chemical class 0.000 claims 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 54
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 19
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 19
- 239000000047 product Substances 0.000 description 15
- 238000007792 addition Methods 0.000 description 13
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000009835 boiling Methods 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 238000000605 extraction Methods 0.000 description 5
- 150000002899 organoaluminium compounds Chemical class 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 4
- 229910010068 TiCl2 Inorganic materials 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 4
- OJOSABWCUVCSTQ-UHFFFAOYSA-N cyclohepta-2,4,6-trienylium Chemical class C1=CC=C[CH+]=C[CH]1 OJOSABWCUVCSTQ-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 239000011949 solid catalyst Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- KDUIUFJBNGTBMD-DLMDZQPMSA-N [8]annulene Chemical compound C/1=C/C=C\C=C/C=C\1 KDUIUFJBNGTBMD-DLMDZQPMSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 239000011859 microparticle Substances 0.000 description 3
- 150000003018 phosphorus compounds Chemical class 0.000 description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 238000000944 Soxhlet extraction Methods 0.000 description 2
- 125000002015 acyclic group Chemical group 0.000 description 2
- 125000005365 aminothiol group Chemical class 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- ICPMUWPXCAVOOQ-UHFFFAOYSA-N cycloocta-1,3,5-triene Chemical compound C1CC=CC=CC=C1 ICPMUWPXCAVOOQ-UHFFFAOYSA-N 0.000 description 2
- KDUIUFJBNGTBMD-UHFFFAOYSA-N cyclooctatetraene Chemical compound C1=CC=CC=CC=C1 KDUIUFJBNGTBMD-UHFFFAOYSA-N 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 150000003003 phosphines Chemical class 0.000 description 2
- 229920001384 propylene homopolymer Polymers 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- 125000003396 thiol group Chemical class [H]S* 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- MDYOLVRUBBJPFM-UHFFFAOYSA-N tropolone Chemical compound OC1=CC=CC=CC1=O MDYOLVRUBBJPFM-UHFFFAOYSA-N 0.000 description 2
- 238000004846 x-ray emission Methods 0.000 description 2
- YPTUACJIJAJXGU-UHFFFAOYSA-N 1,2-dimethylcycloocta-1,3,5,7-tetraene Chemical compound CC1=C(C)C=CC=CC=C1 YPTUACJIJAJXGU-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- VYHWQHYSUMPIHU-UHFFFAOYSA-N 1-methoxycyclohepta-1,3,5-triene Chemical compound COC1=CC=CC=CC1 VYHWQHYSUMPIHU-UHFFFAOYSA-N 0.000 description 1
- QMRIOEQPJDFOPT-UHFFFAOYSA-N 1-methylcyclohepta-1,3,5-triene Chemical compound CC1=CC=CC=CC1 QMRIOEQPJDFOPT-UHFFFAOYSA-N 0.000 description 1
- ISUWHFAMPMYJOM-UHFFFAOYSA-N 10,11lambda4,12-trithiaheptacyclo[19.3.1.03,8.09,24.011,23.013,22.014,19]pentacosa-1,3,5,7,9(24),11(23),13(22),14,16,18,20-undecaen-25-one Chemical compound O=C1C2=CC3=CC=CC=C3C3=C2C2=S(S3)SC3=C4C=CC=CC4=CC1=C23 ISUWHFAMPMYJOM-UHFFFAOYSA-N 0.000 description 1
- UXQAEOWCSOPBLF-UHFFFAOYSA-N 2,2,3,3-tetramethyloctane Chemical compound CCCCCC(C)(C)C(C)(C)C UXQAEOWCSOPBLF-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 239000007818 Grignard reagent Substances 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 101100010166 Mus musculus Dok3 gene Proteins 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- GVXQKKNXXVBVNI-UHFFFAOYSA-N alumane N,N-diethylethanamine Chemical compound [H][Al]([H])[H].CCN(CC)CC GVXQKKNXXVBVNI-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229920001585 atactic polymer Polymers 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- QQVQUYQELXYMTG-UHFFFAOYSA-N ethoxyphosphane Chemical compound CCOP QQVQUYQELXYMTG-UHFFFAOYSA-N 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 150000004795 grignard reagents Chemical class 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 125000005936 piperidyl group Chemical group 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- MWWATHDPGQKSAR-UHFFFAOYSA-N propyne Chemical group CC#C MWWATHDPGQKSAR-UHFFFAOYSA-N 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 125000000168 pyrrolyl group Chemical group 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 108010009303 tyrosyl 1,2,3,4-tetrahydro-3-isoquinolinecarbonyl-phenylalanine Proteins 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB56168/73A GB1486194A (en) | 1973-12-04 | 1973-12-04 | Olefine polymer olefine polymerisation process and catalyst |
| GB1374174 | 1974-03-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO744372L true NO744372L (es) | 1975-06-23 |
Family
ID=26249968
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO744372A NO744372L (es) | 1973-12-04 | 1974-12-04 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4136243A (es) |
| JP (1) | JPS5093888A (es) |
| AT (1) | AT339039B (es) |
| AU (1) | AU2513677A (es) |
| BR (1) | BR7410146A (es) |
| CA (1) | CA1054131A (es) |
| DE (1) | DE2457278A1 (es) |
| ES (1) | ES432605A1 (es) |
| FR (1) | FR2253030B1 (es) |
| IE (1) | IE40215B1 (es) |
| NL (1) | NL7415791A (es) |
| NO (1) | NO744372L (es) |
| SE (1) | SE7415197L (es) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50108384A (es) * | 1974-02-01 | 1975-08-26 | ||
| JPS5144190A (ja) * | 1974-10-15 | 1976-04-15 | Tokuyama Soda Kk | Ryushijohoripuropiren mataha puropiren * echirenkyojugotaino seizohoho |
| US4111834A (en) * | 1975-05-28 | 1978-09-05 | Imperial Chemical Industries Limited | Process for preparing a transition metal compound and it's use as a component in an olefin polymerization catalyst |
| JPS537786A (en) * | 1976-07-09 | 1978-01-24 | Sumitomo Chem Co Ltd | Preparation of propylene polymer or copolymer |
| JPS5490094A (en) * | 1977-12-28 | 1979-07-17 | Toyo Sutoufuaa Kemikaru Yuugen | Titanium trichloride catalyst component and monoo or copolymerization of alphaaolefin |
| US4258161A (en) * | 1978-02-14 | 1981-03-24 | Mitsubishi Chemical Industries Ltd. | Process for polymerizing propylene |
| US4222893A (en) * | 1978-04-03 | 1980-09-16 | Standard Oil Company (Indiana) | Process for forming high performance titanium trichloride olefin polymerization catalyst components |
| JPS598362B2 (ja) * | 1978-06-23 | 1984-02-24 | 有限会社東洋ストウフア−・ケミカル | α−オレフイン重合用触媒 |
| US4543400A (en) * | 1978-09-26 | 1985-09-24 | Exxon Research & Engineering Co. | Titanium trichloride catalyst component and the process for the production thereof |
| US4211670A (en) * | 1979-01-25 | 1980-07-08 | Hercules Incorporated | Titanium trichloride catalyst component for propylene polymerization |
| US4395358A (en) * | 1979-02-12 | 1983-07-26 | Exxon Research & Engineering Co. | Titanium trichloride catalyst complex and process for the production thereof |
| US4262104A (en) * | 1979-02-12 | 1981-04-14 | Exxon Research & Engineering Co. | Titanium trichloride catalyst complex and process for the production thereof |
| DE3064564D1 (en) * | 1979-04-30 | 1983-09-22 | Shell Int Research | Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions |
| CA1141093A (en) * | 1979-05-17 | 1983-02-08 | Brian L. Goodall | Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions |
| EP0021753B1 (en) * | 1979-06-20 | 1984-03-14 | Sumitomo Chemical Company, Limited | Method for production of highly crystalline olefin polymers |
| JPS591723B2 (ja) * | 1980-01-17 | 1984-01-13 | チッソ株式会社 | α−オレフイン重合体を製造する方法 |
| JPS5928573B2 (ja) * | 1980-02-05 | 1984-07-13 | チッソ株式会社 | α−オレフイン重合体の製造方法 |
| JPS6023764B2 (ja) * | 1980-02-27 | 1985-06-10 | チッソ株式会社 | α−オレフイン重合体を製造する方法 |
| JPS5759902A (en) * | 1980-09-29 | 1982-04-10 | Chisso Corp | Preparation of alpha-olefinic polymer |
| GB2114581B (en) * | 1981-12-17 | 1985-08-14 | Chisso Corp | Ziegler catalyst for producing polypropylene |
| JPS58219207A (ja) * | 1982-06-15 | 1983-12-20 | Chisso Corp | 高剛性高溶融粘弾性ポリプロピレンとその製造法 |
| US4525467A (en) * | 1984-01-16 | 1985-06-25 | Exxon Research & Engineering Co. | High efficiency polymerization catalyst component for use in the polymerization of propylene and higher alpha-olefins |
| IT1173452B (it) * | 1984-03-20 | 1987-06-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione delle olefine |
| GB8521431D0 (en) * | 1985-08-28 | 1985-10-02 | Shell Int Research | Spherical magnesium alkoxide particles |
| US4914069A (en) * | 1987-05-04 | 1990-04-03 | Shell Oil Company | Preparation of olefin polymerization catalyst component |
| US4948770A (en) * | 1987-06-29 | 1990-08-14 | Shell Oil Company | Method for crystallizing magnesium chloride and method for using in a catalyst composition |
| US5780379A (en) * | 1987-09-25 | 1998-07-14 | Solvay Polyolefins Europe-Belgium (Societe Anonyme) | Process for the stereospecific polymerization of alpha-olefins and catalyst system which can be employed for this polymerization |
| FR2628430B1 (fr) * | 1988-03-09 | 1992-04-17 | Solvay | Procede pour la polymerisation stereospecifique des alpha-olefines et systeme catalytique utilisable pour cette polymerisation |
| US4818799A (en) * | 1987-11-13 | 1989-04-04 | Shell Oil Company | Process for the in-reactor stabilization of polyolefins |
| US5206315A (en) * | 1989-04-10 | 1993-04-27 | Phillips Petroleum Company | Process for polymerizing 1-olefins and catalyst therefor |
| US5270410A (en) * | 1989-04-25 | 1993-12-14 | Shell Oil Company | Process for the production of elastomeric, primarily syndiotactic polypropylene and catalysts for use in said process |
| US5270276A (en) * | 1989-04-25 | 1993-12-14 | Shell Oil Company | Process for the production of elastomeric, primarily syndiotactic polypropylene and catalysts for use in said process |
| US4971936A (en) * | 1989-07-10 | 1990-11-20 | Shell Oil Company | Catalyst component for making primarily isotactic elastomeric polypropylene or polybutene |
| US5089573A (en) * | 1990-02-26 | 1992-02-18 | Shell Oil Company | Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process |
| US5118649A (en) * | 1990-02-26 | 1992-06-02 | Shell Oil Company | Process for the production of elastomeric primarily isotactic polyolefins and catalysts for use in said process |
| US5118767A (en) * | 1990-02-26 | 1992-06-02 | Shell Oil Company | Process for producing mildly elastomeric primarily isotatic polypropylene and poly-1-butene |
| US5164352A (en) * | 1990-05-11 | 1992-11-17 | Shell Oil Company | Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process |
| US5118768A (en) * | 1990-05-11 | 1992-06-02 | Shell Oil Company | Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process |
| US5451555A (en) * | 1991-06-27 | 1995-09-19 | Nippon Oil Co., Ltd. | Catalyst components for polymerization of olefins |
| US5414063A (en) * | 1993-03-30 | 1995-05-09 | Huntsman Polypropylene Corporation | Process for the production of polypropylene |
| US7078362B2 (en) * | 2004-12-09 | 2006-07-18 | Equistar Chemicals, Lp | Carbene donor-modified Ziegler-Natta catalysts |
| US20110082268A1 (en) * | 2009-10-02 | 2011-04-07 | Sandor Nagy | Indazole-modified ziegler-natta catalyst system |
| US20110082270A1 (en) * | 2009-10-02 | 2011-04-07 | Sandor Nagy | Pyridazine-modified ziegler-natta catalyst system |
| US8017708B2 (en) | 2009-10-02 | 2011-09-13 | Equistar Chemicals, Lp | Nitroso-modified Ziegler-Natta catalyst system |
| US7871952B1 (en) | 2009-10-02 | 2011-01-18 | Equistar Chemicals, Lp | 2-hydroxypyridine N-oxide-modified ziegler-natta catalyst system |
| EP4143242A1 (en) | 2020-04-30 | 2023-03-08 | Dow Global Technologies LLC | Ziegler-natta (pro)catalyst systems made with azaheterocyclic compound |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2971950A (en) * | 1957-08-05 | 1961-02-14 | Montedison Spa | Production of isotactic poly (alpha-olefins) having regulated molecular weight |
| DE1445225B2 (de) * | 1960-09-24 | 1971-11-18 | Badische Anilin & Soda Fabrik AG, 6700 Ludwigshafen | Verfahren zur polymerisation von monoalpha olefinen mit drei oder mehr kohlenstoffatomen |
| BE637453A (es) | 1963-09-19 | |||
| US3219648A (en) * | 1964-01-08 | 1965-11-23 | Gulf Oil Corp | Polyolefin catalysts and processes |
| NL6618340A (es) * | 1966-01-04 | 1967-07-05 | ||
| US3549608A (en) * | 1966-12-05 | 1970-12-22 | Eastman Kodak Co | Stereosymmetric polypropylene |
| US3600463A (en) * | 1967-12-18 | 1971-08-17 | Eastman Kodak Co | Process for producing substantially ash-free polyolefin polymers |
| US3635930A (en) * | 1969-03-27 | 1972-01-18 | Phillips Petroleum Co | Carbon disulfide with trialkyl phosphine as adjuvant for polymerization catalyst and polymerization process |
| DE2054950A1 (de) * | 1970-11-07 | 1972-05-10 | Farbwerke Hoechst AG, vorm. Meister Lucius & Brüning, 6000 Frankfurt | Mischkatalysator Our Polymerisation von alpha-Olefinen |
| CH543546A (fr) | 1971-03-23 | 1973-10-31 | Solvay | Système catalytique de polymérisation des alpha-oléfines |
| US3984350A (en) * | 1974-05-09 | 1976-10-05 | Standard Oil Company (Indiana) | Catalyst component comprising brown titanium trichloride |
-
1974
- 1974-11-20 IE IE2394/74A patent/IE40215B1/xx unknown
- 1974-12-04 NL NL7415791A patent/NL7415791A/xx not_active Application Discontinuation
- 1974-12-04 JP JP49139345A patent/JPS5093888A/ja active Pending
- 1974-12-04 AT AT971074A patent/AT339039B/de not_active IP Right Cessation
- 1974-12-04 BR BR10146/74A patent/BR7410146A/pt unknown
- 1974-12-04 CA CA215,256A patent/CA1054131A/en not_active Expired
- 1974-12-04 FR FR7439622A patent/FR2253030B1/fr not_active Expired
- 1974-12-04 SE SE7415197A patent/SE7415197L/xx unknown
- 1974-12-04 ES ES432605A patent/ES432605A1/es not_active Expired
- 1974-12-04 NO NO744372A patent/NO744372L/no unknown
- 1974-12-04 DE DE19742457278 patent/DE2457278A1/de not_active Withdrawn
- 1974-12-04 US US05/529,585 patent/US4136243A/en not_active Expired - Lifetime
-
1977
- 1977-05-13 AU AU25136/77A patent/AU2513677A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ATA971074A (de) | 1977-01-15 |
| BR7410146A (pt) | 1976-06-08 |
| FR2253030A1 (es) | 1975-06-27 |
| DE2457278A1 (de) | 1975-06-05 |
| IE40215B1 (en) | 1979-04-11 |
| SE7415197L (es) | 1975-06-05 |
| IE40215L (en) | 1975-06-04 |
| CA1054131A (en) | 1979-05-08 |
| ES432605A1 (es) | 1977-02-16 |
| FR2253030B1 (es) | 1977-03-25 |
| US4136243A (en) | 1979-01-23 |
| AU7591674A (en) | 1976-06-03 |
| NL7415791A (nl) | 1975-06-06 |
| AT339039B (de) | 1977-09-26 |
| JPS5093888A (es) | 1975-07-26 |
| AU2513677A (en) | 1977-07-21 |
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