NO328001B1 - Fremgangsmate og katalysator for selektiv fremstilling av eddiksyre ved katalytisk oksydasjon av etan og/eller etylen - Google Patents
Fremgangsmate og katalysator for selektiv fremstilling av eddiksyre ved katalytisk oksydasjon av etan og/eller etylen Download PDFInfo
- Publication number
- NO328001B1 NO328001B1 NO20025148A NO20025148A NO328001B1 NO 328001 B1 NO328001 B1 NO 328001B1 NO 20025148 A NO20025148 A NO 20025148A NO 20025148 A NO20025148 A NO 20025148A NO 328001 B1 NO328001 B1 NO 328001B1
- Authority
- NO
- Norway
- Prior art keywords
- elements
- catalyst
- acetic acid
- ethane
- ethylene
- Prior art date
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title claims abstract description 169
- 239000003054 catalyst Substances 0.000 title claims abstract description 76
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 title claims abstract description 48
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 239000005977 Ethylene Substances 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 28
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 24
- 230000003647 oxidation Effects 0.000 title claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 230000003197 catalytic effect Effects 0.000 title description 5
- 230000008569 process Effects 0.000 title description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000001301 oxygen Substances 0.000 claims abstract description 35
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 35
- 239000000203 mixture Substances 0.000 claims abstract description 31
- 239000010955 niobium Substances 0.000 claims abstract description 29
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 20
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 20
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 17
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 15
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 14
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 13
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 13
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 13
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 13
- 229910052715 tantalum Inorganic materials 0.000 claims abstract description 13
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 12
- 229910052745 lead Inorganic materials 0.000 claims abstract description 12
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 12
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 12
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 12
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 11
- 229910052712 strontium Inorganic materials 0.000 claims abstract description 11
- 229910052718 tin Inorganic materials 0.000 claims abstract description 11
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 11
- 229910052770 Uranium Inorganic materials 0.000 claims abstract description 10
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 10
- 229910052796 boron Inorganic materials 0.000 claims abstract description 10
- 229910052802 copper Inorganic materials 0.000 claims abstract description 10
- 229910052735 hafnium Inorganic materials 0.000 claims abstract description 10
- 229910052742 iron Inorganic materials 0.000 claims abstract description 10
- 229910052701 rubidium Inorganic materials 0.000 claims abstract description 10
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 10
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 10
- 229910052793 cadmium Inorganic materials 0.000 claims abstract description 9
- 229910052792 caesium Inorganic materials 0.000 claims abstract description 9
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 9
- 229910052738 indium Inorganic materials 0.000 claims abstract description 9
- 229910052741 iridium Inorganic materials 0.000 claims abstract description 9
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 9
- 229910052709 silver Inorganic materials 0.000 claims abstract description 9
- 229910052737 gold Inorganic materials 0.000 claims abstract description 8
- 229910052703 rhodium Inorganic materials 0.000 claims abstract description 8
- 229910052714 tellurium Inorganic materials 0.000 claims abstract description 8
- 239000007789 gas Substances 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 8
- 229910052707 ruthenium Inorganic materials 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 229910052762 osmium Inorganic materials 0.000 claims description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052788 barium Inorganic materials 0.000 claims description 5
- 239000001569 carbon dioxide Substances 0.000 claims description 4
- 239000012876 carrier material Substances 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 3
- 238000010924 continuous production Methods 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 30
- 230000001590 oxidative effect Effects 0.000 abstract description 4
- 150000003863 ammonium salts Chemical class 0.000 abstract description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 26
- 239000010936 titanium Substances 0.000 description 15
- 239000011575 calcium Substances 0.000 description 11
- 239000011651 chromium Substances 0.000 description 10
- 239000011777 magnesium Substances 0.000 description 10
- 239000011572 manganese Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 239000011701 zinc Substances 0.000 description 7
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 6
- 229910001882 dioxygen Inorganic materials 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 229910052727 yttrium Inorganic materials 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 5
- 239000011733 molybdenum Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 229910052790 beryllium Inorganic materials 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000012495 reaction gas Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 235000018660 ammonium molybdate Nutrition 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- YJVFFLUZDVXJQI-UHFFFAOYSA-L palladium(ii) acetate Chemical compound [Pd+2].CC([O-])=O.CC([O-])=O YJVFFLUZDVXJQI-UHFFFAOYSA-L 0.000 description 2
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000007306 turnover Effects 0.000 description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
- 229910052580 B4C Inorganic materials 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910003206 NH4VO3 Inorganic materials 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 1
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- YZYDPPZYDIRSJT-UHFFFAOYSA-K boron phosphate Chemical compound [B+3].[O-]P([O-])([O-])=O YZYDPPZYDIRSJT-UHFFFAOYSA-K 0.000 description 1
- 229910000149 boron phosphate Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- IJHFIVUWUURYJD-UHFFFAOYSA-M lanthanum(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[La+3] IJHFIVUWUURYJD-UHFFFAOYSA-M 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 150000002941 palladium compounds Chemical class 0.000 description 1
- MUJIDPITZJWBSW-UHFFFAOYSA-N palladium(2+) Chemical compound [Pd+2] MUJIDPITZJWBSW-UHFFFAOYSA-N 0.000 description 1
- RFLFDJSIZCCYIP-UHFFFAOYSA-L palladium(2+);sulfate Chemical compound [Pd+2].[O-]S([O-])(=O)=O RFLFDJSIZCCYIP-UHFFFAOYSA-L 0.000 description 1
- LXNAVEXFUKBNMK-UHFFFAOYSA-N palladium(II) acetate Substances [Pd].CC(O)=O.CC(O)=O LXNAVEXFUKBNMK-UHFFFAOYSA-N 0.000 description 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
- 229910000364 palladium(II) sulfate Inorganic materials 0.000 description 1
- JKDRQYIYVJVOPF-FDGPNNRMSA-L palladium(ii) acetylacetonate Chemical compound [Pd+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O JKDRQYIYVJVOPF-FDGPNNRMSA-L 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910021426 porous silicon Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910000166 zirconium phosphate Inorganic materials 0.000 description 1
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
- B01J23/6525—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/18—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10024437A DE10024437A1 (de) | 2000-05-19 | 2000-05-19 | Verfahren zur selektiven Herstellung von Essigsäure durch katalytische Oxidation von Ethan |
| PCT/EP2001/004987 WO2001090039A1 (de) | 2000-05-19 | 2001-05-03 | Verfahren zur selektiven herstellung von essigsäure durch katalytische oxidation von ethan und/oder ethylen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO20025148D0 NO20025148D0 (no) | 2002-10-25 |
| NO20025148L NO20025148L (no) | 2002-10-25 |
| NO328001B1 true NO328001B1 (no) | 2009-11-09 |
Family
ID=7642572
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20025148A NO328001B1 (no) | 2000-05-19 | 2002-10-25 | Fremgangsmate og katalysator for selektiv fremstilling av eddiksyre ved katalytisk oksydasjon av etan og/eller etylen |
Country Status (23)
| Country | Link |
|---|---|
| US (1) | US7015355B2 (zh) |
| EP (1) | EP1286942B1 (zh) |
| JP (1) | JP4116293B2 (zh) |
| KR (1) | KR100660311B1 (zh) |
| CN (2) | CN1441767A (zh) |
| AT (1) | ATE429413T1 (zh) |
| AU (2) | AU2001273986C1 (zh) |
| BR (1) | BR0110848B1 (zh) |
| CA (1) | CA2409933C (zh) |
| CZ (1) | CZ20023703A3 (zh) |
| DE (2) | DE10024437A1 (zh) |
| ES (1) | ES2324932T3 (zh) |
| MX (1) | MXPA02011419A (zh) |
| MY (1) | MY129521A (zh) |
| NO (1) | NO328001B1 (zh) |
| NZ (1) | NZ522266A (zh) |
| PL (1) | PL202774B1 (zh) |
| PT (1) | PT1286942E (zh) |
| RS (1) | RS50466B (zh) |
| RU (1) | RU2245322C2 (zh) |
| UA (1) | UA72812C2 (zh) |
| WO (1) | WO2001090039A1 (zh) |
| ZA (1) | ZA200210056B (zh) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0223681D0 (en) * | 2002-10-10 | 2002-11-20 | Bp Chem Int Ltd | Catalyst and process |
| US7009074B2 (en) | 2004-07-28 | 2006-03-07 | The Regents Of The University Of California | Process for direct oxidation of methane to acetic acid |
| KR100807972B1 (ko) * | 2005-08-10 | 2008-02-28 | 주식회사 엘지화학 | 아크릴산 선택성이 높은 복합 금속 산화물 촉매 |
| BRPI0707535B1 (pt) * | 2006-02-07 | 2016-12-20 | Celanese Int Corp | processos para a produção de ácido acético |
| CA2640681C (en) * | 2006-02-07 | 2014-01-28 | Celanese International Corporation | Use of predehydration towers in an ethane oxidation to acetic acid/ethylene process |
| FR2963101B1 (fr) | 2010-07-22 | 2013-02-15 | Commissariat Energie Atomique | Detecteur de particules et procede de realisation d'un tel detecteur |
| US20140275619A1 (en) | 2013-03-15 | 2014-09-18 | Celanese International Corporation | Process for Producing Acetic Acid and/or Ethanol By Methane Oxidation |
| CN103664572B (zh) * | 2013-12-14 | 2015-05-27 | 济南开发区星火科学技术研究院 | 一种由乙烷制备醋酸的工艺 |
| US10501390B2 (en) | 2014-06-30 | 2019-12-10 | Shell Oil Company | Alkane oxidative dehydrogenation and/or alkene oxidation |
| WO2016001112A1 (en) * | 2014-06-30 | 2016-01-07 | Shell Internationale Research Maatschappij B.V. | Treatment of a mixed metal oxide catalyst containing molybdenum, vanadium, niobium and optionally tellurium |
| CN108025998A (zh) * | 2015-09-18 | 2018-05-11 | 国际壳牌研究有限公司 | 烷烃氧化脱氢 |
| WO2020058843A1 (en) * | 2018-09-17 | 2020-03-26 | Sabic Global Technologies B.V. | A selective oxidation catalyst and a method for oxidizing c2 hydrocarbons in the presence of the selective oxidation catalyst |
| CN110963880A (zh) * | 2018-09-28 | 2020-04-07 | 中国科学院大连化学物理研究所 | 二氧化碳作为原料气稀释剂的乙烷氧化制乙烯工艺方法 |
| CN110963879A (zh) * | 2018-09-28 | 2020-04-07 | 中国科学院大连化学物理研究所 | 水作为原料气稀释剂的乙烷催化氧化制乙烯和乙酸的联产工艺方法 |
| IL282699B2 (en) | 2018-11-02 | 2024-05-01 | Shell Int Research | Wastewater separation of oxidative dehydrogenation of ethane |
| CN109847744B (zh) * | 2018-12-26 | 2022-02-15 | 万华化学集团股份有限公司 | 氨氧化催化剂，及其制备方法和制备间苯二甲腈的方法 |
| CN115487820B (zh) * | 2021-06-18 | 2024-06-28 | 中国石油化工股份有限公司 | 氨氧化催化剂及其制备方法和应用 |
| CN116408061A (zh) * | 2021-12-31 | 2023-07-11 | 中国石油天然气股份有限公司 | 乙烷选择氧化制乙酸和乙烯的催化剂及其制备方法与应用 |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4384897A (en) * | 1981-11-23 | 1983-05-24 | The Regents Of The University Of California | Method of treating biomass material |
| US4359504A (en) * | 1979-09-28 | 1982-11-16 | E. I. Du Pont De Nemours And Company | Dual-layer coating containing aluminum-flake pigment and coated article |
| SE432951B (sv) * | 1980-05-28 | 1984-04-30 | Eka Ab | Pappersprodukt innehallande cellulosafibrer och ett bindemedelssystem som omfattar kolloidal kiselsyra och katjonisk sterkelse samt forfarande for framstellning av pappersprodukten |
| US4506062A (en) * | 1982-08-09 | 1985-03-19 | Allied Colloids Limited | Inverse suspension polymerization process |
| GB8309275D0 (en) * | 1983-04-06 | 1983-05-11 | Allied Colloids Ltd | Dissolution of water soluble polymers in water |
| GB8401206D0 (en) * | 1984-01-17 | 1984-02-22 | Allied Colloids Ltd | Polymers and aqueous solutions |
| SE8403062L (sv) * | 1984-06-07 | 1985-12-08 | Eka Ab | Forfarande vid papperstillverkning |
| SE449876B (sv) * | 1984-12-07 | 1987-05-25 | Nobel Chematur Ab | Forfarande for framstellning av etanol med ett ytterligare centrifugalsepareringssteg, placerat antingen fore eller efter det primera destillationssteget |
| US4650689A (en) * | 1985-03-25 | 1987-03-17 | Urban Fuels, Inc. | Process for ethanol production from cellulosic materials |
| EP0202780B2 (en) * | 1985-04-25 | 1998-12-09 | Ciba Specialty Chemicals Water Treatments Limited | Flocculation processes |
| US4728613A (en) * | 1985-09-04 | 1988-03-01 | Miles Laboratories, Inc. | Method for the recovery of extracellular enzymes from whole fermentation beer |
| GB8602121D0 (en) * | 1986-01-29 | 1986-03-05 | Allied Colloids Ltd | Paper & paper board |
| US4864130A (en) * | 1986-06-04 | 1989-09-05 | Arch Development Corporation | Photo ion spectrometer |
| US5049692A (en) | 1987-11-25 | 1991-09-17 | Mitsubishi Kasei Corporation | Catalytic conversion of alkanes to nitriles, and a catalyst therefor |
| US5176891A (en) * | 1988-01-13 | 1993-01-05 | Eka Chemicals, Inc. | Polyaluminosilicate process |
| GB8802973D0 (en) | 1988-02-10 | 1988-03-09 | Molins Plc | Wrapping machines |
| US5681480A (en) * | 1991-08-02 | 1997-10-28 | Allied Colloids Limited | Dewatering of aqueous suspensions |
| US5209854A (en) * | 1992-06-29 | 1993-05-11 | Nalco Chemical Company | Pulp waste color removal with diallyl dimethyl ammonium chloride copolymers |
| US5552316A (en) * | 1993-06-04 | 1996-09-03 | Environmental Marketing Services, Ltd. | Clarifying E. coli fermentation broths with a combination of anionic and cationic flocculants |
| US5571703A (en) * | 1993-12-23 | 1996-11-05 | Controlled Environmental Systems Corporation | Municipal solid waste processing facility and commercial ethanol production process |
| US5482693A (en) * | 1994-03-14 | 1996-01-09 | E. I. Du Pont De Nemours And Company | Process for preparing water soluble polyaluminosilicates |
| US6071379A (en) * | 1996-09-24 | 2000-06-06 | Nalco Chemical Company | Papermaking process utilizing hydrophilic dispersion polymers of diallyldimethyl ammonium chloride and acrylamide as retention and drainage aids |
| MY120719A (en) * | 1997-01-20 | 2005-11-30 | Ciba Spec Chem Water Treat Ltd | Polymeric compositions and their production and uses |
| EP0895809B1 (en) * | 1997-08-05 | 2014-03-19 | Asahi Kasei Kabushiki Kaisha | Process Using Niobium-containing Aqueous Solution in Producing Niobium-containing Oxide Catalyst |
| ATE366844T1 (de) * | 1997-09-30 | 2007-08-15 | Nalco Chemical Co | Herstellung von papier mit kolloidalen borosilikaten |
| US6166123A (en) * | 1997-10-07 | 2000-12-26 | H. B. Fuller Company | Reflective composition of particles with resinous binder and process for preparing same |
| DE19745902A1 (de) * | 1997-10-17 | 1999-04-22 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure durch katalytische Oxidation von Ethan |
| WO1999055625A1 (en) * | 1998-04-24 | 1999-11-04 | Nalco Chemical Company | Use of polymer dispersions for paper mill color removal |
| US6217778B1 (en) * | 1999-09-08 | 2001-04-17 | Nalco Chemical Company | Anionic and nonionic dispersion polymers for clarification and dewatering |
| GB0218021D0 (en) * | 2002-08-05 | 2002-09-11 | Ciba Spec Chem Water Treat Ltd | Production of a fermentation product |
-
2000
- 2000-05-19 DE DE10024437A patent/DE10024437A1/de not_active Withdrawn
-
2001
- 2001-03-05 UA UA20021210279A patent/UA72812C2/uk unknown
- 2001-05-03 DE DE50114853T patent/DE50114853D1/de not_active Expired - Lifetime
- 2001-05-03 MX MXPA02011419A patent/MXPA02011419A/es active IP Right Grant
- 2001-05-03 ES ES01940393T patent/ES2324932T3/es not_active Expired - Lifetime
- 2001-05-03 PT PT01940393T patent/PT1286942E/pt unknown
- 2001-05-03 CZ CZ20023703A patent/CZ20023703A3/cs unknown
- 2001-05-03 EP EP01940393A patent/EP1286942B1/de not_active Expired - Lifetime
- 2001-05-03 AU AU2001273986A patent/AU2001273986C1/en not_active Ceased
- 2001-05-03 CN CN01809714A patent/CN1441767A/zh active Pending
- 2001-05-03 RU RU2002134460/04A patent/RU2245322C2/ru not_active IP Right Cessation
- 2001-05-03 AU AU7398601A patent/AU7398601A/xx active Pending
- 2001-05-03 NZ NZ522266A patent/NZ522266A/en not_active IP Right Cessation
- 2001-05-03 JP JP2001586230A patent/JP4116293B2/ja not_active Expired - Fee Related
- 2001-05-03 AT AT01940393T patent/ATE429413T1/de not_active IP Right Cessation
- 2001-05-03 KR KR1020027015565A patent/KR100660311B1/ko not_active IP Right Cessation
- 2001-05-03 CN CN2007101041259A patent/CN101041135B/zh not_active Expired - Fee Related
- 2001-05-03 CA CA002409933A patent/CA2409933C/en not_active Expired - Fee Related
- 2001-05-03 RS YUP-839/02A patent/RS50466B/sr unknown
- 2001-05-03 US US10/258,758 patent/US7015355B2/en not_active Expired - Lifetime
- 2001-05-03 BR BRPI0110848-4A patent/BR0110848B1/pt not_active IP Right Cessation
- 2001-05-03 PL PL358292A patent/PL202774B1/pl unknown
- 2001-05-03 WO PCT/EP2001/004987 patent/WO2001090039A1/de not_active Application Discontinuation
- 2001-05-17 MY MYPI20012334A patent/MY129521A/en unknown
-
2002
- 2002-10-25 NO NO20025148A patent/NO328001B1/no not_active IP Right Cessation
- 2002-12-11 ZA ZA200210056A patent/ZA200210056B/en unknown
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