NO324681B1 - Barete fosfinimin-cyklopentadienyl katalysatorer og fremgangsmate for anvendelse av samme i en polymeriseringsprosess - Google Patents
Barete fosfinimin-cyklopentadienyl katalysatorer og fremgangsmate for anvendelse av samme i en polymeriseringsprosess Download PDFInfo
- Publication number
- NO324681B1 NO324681B1 NO19983151A NO983151A NO324681B1 NO 324681 B1 NO324681 B1 NO 324681B1 NO 19983151 A NO19983151 A NO 19983151A NO 983151 A NO983151 A NO 983151A NO 324681 B1 NO324681 B1 NO 324681B1
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- Norway
- Prior art keywords
- radical
- group
- catalyst component
- radicals
- catalyst
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- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 5
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- WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 2
- 241000349731 Afzelia bipindensis Species 0.000 description 2
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- QMBQEXOLIRBNPN-UHFFFAOYSA-L zirconocene dichloride Chemical compound [Cl-].[Cl-].[Zr+4].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 QMBQEXOLIRBNPN-UHFFFAOYSA-L 0.000 description 2
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- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 125000002097 pentamethylcyclopentadienyl group Chemical group 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Chemical group C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 229910000064 phosphane Inorganic materials 0.000 description 1
- 150000003002 phosphanes Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- NLPMQGKZYAYAFE-UHFFFAOYSA-K titanium(iii) fluoride Chemical compound F[Ti](F)F NLPMQGKZYAYAFE-UHFFFAOYSA-K 0.000 description 1
- MDCWDBMBZLORER-UHFFFAOYSA-N triphenyl borate Chemical compound C=1C=CC=CC=1OB(OC=1C=CC=CC=1)OC1=CC=CC=C1 MDCWDBMBZLORER-UHFFFAOYSA-N 0.000 description 1
- OLFPYUPGPBITMH-UHFFFAOYSA-N tritylium Chemical compound C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 OLFPYUPGPBITMH-UHFFFAOYSA-N 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002210131A CA2210131C (en) | 1997-07-09 | 1997-07-09 | Supported phosphinimine-cp catalysts |
Publications (2)
| Publication Number | Publication Date |
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| NO983151L NO983151L (no) | 1999-01-11 |
| NO324681B1 true NO324681B1 (no) | 2007-12-03 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| NO19983151A NO324681B1 (no) | 1997-07-09 | 1998-07-08 | Barete fosfinimin-cyklopentadienyl katalysatorer og fremgangsmate for anvendelse av samme i en polymeriseringsprosess |
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| Country | Link |
|---|---|
| US (1) | US5965677A (xx) |
| EP (1) | EP0890581B1 (xx) |
| JP (1) | JP4237298B2 (xx) |
| CN (1) | CN1222548C (xx) |
| AT (1) | ATE235518T1 (xx) |
| AU (1) | AU740558B2 (xx) |
| BR (1) | BR9802353A (xx) |
| CA (1) | CA2210131C (xx) |
| DE (1) | DE69812485T2 (xx) |
| ES (1) | ES2196493T3 (xx) |
| FI (1) | FI120941B (xx) |
| IN (1) | IN1998KO01071A (xx) |
| NO (1) | NO324681B1 (xx) |
| RU (1) | RU2203908C2 (xx) |
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| ATE200785T1 (de) * | 1996-07-04 | 2001-05-15 | Basf Ag | Verfahren zur herstellung von geträgerten übergangsmetallkatalysatoren |
| CA2206944C (en) * | 1997-05-30 | 2006-08-29 | Douglas W. Stephan | High temperature solution polymerization process |
| CA2228923A1 (en) * | 1998-02-06 | 1999-08-06 | Nova Chemicals Ltd. | Process for preparing supported olefin polymerization catalyst |
| DE69935815T2 (de) | 1998-07-01 | 2007-12-27 | Exxonmobil Chemical Patents Inc., Baytown | Elastische Mischung mit Kristallpolymeren und kristallisierbaren Polymeren des Propens |
| CA2243783C (en) * | 1998-07-21 | 2007-06-05 | Nova Chemicals Ltd. | Bis-phosphinimine catalyst |
| CA2243726C (en) * | 1998-07-21 | 2006-12-12 | Nova Chemicals Ltd. | Cyclopentadienyl/phosphinimine catalyst with one and only one activatable ligand |
| CA2245375C (en) * | 1998-08-19 | 2006-08-15 | Nova Chemicals Ltd. | Dual reactor polyethylene process using a phosphinimine catalyst |
| CA2247703C (en) * | 1998-09-22 | 2007-04-17 | Nova Chemicals Ltd. | Dual reactor ethylene polymerization process |
| CA2254512C (en) * | 1998-11-25 | 2008-02-12 | Nova Chemicals Ltd. | Slurry polymerization process using an unsupported phosphinimine catalyst |
| CA2254841C (en) * | 1998-11-26 | 2007-02-06 | Nova Chemicals Ltd. | Nitrogen substituted phosphinimine ligand |
| CA2254601C (en) * | 1998-11-27 | 2007-10-23 | Nova Chemicals Ltd. | Aluminum-phosphinimine complexes as catalysts for the (co)polymerization of ethylene |
| US6852811B1 (en) * | 1998-12-30 | 2005-02-08 | The Dow Chemical Company | Process for preparing a supported polymerization catalyst using reduced amounts of solvent and polymerization process |
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| CA2278042C (en) * | 1999-07-19 | 2008-12-16 | Nova Chemicals Corporation | Mixed phosphinimine catalyst |
| CA2282070C (en) | 1999-09-10 | 2008-12-09 | Nova Chemicals Corporation | Hydrocarbyl phosphinimine/cyclopentadienyl complexes of group iv metals and preparation thereof |
| US6281306B1 (en) * | 1999-12-16 | 2001-08-28 | Univation Technologies, Llc | Method of polymerization |
| US6340771B1 (en) * | 1999-12-22 | 2002-01-22 | Nova Chemicals (International) S. A. | “Sweet” MAO |
| US6852659B1 (en) | 2000-11-16 | 2005-02-08 | Univation Technologies, Llc | Method for preparing a catalyst composition and its use in a polymerization process |
| CN1478105A (zh) * | 2000-11-17 | 2004-02-25 | 尤尼威蒂恩技术有限责任公司 | 催化剂组合物的制备方法及其在聚合过程中的应用 |
| US6555495B2 (en) * | 2000-12-06 | 2003-04-29 | Univation Technologies, Llc | Catalyst support method and polymerization with supported catalysts |
| JP5156167B2 (ja) | 2001-04-12 | 2013-03-06 | エクソンモービル・ケミカル・パテンツ・インク | プロピレン−エチレンポリマー及び製造法 |
| WO2002088200A1 (en) | 2001-04-30 | 2002-11-07 | W.R. Grace & Co.-Conn. | Supported dual transition metal catalyst systems |
| US6943224B2 (en) | 2001-04-30 | 2005-09-13 | W. R. Grace & Co.-Conn. | Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby |
| WO2003000790A1 (en) | 2001-06-22 | 2003-01-03 | Exxonmobil Chemical Patents, Inc. | Metallocene-produced very low density polyethylenes or linear lowdensity polyethylenes as impact modifiers |
| DE10140202A1 (de) * | 2001-08-16 | 2003-03-06 | Bayer Ag | Vanadium-Imido-Phosphoraniminato für die Olefinpolymerisation |
| CA2357385C (en) * | 2001-09-17 | 2010-06-15 | Nova Chemicals Corporation | Supported phosphinimine polymerization catalyst |
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| US6943215B2 (en) | 2001-11-06 | 2005-09-13 | Dow Global Technologies Inc. | Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers |
| US6927256B2 (en) | 2001-11-06 | 2005-08-09 | Dow Global Technologies Inc. | Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent |
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| RU2375381C2 (ru) | 2004-03-17 | 2009-12-10 | Дау Глобал Текнолоджиз Инк. | Состав катализатора, содержащий челночный агент, для формирования мульти-блок-сополимера высшего олефина |
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| US9051229B2 (en) | 2012-12-21 | 2015-06-09 | Governors Of The University Of Alberta | Transition metal catalysts for C—O hydrogenolysis and hydrodeoxygenation |
| US9120741B2 (en) | 2012-12-21 | 2015-09-01 | Governors Of The University Of Alberta | Transition metal catalysts for hydrogenation and hydrosilylation |
| US9120984B2 (en) | 2012-12-21 | 2015-09-01 | Governors Of The University Of Alberta | Transition metal catalysts for hydrodesulfurization |
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| TWI756272B (zh) | 2016-09-30 | 2022-03-01 | 美商陶氏全球科技有限責任公司 | 適用於鏈梭移之封端多頭或雙頭組合物及其製備方法 |
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| EP3768686A1 (en) | 2018-03-19 | 2021-01-27 | Dow Global Technologies, LLC | Silicon-terminated organo-metal compounds and processes for preparing the same |
| CN113474405A (zh) | 2018-12-28 | 2021-10-01 | 陶氏环球技术有限责任公司 | 包括不饱和聚烯烃的可固化组合物 |
| US20220081500A1 (en) | 2018-12-28 | 2022-03-17 | Dow Global Technologies Llc | Curable compositions comprising unsaturated polyolefins |
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| CN115698102A (zh) | 2020-05-29 | 2023-02-03 | 陶氏环球技术有限责任公司 | 减弱的后茂金属催化剂 |
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| US4897455A (en) * | 1985-06-21 | 1990-01-30 | Exxon Chemical Patents Inc. | Polymerization process |
| US5077255A (en) * | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
| US5198401A (en) * | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US5153157A (en) * | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| US5352749A (en) * | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| US5332706A (en) * | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
| DE4409249A1 (de) * | 1994-03-18 | 1995-09-21 | Witco Gmbh | Verfahren zur Herstellung von Alkylaluminoxan auf inerten Trägermaterialien |
| US5557023A (en) * | 1995-05-23 | 1996-09-17 | The Governors Of The University Of Alberta | Olefin oligomerization in the presence of novel complexes |
| CA2206944C (en) * | 1997-05-30 | 2006-08-29 | Douglas W. Stephan | High temperature solution polymerization process |
-
1997
- 1997-07-09 CA CA002210131A patent/CA2210131C/en not_active Expired - Lifetime
- 1997-10-29 US US08/959,589 patent/US5965677A/en not_active Expired - Lifetime
-
1998
- 1998-06-16 IN IN1071CA1998 patent/IN1998KO01071A/en unknown
- 1998-06-17 AU AU71920/98A patent/AU740558B2/en not_active Expired
- 1998-06-17 FI FI981404A patent/FI120941B/fi not_active IP Right Cessation
- 1998-07-06 EP EP98305352A patent/EP0890581B1/en not_active Expired - Lifetime
- 1998-07-06 DE DE69812485T patent/DE69812485T2/de not_active Expired - Lifetime
- 1998-07-06 ES ES98305352T patent/ES2196493T3/es not_active Expired - Lifetime
- 1998-07-06 AT AT98305352T patent/ATE235518T1/de active
- 1998-07-08 RU RU98113411/04A patent/RU2203908C2/ru active
- 1998-07-08 JP JP19288198A patent/JP4237298B2/ja not_active Expired - Lifetime
- 1998-07-08 NO NO19983151A patent/NO324681B1/no not_active IP Right Cessation
- 1998-07-08 BR BR9802353-5A patent/BR9802353A/pt not_active IP Right Cessation
- 1998-07-09 CN CN98115968.0A patent/CN1222548C/zh not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP4237298B2 (ja) | 2009-03-11 |
| IN1998KO01071A (xx) | 2015-07-10 |
| EP0890581A1 (en) | 1999-01-13 |
| FI981404A0 (fi) | 1998-06-17 |
| CN1206015A (zh) | 1999-01-27 |
| EP0890581B1 (en) | 2003-03-26 |
| FI120941B (fi) | 2010-05-14 |
| AU7192098A (en) | 1999-01-21 |
| ATE235518T1 (de) | 2003-04-15 |
| RU2203908C2 (ru) | 2003-05-10 |
| FI981404A (fi) | 1999-01-10 |
| NO983151L (no) | 1999-01-11 |
| JPH1171420A (ja) | 1999-03-16 |
| CA2210131C (en) | 2005-08-02 |
| CA2210131A1 (en) | 1999-01-09 |
| AU740558B2 (en) | 2001-11-08 |
| ES2196493T3 (es) | 2003-12-16 |
| CN1222548C (zh) | 2005-10-12 |
| DE69812485D1 (de) | 2003-04-30 |
| US5965677A (en) | 1999-10-12 |
| DE69812485T2 (de) | 2004-03-04 |
| BR9802353A (pt) | 1999-12-14 |
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