NO321051B1 - Katalysatorsammensetning og fremgangsmate for oksidasjon av etan og/eller etylen til eddiksyre, samt anvendelse av katalysatorsammensetningen i en integrert fremgangsmate for fremstilling av eddiksyre og/eller vinylacetat. - Google Patents
Katalysatorsammensetning og fremgangsmate for oksidasjon av etan og/eller etylen til eddiksyre, samt anvendelse av katalysatorsammensetningen i en integrert fremgangsmate for fremstilling av eddiksyre og/eller vinylacetat. Download PDFInfo
- Publication number
- NO321051B1 NO321051B1 NO20004909A NO20004909A NO321051B1 NO 321051 B1 NO321051 B1 NO 321051B1 NO 20004909 A NO20004909 A NO 20004909A NO 20004909 A NO20004909 A NO 20004909A NO 321051 B1 NO321051 B1 NO 321051B1
- Authority
- NO
- Norway
- Prior art keywords
- catalyst composition
- acetic acid
- ethylene
- composition according
- ethane
- Prior art date
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title claims description 141
- 239000003054 catalyst Substances 0.000 title claims description 102
- 239000000203 mixture Substances 0.000 title claims description 68
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 title claims description 45
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 42
- 239000005977 Ethylene Substances 0.000 title claims description 42
- 238000000034 method Methods 0.000 title claims description 28
- 238000004519 manufacturing process Methods 0.000 title claims description 20
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 title claims description 16
- 230000003647 oxidation Effects 0.000 title claims description 16
- 238000007254 oxidation reaction Methods 0.000 title claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 26
- 229910052760 oxygen Inorganic materials 0.000 claims description 26
- 239000001301 oxygen Substances 0.000 claims description 26
- 239000007789 gas Substances 0.000 claims description 19
- 229910052787 antimony Inorganic materials 0.000 claims description 13
- 229910052741 iridium Inorganic materials 0.000 claims description 13
- 229910052709 silver Inorganic materials 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 229910052748 manganese Inorganic materials 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 229910001882 dioxygen Inorganic materials 0.000 claims description 10
- 229910052804 chromium Inorganic materials 0.000 claims description 9
- 229910052749 magnesium Inorganic materials 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- 229910052763 palladium Inorganic materials 0.000 claims description 9
- 229910052702 rhenium Inorganic materials 0.000 claims description 9
- 229910052716 thallium Inorganic materials 0.000 claims description 9
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 8
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 8
- 229910052745 lead Inorganic materials 0.000 claims description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims description 8
- 229910052707 ruthenium Inorganic materials 0.000 claims description 8
- 239000004332 silver Substances 0.000 claims description 8
- 229910052715 tantalum Inorganic materials 0.000 claims description 8
- 229910052718 tin Inorganic materials 0.000 claims description 8
- 229910052791 calcium Inorganic materials 0.000 claims description 7
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 7
- 229910052697 platinum Inorganic materials 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 6
- 229910052735 hafnium Inorganic materials 0.000 claims description 6
- 238000011084 recovery Methods 0.000 claims description 6
- 229910052701 rubidium Inorganic materials 0.000 claims description 6
- 229910052712 strontium Inorganic materials 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- 229910052770 Uranium Inorganic materials 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 5
- 229910052793 cadmium Inorganic materials 0.000 claims description 5
- 229910052792 caesium Inorganic materials 0.000 claims description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 229910052788 barium Inorganic materials 0.000 claims description 4
- 239000001569 carbon dioxide Substances 0.000 claims description 4
- 229910052733 gallium Inorganic materials 0.000 claims description 4
- 239000008246 gaseous mixture Substances 0.000 claims description 4
- 229910052738 indium Inorganic materials 0.000 claims description 4
- 238000004064 recycling Methods 0.000 claims description 4
- 229910052703 rhodium Inorganic materials 0.000 claims description 4
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 238000004821 distillation Methods 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 15
- 239000010955 niobium Substances 0.000 description 9
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 8
- 229910052758 niobium Inorganic materials 0.000 description 8
- 239000010936 titanium Substances 0.000 description 8
- 229910052720 vanadium Inorganic materials 0.000 description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- 229910052750 molybdenum Inorganic materials 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 6
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 5
- 229940010552 ammonium molybdate Drugs 0.000 description 5
- 235000018660 ammonium molybdate Nutrition 0.000 description 5
- 239000011609 ammonium molybdate Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000001307 helium Substances 0.000 description 5
- 229910052734 helium Inorganic materials 0.000 description 5
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 5
- 235000006408 oxalic acid Nutrition 0.000 description 5
- YHBDIEWMOMLKOO-UHFFFAOYSA-I pentachloroniobium Chemical compound Cl[Nb](Cl)(Cl)(Cl)Cl YHBDIEWMOMLKOO-UHFFFAOYSA-I 0.000 description 5
- 229910052721 tungsten Inorganic materials 0.000 description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 4
- JVLRYPRBKSMEBF-UHFFFAOYSA-K diacetyloxystibanyl acetate Chemical compound [Sb+3].CC([O-])=O.CC([O-])=O.CC([O-])=O JVLRYPRBKSMEBF-UHFFFAOYSA-K 0.000 description 4
- 239000011733 molybdenum Substances 0.000 description 4
- HRLYFPKUYKFYJE-UHFFFAOYSA-N tetraoxorhenate(2-) Chemical compound [O-][Re]([O-])(=O)=O HRLYFPKUYKFYJE-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- 229910052785 arsenic Inorganic materials 0.000 description 3
- 229910052790 beryllium Inorganic materials 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 229910052727 yttrium Inorganic materials 0.000 description 3
- 229910052684 Cerium Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- LGDAGYXJBDILKZ-UHFFFAOYSA-N [2-methyl-1,1-dioxo-3-(pyridin-2-ylcarbamoyl)-1$l^{6},2-benzothiazin-4-yl] 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC=1C2=CC=CC=C2S(=O)(=O)N(C)C=1C(=O)NC1=CC=CC=N1 LGDAGYXJBDILKZ-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000011067 equilibration Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 229910052762 osmium Inorganic materials 0.000 description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- YGOVEJPTJBNYBI-UHFFFAOYSA-H Cl[Ir](Cl)(Cl)(Cl)(Cl)Cl.N Chemical compound Cl[Ir](Cl)(Cl)(Cl)(Cl)Cl.N YGOVEJPTJBNYBI-UHFFFAOYSA-H 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 229910000856 hastalloy Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- YJVFFLUZDVXJQI-UHFFFAOYSA-L palladium(ii) acetate Chemical compound [Pd+2].CC([O-])=O.CC([O-])=O YJVFFLUZDVXJQI-UHFFFAOYSA-L 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 description 1
- 229940071536 silver acetate Drugs 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- -1 that described Chemical compound 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
- B01J23/6525—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
- B01J23/686—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9807142.6A GB9807142D0 (en) | 1998-04-02 | 1998-04-02 | Catalyst and process utilising the catalyst |
| PCT/GB1999/000996 WO1999051339A1 (en) | 1998-04-02 | 1999-03-31 | Catalyst and process for the oxidation of ethane and/or ethylene |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO20004909D0 NO20004909D0 (no) | 2000-09-29 |
| NO20004909L NO20004909L (no) | 2000-11-17 |
| NO321051B1 true NO321051B1 (no) | 2006-03-06 |
Family
ID=10829783
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20004909A NO321051B1 (no) | 1998-04-02 | 2000-09-29 | Katalysatorsammensetning og fremgangsmate for oksidasjon av etan og/eller etylen til eddiksyre, samt anvendelse av katalysatorsammensetningen i en integrert fremgangsmate for fremstilling av eddiksyre og/eller vinylacetat. |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US6350716B1 (id) |
| EP (1) | EP1069945B1 (id) |
| JP (1) | JP4374140B2 (id) |
| KR (1) | KR100540016B1 (id) |
| CN (1) | CN1138596C (id) |
| AU (1) | AU3160899A (id) |
| BR (1) | BR9909164B1 (id) |
| DE (1) | DE69907899T2 (id) |
| ES (1) | ES2200516T3 (id) |
| GB (1) | GB9807142D0 (id) |
| ID (1) | ID26782A (id) |
| NO (1) | NO321051B1 (id) |
| RU (1) | RU2208480C2 (id) |
| SG (1) | SG105561A1 (id) |
| TR (1) | TR200002817T2 (id) |
| UA (1) | UA66848C2 (id) |
| WO (1) | WO1999051339A1 (id) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9819221D0 (en) | 1998-09-04 | 1998-10-28 | Bp Chem Int Ltd | Process for the production of acetic acid |
| US6114278A (en) * | 1998-11-16 | 2000-09-05 | Saudi Basic Industries Corporation | Catalysts for catalytic oxidation of propane to acrylic acid, methods of making and using the same |
| US6417422B1 (en) * | 1999-02-22 | 2002-07-09 | Symyx Technologies, Inc. | Ni catalysts and methods for alkane dehydrogenation |
| GB9907704D0 (en) | 1999-04-01 | 1999-05-26 | Bp Chem Int Ltd | Catalyst and process utilising the catalyst |
| JP4809532B2 (ja) * | 1999-11-15 | 2011-11-09 | サウディ ベーシック インダストリーズ コーポレイション | プロパンのアクリル酸への接触酸化用触媒、その製造法及び使用法 |
| US6693059B2 (en) * | 2000-02-09 | 2004-02-17 | Rohm And Haas Company | Process for preparing a catalyst and catalytic oxidation therewith |
| GB0014584D0 (en) * | 2000-06-14 | 2000-08-09 | Bp Chem Int Ltd | Apparatus and process |
| GB0026243D0 (en) * | 2000-10-26 | 2000-12-13 | Bp Chem Int Ltd | Process |
| GB0026242D0 (en) | 2000-10-26 | 2000-12-13 | Bp Chem Int Ltd | Apparatus and process |
| US7368599B2 (en) * | 2001-10-16 | 2008-05-06 | Bp Chemicals Limited | Ethane oxidation catalyst and process utilising the catalyst |
| TWI322709B (en) * | 2001-12-04 | 2010-04-01 | Bp Chem Int Ltd | Oxidation process in fluidised bed reactor |
| US6919472B2 (en) * | 2001-12-21 | 2005-07-19 | Saudi Basic Industries Corporation | Catalyst compositions for the selective conversion of alkanes to unsaturated carboxylic acids, methods of making and methods of using thereof |
| GB0223681D0 (en) * | 2002-10-10 | 2002-11-20 | Bp Chem Int Ltd | Catalyst and process |
| US7718811B2 (en) | 2002-11-26 | 2010-05-18 | Ineos Europe Limited | Oxidation process in fluidised bed reactor |
| CN1871064B (zh) * | 2003-08-21 | 2015-04-01 | 英国石油化学品有限公司 | 催化剂组合物及其在乙烷氧化中的用途 |
| US7727928B2 (en) | 2004-07-30 | 2010-06-01 | Bp Chemicals Limited | Catalyst composition and use thereof in ethane oxidation |
| EP2628534A1 (en) * | 2009-11-02 | 2013-08-21 | Dow Global Technologies LLC | Supported rhodium synthesis gas conversion catalyst compositions |
| CN102939154B (zh) * | 2010-04-09 | 2014-09-10 | 陶氏环球技术有限责任公司 | 用于生产混合的醇的催化剂组合物 |
| EP2853521B1 (en) | 2010-05-24 | 2018-10-10 | Siluria Technologies, Inc. | Method for the oxidative coupling of methane in the presence of a nanowire catalyst |
| EP3702028A1 (en) | 2011-05-24 | 2020-09-02 | Siluria Technologies, Inc. | Catalysts for petrochemical catalysis |
| CA2856310C (en) | 2011-11-29 | 2021-09-21 | Siluria Technologies, Inc. | Nanowire catalysts and methods for their use and preparation |
| US9545610B2 (en) | 2013-03-04 | 2017-01-17 | Nova Chemicals (International) S.A. | Complex comprising oxidative dehydrogenation unit |
| EP2969184A4 (en) | 2013-03-15 | 2016-12-21 | Siluria Technologies Inc | CATALYSTS FOR PETROCHEMICAL CATALYSIS |
| US9956544B2 (en) | 2014-05-02 | 2018-05-01 | Siluria Technologies, Inc. | Heterogeneous catalysts |
| SG11201701718XA (en) | 2014-09-17 | 2017-04-27 | Siluria Technologies Inc | Catalysts for oxidative coupling of methane and oxidative dehydrogenation of ethane |
| CN106582866B (zh) * | 2015-10-19 | 2019-08-06 | 中国石油化工股份有限公司 | 制备乙烯法醋酸乙烯所用的催化剂 |
| CN106582820B (zh) * | 2015-10-19 | 2019-07-05 | 中国石油化工股份有限公司 | 乙烯法醋酸乙烯合成所用的催化剂 |
| EP3429747A2 (en) | 2016-03-16 | 2019-01-23 | Siluria Technologies, Inc. | Catalysts and methods for natural gas processes |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2885409A (en) * | 1957-05-27 | 1959-05-05 | American Cyanamid Co | Maleic anhydride production and catalyst therefor |
| GB944494A (en) * | 1961-01-06 | 1963-12-18 | Allied Chem | Improvements relating to oxidation catalysts |
| JPS552619A (en) * | 1978-06-21 | 1980-01-10 | Nippon Kayaku Co Ltd | Preparation of methacrylic acid and catalyst |
| US4250346A (en) * | 1980-04-14 | 1981-02-10 | Union Carbide Corporation | Low temperature oxydehydrogenation of ethane to ethylene |
| US4419270A (en) * | 1980-06-26 | 1983-12-06 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Oxidation catalyst |
| GB8915410D0 (en) | 1989-07-05 | 1989-08-23 | Bp Chem Int Ltd | Chemical process |
| US4524236A (en) * | 1984-06-28 | 1985-06-18 | Union Carbide Corporation | Process for oxydehydrogenation of ethane to ethylene |
| US4568790A (en) * | 1984-06-28 | 1986-02-04 | Union Carbide Corporation | Process for oxydehydrogenation of ethane to ethylene |
| US4596787A (en) | 1985-04-11 | 1986-06-24 | Union Carbide Corporation | Process for preparing a supported catalyst for the oxydehydrogenation of ethane to ethylene |
| US4808563A (en) * | 1986-03-24 | 1989-02-28 | The Standard Oil Company | Molybdenum-tungsten-containing catalyst for methane conversion process |
| US4797381A (en) * | 1987-07-30 | 1989-01-10 | The Standard Oil Company | Preparation of abrasion resistant alumina-supported vanadium-antimony oxidic catalysts |
| DE4022212A1 (de) * | 1990-07-12 | 1992-01-16 | Basf Ag | Massen der allgemeinen formel mo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)2(pfeil abwaerts)(pfeil hoch)p(pfeil hoch)(pfeil abwaerts)a(pfeil abwaerts)(pfeil hoch)v(pfeil hoch)(pfeil abwaerts)b(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)1(pfeil hoch)(pfeil abwaerts)c(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)2(pfeil hoch)(pfeil abwaerts)d(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)3(pfeil hoch)(pfeil abwaerts)e(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil hoch)b(pfeil hoch)(pfeil abwaerts)f(pfeil abwaerts)(pfeil hoch)r(pfeil hoch)(pfeil hoch)e(pfeil hoch)(pfeil abwaerts)g(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil abwaerts)h(pfeil abwaerts)(pfeil hoch)o(pfeil hoch)(pfeil abwaerts)n(pfeil abwaerts) |
| US5300682A (en) | 1991-06-10 | 1994-04-05 | The Standard Oil Co. | Catalytic oxidation of ethane to acetic acid |
| DE4335973A1 (de) * | 1993-10-21 | 1995-04-27 | Basf Ag | Verfahren zur Herstellung von katalytisch aktiven Multimetalloxidmassen, die als Grundbestandteile die Elemente V und Mo in oxidischer Form enthalten |
| US5498588A (en) * | 1994-09-09 | 1996-03-12 | The Standard Oil Company | Surface modification and promotion of vanadium antimony oxide catalysts |
| FR2728898B1 (fr) | 1994-12-29 | 1997-01-31 | Rhone Poulenc Chimie | Procede de preparation d'acides carboxyliques par oxydation menagee des alcanes correspondants |
| DE19519004A1 (de) | 1995-05-24 | 1996-11-28 | Hoechst Ag | Neue selen- und rutheniumhaltige Metalloxidkatalysatoren sowie ein Verfahren zu ihrer Herstellung und ihre Verwendung |
| US5625084A (en) * | 1996-01-31 | 1997-04-29 | Arco Chemical Technology, L.P. | Vapor phase oxidation of propylene to propylene oxide |
| DE19620542A1 (de) | 1996-05-22 | 1997-11-27 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure |
| DE19630832A1 (de) * | 1996-07-31 | 1998-02-05 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure |
| GB9616573D0 (en) | 1996-08-07 | 1996-09-25 | Bp Chem Int Ltd | Process |
| US5994580A (en) * | 1996-10-21 | 1999-11-30 | Toagosei Co., Ltd. | Process for producing acrylic acid |
| DE19717076A1 (de) | 1997-04-23 | 1998-10-29 | Hoechst Ag | Katalysator und Verfahren zur katalytischen Oxidation von Ethan zu Essigsäure |
| US6013597A (en) * | 1997-09-17 | 2000-01-11 | Saudi Basic Industries Corporation | Catalysts for the oxidation of ethane to acetic acid processes of making same and, processes of using same |
| DE19745902A1 (de) | 1997-10-17 | 1999-04-22 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure durch katalytische Oxidation von Ethan |
| US6043185A (en) * | 1999-04-02 | 2000-03-28 | The Standard Oil Company | Gallium promoted molybdenum vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation |
-
1998
- 1998-04-02 GB GBGB9807142.6A patent/GB9807142D0/en not_active Ceased
-
1999
- 1999-03-31 TR TR2000/02817T patent/TR200002817T2/xx unknown
- 1999-03-31 ID IDW20001966A patent/ID26782A/id unknown
- 1999-03-31 SG SG200205777A patent/SG105561A1/en unknown
- 1999-03-31 RU RU2000127740/04A patent/RU2208480C2/ru not_active IP Right Cessation
- 1999-03-31 BR BRPI9909164-0A patent/BR9909164B1/pt not_active IP Right Cessation
- 1999-03-31 WO PCT/GB1999/000996 patent/WO1999051339A1/en active IP Right Grant
- 1999-03-31 EP EP99913496A patent/EP1069945B1/en not_active Expired - Lifetime
- 1999-03-31 CN CNB998067091A patent/CN1138596C/zh not_active Expired - Fee Related
- 1999-03-31 ES ES99913496T patent/ES2200516T3/es not_active Expired - Lifetime
- 1999-03-31 AU AU31608/99A patent/AU3160899A/en not_active Abandoned
- 1999-03-31 DE DE69907899T patent/DE69907899T2/de not_active Expired - Lifetime
- 1999-03-31 UA UA2000116193A patent/UA66848C2/uk unknown
- 1999-03-31 KR KR10-2000-7011019A patent/KR100540016B1/ko not_active IP Right Cessation
- 1999-03-31 JP JP2000542098A patent/JP4374140B2/ja not_active Expired - Fee Related
-
2000
- 2000-09-20 US US09/665,905 patent/US6350716B1/en not_active Expired - Lifetime
- 2000-09-29 NO NO20004909A patent/NO321051B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ES2200516T3 (es) | 2004-03-01 |
| NO20004909D0 (no) | 2000-09-29 |
| JP4374140B2 (ja) | 2009-12-02 |
| CN1138596C (zh) | 2004-02-18 |
| UA66848C2 (uk) | 2004-06-15 |
| US6350716B1 (en) | 2002-02-26 |
| BR9909164A (pt) | 2001-10-16 |
| BR9909164B1 (pt) | 2010-07-13 |
| RU2208480C2 (ru) | 2003-07-20 |
| KR20010042430A (ko) | 2001-05-25 |
| CN1303320A (zh) | 2001-07-11 |
| EP1069945B1 (en) | 2003-05-14 |
| ID26782A (id) | 2001-02-08 |
| WO1999051339A1 (en) | 1999-10-14 |
| DE69907899D1 (de) | 2003-06-18 |
| NO20004909L (no) | 2000-11-17 |
| JP2002510543A (ja) | 2002-04-09 |
| DE69907899T2 (de) | 2004-01-22 |
| KR100540016B1 (ko) | 2005-12-29 |
| GB9807142D0 (en) | 1998-06-03 |
| SG105561A1 (en) | 2004-08-27 |
| EP1069945A1 (en) | 2001-01-24 |
| AU3160899A (en) | 1999-10-25 |
| TR200002817T2 (tr) | 2000-12-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| NO321051B1 (no) | Katalysatorsammensetning og fremgangsmate for oksidasjon av etan og/eller etylen til eddiksyre, samt anvendelse av katalysatorsammensetningen i en integrert fremgangsmate for fremstilling av eddiksyre og/eller vinylacetat. | |
| US6333444B1 (en) | Oxidation catalyst and process utilizing the catalyst | |
| EP1296925B1 (en) | Process for the production of vinyl acetate | |
| NO323890B1 (no) | Fremgangsmate for selektiv fremstilling av eddiksyre og katalysatorer egnet for fremstillingen | |
| CA2410999C (en) | Integrated process for the production of vinyl acetate | |
| AU2000249242A1 (en) | Integrated process for the production of vinyl acetate | |
| NO326454B1 (no) | Fremgangsmate og katalysator for fremstilling av eddiksyre ved katalytisk oksidasjon av etan | |
| KR100932416B1 (ko) | 에탄 산화 촉매 및 상기 촉매의 이용 방법 | |
| KR100978775B1 (ko) | 혼합 금속 산화물 촉매 및 아세트산 제조 방법 | |
| KR100628675B1 (ko) | 비닐 아세테이트의 제조방법 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM1K | Lapsed by not paying the annual fees |