NO304275B1 - Flertrinns fremgangsmÕte for hydrogenavsvovling - Google Patents
Flertrinns fremgangsmÕte for hydrogenavsvovling Download PDFInfo
- Publication number
- NO304275B1 NO304275B1 NO914379A NO914379A NO304275B1 NO 304275 B1 NO304275 B1 NO 304275B1 NO 914379 A NO914379 A NO 914379A NO 914379 A NO914379 A NO 914379A NO 304275 B1 NO304275 B1 NO 304275B1
- Authority
- NO
- Norway
- Prior art keywords
- hydrogen
- zone
- desulphurisation
- liquid
- line
- Prior art date
Links
- 239000001257 hydrogen Substances 0.000 title claims abstract description 264
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 264
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 261
- 238000006477 desulfuration reaction Methods 0.000 title claims description 74
- 230000023556 desulfurization Effects 0.000 title claims description 74
- 238000000034 method Methods 0.000 title claims description 60
- 230000008569 process Effects 0.000 title claims description 22
- 239000007789 gas Substances 0.000 claims abstract description 105
- 239000007788 liquid Substances 0.000 claims abstract description 101
- 239000003054 catalyst Substances 0.000 claims abstract description 75
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 70
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 70
- 239000011593 sulfur Substances 0.000 claims abstract description 67
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 32
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 32
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 31
- 239000000463 material Substances 0.000 claims abstract description 22
- 239000003085 diluting agent Substances 0.000 claims abstract description 10
- 239000011344 liquid material Substances 0.000 claims abstract description 5
- 239000007787 solid Substances 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims description 31
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 9
- 238000004064 recycling Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 3
- 238000012544 monitoring process Methods 0.000 claims description 3
- 238000007664 blowing Methods 0.000 claims description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract description 49
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract description 45
- 239000005864 Sulphur Substances 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 description 35
- 238000005984 hydrogenation reaction Methods 0.000 description 28
- 125000003118 aryl group Chemical group 0.000 description 26
- -1 alkyl mercaptans Chemical class 0.000 description 19
- 239000003921 oil Substances 0.000 description 17
- 230000000694 effects Effects 0.000 description 15
- 239000000047 product Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 14
- 238000004517 catalytic hydrocracking Methods 0.000 description 13
- 150000001491 aromatic compounds Chemical class 0.000 description 10
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 238000012545 processing Methods 0.000 description 10
- 238000000926 separation method Methods 0.000 description 10
- 150000003464 sulfur compounds Chemical class 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 239000010779 crude oil Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000012071 phase Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 230000009467 reduction Effects 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 238000011049 filling Methods 0.000 description 6
- 239000007791 liquid phase Substances 0.000 description 6
- 150000003568 thioethers Chemical class 0.000 description 6
- 229910052593 corundum Inorganic materials 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- IYYZUPMFVPLQIF-UHFFFAOYSA-N dibenzothiophene Chemical compound C1=CC=C2C3=CC=CC=C3SC2=C1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 description 5
- 239000002283 diesel fuel Substances 0.000 description 5
- 230000002349 favourable effect Effects 0.000 description 5
- 239000011261 inert gas Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 229930192474 thiophene Natural products 0.000 description 5
- 229910001845 yogo sapphire Inorganic materials 0.000 description 5
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 238000007327 hydrogenolysis reaction Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 3
- 239000008186 active pharmaceutical agent Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 150000002019 disulfides Chemical class 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000012263 liquid product Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000007670 refining Methods 0.000 description 3
- 150000003577 thiophenes Chemical class 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 2
- YEUHHUCOSQOCIX-UHFFFAOYSA-N Benzo[b]naphtho[2,1-d]thiophene Chemical compound C1=CC2=CC=CC=C2C2=C1C1=CC=CC=C1S2 YEUHHUCOSQOCIX-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000000567 combustion gas Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- CMKBCTPCXZNQKX-UHFFFAOYSA-N cyclohexanethiol Chemical compound SC1CCCCC1 CMKBCTPCXZNQKX-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- NLPVCCRZRNXTLT-UHFFFAOYSA-N dioxido(dioxo)molybdenum;nickel(2+) Chemical compound [Ni+2].[O-][Mo]([O-])(=O)=O NLPVCCRZRNXTLT-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 238000005485 electric heating Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 230000003134 recirculating effect Effects 0.000 description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 description 2
- 238000005201 scrubbing Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- UDKYUQZDRMRDOR-UHFFFAOYSA-N tungsten Chemical compound [W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W] UDKYUQZDRMRDOR-UHFFFAOYSA-N 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- YJUFGFXVASPYFQ-UHFFFAOYSA-N 2,3-dihydro-1-benzothiophene Chemical class C1=CC=C2SCCC2=C1 YJUFGFXVASPYFQ-UHFFFAOYSA-N 0.000 description 1
- WVDYBOADDMMFIY-UHFFFAOYSA-N Cyclopentanethiol Chemical compound SC1CCCC1 WVDYBOADDMMFIY-UHFFFAOYSA-N 0.000 description 1
- CUDSBWGCGSUXDB-UHFFFAOYSA-N Dibutyl disulfide Chemical compound CCCCSSCCCC CUDSBWGCGSUXDB-UHFFFAOYSA-N 0.000 description 1
- HTIRHQRTDBPHNZ-UHFFFAOYSA-N Dibutyl sulfide Chemical compound CCCCSCCCC HTIRHQRTDBPHNZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- NBHIDQCTZATZRL-UHFFFAOYSA-N [O-2].[Al+3].[Mo+4].[Co+2] Chemical compound [O-2].[Al+3].[Mo+4].[Co+2] NBHIDQCTZATZRL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- KYYSIVCCYWZZLR-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)molybdenum Chemical compound [Co+2].[O-][Mo]([O-])(=O)=O KYYSIVCCYWZZLR-UHFFFAOYSA-N 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006392 deoxygenation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000010771 distillate fuel oil Substances 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 125000001741 organic sulfur group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- VRRFSFYSLSPWQY-UHFFFAOYSA-N sulfanylidenecobalt Chemical compound [Co]=S VRRFSFYSLSPWQY-UHFFFAOYSA-N 0.000 description 1
- XCUPBHGRVHYPQC-UHFFFAOYSA-N sulfanylidenetungsten Chemical compound [W]=S XCUPBHGRVHYPQC-UHFFFAOYSA-N 0.000 description 1
- 238000005486 sulfidation Methods 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 230000003685 thermal hair damage Effects 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910003158 γ-Al2O3 Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/72—Controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/007—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/14—White oil, eating oil
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Glass Compositions (AREA)
- Iron Core Of Rotating Electric Machines (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB898910711A GB8910711D0 (en) | 1989-05-10 | 1989-05-10 | Process |
| PCT/GB1990/000718 WO1990013617A1 (en) | 1989-05-10 | 1990-05-09 | Multi-step hydrodesulphurisation process |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO914379D0 NO914379D0 (no) | 1991-11-08 |
| NO914379L NO914379L (no) | 1992-01-06 |
| NO304275B1 true NO304275B1 (no) | 1998-11-23 |
Family
ID=34839930
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO914379A NO304275B1 (no) | 1989-05-10 | 1991-11-08 | Flertrinns fremgangsmÕte for hydrogenavsvovling |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5292428A (da) |
| EP (1) | EP0474664B1 (da) |
| JP (1) | JP2895621B2 (da) |
| AT (1) | ATE109198T1 (da) |
| CA (1) | CA2054679A1 (da) |
| DE (1) | DE69011112T2 (da) |
| DK (1) | DK0474664T3 (da) |
| ES (1) | ES2061036T3 (da) |
| FI (1) | FI915261A0 (da) |
| GB (1) | GB8910711D0 (da) |
| HU (1) | HUT67610A (da) |
| NO (1) | NO304275B1 (da) |
| WO (1) | WO1990013617A1 (da) |
Families Citing this family (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1992008772A1 (en) * | 1989-05-10 | 1992-05-29 | Davy Mckee (London) Limited | Hydrodesulphurisation process |
| EP0793701B1 (en) * | 1994-11-25 | 1999-01-27 | Kvaerner Process Technology Limited | Multi-step hydrodesulfurization process |
| JP3387700B2 (ja) * | 1995-07-26 | 2003-03-17 | 新日本石油株式会社 | 接触分解ガソリンの脱硫方法 |
| US6153086A (en) * | 1996-08-23 | 2000-11-28 | Exxon Research And Engineering Company | Combination cocurrent and countercurrent staged hydroprocessing with a vapor stage |
| US7288182B1 (en) | 1997-07-15 | 2007-10-30 | Exxonmobil Research And Engineering Company | Hydroprocessing using bulk Group VIII/Group VIB catalysts |
| US7232515B1 (en) | 1997-07-15 | 2007-06-19 | Exxonmobil Research And Engineering Company | Hydrofining process using bulk group VIII/Group VIB catalysts |
| US7513989B1 (en) | 1997-07-15 | 2009-04-07 | Exxonmobil Research And Engineering Company | Hydrocracking process using bulk group VIII/Group VIB catalysts |
| US7229548B2 (en) * | 1997-07-15 | 2007-06-12 | Exxonmobil Research And Engineering Company | Process for upgrading naphtha |
| US6582590B1 (en) * | 1997-07-15 | 2003-06-24 | Exxonmobil Research And Engineering Company | Multistage hydroprocessing using bulk multimetallic catalyst |
| US6495029B1 (en) | 1997-08-22 | 2002-12-17 | Exxon Research And Engineering Company | Countercurrent desulfurization process for refractory organosulfur heterocycles |
| CA2243267C (en) | 1997-09-26 | 2003-12-30 | Exxon Research And Engineering Company | Countercurrent reactor with interstage stripping of nh3 and h2s in gas/liquid contacting zones |
| US6103773A (en) † | 1998-01-27 | 2000-08-15 | Exxon Research And Engineering Co | Gas conversion using hydrogen produced from syngas for removing sulfur from gas well hydrocarbon liquids |
| US6663768B1 (en) * | 1998-03-06 | 2003-12-16 | Chevron U.S.A. Inc. | Preparing a HGH viscosity index, low branch index dewaxed |
| US6036844A (en) * | 1998-05-06 | 2000-03-14 | Exxon Research And Engineering Co. | Three stage hydroprocessing including a vapor stage |
| US6054041A (en) * | 1998-05-06 | 2000-04-25 | Exxon Research And Engineering Co. | Three stage cocurrent liquid and vapor hydroprocessing |
| US6103104A (en) * | 1998-05-07 | 2000-08-15 | Exxon Research And Engineering Company | Multi-stage hydroprocessing of middle distillates to avoid color bodies |
| US6156084A (en) | 1998-06-24 | 2000-12-05 | International Fuel Cells, Llc | System for desulfurizing a fuel for use in a fuel cell power plant |
| US6083378A (en) * | 1998-09-10 | 2000-07-04 | Catalytic Distillation Technologies | Process for the simultaneous treatment and fractionation of light naphtha hydrocarbon streams |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE571792A (da) * | ||||
| GB1191220A (en) * | 1968-07-05 | 1970-05-13 | Shell Int Research | Process and apparatus for carrying out chemical reactions |
| US3809644A (en) * | 1972-08-01 | 1974-05-07 | Hydrocarbon Research Inc | Multiple stage hydrodesulfurization of residuum |
| US3847799A (en) * | 1972-10-10 | 1974-11-12 | Universal Oil Prod Co | Conversion of black oil to low-sulfur fuel oil |
| NL187026C (nl) * | 1976-07-08 | 1991-05-01 | Shell Int Research | Werkwijze voor het ontmetalliseren van koolwaterstofolien. |
| US4243519A (en) * | 1979-02-14 | 1981-01-06 | Exxon Research & Engineering Co. | Hydrorefining process |
-
1989
- 1989-05-10 GB GB898910711A patent/GB8910711D0/en active Pending
-
1990
- 1990-05-09 DE DE69011112T patent/DE69011112T2/de not_active Expired - Fee Related
- 1990-05-09 DK DK90907296.9T patent/DK0474664T3/da active
- 1990-05-09 EP EP90907296A patent/EP0474664B1/en not_active Expired - Lifetime
- 1990-05-09 AT AT90907296T patent/ATE109198T1/de active
- 1990-05-09 CA CA002054679A patent/CA2054679A1/en not_active Abandoned
- 1990-05-09 ES ES90907296T patent/ES2061036T3/es not_active Expired - Lifetime
- 1990-05-09 JP JP2507007A patent/JP2895621B2/ja not_active Expired - Fee Related
- 1990-05-09 WO PCT/GB1990/000718 patent/WO1990013617A1/en active IP Right Grant
- 1990-05-09 US US07/781,173 patent/US5292428A/en not_active Expired - Lifetime
- 1990-11-07 HU HU9300997A patent/HUT67610A/hu unknown
-
1991
- 1991-11-08 NO NO914379A patent/NO304275B1/no unknown
- 1991-11-08 FI FI915261A patent/FI915261A0/fi not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| GB8910711D0 (en) | 1989-06-28 |
| HUT67610A (en) | 1995-04-28 |
| CA2054679A1 (en) | 1990-11-11 |
| ATE109198T1 (de) | 1994-08-15 |
| DE69011112D1 (de) | 1994-09-01 |
| WO1990013617A1 (en) | 1990-11-15 |
| HU9300997D0 (en) | 1993-08-30 |
| NO914379D0 (no) | 1991-11-08 |
| ES2061036T3 (es) | 1994-12-01 |
| DK0474664T3 (da) | 1995-03-27 |
| FI915261A0 (fi) | 1991-11-08 |
| EP0474664B1 (en) | 1994-07-27 |
| DE69011112T2 (de) | 1994-11-10 |
| EP0474664A1 (en) | 1992-03-18 |
| US5292428A (en) | 1994-03-08 |
| JPH04505179A (ja) | 1992-09-10 |
| NO914379L (no) | 1992-01-06 |
| JP2895621B2 (ja) | 1999-05-24 |
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