NO137553C - Pulverformet overtrekksmiddel paa basis av blokkerte polyisocyanater og hydroksylholdige polyestere - Google Patents

Pulverformet overtrekksmiddel paa basis av blokkerte polyisocyanater og hydroksylholdige polyestere

Info

Publication number
NO137553C
NO137553C NO340/72A NO34072A NO137553C NO 137553 C NO137553 C NO 137553C NO 340/72 A NO340/72 A NO 340/72A NO 34072 A NO34072 A NO 34072A NO 137553 C NO137553 C NO 137553C
Authority
NO
Norway
Prior art keywords
hydroxyl
based coating
containing polyesters
powdered poly
coating polyisocyanates
Prior art date
Application number
NO340/72A
Other languages
English (en)
Other versions
NO137553B (no
Inventor
Karl Schmitt
Josef Disteldorf
Felix Schmitt
Original Assignee
Veba Chemie Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Veba Chemie Ag filed Critical Veba Chemie Ag
Publication of NO137553B publication Critical patent/NO137553B/no
Publication of NO137553C publication Critical patent/NO137553C/no

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4219—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from aromatic dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/33—Heterocyclic compounds
    • A61K31/335—Heterocyclic compounds having oxygen as the only ring hetero atom, e.g. fungichromin
    • A61K31/35—Heterocyclic compounds having oxygen as the only ring hetero atom, e.g. fungichromin having six-membered rings with one oxygen as the only ring hetero atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P37/00—Drugs for immunological or allergic disorders
    • A61P37/08—Antiallergic agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/78—Ring systems having three or more relevant rings
    • C07D311/80—Dibenzopyrans; Hydrogenated dibenzopyrans
    • C07D311/82—Xanthenes
    • C07D311/84—Xanthenes with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 9
    • C07D311/86—Oxygen atoms, e.g. xanthones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
    • C08G18/8074—Lactams
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2150/00—Compositions for coatings
    • C08G2150/20—Compositions for powder coatings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S524/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S524/904—Powder coating compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/934—Powdered coating composition
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Materials Engineering (AREA)
  • Epidemiology (AREA)
  • Wood Science & Technology (AREA)
  • Pulmonology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Immunology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)
NO340/72A 1971-02-08 1972-02-08 Pulverformet overtrekksmiddel paa basis av blokkerte polyisocyanater og hydroksylholdige polyestere NO137553C (no)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19712105777 DE2105777C3 (de) 1971-02-08 1971-02-08 Pulverförmige Überzugsmasse

Publications (2)

Publication Number Publication Date
NO137553B NO137553B (no) 1977-12-05
NO137553C true NO137553C (no) 1978-03-15

Family

ID=5798092

Family Applications (1)

Application Number Title Priority Date Filing Date
NO340/72A NO137553C (no) 1971-02-08 1972-02-08 Pulverformet overtrekksmiddel paa basis av blokkerte polyisocyanater og hydroksylholdige polyestere

Country Status (17)

Country Link
US (2) US3822240A (no)
JP (1) JPS5651190B1 (no)
AT (1) AT317381B (no)
BE (1) BE779094A (no)
CA (1) CA982733A (no)
CH (1) CH569071A5 (no)
DE (1) DE2105777C3 (no)
DK (1) DK140106C (no)
ES (1) ES399481A0 (no)
FR (1) FR2124567B1 (no)
GB (2) GB1390111A (no)
IE (1) IE36072B1 (no)
IT (1) IT947383B (no)
LU (1) LU64724A1 (no)
NL (1) NL170863C (no)
NO (1) NO137553C (no)
SE (1) SE389871B (no)

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US4093674A (en) * 1972-11-30 1978-06-06 Nippon Paint Co., Ltd. Powder coating composition
JPS4994729A (no) * 1972-11-30 1974-09-09
US4151152A (en) * 1973-09-18 1979-04-24 Veba-Chemie Aktiengesellschaft Stable fast-setting varnishes based on polyesters and blocked aliphatic diisocyanate
DE2404740C2 (de) * 1974-02-01 1982-04-29 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von Filmen und Überzügen und Beschichtungsmittel
DE2414427A1 (de) * 1974-03-26 1975-10-23 Cassella Farbwerke Mainkur Ag Hitzehaertendes ueberzugsmittel in form einer dispersion
US3998716A (en) * 1974-06-03 1976-12-21 Inmont Corporation Method of applying coatings
BE830440A (fr) * 1974-06-21 1975-10-16 Composition de poudre pour revetement et son obtention
US3931117A (en) * 1974-08-01 1976-01-06 Cook Paint And Varnish Company Coating powders for protective films based on ε-caprolactam-blocked isocyanates
US4107148A (en) * 1974-08-22 1978-08-15 Toyo Boseki Kabushiki Kaisha Powder coating composition comprising a mixture of a polyester and plural silicone compounds
GB1479987A (en) * 1975-06-20 1977-07-13 Interox Chemicals Ltd Polyurethanes
DE2542706C3 (de) * 1975-09-25 1981-04-09 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von Imidgruppen enthaltenden Polykondensaten
US4182840A (en) * 1976-09-22 1980-01-08 Rhone-Poulenc Industries Cross-linkable saturated powderous compositions and powderous painting and coating compositions containing same
DE2707656C2 (de) * 1977-02-23 1986-04-17 Bayer Ag, 5090 Leverkusen Pulverförmige Überzugsmittel
DE2712931A1 (de) * 1977-03-24 1978-09-28 Veba Chemie Ag Isocyanuratgruppen - und endstaendig- blockierte isocyanatgruppen - enthaltende verbindungen
US4172192A (en) * 1977-04-04 1979-10-23 Kemerica, Inc. Process for stabilizing thermoplastic polyurethanes and stabilized product
DE2732662A1 (de) * 1977-07-20 1979-02-01 Veba Chemie Ag Isocyanuratgruppen - und endstaendig- blockierte isocyanatgruppen-enthaltende verbindungen
DE2735497A1 (de) 1977-08-06 1979-02-15 Veba Chemie Ag Pulverfoermige polyurethanlacke
DE2929150A1 (de) * 1979-07-19 1981-02-12 Huels Chemische Werke Ag Pulverfoermige ueberzugsmassen mit hoher lagerstabilitaet sowie deren herstellung
US4248744A (en) * 1979-08-20 1981-02-03 Inmont Corporation Thermosetting powders
DE2938855A1 (de) * 1979-09-26 1981-04-09 Chemische Werke Hüls AG, 4370 Marl Einkomponenten-einbrennlacke
DE3004876A1 (de) * 1980-02-09 1981-08-20 Chemische Werke Hüls AG, 4370 Marl Blockierte polyisocyanate mit hoher reaktionsfaehigkeit, ihre herstellung und verwendung
JPS5738869A (en) * 1980-08-18 1982-03-03 Takeda Chem Ind Ltd Polyurethane powdered coating composition
DE3039824A1 (de) * 1980-10-22 1982-05-27 Bayer Ag, 5090 Leverkusen Neue lackpolyisocyanate, ein verfahren zu ihrer herstellung, sowie ihre verwendung als isocyanatkomponente in hitzehaertbaren zweikomponenten-polyurethanlacken
US4395529A (en) * 1981-07-20 1983-07-26 Cargill, Incorporated Coating powders for protective films based on epsilon-caprolactam blocked isocyanates
DE3134640C1 (de) * 1981-09-02 1983-01-27 Dynamit Nobel Ag, 5210 Troisdorf Saeuresterilisationsfeste Polyesterlacke
DE3143060A1 (de) * 1981-10-30 1983-05-11 Chemische Werke Hüls AG, 4370 Marl Pulverlacke auf der basis von blockierten isophorondiisocyanataddukten
US4452930A (en) * 1983-02-10 1984-06-05 Ppg Industries, Inc. Curable compositions containing novel urethane curing agents
US4452963A (en) * 1983-02-10 1984-06-05 Ppg Industries, Inc. Low temperature urethane curing agents
US4452681A (en) * 1983-02-10 1984-06-05 Ppg Industries, Inc. Method of electrodeposition of coating compositions containing novel urethane curing agents
DE3312028A1 (de) * 1983-04-02 1984-10-11 Chemische Werke Hüls AG, 4370 Marl Blockierte polysocyanate, ihre herstellung und verwendung
US4501821A (en) * 1983-07-28 1985-02-26 Ppg Industries, Inc. Property enhancement of anionically polymerized nylon with dual initiators
DE3328131C2 (de) * 1983-08-04 1994-02-03 Huels Chemische Werke Ag Pulverlacke auf der Basis teilblockierter IPDI-Isocyanurate und hydroxylgruppenhaltiger Polyester sowie ein Verfahren zur Herstellung matter Überzüge
US4542177A (en) * 1984-06-29 1985-09-17 Mobay Chemical Corporation Thermoplastic polyester molding composition having an improved impact performance
DE3434881A1 (de) * 1984-09-22 1986-04-03 Hüls AG, 4370 Marl Lagerstabile polyurethanharz-pulverlacke
DE3536017A1 (de) * 1985-10-09 1987-04-09 Huels Chemische Werke Ag Ganz oder teilweise mit epsilon-caprolactam blockiertes trans-cyclohexan-1,4-diisocyanat, dessen herstellung und verwendung
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DE3624775A1 (de) * 1986-07-22 1988-01-28 Bayer Ag Pulverlack und seine verwendung zur beschichtung von hitzeresistenten substraten
US4957814A (en) * 1989-04-21 1990-09-18 Eastman Kodak Company Powder coating compositions
US4988793A (en) * 1989-05-23 1991-01-29 Eastman Kodak Company Powder coating compositions
US4973646A (en) * 1990-04-09 1990-11-27 Eastman Kodak Company Powder coating compositions
JPH04234427A (ja) * 1990-12-03 1992-08-24 Nalco Chem Co 蛍光顔料を生産するのに適した結晶性ポリエステル樹脂
US5160792A (en) * 1991-02-04 1992-11-03 Eastman Kodak Company Thermosetting powder coating compositions
US5583196A (en) * 1992-01-31 1996-12-10 Karl Fischer Industrieanlagen Gmbh Melt formed from polyurethane and/or polyurethane urea elastomer and method for producing the same
US5552191A (en) * 1992-02-14 1996-09-03 Morton International, Inc. Triboelectric coating powder and process
DE4204995C2 (de) * 1992-02-19 1994-11-03 Huels Chemische Werke Ag Mit 2,5-Diketopiperazinen blockierte Diisocyanate, ein Verfahren zu ihrer Herstellung sowie ihre Verwendung in Polyurethan-Pulverlacken
US5554692A (en) * 1994-01-06 1996-09-10 Ferro Corporation Blocked isocyanate crosslinkers based on pentaerythritol for use in thermosetting coatings
US5405920A (en) * 1994-08-08 1995-04-11 Eastman Chemical Company Polyurethane powder coatings
DE9413475U1 (de) 1994-08-20 1994-10-13 Mannesmann Kienzle Gmbh Fahrtschreiber mit Mitteln zur geräteseitigen Befestigung eines den Geberleitungen zugeordneten Schutzrohres
DE19603389A1 (de) 1996-01-31 1997-08-07 Huels Chemische Werke Ag Blockierte aliphatische Diisocyanate oder Diisocyanat-Addukte
DE19604581A1 (de) 1996-02-08 1997-08-14 Bayer Ag Polyurethan-Pulvermattlacke
DE10008928A1 (de) 2000-02-25 2001-08-30 Degussa Transparente oder pigmentierte Pulverlacke mit Vernetzern aus Hydroxyalkylamiden und blockierten, nicht aromatischen Polyisocyanaten
DE10033097A1 (de) 2000-07-07 2002-01-17 Degussa Verfahren zur Herstellung von hochreaktiven(semi)kristallinen und amorphen blockierten Polyisocyanaten
DE10159768A1 (de) * 2001-12-05 2003-06-26 Degussa Verwendung von Polyurethan-Pulverlacken
DE10260300A1 (de) * 2002-12-20 2004-07-01 Bayer Ag Abspalterfreie Pulverlackvernetzer
WO2006029141A1 (en) * 2004-09-03 2006-03-16 Dow Global Technologies Inc. Blocked isocyanates and their use in coating compositions
EP2771420B1 (en) * 2011-10-25 2018-12-19 Hewlett-Packard Development Company, L.P. Liquid electrophotographic inks
US20190211203A1 (en) * 2018-01-11 2019-07-11 Celanese International Corporation Copolyester Polymer Composition With Enhanced Elastic Properties

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US3245961A (en) * 1962-08-28 1966-04-12 Nopco Chem Co Polyureas from caprolactamblocked isocyanates
GB1032059A (en) * 1963-10-29 1966-06-08 Takeda Chemical Industries Ltd Blocked isocyanate compositions
DE1469467A1 (de) * 1964-06-22 1969-01-23 Elastomer Ag Verfahren zur Erzeugung duenner Oberflaechenbeschichtungen mit Polyurethanen
DE1900204A1 (de) * 1969-01-03 1970-08-20 Bayer Ag Pulverfoermige,thermisch selbstvernetzende Bindemittel
BE758924A (fr) * 1969-11-15 1971-05-13 Bayer Ag Agents d'enduction pulverulents
US3808160A (en) * 1970-05-28 1974-04-30 Du Pont Cross-linkable coating composition of a hydroxyl containing polyester and a blocked polyisocyanate
US3660359A (en) * 1970-06-05 1972-05-02 Ford Motor Co Thermoset resins with hydroxy acrylate methacrylonitrile and blocked isocyanate
US3819586A (en) * 1970-09-29 1974-06-25 Bayer Ag Coating material based on blocked polyurethanes
DE2131299C3 (de) * 1971-06-24 1981-04-23 Bayer Ag, 5090 Leverkusen Durch Hitzeeinwirkung härtbare Gemische und Verfahren zur Herstellung von Formkörpern aus diesen Gemischen
JPS492179A (no) * 1972-04-20 1974-01-10
DE2236514A1 (de) * 1972-07-26 1974-02-07 Degussa Verfahren zur herstellung von pulverisierbaren, hitzehaertbaren ueberzugsmitteln

Also Published As

Publication number Publication date
SE389871B (sv) 1976-11-22
IE36072B1 (en) 1976-08-04
FR2124567A1 (no) 1972-09-22
DK140106C (da) 1979-11-19
NO137553B (no) 1977-12-05
DE2105777C3 (de) 1976-02-05
CA982733A (en) 1976-01-27
CH569071A5 (no) 1975-11-14
BE779094A (fr) 1972-05-30
NL170863C (nl) 1983-01-03
JPS5651190B1 (no) 1981-12-03
US4212962A (en) 1980-07-15
GB1390112A (en) 1975-04-09
GB1390111A (en) 1975-04-09
IT947383B (it) 1973-05-21
AT317381B (de) 1974-08-26
DK140106B (da) 1979-06-18
DE2105777B2 (de) 1975-06-26
ATA95274A (de) 1975-01-15
IE36072L (en) 1972-08-08
DE2105777A1 (de) 1972-08-24
ES399481A0 (es) 1975-07-01
NL7201656A (no) 1972-08-10
FR2124567B1 (no) 1976-10-29
US3822240A (en) 1974-07-02
LU64724A1 (no) 1972-07-04

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