NO135317B - - Google Patents
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- Publication number
- NO135317B NO135317B NO1748/72A NO174872A NO135317B NO 135317 B NO135317 B NO 135317B NO 1748/72 A NO1748/72 A NO 1748/72A NO 174872 A NO174872 A NO 174872A NO 135317 B NO135317 B NO 135317B
- Authority
- NO
- Norway
- Prior art keywords
- styrene
- transition metal
- polymerization
- aluminum
- vanadium
- Prior art date
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 26
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 6
- 229910052723 transition metal Inorganic materials 0.000 claims description 6
- 150000003624 transition metals Chemical class 0.000 claims description 6
- -1 vanadium halide Chemical class 0.000 claims description 6
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 229910021552 Vanadium(IV) chloride Inorganic materials 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical group Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 claims description 3
- 230000000737 periodic effect Effects 0.000 claims description 2
- 150000003623 transition metal compounds Chemical class 0.000 claims 2
- 239000012442 inert solvent Substances 0.000 claims 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D498/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D498/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
- C07D498/08—Bridged systems
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Saccharide Compounds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT8960871 | 1971-06-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO135317B true NO135317B (fr) | 1976-12-13 |
| NO135317C NO135317C (fr) | 1977-03-23 |
Family
ID=11331613
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO1748/72A NO135317C (fr) | 1971-06-24 | 1972-05-16 |
Country Status (24)
| Country | Link |
|---|---|
| JP (1) | JPS5123520B1 (fr) |
| AR (1) | AR192939A1 (fr) |
| AT (1) | AT315373B (fr) |
| BE (1) | BE784532A (fr) |
| CA (1) | CA983487A (fr) |
| CH (1) | CH564012A5 (fr) |
| DD (1) | DD99783A5 (fr) |
| DE (1) | DE2227173C2 (fr) |
| DK (1) | DK138457B (fr) |
| ES (1) | ES403549A1 (fr) |
| FI (1) | FI54313C (fr) |
| FR (1) | FR2143410B1 (fr) |
| GB (1) | GB1336399A (fr) |
| HU (1) | HU163901B (fr) |
| IE (1) | IE36443B1 (fr) |
| IL (1) | IL39306A (fr) |
| LU (1) | LU65460A1 (fr) |
| NL (1) | NL159985C (fr) |
| NO (1) | NO135317C (fr) |
| PL (1) | PL81998B1 (fr) |
| RO (1) | RO62778A (fr) |
| SE (2) | SE383740B (fr) |
| SU (1) | SU440841A3 (fr) |
| ZA (1) | ZA722667B (fr) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2728869A1 (de) * | 1976-06-25 | 1977-12-29 | Antibiotice Iasi Intreprindere | Rifamycinen und verfahren zu deren herstellung |
| PH13381A (en) * | 1977-03-31 | 1980-03-25 | Takeda Chemical Industries Ltd | Antibiotic c-15003 |
| US4137230A (en) * | 1977-11-14 | 1979-01-30 | Takeda Chemical Industries, Ltd. | Method for the production of maytansinoids |
| US4447432A (en) * | 1981-11-17 | 1984-05-08 | Farmitalia Carlo Erba S.P.A. | Azino rifamycins |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR208F (fr) * | 1964-07-31 |
-
1971
- 1971-06-08 GB GB1945872A patent/GB1336399A/en not_active Expired
-
1972
- 1972-04-19 ZA ZA722667A patent/ZA722667B/xx unknown
- 1972-04-25 IL IL39306A patent/IL39306A/en unknown
- 1972-05-04 AR AR241804A patent/AR192939A1/es active
- 1972-05-11 IE IE634/72A patent/IE36443B1/xx unknown
- 1972-05-16 NO NO1748/72A patent/NO135317C/no unknown
- 1972-05-24 FI FI1450/72A patent/FI54313C/fi active
- 1972-06-02 JP JP47054998A patent/JPS5123520B1/ja active Pending
- 1972-06-03 DE DE2227173A patent/DE2227173C2/de not_active Expired
- 1972-06-05 LU LU65460D patent/LU65460A1/xx unknown
- 1972-06-05 CH CH827872A patent/CH564012A5/xx not_active IP Right Cessation
- 1972-06-05 DD DD163438A patent/DD99783A5/xx unknown
- 1972-06-05 SU SU1789259A patent/SU440841A3/ru active
- 1972-06-05 PL PL1972155843A patent/PL81998B1/pl unknown
- 1972-06-06 DK DK279672AA patent/DK138457B/da not_active IP Right Cessation
- 1972-06-06 ES ES403549A patent/ES403549A1/es not_active Expired
- 1972-06-06 RO RO7200071157A patent/RO62778A/fr unknown
- 1972-06-06 SE SE7207427A patent/SE383740B/xx unknown
- 1972-06-06 AT AT486072A patent/AT315373B/de not_active IP Right Cessation
- 1972-06-06 HU HULE659A patent/HU163901B/hu unknown
- 1972-06-07 BE BE784532A patent/BE784532A/fr not_active IP Right Cessation
- 1972-06-22 NL NL7208592.A patent/NL159985C/xx not_active IP Right Cessation
- 1972-06-23 FR FR7222863A patent/FR2143410B1/fr not_active Expired
- 1972-06-26 CA CA145,745A patent/CA983487A/en not_active Expired
-
1975
- 1975-09-03 SE SE7509793A patent/SE400558B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB1336399A (en) | 1973-11-07 |
| NL159985C (nl) | 1979-09-17 |
| DD99783A5 (fr) | 1973-08-20 |
| RO62778A (fr) | 1978-01-15 |
| AR192939A1 (es) | 1973-03-21 |
| IE36443B1 (en) | 1976-11-10 |
| NO135317C (fr) | 1977-03-23 |
| NL7208592A (fr) | 1972-12-28 |
| AT315373B (de) | 1974-05-27 |
| PL81998B1 (fr) | 1975-10-31 |
| IE36443L (en) | 1972-12-24 |
| IL39306A (en) | 1977-07-31 |
| IL39306A0 (en) | 1972-06-28 |
| LU65460A1 (fr) | 1972-10-05 |
| DE2227173C2 (fr) | 1988-12-08 |
| SE383740B (sv) | 1976-03-29 |
| AU4143672A (en) | 1973-10-25 |
| JPS5123520B1 (fr) | 1976-07-17 |
| SE7509793L (sv) | 1975-09-03 |
| SE400558B (sv) | 1978-04-03 |
| CH564012A5 (fr) | 1975-07-15 |
| DK138457C (fr) | 1979-02-19 |
| ES403549A1 (es) | 1975-05-01 |
| FI54313B (fi) | 1978-07-31 |
| SU440841A3 (ru) | 1974-08-25 |
| FR2143410A1 (fr) | 1973-02-02 |
| FI54313C (fi) | 1978-11-10 |
| DE2227173A1 (fr) | 1972-12-28 |
| FR2143410B1 (fr) | 1975-08-08 |
| CA983487A (en) | 1976-02-10 |
| BE784532A (fr) | 1972-10-02 |
| NL159985B (nl) | 1979-04-17 |
| HU163901B (fr) | 1973-11-28 |
| DK138457B (da) | 1978-09-11 |
| ZA722667B (en) | 1973-01-31 |
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