NO124210B - - Google Patents
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- Publication number
- NO124210B NO124210B NO16643767A NO16643767A NO124210B NO 124210 B NO124210 B NO 124210B NO 16643767 A NO16643767 A NO 16643767A NO 16643767 A NO16643767 A NO 16643767A NO 124210 B NO124210 B NO 124210B
- Authority
- NO
- Norway
- Prior art keywords
- suspension
- weight
- polymer
- monomer
- polymerization
- Prior art date
Links
- 239000000725 suspension Substances 0.000 claims description 78
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 66
- 239000000178 monomer Substances 0.000 claims description 59
- 238000006116 polymerization reaction Methods 0.000 claims description 43
- 238000006243 chemical reaction Methods 0.000 claims description 37
- 229920000642 polymer Polymers 0.000 claims description 35
- 239000003054 catalyst Substances 0.000 claims description 31
- 229920000126 latex Polymers 0.000 claims description 30
- 239000004816 latex Substances 0.000 claims description 30
- 239000000203 mixture Substances 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 239000002245 particle Substances 0.000 claims description 19
- 229920001577 copolymer Polymers 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 16
- 238000007334 copolymerization reaction Methods 0.000 claims description 8
- 239000011541 reaction mixture Substances 0.000 claims description 6
- 239000007900 aqueous suspension Substances 0.000 claims description 2
- 229920000578 graft copolymer Polymers 0.000 claims 10
- 239000000047 product Substances 0.000 description 30
- 229920000915 polyvinyl chloride Polymers 0.000 description 20
- 239000004800 polyvinyl chloride Substances 0.000 description 20
- 238000004519 manufacturing process Methods 0.000 description 13
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 9
- 206010039509 Scab Diseases 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 6
- 229920001944 Plastisol Polymers 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- -1 alkyl sulphates Chemical class 0.000 description 4
- 238000005345 coagulation Methods 0.000 description 4
- 230000015271 coagulation Effects 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 239000004999 plastisol Substances 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- ZQMIGQNCOMNODD-UHFFFAOYSA-N diacetyl peroxide Chemical compound CC(=O)OOC(C)=O ZQMIGQNCOMNODD-UHFFFAOYSA-N 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 238000003828 vacuum filtration Methods 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000012874 anionic emulsifier Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000035611 feeding Effects 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000011551 heat transfer agent Substances 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000009740 moulding (composite fabrication) Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000011085 pressure filtration Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
- C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR46461A FR1485547A (fr) | 1966-01-19 | 1966-01-19 | Procédé continu de polymérisation du chlorure de vinyle |
| FR85628A FR91709E (fr) | 1966-01-19 | 1966-11-30 | Procédé continu de polymérisation du chlorure de vinyle |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO124210B true NO124210B (da) | 1972-03-20 |
Family
ID=26168066
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO16643767A NO124210B (da) | 1966-01-19 | 1967-01-18 |
Country Status (13)
| Country | Link |
|---|---|
| AT (1) | AT277574B (da) |
| BE (1) | BE692903A (da) |
| CH (1) | CH488752A (da) |
| DE (1) | DE1745220C3 (da) |
| DK (1) | DK128499B (da) |
| ES (1) | ES335797A1 (da) |
| FI (1) | FI46074C (da) |
| FR (2) | FR1485547A (da) |
| GB (1) | GB1170963A (da) |
| LU (1) | LU52837A1 (da) |
| NL (1) | NL140533B (da) |
| NO (1) | NO124210B (da) |
| SE (1) | SE358402B (da) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2234321B1 (da) * | 1973-06-08 | 1976-06-11 | Rhone Progil | |
| HU173513B (hu) * | 1975-04-30 | 1979-05-28 | Rhone Poulenc Ind | Sposob polimerizacii vinilkhlorida v sshitojj mikrosuspensii |
| FR2587031B1 (fr) * | 1985-09-06 | 1987-12-11 | Atochem | Procede de preparation en microsuspension de latex d'homo- et copolymeres du chlorure de vinyle utilisables comme produits d'ensemencement |
| FR2596763B1 (fr) * | 1986-04-03 | 1988-06-03 | Atochem | Procede de preparation en microsuspension de latex d'homo- et copolymeres du chlorure de vinyle utilisables comme produits d'ensemencement |
| FR2607138B1 (fr) * | 1986-11-24 | 1990-05-04 | Atochem | Procede de preparation en microsuspension ensemencee d'homo- et copolymeres du chlorure de vinyle |
| ATE165845T1 (de) | 1992-02-13 | 1998-05-15 | Europ Vinyls Corp Technology A | Polymerisationsverfahren |
-
1966
- 1966-01-19 FR FR46461A patent/FR1485547A/fr not_active Expired
- 1966-11-30 FR FR85628A patent/FR91709E/fr not_active Expired
-
1967
- 1967-01-13 FI FI9367A patent/FI46074C/fi active
- 1967-01-16 GB GB222467A patent/GB1170963A/en not_active Expired
- 1967-01-18 DE DE1967P0041235 patent/DE1745220C3/de not_active Expired
- 1967-01-18 LU LU52837D patent/LU52837A1/xx unknown
- 1967-01-18 ES ES0335797A patent/ES335797A1/es not_active Expired
- 1967-01-18 CH CH73967A patent/CH488752A/fr not_active IP Right Cessation
- 1967-01-18 NO NO16643767A patent/NO124210B/no unknown
- 1967-01-18 DK DK29167A patent/DK128499B/da unknown
- 1967-01-19 NL NL6700851A patent/NL140533B/xx not_active IP Right Cessation
- 1967-01-19 BE BE692903D patent/BE692903A/xx not_active IP Right Cessation
- 1967-01-19 SE SE81667A patent/SE358402B/xx unknown
- 1967-01-19 AT AT58467A patent/AT277574B/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| FR1485547A (fr) | 1967-06-23 |
| NL140533B (nl) | 1973-12-17 |
| GB1170963A (en) | 1969-11-19 |
| DE1745220A1 (de) | 1972-07-27 |
| DK128499B (da) | 1974-05-13 |
| FR91709E (fr) | 1968-08-02 |
| SE358402B (da) | 1973-07-30 |
| LU52837A1 (da) | 1967-07-18 |
| CH488752A (fr) | 1970-04-15 |
| AT277574B (de) | 1969-12-29 |
| DE1745220B2 (de) | 1975-06-26 |
| FI46074B (da) | 1972-08-31 |
| FI46074C (fi) | 1972-12-11 |
| ES335797A1 (es) | 1967-12-01 |
| DE1745220C3 (de) | 1980-05-08 |
| NL6700851A (da) | 1967-07-20 |
| BE692903A (da) | 1967-07-19 |
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