NL9100217A - Moleculaire-zeefkristallen bevattend anorganisch composietmembraan. - Google Patents
Moleculaire-zeefkristallen bevattend anorganisch composietmembraan. Download PDFInfo
- Publication number
- NL9100217A NL9100217A NL9100217A NL9100217A NL9100217A NL 9100217 A NL9100217 A NL 9100217A NL 9100217 A NL9100217 A NL 9100217A NL 9100217 A NL9100217 A NL 9100217A NL 9100217 A NL9100217 A NL 9100217A
- Authority
- NL
- Netherlands
- Prior art keywords
- crystals
- support
- molecular sieve
- membrane
- layer
- Prior art date
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- 239000013078 crystal Substances 0.000 title claims abstract description 191
- 239000012528 membrane Substances 0.000 title claims abstract description 97
- 239000002131 composite material Substances 0.000 title claims abstract description 8
- 239000002808 molecular sieve Substances 0.000 claims abstract description 109
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 109
- 239000011159 matrix material Substances 0.000 claims abstract description 35
- 239000011148 porous material Substances 0.000 claims abstract description 35
- 239000002356 single layer Substances 0.000 claims abstract description 19
- 238000012986 modification Methods 0.000 claims abstract description 6
- 230000004048 modification Effects 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 100
- 239000010410 layer Substances 0.000 claims description 87
- 230000008569 process Effects 0.000 claims description 35
- 239000004927 clay Substances 0.000 claims description 26
- 239000010408 film Substances 0.000 claims description 24
- 239000000919 ceramic Substances 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 18
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 238000005530 etching Methods 0.000 claims description 9
- 239000005388 borosilicate glass Substances 0.000 claims description 7
- 238000005498 polishing Methods 0.000 claims description 6
- 239000004590 silicone sealant Substances 0.000 claims description 6
- 230000003197 catalytic effect Effects 0.000 claims description 5
- 229910052680 mordenite Inorganic materials 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910010293 ceramic material Inorganic materials 0.000 claims 2
- 239000010457 zeolite Substances 0.000 description 38
- 239000000725 suspension Substances 0.000 description 33
- 239000000843 powder Substances 0.000 description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 21
- 229910021536 Zeolite Inorganic materials 0.000 description 21
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 21
- 238000002360 preparation method Methods 0.000 description 19
- 238000000926 separation method Methods 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 16
- 238000000151 deposition Methods 0.000 description 16
- 230000008021 deposition Effects 0.000 description 15
- 239000000463 material Substances 0.000 description 15
- 230000015572 biosynthetic process Effects 0.000 description 14
- 239000000203 mixture Substances 0.000 description 14
- 238000005229 chemical vapour deposition Methods 0.000 description 13
- 238000003786 synthesis reaction Methods 0.000 description 12
- 230000008901 benefit Effects 0.000 description 10
- 210000003298 dental enamel Anatomy 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical group CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 9
- 238000009792 diffusion process Methods 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 239000007789 gas Substances 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000012071 phase Substances 0.000 description 8
- 239000000377 silicon dioxide Substances 0.000 description 8
- 238000002425 crystallisation Methods 0.000 description 7
- 230000008025 crystallization Effects 0.000 description 7
- 238000009826 distribution Methods 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- 238000003618 dip coating Methods 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 235000012239 silicon dioxide Nutrition 0.000 description 6
- 238000010304 firing Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- -1 alkoxy silicates Chemical class 0.000 description 4
- 229910052796 boron Inorganic materials 0.000 description 4
- 239000000969 carrier Substances 0.000 description 4
- 238000007598 dipping method Methods 0.000 description 4
- 239000000428 dust Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000005191 phase separation Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000005297 pyrex Substances 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 238000007873 sieving Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- WRECIMRULFAWHA-UHFFFAOYSA-N trimethyl borate Chemical compound COB(OC)OC WRECIMRULFAWHA-UHFFFAOYSA-N 0.000 description 3
- 238000007740 vapor deposition Methods 0.000 description 3
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 2
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 150000004703 alkoxides Chemical class 0.000 description 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229920005597 polymer membrane Polymers 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 229910017119 AlPO Inorganic materials 0.000 description 1
- 241000283726 Bison Species 0.000 description 1
- 229910000599 Cr alloy Inorganic materials 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910000085 borane Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229940075614 colloidal silicon dioxide Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000001312 dry etching Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012229 microporous material Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 238000005373 pervaporation Methods 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 239000012465 retentate Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- BGQMOFGZRJUORO-UHFFFAOYSA-M tetrapropylammonium bromide Chemical compound [Br-].CCC[N+](CCC)(CCC)CCC BGQMOFGZRJUORO-UHFFFAOYSA-M 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- 230000007723 transport mechanism Effects 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 238000002525 ultrasonication Methods 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1216—Three or more layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0046—Inorganic membrane manufacture by slurry techniques, e.g. die or slip-casting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0051—Inorganic membrane manufacture by controlled crystallisation, e,.g. hydrothermal growth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0069—Inorganic membrane manufacture by deposition from the liquid phase, e.g. electrochemical deposition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/028—Molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/028—Molecular sieves
- B01D71/0281—Zeolites
-
- B01J35/59—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/08—Specific temperatures applied
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/08—Specific temperatures applied
- B01D2323/081—Heating
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Glass Compositions (AREA)
- Liquid Crystal Substances (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Laminated Bodies (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL9100217A NL9100217A (nl) | 1991-02-07 | 1991-02-07 | Moleculaire-zeefkristallen bevattend anorganisch composietmembraan. |
| PCT/NL1992/000029 WO1992013631A1 (en) | 1991-02-07 | 1992-02-07 | An inorganic composite membrane comprising molecular sieve crystals |
| EP92905770A EP0570486B1 (de) | 1991-02-07 | 1992-02-07 | Anorganische verbundmenbran, die molekularsiebkristalle enthaelt |
| US08/098,287 US5429743A (en) | 1991-02-07 | 1992-02-07 | Inorganic composite membrane comprising molecular sieve crystals |
| DE69228985T DE69228985T2 (de) | 1991-02-07 | 1992-02-07 | Anorganische verbundmenbran, die molekularsiebkristalle enthaelt |
| ES92905770T ES2132117T3 (es) | 1991-02-07 | 1992-02-07 | Membrana inorganica de material compuesto que comprende cristales de tamiz molecular. |
| CA002103585A CA2103585A1 (en) | 1991-02-07 | 1992-02-07 | Inorganic composite membrane comprising molecular sieve crystals |
| AT92905770T ATE179092T1 (de) | 1991-02-07 | 1992-02-07 | Anorganische verbundmenbran, die molekularsiebkristalle enthaelt |
| AU13519/92A AU1351992A (en) | 1991-02-07 | 1992-02-07 | An inorganic composite membrane comprising molecular sieve crystals |
| BR9205598A BR9205598A (pt) | 1991-02-07 | 1992-02-07 | Membrana compósita inorgânica contendo cristais de peneira molecular e processo para produzir a mesma |
| NO932809A NO303970B1 (no) | 1991-02-07 | 1993-08-06 | Uorgansik komposittmembran omfattende molekylvektkrystaller, og fremgangsmåte for fremstilling av membranen |
| US08/402,108 US5753121A (en) | 1991-02-07 | 1995-03-10 | Inorganic composite membrane comprising molecular sieve crystals |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL9100217 | 1991-02-07 | ||
| NL9100217A NL9100217A (nl) | 1991-02-07 | 1991-02-07 | Moleculaire-zeefkristallen bevattend anorganisch composietmembraan. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL9100217A true NL9100217A (nl) | 1992-09-01 |
Family
ID=19858845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL9100217A NL9100217A (nl) | 1991-02-07 | 1991-02-07 | Moleculaire-zeefkristallen bevattend anorganisch composietmembraan. |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US5429743A (de) |
| EP (1) | EP0570486B1 (de) |
| AT (1) | ATE179092T1 (de) |
| AU (1) | AU1351992A (de) |
| BR (1) | BR9205598A (de) |
| CA (1) | CA2103585A1 (de) |
| DE (1) | DE69228985T2 (de) |
| ES (1) | ES2132117T3 (de) |
| NL (1) | NL9100217A (de) |
| NO (1) | NO303970B1 (de) |
| WO (1) | WO1992013631A1 (de) |
Families Citing this family (71)
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| NL9100217A (nl) * | 1991-02-07 | 1992-09-01 | Univ Delft Tech | Moleculaire-zeefkristallen bevattend anorganisch composietmembraan. |
| NL9201204A (nl) * | 1992-07-06 | 1994-02-01 | Stichting Tech Wetenschapp | Membraan. |
| NL9201940A (nl) * | 1992-11-05 | 1994-06-01 | Univ Delft Tech | Katalysatorsysteem van het gestructureerde type. |
| ATE339249T1 (de) * | 1993-04-23 | 2006-10-15 | Exxonmobil Res & Eng Co | Molekularsiebschichten und verfahren zu ihrer herstellung |
| NL9401260A (nl) * | 1993-11-12 | 1995-06-01 | Cornelis Johannes Maria Van Ri | Membraan voor microfiltratie, ultrafiltratie, gasscheiding en katalyse, werkwijze ter vervaardiging van een dergelijk membraan, mal ter vervaardiging van een dergelijk membraan, alsmede diverse scheidingssystemen omvattende een dergelijk membraan. |
| JP3371533B2 (ja) * | 1994-03-31 | 2003-01-27 | エヌオーケー株式会社 | ガス分離膜の製造法 |
| US5672388A (en) * | 1994-07-08 | 1997-09-30 | Exxon Research & Engineering Company | Membrane reparation and poer size reduction using interfacial ozone assisted chemical vapor deposition |
| US5763347A (en) * | 1994-07-08 | 1998-06-09 | Exxon Research And Engineering Company | In-situ crystallized zeolite containing composition (LAI-ISC) |
| DE69533510T2 (de) * | 1994-07-08 | 2005-09-15 | Exxon Research And Engineering Co. | Zeolith enthaltende zusammensetzung mit einer selektivität erhhöhenden beschichtung |
| US5824617A (en) * | 1994-07-08 | 1998-10-20 | Exxon Research & Engineering Company | Low alkaline inverted in-situ crystallized zeolite membrane |
| US5871650A (en) * | 1994-07-08 | 1999-02-16 | Exxon Research And Engineering Company | Supported zeolite membranes with controlled crystal width and preferred orientation grown on a growth enhancing layer |
| US5654061A (en) * | 1995-01-17 | 1997-08-05 | E. I. Du Pont De Nemours And Company | Sulfide scavenging packaging materials |
| GB9502292D0 (en) * | 1995-02-06 | 1995-03-29 | Bratton Graham J | Adsorbent material |
| KR0158431B1 (ko) * | 1995-06-23 | 1998-11-16 | 윤덕용 | 수소분리용 무기재료막의 제조방법 |
| CA2226925C (en) * | 1995-07-14 | 2006-10-17 | Subhas K. Sikdar | Absorbent filled membranes for removal of volatile compounds from wastewater |
| FR2742070B1 (fr) * | 1995-12-08 | 1998-01-09 | Inst Francais Du Petrole | Procede d'elaboration controlee de membranes de zeolithe supportee |
| GB9600082D0 (en) * | 1996-01-04 | 1996-03-06 | Exxon Chemical Patents Inc | Molecular sieves and processes for their manufacture |
| SE9600970D0 (sv) * | 1996-03-14 | 1996-03-14 | Johan Sterte | Förfarande för framställning av mycket tunna filmer av molekylsiktar |
| GB9607090D0 (en) * | 1996-04-03 | 1996-06-05 | Bratton Graham J | Improved membrane |
| US5789024A (en) * | 1996-05-15 | 1998-08-04 | New Jersey Institute Of Technology | Subnanoscale composite, N2-permselective membrane for the separation of volatile organic compounds |
| US6471745B1 (en) * | 1996-06-28 | 2002-10-29 | University Of Delaware | Nanoporous carbon catalytic membranes and method for making the same |
| US5972079A (en) * | 1996-06-28 | 1999-10-26 | University Of Delaware | Supported carbogenic molecular sieve membrane and method of producing the same |
| JP4044984B2 (ja) * | 1997-01-08 | 2008-02-06 | 日本碍子株式会社 | 吸着材 |
| US6043177A (en) * | 1997-01-21 | 2000-03-28 | University Technology Corporation | Modification of zeolite or molecular sieve membranes using atomic layer controlled chemical vapor deposition |
| US6060415A (en) * | 1997-02-10 | 2000-05-09 | National Science Council | Aligned molecular sieve crystals grown on anodic alumina membrane |
| GB9709340D0 (en) * | 1997-05-09 | 1997-06-25 | Johnson Matthey Plc | Improvements in coated materials |
| JP2981884B1 (ja) * | 1998-06-29 | 1999-11-22 | 工業技術院長 | ゼオライト膜の製造方法 |
| EP1118378A1 (de) * | 1998-08-28 | 2001-07-25 | Toray Industries, Inc. | Übertragbarer film, elektrolytischer katalysator, verfahren zur herstellung von zeolith-filmen, mfi-zeolithfilm und veffahren zur trennung |
| NL1010097C2 (nl) * | 1998-09-15 | 2000-03-17 | Univ Twente | Scheidingsinrichting met keramisch membraan. |
| FR2786710B1 (fr) * | 1998-12-04 | 2001-11-16 | Ceramiques Tech Soc D | Membrane comprenant un support poreux et une couche d'un tamis modeculaire et son procede de preparation |
| US6649255B1 (en) | 1999-03-04 | 2003-11-18 | Douglas E. Fain, Sr. | Article and method for producing extremely small pore inorganic membranes |
| GB9905560D0 (en) * | 1999-03-11 | 1999-05-05 | Exxon Chemical Patents Inc | Process for the manufacture of supported materials |
| JP2003500189A (ja) * | 1999-05-20 | 2003-01-07 | エクソンモービル・ケミカル・パテンツ・インク | 炭化水素転化方法及びその方法に有用な触媒 |
| EP1202791B1 (de) * | 1999-06-11 | 2006-12-27 | Gas Separation Technology, Inc. | Poröses gasdurchlässiges material zur gastrennung |
| DE19952725C1 (de) * | 1999-10-26 | 2001-05-17 | Inst Angewandte Chemie Berlin | Gasdurchlässige Membran und deren Verwendung zur Steuerung des Gasdurchganges |
| US6767384B1 (en) | 2000-01-21 | 2004-07-27 | The Regents Of The University Of Colorado | Isomorphously substituted molecular sieve membranes |
| JP4527229B2 (ja) * | 2000-02-28 | 2010-08-18 | 日本碍子株式会社 | モルデナイトゼオライト膜およびその製造方法 |
| JP3871501B2 (ja) * | 2000-08-07 | 2007-01-24 | 株式会社ノリタケカンパニーリミテド | ゼオライト膜とその製造方法と膜リアクター |
| US6395067B1 (en) * | 2000-09-15 | 2002-05-28 | Engelhard Corporation | Geometric separation processes involving modified CTS membranes |
| GB0106478D0 (en) * | 2001-03-16 | 2001-05-02 | Univ Robert Gordon | Apparatus and method |
| MXPA04002508A (es) * | 2001-09-17 | 2004-05-31 | Ngk Insulators Ltd | Metodo para preparar membrana de zeolita tipo ddr, membrana de zeolita tipo ddr y membrana de zeolita tipo ddr compuesta y metodo para preparar las mismas. |
| US6626980B2 (en) * | 2001-09-21 | 2003-09-30 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Mixed matrix membranes incorporating chabazite type molecular sieves |
| US20080134884A1 (en) * | 2002-06-24 | 2008-06-12 | Jack Sammons | Porous gas permeable material for gas separation |
| US6663805B1 (en) | 2002-09-20 | 2003-12-16 | L'air Liquide Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process for making hollow fiber mixed matrix membranes |
| KR100460450B1 (ko) * | 2002-10-04 | 2004-12-08 | 한국화학연구원 | 함침-롤링법에 의한 열적 안정성이 우수한 실리카 복합막의 제조방법 |
| CN100429150C (zh) * | 2003-08-06 | 2008-10-29 | 三菱化学株式会社 | 沸石膜的制法和制造装置及由该法得到的沸石管状分离膜 |
| US20110309016A1 (en) * | 2005-08-24 | 2011-12-22 | Mikel Duke | Desalination method and apparatus |
| JP2007126341A (ja) * | 2005-11-07 | 2007-05-24 | Toshiba Corp | 異方性多孔質材料 |
| US20090114089A1 (en) * | 2007-11-02 | 2009-05-07 | Chunqing Liu | Microporous Aluminophosphate Molecular Sieve Membranes for Highly Selective Separations |
| US20090126567A1 (en) * | 2007-11-16 | 2009-05-21 | Chunqing Liu | Mixed Matrix Membranes Containing Molecular Sieves With Thin Plate Morphology |
| GB0723841D0 (en) | 2007-12-06 | 2008-01-16 | Univ Leuven Kath | Enhancing catalytic activity of nanoprous materials |
| WO2009158013A1 (en) * | 2008-06-26 | 2009-12-30 | Nano Terra Inc. | Methods for reducing the sensory effects of odorous compounds |
| GR20080100438A (el) * | 2008-06-27 | 2010-01-27 | Μεθοδος χημικης διεισδυσης ατμων χαμηλης θερμοκρασιας, για την τροποποιηση του μεγεθους των πορων και την επιδιορθωση ατελειων σε μικροπορωδεις και νανοπορωδεις μεμβρανες | |
| DE102008049756A1 (de) * | 2008-09-30 | 2010-05-27 | Osram Gesellschaft mit beschränkter Haftung | Schaltungsträger mit Transformator |
| ITCS20100003A1 (it) | 2010-02-09 | 2011-08-10 | Univ Calabria | Membrana zeolitica per adesioni e colture di cellule, procedimento per la preparazione ed applicazione. |
| AU2011223580B2 (en) * | 2010-03-04 | 2014-03-27 | Shell Internationale Research Maatschappij B.V. | Method of making SAPO-34 membranes for use in gas separations |
| US8337588B2 (en) * | 2010-04-12 | 2012-12-25 | The Ohio State University Research Foundation | Modified zeolite Y membranes for high-performance CO2 separation |
| US8647997B2 (en) * | 2010-11-30 | 2014-02-11 | General Electric Company | Zeolite membrane and methods of making the same |
| WO2015066337A1 (en) | 2013-10-31 | 2015-05-07 | University Of Florida Research Foundation, Inc. | Porous polymer membranes, methods of making, and methods of use |
| WO2016108996A1 (en) | 2014-10-17 | 2016-07-07 | The University Of Florida Research Foundation, Inc. | Methods and structures for light regulating coatings |
| US10189967B2 (en) | 2015-05-08 | 2019-01-29 | University Of Florida Research Foundation, Inc. | Macroporous photonic crystal membrane, methods of making, and methods of use |
| US11024859B2 (en) | 2016-02-04 | 2021-06-01 | Board Of Regents, The University Of Texas System | High temperature humidification membranes |
| CN106179195B (zh) * | 2016-07-11 | 2019-08-23 | 武汉理工大学 | 一种梯度复合结构多级孔薄膜及其制备方法 |
| WO2018035091A1 (en) | 2016-08-15 | 2018-02-22 | University Of Florida Research Foundation, Inc. | Methods and compositions relating to tunable nanoporous coatings |
| CN108295670B (zh) * | 2017-01-12 | 2019-11-19 | 北京赛特超润界面科技有限公司 | 一种仿生二维离子通道功能膜材料及其制备方法 |
| US11467094B2 (en) | 2017-05-17 | 2022-10-11 | University Of Florida Research Foundation, Inc. | Methods and sensors for detection |
| US11480527B2 (en) | 2017-12-20 | 2022-10-25 | University Of Florida Research Foundation, Inc. | Methods and sensors for detection |
| WO2019126171A1 (en) | 2017-12-21 | 2019-06-27 | University Of Florida Research Foundation | Substrates having a broadband antireflection layer and methods of forming a broadband antireflection layer |
| US11819277B2 (en) | 2018-06-20 | 2023-11-21 | University Of Florida Research Foundation, Inc. | Intraocular pressure sensing material, devices, and uses thereof |
| CN112744828B (zh) * | 2019-10-31 | 2022-10-14 | 上海工程技术大学 | 一种超薄分子筛膜及其制备方法 |
| EP4149665A1 (de) * | 2020-05-12 | 2023-03-22 | ExxonMobil Technology and Engineering Company | Wachs- und schmierbasisprodukte mit formselektiver membrantrennung |
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| US2924630A (en) * | 1957-06-28 | 1960-02-09 | Union Oil Co | Fluid diffusion fractionation |
| US4012206A (en) * | 1972-12-02 | 1977-03-15 | Gas Developments Corporation | Air cleaning adsorption process |
| DE2641631C3 (de) * | 1976-09-16 | 1980-04-10 | Glienke, Peter O., 7582 Buehlertal | Verfahren zur Herstellung eines porösen keramischen Leichtgewichterzeugnisses |
| US5127925A (en) * | 1982-12-13 | 1992-07-07 | Allied-Signal Inc. | Separation of gases by means of mixed matrix membranes |
| JPS6028826A (ja) * | 1983-07-26 | 1985-02-14 | Hiroshi Suzuki | かご型ゼオライト薄膜表層を有する複合膜及びその製造法 |
| JPS60129119A (ja) * | 1983-12-15 | 1985-07-10 | Matsushita Electric Ind Co Ltd | 気体分離膜 |
| US4800187A (en) * | 1987-10-28 | 1989-01-24 | Corning Glass Works | Method of crystallizing a zeolite on the surface of a monolithic ceramic substrate |
| DE3827049A1 (de) * | 1988-08-10 | 1990-02-15 | Schulten Rudolf Prof Dr | Zeolithisches molekularsieb zur trennung von fluiden |
| JPH03221588A (ja) * | 1990-01-26 | 1991-09-30 | Showa Shell Sekiyu Kk | 液晶組成物用配合剤およびそれらを含む液晶組成物 |
| US5019263A (en) * | 1990-06-05 | 1991-05-28 | Mobil Oil Corp. | Membrane composed of a pure molecular sieve |
| US5069794A (en) * | 1990-06-05 | 1991-12-03 | Mobil Oil Corp. | Separation of mixture components over membrane composed of a pure molecular sieve |
| US5110478A (en) * | 1990-06-05 | 1992-05-05 | Mobil Oil Corp. | Catalytic conversion over membrane composed of a pure molecular sieve |
| NL9100217A (nl) * | 1991-02-07 | 1992-09-01 | Univ Delft Tech | Moleculaire-zeefkristallen bevattend anorganisch composietmembraan. |
-
1991
- 1991-02-07 NL NL9100217A patent/NL9100217A/nl not_active Application Discontinuation
-
1992
- 1992-02-07 DE DE69228985T patent/DE69228985T2/de not_active Expired - Fee Related
- 1992-02-07 CA CA002103585A patent/CA2103585A1/en not_active Abandoned
- 1992-02-07 EP EP92905770A patent/EP0570486B1/de not_active Expired - Lifetime
- 1992-02-07 AT AT92905770T patent/ATE179092T1/de not_active IP Right Cessation
- 1992-02-07 BR BR9205598A patent/BR9205598A/pt not_active Application Discontinuation
- 1992-02-07 AU AU13519/92A patent/AU1351992A/en not_active Abandoned
- 1992-02-07 WO PCT/NL1992/000029 patent/WO1992013631A1/en active IP Right Grant
- 1992-02-07 US US08/098,287 patent/US5429743A/en not_active Expired - Lifetime
- 1992-02-07 ES ES92905770T patent/ES2132117T3/es not_active Expired - Lifetime
-
1993
- 1993-08-06 NO NO932809A patent/NO303970B1/no not_active IP Right Cessation
-
1995
- 1995-03-10 US US08/402,108 patent/US5753121A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU1351992A (en) | 1992-09-07 |
| US5429743A (en) | 1995-07-04 |
| EP0570486B1 (de) | 1999-04-21 |
| NO932809D0 (no) | 1993-08-06 |
| WO1992013631A1 (en) | 1992-08-20 |
| ES2132117T3 (es) | 1999-08-16 |
| BR9205598A (pt) | 1994-06-14 |
| NO932809L (no) | 1993-10-07 |
| EP0570486A1 (de) | 1993-11-24 |
| US5753121A (en) | 1998-05-19 |
| DE69228985T2 (de) | 1999-10-14 |
| ATE179092T1 (de) | 1999-05-15 |
| CA2103585A1 (en) | 1992-08-08 |
| NO303970B1 (no) | 1998-10-05 |
| DE69228985D1 (de) | 1999-05-27 |
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