NL2033665B1 - High-temperature-resistant organic silicone elastomer and preparation method thereof - Google Patents
High-temperature-resistant organic silicone elastomer and preparation method thereof Download PDFInfo
- Publication number
- NL2033665B1 NL2033665B1 NL2033665A NL2033665A NL2033665B1 NL 2033665 B1 NL2033665 B1 NL 2033665B1 NL 2033665 A NL2033665 A NL 2033665A NL 2033665 A NL2033665 A NL 2033665A NL 2033665 B1 NL2033665 B1 NL 2033665B1
- Authority
- NL
- Netherlands
- Prior art keywords
- silicone elastomer
- preparation
- organic silicone
- titanium
- resistant organic
- Prior art date
Links
- 229920002379 silicone rubber Polymers 0.000 title claims abstract description 65
- 238000002360 preparation method Methods 0.000 title claims abstract description 38
- 229920002545 silicone oil Polymers 0.000 claims abstract description 34
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 33
- 239000002105 nanoparticle Substances 0.000 claims abstract description 31
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000006243 chemical reaction Methods 0.000 claims abstract description 14
- 230000003068 static effect Effects 0.000 claims abstract description 14
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 claims abstract description 14
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 13
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 12
- 239000000178 monomer Substances 0.000 claims abstract description 12
- 229910000077 silane Inorganic materials 0.000 claims abstract description 12
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical group CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical class ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 42
- 239000000243 solution Substances 0.000 claims description 35
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 15
- 239000011259 mixed solution Substances 0.000 claims description 9
- 239000010936 titanium Substances 0.000 claims description 9
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 8
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical class O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 6
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 235000019260 propionic acid Nutrition 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical class CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims 7
- 241001214257 Mene Species 0.000 claims 1
- 239000003245 coal Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000007789 sealing Methods 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 5
- 229960005196 titanium dioxide Drugs 0.000 description 11
- 239000007787 solid Substances 0.000 description 10
- 235000010215 titanium dioxide Nutrition 0.000 description 9
- 125000004122 cyclic group Chemical group 0.000 description 8
- 238000001228 spectrum Methods 0.000 description 8
- 238000001757 thermogravimetry curve Methods 0.000 description 8
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 238000009210 therapy by ultrasound Methods 0.000 description 5
- 229940093476 ethylene glycol Drugs 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 229940095574 propionic acid Drugs 0.000 description 3
- -1 siloxanes Chemical class 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000013375 chromatographic separation Methods 0.000 description 1
- 229940000425 combination drug Drugs 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 210000004379 membrane Anatomy 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
Claims (10)
1. Bereidingsmethode van een hoog-temperatuurbestendig organisch siliconenelastomeer, omvattende de volgende stappen: het uniform mengen van een hydroxylsiliconenolie en een silaanmo- nomeer verknopingsmiddel, het toevoegen van KH550 en tin-octoaat, en het mengsel toestaan voor statische reactie-uitharding, waarbij de hydroxylsiliconenolie een methyl-eindstandige hydroxylsilico- nenolie is; en het silaanmonomeer verknopingsmiddel methyltrimethoxysilaan of fe- nyltrimethoxysilaan is.
2. Bereidingsmethode van een hoog-temperatuurbestendig organisch siliconenelastomeer volgens conclusie 1, die verder een stap omvat van het modificeren van het organische siliconenelastomeer door het toevoegen van titaniumdioxide nanodeeltjes of cyclische tita- nium-oxo-clustermoleculen Ti::0:¢ (EG): (PAC).s(EtQ) 1s aan het reactie- systeem, waarbij EG staat voor ethyleenglycol, PAc staat voor ge- deprotoneerd propionzuur en EtO staat voor gedeprotoneerd ethanol.
3. Bereidingsmethode van een hoog-temperatuurbestendig organisch siliconenelastomeer volgens conclusie 2, waarbij een structuurfor- mule van de cyclische titanium-oxo-clustermoleculen Ti32O0:16 (EG) 32 (PAC) 16 (EtO) 16 als volgt is: wr | ww md ~ RE my : 4 L Dr hed >” mea i Le Ss, Leda RET Le MAA ey an} ae? et di ek et Dn MCL Yt, By Dd Ne Vb el - Tw Ny SONA Ag A Les El yd Lay STN NS ee | > SOEs Coal Jee NT en ’ VT XD ET Vi ket dd A] ee EL A] ee NL TNT ee De | AS of A 1 \, ng / dr ON í CAT dee fo PLN Nd ER Oan AEL ANT EE Len le \ i KF % Fi “adel AEs ee YT Fas mene TT ANE TT A eN TIT pee ST LY a EET ESV RAY SE BLN Lag ee Vr a ST TE see ESTING \ ne po eN \ ee TT Ta ANA TTT 3 ch be sor ==
4. Bereidingsmethode van een hoge-temperatuurbestendig organisch siliconenelastomeer volgens conclusie 3, waarbij de cyclische ti- tanium-oxo-clustermoleculen worden toegevoegd in een vorm van een dichloormethaanoplossing van cyclische titanium-oxo-clusters; of waarbij een bereidingsmethode van de cyclische titanium-oxo- clustermoleculen Ti320:15(EG)}3:2(PAc)is (EtO)1s de volgende stappen om- vat: het toevoegen van titanium isopropoxide aan een gemengde oplossing van propionzuur en ethyleenglycol, het uniform mengen, afdichten, verwarmen en roeren van de oplossing bij 90 tot 110 °C gedurende 20 tot 30 uur om de cyclische titanium-oxo-clustermoleculen Ti320:6 (EG) 32 (PAC) 5 (EEO); te verkrijgen.
5. Bereidingsmethode van een hoge-temperatuurbestendig organisch siliconenelastomeer volgens conclusie 1, waarbij een viscositeit van de methyl-eindstandige hydroxylsiliconenolie 650 tot 750 cP is.
6. Bereidingsmethode van een hoge-temperatuurbestendig organisch siliconenelastomeer volgens conclusie 2, waarbij de titaniumdioxi- de nanodeeltjes P25-type zijn met een gemiddelde deeltjesdiameter van 25 nm.
7. Bereidingsmethode van een hoge-temperatuurbestendig organisch siliconenelastomeer volgens conclusie 1, waarbij het silaanmono- meer verknopingsmiddel fenyltrimethoxysilaan is.
8. Bereidingsmethode van een hoge-temperatuurbestendig organisch siliconenelastomeer volgens conclusie 1, waarbij een molaire ver- houding van de hydroxylsiliconenolie, het silaanmonomeer verkno- pings middel, KH550 en het tin-octoaat is 1040: 15-25: 2-4: 0,8- 1,2; of waarbij een massa van de titaniumdioxide nanodeeltjes 2 tot 4% van die van de hydroxylsiliconenolie is; waarbij een massa van de cyclische titanium-oxo-clusters 1 tot 4% van die van de hydroxylsiliconenolie is.
9. Bereidingsmethode van een hoge-temperatuurbestendig organisch siliconenelastomeer volgens conclusie 1, waarbij een temperatuur van de statische reactie-uitharding 20 tot 30 °C is.
10. Hoge-temperatuurbestendig organisch siliconenelastomeer, be- reid door de bereidingsmethode volgens een van conclusies 1 tot 9.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211057864.8A CN115490863B (zh) | 2022-08-31 | 2022-08-31 | 一种耐高温有机硅弹性体及其制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL2033665B1 true NL2033665B1 (en) | 2024-03-12 |
Family
ID=84468565
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL2033665A NL2033665B1 (en) | 2022-08-31 | 2022-12-05 | High-temperature-resistant organic silicone elastomer and preparation method thereof |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN115490863B (nl) |
| NL (1) | NL2033665B1 (nl) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20200190358A1 (en) * | 2018-12-13 | 2020-06-18 | Momentive Performance Materials Inc. | Organosiloxane coating composition and uses thereof |
| US20210238417A1 (en) * | 2018-04-19 | 2021-08-05 | Wacker Chemie Ag | Polysiloxane composition |
| WO2022140217A1 (en) * | 2020-12-22 | 2022-06-30 | Dow Silicones Corporation | Sealant composition |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5482698B2 (ja) * | 2011-03-16 | 2014-05-07 | 信越化学工業株式会社 | ２液混合型室温硬化性オルガノポリシロキサン組成物 |
| CN103146339A (zh) * | 2013-03-22 | 2013-06-12 | 江苏创景科技有限公司 | 脱醇型快固化有机硅密封胶及其制备方法 |
| CN105219340A (zh) * | 2015-09-09 | 2016-01-06 | 浙江汇杰有机硅股份有限公司 | 一种耐温耐油有机硅免垫胶及其制备方法 |
| CN112080247B (zh) * | 2020-09-02 | 2022-04-29 | 圣戈班汇杰(杭州)新材料有限公司 | 一种可粘结rtv硅酮胶的水性硅酮胶 |
| CN113480569B (zh) * | 2021-07-08 | 2022-08-12 | 江西省科学院应用化学研究所 | 钛氧簇型化合物及其制备与作为电子传输材料的应用 |
-
2022
- 2022-08-31 CN CN202211057864.8A patent/CN115490863B/zh active Active
- 2022-12-05 NL NL2033665A patent/NL2033665B1/en active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20210238417A1 (en) * | 2018-04-19 | 2021-08-05 | Wacker Chemie Ag | Polysiloxane composition |
| US20200190358A1 (en) * | 2018-12-13 | 2020-06-18 | Momentive Performance Materials Inc. | Organosiloxane coating composition and uses thereof |
| WO2022140217A1 (en) * | 2020-12-22 | 2022-06-30 | Dow Silicones Corporation | Sealant composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115490863A (zh) | 2022-12-20 |
| CN115490863B (zh) | 2023-11-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2017206671A1 (zh) | 具有动态交联结构的动态聚合物 | |
| CN109054734A (zh) | 一种基于含氨基硅氧烷制备的胶黏剂及其制备和使用方法 | |
| CN111139052B (zh) | 一种低浓度的羟丙基胍胶压裂液及制备方法 | |
| CN107082885B (zh) | 一种poss基氨基改性聚丙撑碳酸酯及其制备方法 | |
| WO2019096188A1 (zh) | 硅氧烷桥基硅烷封端的硅氧烷桥基梯形聚硅氧烷及其制备方法 | |
| EP3353227B1 (en) | Epoxy terminated butadiene and butadiene acrylonitrile copolymers | |
| CN109851759A (zh) | 有机硅改性环氧树脂、其制备方法以及有机硅改性环氧树脂胶黏剂 | |
| NL2033665B1 (en) | High-temperature-resistant organic silicone elastomer and preparation method thereof | |
| CN115286799A (zh) | 一种三嵌段聚硅氧烷季铵盐及其制备方法 | |
| CN109485853B (zh) | 一种聚硅氧烷/全氢聚硅氮烷杂化聚合物及其合成方法 | |
| CN105111747B (zh) | 一种自催化的脱酮肟型室温硫化硅橡胶及其制备方法 | |
| CN105754087A (zh) | 一种端硅氧烷聚醚的制备方法 | |
| CN100471898C (zh) | 星型多臂硅油的制备方法 | |
| CN113388274B (zh) | 一种耐磨水润滑自修复涂层及其制备方法 | |
| CN103906753B (zh) | 含烷氧基甲硅烷基的异氰脲酸酯环氧化合物、它的制备方法、包括它的组合物、组合物的固化产物和组合物的应用 | |
| Ramirez et al. | Thermal behaviour of a polyhedral oligomeric silsesquioxane with epoxy resin cured by diamines | |
| CN116589973B (zh) | 一种耐高温cob封装胶及其制备方法 | |
| CN110437624B (zh) | 一种透明双官能环氧树脂-硅橡胶嵌段网络材料 | |
| CN110724268A (zh) | 一种含二甲基硅氧烷悬挂链的双酚a型环氧树脂的制备方法及其应用 | |
| KR102364516B1 (ko) | 자가치유성 폴리우레아/졸-겔 실리카 나노하이브리드 경화물 및 그 제조방법 | |
| CN106543957A (zh) | 双组分增韧型聚二苯基硼硅氧烷胶黏剂及其制备和应用方法 | |
| CN112876686A (zh) | 一种耐烧蚀碳硼烷有机硅聚合物及其制备方法与应用 | |
| CN114214048A (zh) | 一种固井工作液用抗高温悬浮稳定剂及其制备方法 | |
| CN109825274B (zh) | 水基压裂液组合物和水基压裂液 | |
| JPH0465429A (ja) | ポリシルエチレンシロキサン |