NL2031434B1 - Modified vinyl silane and preparation method and application thereof - Google Patents
Modified vinyl silane and preparation method and application thereof Download PDFInfo
- Publication number
- NL2031434B1 NL2031434B1 NL2031434A NL2031434A NL2031434B1 NL 2031434 B1 NL2031434 B1 NL 2031434B1 NL 2031434 A NL2031434 A NL 2031434A NL 2031434 A NL2031434 A NL 2031434A NL 2031434 B1 NL2031434 B1 NL 2031434B1
- Authority
- NL
- Netherlands
- Prior art keywords
- vinyl silane
- modified
- modified vinyl
- catalyst
- silane
- Prior art date
Links
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 title claims abstract description 91
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 229920002545 silicone oil Polymers 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 239000003054 catalyst Substances 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 22
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- 229920002554 vinyl polymer Polymers 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 10
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 8
- -1 cyclic dimethylsiloxane Chemical class 0.000 claims description 6
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical group CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 229910000077 silane Inorganic materials 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 5
- MABAWBWRUSBLKQ-UHFFFAOYSA-N ethenyl-tri(propan-2-yloxy)silane Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)C=C MABAWBWRUSBLKQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000003518 caustics Substances 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 238000003786 synthesis reaction Methods 0.000 claims description 3
- 239000003607 modifier Substances 0.000 claims 4
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000000843 powder Substances 0.000 abstract description 17
- 239000007822 coupling agent Substances 0.000 abstract description 4
- 238000007142 ring opening reaction Methods 0.000 abstract description 2
- 239000002210 silicon-based material Substances 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 21
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- 239000000347 magnesium hydroxide Substances 0.000 description 12
- 229960000816 magnesium hydroxide Drugs 0.000 description 12
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 12
- 235000012254 magnesium hydroxide Nutrition 0.000 description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 230000004913 activation Effects 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 235000019441 ethanol Nutrition 0.000 description 5
- 238000002329 infrared spectrum Methods 0.000 description 5
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 4
- 238000012795 verification Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000012496 blank sample Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 239000011368 organic material Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- UUFQTNFCRMXOAE-UHFFFAOYSA-N 1-methylmethylene Chemical compound C[CH] UUFQTNFCRMXOAE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001808 coupling effect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006462 rearrangement reaction Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
- C07F7/1872—Preparation; Treatments not provided for in C07F7/20
- C07F7/188—Preparation; Treatments not provided for in C07F7/20 by reactions involving the formation of Si-O linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/06—Preparatory processes
- C08G77/10—Equilibration processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5425—Silicon-containing compounds containing oxygen containing at least one C=C bond
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/02—Compounds of alkaline earth metals or magnesium
- C09C1/028—Compounds containing only magnesium as metal
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/12—Treatment with organosilicon compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/045—Polysiloxanes containing less than 25 silicon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Silicon Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Claims (10)
1. Gemodificeerde vinylsilaan, met de structuur zoals getoond in formule I: OR: I Formule I; OR; si STD OR, waarin geldt dat, R staat voor of = 2 a 0 - Jo Son FL SL { } 3 Si = OR, J ; waarbij Ry; staat voor methyl, ethyl, propyl of isopropyl; waarbij voorts geldt dat x = 2 tot 8, en y = 1 tot 50.
2. Gemodificeerd vinylsilaan volgens conclusie 1, waarbij de vis- cositeit van het gemodificeerde vinylsilaan 2 tot 50 mPa/s be- draagt.
3. Werkwijze voor het bereiden van het gemodificeerde vinylsilaan volgens conclusie 1 of 2, omvattende de volgende stappen: het mengen van vinylsilaan, een modificerend middel, een katalysa- tor en water, en het uitvoeren van een modificerende reactie om het gemodificeerde vinylsilaan te verkrijgen; waarbij het vinylsilaan vinyltrialkoxysilaan omvat; waarbij het vinyltrialkoxysilaan vinyltrimethoxysilaan, vinyltriethoxysilaan,
vinyltriproxysilaan of vinyltriisopropoxysilaan omvat; waarbij het modificerende middel siliconenolie of cyclisch dime- thylsiloxaan omvat; waarbij de siliconenolie de structuur heeft zoals weergegeven in formule II: / J \ ~~ ~~ ot ~o tn ~~ Formule II, waarbij geldt dat m = 1 tot 50; waarbij de dimethylsiloxaan cyclische verbinding de structuur heeft die wordt weergegeven in de formule III: Lo Ra \ | It A Formule IIT, waarbij geldt dat n = 2~8.
4. Werkwijze volgens conclusie 3, waarbij de massaverhouding van vinylsilaan tot het modificerende middel 1: (0,3 tot 1,2) is.
5. Werkwijze volgens conclusie 3, waarbij de katalysator bijtende alkali of geconcentreerd zwavelzuur omvat.
6. Werkwijze volgens conclusie 3 of 5, waarbij de massa van de ka- talysator 0,01 tot 0,03% van de totale massa aan vinylsilaan en het modificerende middel uitmaakt.
7. Werkwijze volgens conclusie 3, waarbij de massa aan water 5 tot 20% van de massa aan vinylsilaan uitmaakt.
8. Werkwijze volgens conclusie 3, waarbij de temperatuur van de modificerende reactie 50 tot 100 °C is en de tijd 1 tot 12 uur be- draagt.
9. Werkwijze volgens conclusie 3, waarbij het mengproces van vi- nylsilaan, het modificerende middel, de katalysator en water de volgende stappen omvat: het mengen van vinylsilaan en het modifi- cerende middel, verhitten tot 50 tot 100 °C, het tegelijkertijd toevoegen van water en de katalysator aan het verkregen mengsel, waarbij de tijd van het toevoegen van water en de katalysator 0,5 tot 2 uur is.
10. Toepassing van het gemodificeerde vinylsilaan volgens conclu- sie 1 of 2 of het gemodificeerde vinylsilaan bereid met de berei- dingswerkwijze van een van de conclusies 3 tot 9 bij de synthese van organische en anorganische hybride materialen.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210011879.4A CN114805426B (zh) | 2022-01-07 | 2022-01-07 | 一种改性乙烯基硅烷及其制备方法和应用 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL2031434B1 true NL2031434B1 (en) | 2023-07-13 |
Family
ID=81927963
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL2031434A NL2031434B1 (en) | 2022-01-07 | 2022-03-29 | Modified vinyl silane and preparation method and application thereof |
Country Status (4)
| Country | Link |
|---|---|
| CN (1) | CN114805426B (nl) |
| NL (1) | NL2031434B1 (nl) |
| WO (1) | WO2023130551A1 (nl) |
| ZA (1) | ZA202213851B (nl) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118165547A (zh) * | 2024-05-15 | 2024-06-11 | 杭州崇耀科技发展有限公司 | 一种纳米碳酸钙表面处理剂及制备方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012172176A2 (en) * | 2011-06-14 | 2012-12-20 | Silecs Oy | Method of synthesizing siloxane monomers and use thereof |
| WO2021085586A1 (ja) * | 2019-10-30 | 2021-05-06 | ダウ・東レ株式会社 | オルガノポリシロキサン、その製造方法、および熱伝導性シリコーン組成物 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9157009B2 (en) * | 2011-07-07 | 2015-10-13 | Bluestar Silicones France Sas | Uses of carbenes in solution as organopolysiloxane polycondensation catalysts |
| CN103161082B (zh) * | 2013-02-26 | 2015-11-18 | 中国中化股份有限公司 | 一种有机硅改性涂料印花粘合剂及其制备方法 |
| CN103936995A (zh) * | 2013-05-20 | 2014-07-23 | 深圳市泰科科技有限公司 | 烷氧基封端的线性聚硅氧烷的制备方法 |
| CN103351839A (zh) * | 2013-07-23 | 2013-10-16 | 上海魁固塑胶制品有限公司 | 单组分脱胺型高导电硅橡胶及其制备方法 |
| CN105017493A (zh) * | 2014-04-15 | 2015-11-04 | 辽宁天麒科技有限公司 | 一种有机硅改性弱溶剂吸墨涂层树脂及其制备方法和应用 |
| CN104388042B (zh) * | 2014-10-30 | 2016-04-13 | 广州回天新材料有限公司 | 一种加成型硅橡胶组合物 |
| CN105348813B (zh) * | 2015-12-04 | 2017-12-29 | 厦门安耐伟业新材料有限公司 | 一种可湿‑热双重固化的单组份有机硅组合物及其制备方法 |
| GB2557948B (en) * | 2016-12-16 | 2021-06-23 | Tesa Se | Silicone elastomer composition |
| CN107057000A (zh) * | 2017-02-14 | 2017-08-18 | 中山市博海精细化工有限公司 | 一种防水用硅丙乳液涂料及其制备方法 |
| CN108003348B (zh) * | 2017-12-15 | 2021-02-23 | 长兴（中国）投资有限公司 | 硅氧烷桥基梯形聚硅氧烷，其制备方法及应用 |
| CN112961352B (zh) * | 2021-02-19 | 2022-10-11 | 江西蓝星星火有机硅有限公司 | 甲基乙烯基羟基聚硅氧烷及其制备方法和应用 |
-
2022
- 2022-01-07 CN CN202210011879.4A patent/CN114805426B/zh active Active
- 2022-03-01 WO PCT/CN2022/078517 patent/WO2023130551A1/zh unknown
- 2022-03-29 NL NL2031434A patent/NL2031434B1/en active
- 2022-12-21 ZA ZA2022/13851A patent/ZA202213851B/en unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012172176A2 (en) * | 2011-06-14 | 2012-12-20 | Silecs Oy | Method of synthesizing siloxane monomers and use thereof |
| WO2021085586A1 (ja) * | 2019-10-30 | 2021-05-06 | ダウ・東レ株式会社 | オルガノポリシロキサン、その製造方法、および熱伝導性シリコーン組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN114805426B (zh) | 2024-03-19 |
| CN114805426A (zh) | 2022-07-29 |
| ZA202213851B (en) | 2023-10-25 |
| WO2023130551A1 (zh) | 2023-07-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5262558A (en) | Method of making organo-silicon polymers having mono- and tetra-functional siloxane units | |
| EP0919558B1 (en) | Silatrane derivative, method for manufacturing same, adhesion promoter, and curable silicone compositions | |
| JPH0718078A (ja) | オルガノポリシロキサンおよびその製造方法 | |
| DE4216139A1 (de) | Verfahren zur Herstellung von Organopolysiloxanharz | |
| NL2031434B1 (en) | Modified vinyl silane and preparation method and application thereof | |
| KR102275311B1 (ko) | 트리스[3-(알콕시실릴)프로필] 이소시아누레이트를 제조하는 방법 | |
| JPH03190929A (ja) | 非水系によるシリコーンオリゴマー調製法 | |
| JP3466238B2 (ja) | オルガノポリシロキサンおよびその製造方法 | |
| US10364260B2 (en) | Process for preparing tris[3-(alkoxysilyl)propyl] isocyanurates | |
| JP2715652B2 (ja) | ハイドロジェンポリシロキサンの製造方法 | |
| JP4187843B2 (ja) | シラトラン誘導体、その製造方法、接着促進剤、および硬化性シリコーン組成物 | |
| DE60014737T2 (de) | Phenolfunktionelle Organosilikonverbindungen und Verfahren zu deren Herstellung | |
| TWI434878B (zh) | An organopolysiloxane containing an organofunctional group and a plurality of alkoxy groups having different carbon numbers | |
| JP2000265063A (ja) | シリコーンゴム組成物 | |
| JP6409695B2 (ja) | アミノ基を有する有機ケイ素化合物及びその製造方法 | |
| JPH07157562A (ja) | ポリシロキサンの製造方法 | |
| TW202311357A (zh) | 玻璃成分 | |
| CN101151298A (zh) | 多面体低聚倍半硅氧烷单体组装的方法 | |
| TWI798294B (zh) | 矽烷混合物及其製備方法 | |
| CN110372741A (zh) | 含甘脲环的有机硅化合物及制备方法 | |
| KR20230053668A (ko) | 실록산의 제조 방법 | |
| JP3859851B2 (ja) | 接着促進剤および硬化性シリコーン組成物 | |
| JP5473636B2 (ja) | イソシアヌレート化合物 | |
| TWI431067B (zh) | Containing organic polysiloxane mixed composition | |
| US8524933B2 (en) | Beta-ketoester group-containing organopolysiloxane compound |