MXPA03011425A - Ciclodextrina injertada. - Google Patents
Ciclodextrina injertada.Info
- Publication number
- MXPA03011425A MXPA03011425A MXPA03011425A MXPA03011425A MXPA03011425A MX PA03011425 A MXPA03011425 A MX PA03011425A MX PA03011425 A MXPA03011425 A MX PA03011425A MX PA03011425 A MXPA03011425 A MX PA03011425A MX PA03011425 A MXPA03011425 A MX PA03011425A
- Authority
- MX
- Mexico
- Prior art keywords
- polyolefin
- cyclodextrin
- weight
- compound
- modified polyolefin
- Prior art date
Links
- 229920000858 Cyclodextrin Polymers 0.000 title claims abstract description 233
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 title claims abstract description 202
- 239000000203 mixture Substances 0.000 claims abstract description 143
- 229920000642 polymer Polymers 0.000 claims abstract description 98
- -1 cyclodextrin compound Chemical class 0.000 claims abstract description 47
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 23
- 229920000098 polyolefin Polymers 0.000 claims description 117
- 150000001875 compounds Chemical class 0.000 claims description 48
- 229920005989 resin Polymers 0.000 claims description 39
- 239000011347 resin Substances 0.000 claims description 39
- 229920005672 polyolefin resin Polymers 0.000 claims description 25
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 15
- 239000011148 porous material Substances 0.000 claims description 14
- 239000000155 melt Substances 0.000 claims description 11
- 125000001424 substituent group Chemical group 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid group Chemical group C(\C=C/C(=O)O)(=O)O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 6
- 239000008103 glucose Substances 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 4
- 239000000463 material Substances 0.000 abstract description 68
- 230000004888 barrier function Effects 0.000 abstract description 35
- 239000012535 impurity Substances 0.000 abstract description 7
- 239000000356 contaminant Substances 0.000 abstract description 6
- 229920002554 vinyl polymer Polymers 0.000 abstract description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract description 2
- 229920001684 low density polyethylene Polymers 0.000 description 109
- 239000004702 low-density polyethylene Substances 0.000 description 105
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 48
- 238000002156 mixing Methods 0.000 description 46
- 238000012360 testing method Methods 0.000 description 45
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 description 42
- 235000013305 food Nutrition 0.000 description 42
- 239000000126 substance Substances 0.000 description 36
- 238000000034 method Methods 0.000 description 34
- 239000010410 layer Substances 0.000 description 32
- 239000010408 film Substances 0.000 description 31
- 239000000796 flavoring agent Substances 0.000 description 31
- 150000001299 aldehydes Chemical class 0.000 description 27
- 235000019634 flavors Nutrition 0.000 description 27
- 239000000523 sample Substances 0.000 description 27
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 25
- 229920003300 Plexar® Polymers 0.000 description 25
- 238000004806 packaging method and process Methods 0.000 description 25
- 229920001903 high density polyethylene Polymers 0.000 description 24
- 239000004700 high-density polyethylene Substances 0.000 description 24
- 239000000047 product Substances 0.000 description 22
- 238000006243 chemical reaction Methods 0.000 description 21
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 20
- 239000001116 FEMA 4028 Substances 0.000 description 19
- 235000011175 beta-cyclodextrine Nutrition 0.000 description 19
- 229960004853 betadex Drugs 0.000 description 19
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 19
- 229920003023 plastic Polymers 0.000 description 19
- 239000004033 plastic Substances 0.000 description 19
- 239000011257 shell material Substances 0.000 description 19
- 150000008064 anhydrides Chemical class 0.000 description 18
- 229920001577 copolymer Polymers 0.000 description 18
- 239000000835 fiber Substances 0.000 description 18
- 235000019645 odor Nutrition 0.000 description 18
- 239000004594 Masterbatch (MB) Substances 0.000 description 17
- 229920001112 grafted polyolefin Polymers 0.000 description 16
- 235000015205 orange juice Nutrition 0.000 description 16
- 238000005192 partition Methods 0.000 description 15
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 14
- 230000008569 process Effects 0.000 description 14
- 230000009467 reduction Effects 0.000 description 14
- 229920004482 WACKER® Polymers 0.000 description 13
- HFHDHCJBZVLPGP-RWMJIURBSA-N alpha-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO HFHDHCJBZVLPGP-RWMJIURBSA-N 0.000 description 13
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 description 12
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 description 12
- 229920001450 Alpha-Cyclodextrin Polymers 0.000 description 11
- 239000005977 Ethylene Substances 0.000 description 11
- 238000010521 absorption reaction Methods 0.000 description 11
- 229940043377 alpha-cyclodextrin Drugs 0.000 description 11
- 239000007789 gas Substances 0.000 description 11
- 239000000178 monomer Substances 0.000 description 11
- 230000002829 reductive effect Effects 0.000 description 11
- 238000007789 sealing Methods 0.000 description 11
- 230000003068 static effect Effects 0.000 description 11
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 10
- JARKCYVAAOWBJS-UHFFFAOYSA-N hexanal Chemical compound CCCCCC=O JARKCYVAAOWBJS-UHFFFAOYSA-N 0.000 description 10
- 230000008823 permeabilization Effects 0.000 description 10
- 239000004698 Polyethylene Substances 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000004458 analytical method Methods 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 8
- 150000001336 alkenes Chemical class 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 8
- 238000003987 high-resolution gas chromatography Methods 0.000 description 8
- 238000000465 moulding Methods 0.000 description 8
- GYHFUZHODSMOHU-UHFFFAOYSA-N nonanal Chemical compound CCCCCCCCC=O GYHFUZHODSMOHU-UHFFFAOYSA-N 0.000 description 8
- 230000002940 repellent Effects 0.000 description 8
- 239000005871 repellent Substances 0.000 description 8
- 239000003039 volatile agent Substances 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- 229940097362 cyclodextrins Drugs 0.000 description 7
- 125000000524 functional group Chemical group 0.000 description 7
- 239000011521 glass Substances 0.000 description 7
- 235000001510 limonene Nutrition 0.000 description 7
- 229940087305 limonene Drugs 0.000 description 7
- 238000011068 loading method Methods 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 229920001155 polypropylene Polymers 0.000 description 7
- 238000002470 solid-phase micro-extraction Methods 0.000 description 7
- 238000003860 storage Methods 0.000 description 7
- YOMSJEATGXXYPX-UHFFFAOYSA-N 2-methoxy-4-vinylphenol Chemical compound COC1=CC(C=C)=CC=C1O YOMSJEATGXXYPX-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- FXHGMKSSBGDXIY-UHFFFAOYSA-N heptanal Chemical compound CCCCCCC=O FXHGMKSSBGDXIY-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000012528 membrane Substances 0.000 description 6
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- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 6
- 238000011144 upstream manufacturing Methods 0.000 description 6
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- WTEVQBCEXWBHNA-YFHOEESVSA-N citral B Natural products CC(C)=CCC\C(C)=C/C=O WTEVQBCEXWBHNA-YFHOEESVSA-N 0.000 description 5
- 238000001514 detection method Methods 0.000 description 5
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- 230000001105 regulatory effect Effects 0.000 description 5
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- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
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- 150000002632 lipids Chemical class 0.000 description 4
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- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 150000002924 oxiranes Chemical class 0.000 description 4
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- CLYZNABPUKUSDX-UHFFFAOYSA-N trichloromethoxybenzene Chemical compound ClC(Cl)(Cl)OC1=CC=CC=C1 CLYZNABPUKUSDX-UHFFFAOYSA-N 0.000 description 4
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 3
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- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
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- Y10T428/2852—Adhesive compositions
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/3188—Next to cellulosic
- Y10T428/31895—Paper or wood
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/3188—Next to cellulosic
- Y10T428/31895—Paper or wood
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- General Health & Medical Sciences (AREA)
- Wrappers (AREA)
- Laminated Bodies (AREA)
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- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
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| US43252302P | 2002-12-10 | 2002-12-10 | |
| US10/672,297 US7166671B2 (en) | 2002-12-10 | 2003-09-25 | Grafted cyclodextrin |
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| MXPA03011425A true MXPA03011425A (es) | 2005-06-03 |
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| CA (1) | CA2452293C (enExample) |
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2003
- 2003-09-25 US US10/672,297 patent/US7166671B2/en not_active Expired - Lifetime
- 2003-11-27 JP JP2003397846A patent/JP4970706B2/ja not_active Expired - Fee Related
- 2003-12-05 CA CA2452293A patent/CA2452293C/en not_active Expired - Lifetime
- 2003-12-10 KR KR1020030089771A patent/KR101120203B1/ko not_active Expired - Lifetime
- 2003-12-10 CN CNB2003101249634A patent/CN1314746C/zh not_active Expired - Lifetime
- 2003-12-10 MX MXPA03011425A patent/MXPA03011425A/es active IP Right Grant
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2006
- 2006-04-13 US US11/403,457 patent/US8501308B2/en not_active Expired - Fee Related
- 2006-04-13 US US11/403,446 patent/US7365123B2/en not_active Expired - Lifetime
- 2006-04-13 US US11/403,480 patent/US7795333B2/en not_active Expired - Lifetime
- 2006-05-05 US US11/429,579 patent/US7605199B2/en not_active Expired - Lifetime
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Also Published As
| Publication number | Publication date |
|---|---|
| US20060183856A1 (en) | 2006-08-17 |
| US7166671B2 (en) | 2007-01-23 |
| US20060183857A1 (en) | 2006-08-17 |
| US20040110901A1 (en) | 2004-06-10 |
| US20080032110A1 (en) | 2008-02-07 |
| US7605199B2 (en) | 2009-10-20 |
| CN1314746C (zh) | 2007-05-09 |
| CN1609138A (zh) | 2005-04-27 |
| US7365123B2 (en) | 2008-04-29 |
| US7795333B2 (en) | 2010-09-14 |
| CA2452293A1 (en) | 2004-06-10 |
| HK1075059A1 (en) | 2005-12-02 |
| JP2004197084A (ja) | 2004-07-15 |
| US20060182917A1 (en) | 2006-08-17 |
| KR20040050886A (ko) | 2004-06-17 |
| KR101120203B1 (ko) | 2012-03-23 |
| US8501308B2 (en) | 2013-08-06 |
| US8334343B2 (en) | 2012-12-18 |
| CA2452293C (en) | 2013-04-09 |
| US20060205873A1 (en) | 2006-09-14 |
| JP4970706B2 (ja) | 2012-07-11 |
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