MX9702285A - Proceso para preparar 1,3-alcanodioles y 3-hidroxialdehidos. - Google Patents

Proceso para preparar 1,3-alcanodioles y 3-hidroxialdehidos.

Info

Publication number
MX9702285A
MX9702285A MX9702285A MX9702285A MX9702285A MX 9702285 A MX9702285 A MX 9702285A MX 9702285 A MX9702285 A MX 9702285A MX 9702285 A MX9702285 A MX 9702285A MX 9702285 A MX9702285 A MX 9702285A
Authority
MX
Mexico
Prior art keywords
hydroxyaldehydes
alkanediols
preparing
oxirane
percent based
Prior art date
Application number
MX9702285A
Other languages
English (en)
Other versions
MXPA97002285A (es
Inventor
Kevin Dale Allen
Juan Pedro Arhancet
David Cleve Eubanks
Howard Lam-Ho Fong
Thomas Clayton Forschner
David William Johnson
Jiang Jen Lin
Stephen Blake Mullin
Joseph Broun Powell
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/316,680 external-priority patent/US5563302A/en
Priority claimed from US08/316,677 external-priority patent/US5463146A/en
Priority claimed from US08/316,660 external-priority patent/US5585528A/en
Priority claimed from US08/316,669 external-priority patent/US5576471A/en
Priority claimed from US08/316,679 external-priority patent/US5545767A/en
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of MXPA97002285A publication Critical patent/MXPA97002285A/es
Publication of MX9702285A publication Critical patent/MX9702285A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C07C45/57—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom
    • C07C45/58—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom in three-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/80—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C07C47/19—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen containing hydroxy groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Steroid Compounds (AREA)

Abstract

Se describe un proceso para preparar 1,3-alcanodioles y 3-hidroxialdehídos por hidroformilacion de un oxirano con monoxido de carbono e hidrogeno en presencia de uno o más catalizadores de hidroformilacion basados en metal del grupo VIII, el cual puede contener hasta 50 moles % en base del metal del catalizador modificado con fosfina, en el que la concentracion del oxirano al inicio de la reaccion es menor de 15% en peso, basado en el peso de la mezcla de reaccion líquida total. El proceso permite la produccion de 1,3-propanodiol en rendimientos y selectividad elevados.
MX9702285A 1994-09-30 1995-09-28 Proceso para preparar 1,3-alcanodioles y 3-hidroxialdehidos. MX9702285A (es)

Applications Claiming Priority (16)

Application Number Priority Date Filing Date Title
US316677 1994-09-30
US08/316,680 US5563302A (en) 1994-09-30 1994-09-30 Cobalt-catalyzed process for preparing 1,3-propanediol using a lipophilic phosphine oxide promoter
US316,677 1994-09-30
US08/316,677 US5463146A (en) 1994-09-30 1994-09-30 Process for preparing 1,3-propanediol
US08/316,660 US5585528A (en) 1994-09-30 1994-09-30 Cobalt-catalyzed process for preparing 1,3-propanediol using a lipophilic tertiary amine promoter
US316679 1994-09-30
US316,660 1994-09-30
US08/316,669 US5576471A (en) 1994-09-30 1994-09-30 Cobalt-catalyzed process for preparing 1,3-propanediol using a lipophilic dihydroxyarene promoter
US316660 1994-09-30
US316680 1994-09-30
US316669 1994-09-30
US316,669 1994-09-30
US08/316,679 US5545767A (en) 1994-09-30 1994-09-30 Process for preparing 1,3-propanediol
US316,680 1994-09-30
US316,679 1994-09-30
PCT/EP1995/003870 WO1996010552A1 (en) 1994-09-30 1995-09-28 Process for preparing 1,3-alkanediols and 3-hydroxyaldehydes

Publications (2)

Publication Number Publication Date
MXPA97002285A MXPA97002285A (es) 1997-06-01
MX9702285A true MX9702285A (es) 1997-06-28

Family

ID=27541008

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9702285A MX9702285A (es) 1994-09-30 1995-09-28 Proceso para preparar 1,3-alcanodioles y 3-hidroxialdehidos.

Country Status (23)

Country Link
EP (1) EP0783476B1 (es)
JP (1) JP3850439B2 (es)
KR (1) KR100361109B1 (es)
CN (1) CN1074405C (es)
AT (1) ATE174320T1 (es)
AU (1) AU694573B2 (es)
BR (1) BR9509110A (es)
CZ (1) CZ290721B6 (es)
DE (1) DE69506574T2 (es)
DK (1) DK0783476T3 (es)
ES (1) ES2126937T3 (es)
FI (1) FI971268A0 (es)
HU (1) HUT77464A (es)
MX (1) MX9702285A (es)
MY (1) MY113319A (es)
NO (1) NO307562B1 (es)
NZ (1) NZ294599A (es)
PL (1) PL181023B1 (es)
RU (1) RU2142934C1 (es)
SK (1) SK281565B6 (es)
TR (1) TR199501189A2 (es)
TW (1) TW415935B (es)
WO (1) WO1996010552A1 (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CZ289381B6 (cs) * 1994-09-30 2002-01-16 Shell Internationale Research Maatschappij B. V. Způsob přípravy 1,3-alkandiolů a 3-hydroxyaldehydů
KR100396940B1 (ko) * 1994-09-30 2004-02-11 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 1,3-알칸디올및3-히드록시알데히드의제조방법
US5786524A (en) * 1996-05-30 1998-07-28 Shell Oil Company Process for preparation of 1,3-propanediol via hydrogenation of 3-hydroxypropanal
AU719470B2 (en) * 1996-05-30 2000-05-11 Shell Internationale Research Maatschappij B.V. Process for preparing 1,3-alkanediols
DE19852104A1 (de) 1998-11-12 2000-05-18 Degussa Verfahren zur Herstellung von ß-Hydroxyaldehyden
US6586643B2 (en) * 2001-05-18 2003-07-01 Shell Oil Company One-step production of 1,3-propanediol from ethylene oxide and syngas with a catalyst with a N-heterocyclic ligand
TW592819B (en) * 2001-05-18 2004-06-21 Kevin Dale Allen One-step production of 1,3-propanediol from ethylene oxide and syngas with a cobalt-iron catalyst
CN1310864C (zh) * 2004-04-29 2007-04-18 中国石油化工股份有限公司 制备3－羟基丙醛和1，3－丙二醇的方法
CN102826970B (zh) * 2011-06-17 2015-08-19 中国石油化工股份有限公司 一种低碳烯烃氢甲酰化二段反应方法和装置
CN105585436B (zh) * 2014-10-24 2017-11-17 中国石油化工股份有限公司 醋酸乙烯合成1,3‑丙二醇的方法
CN105585441B (zh) * 2014-10-24 2018-02-13 中国石油化工股份有限公司 用于生产1,3‑丙二醇的方法
CN105585435B (zh) * 2014-10-24 2018-02-13 中国石油化工股份有限公司 生产1,3‑丙二醇的方法
CN105585444B (zh) * 2014-10-24 2017-12-15 中国石油化工股份有限公司 1,3‑丙二醇的生产方法
CN105585442B (zh) * 2014-10-24 2017-11-21 中国石油化工股份有限公司 用于1,3‑丙二醇合成的方法
CN108017510B (zh) * 2016-11-03 2021-02-02 万华化学集团股份有限公司 一种羟基特戊醛的制备方法，及其在新戊二醇制备方面的应用
JP2019001746A (ja) * 2017-06-15 2019-01-10 株式会社クラレ ジオールの製造方法
CN111344273B (zh) * 2017-11-15 2023-08-18 三菱化学株式会社 醛制造方法及醇制造方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3456017A (en) * 1965-10-21 1969-07-15 Shell Oil Co Glycol production
US4973741A (en) * 1989-06-29 1990-11-27 Eastman Kodak Company Difunctional products from ethylene oxide and synthesis gas
CN1045202C (zh) * 1993-02-05 1999-09-22 国际壳牌研究有限公司 1,3-二醇及3-羟基醛的制备方法
KR100396940B1 (ko) * 1994-09-30 2004-02-11 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 1,3-알칸디올및3-히드록시알데히드의제조방법
CZ289381B6 (cs) * 1994-09-30 2002-01-16 Shell Internationale Research Maatschappij B. V. Způsob přípravy 1,3-alkandiolů a 3-hydroxyaldehydů

Also Published As

Publication number Publication date
DK0783476T3 (da) 1999-08-16
KR970706226A (ko) 1997-11-03
EP0783476A1 (en) 1997-07-16
ES2126937T3 (es) 1999-04-01
CN1158603A (zh) 1997-09-03
PL181023B1 (pl) 2001-05-31
NO307562B1 (no) 2000-04-25
SK38897A3 (en) 1997-11-05
BR9509110A (pt) 1998-07-14
NO971421L (no) 1997-03-25
ATE174320T1 (de) 1998-12-15
CN1074405C (zh) 2001-11-07
MY113319A (en) 2002-01-31
KR100361109B1 (ko) 2003-03-06
RU2142934C1 (ru) 1999-12-20
AU3744595A (en) 1996-04-26
AU694573B2 (en) 1998-07-23
SK281565B6 (sk) 2001-05-10
WO1996010552A1 (en) 1996-04-11
CZ94497A3 (cs) 1998-02-18
FI971268A (fi) 1997-03-26
NO971421D0 (no) 1997-03-25
TW415935B (en) 2000-12-21
FI971268A0 (fi) 1997-03-26
CZ290721B6 (cs) 2002-10-16
DE69506574D1 (de) 1999-01-21
DE69506574T2 (de) 1999-06-17
JPH10507747A (ja) 1998-07-28
TR199501189A2 (tr) 1996-06-21
HUT77464A (hu) 1998-05-28
EP0783476B1 (en) 1998-12-09
NZ294599A (en) 1998-12-23
JP3850439B2 (ja) 2006-11-29
PL319439A1 (en) 1997-08-04

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MM Annulment or lapse due to non-payment of fees