MX9601040A - Catalizadores y procedimientos para la polimerizacion de olefinas. - Google Patents
Catalizadores y procedimientos para la polimerizacion de olefinas.Info
- Publication number
- MX9601040A MX9601040A MX9601040A MX9601040A MX9601040A MX 9601040 A MX9601040 A MX 9601040A MX 9601040 A MX9601040 A MX 9601040A MX 9601040 A MX9601040 A MX 9601040A MX 9601040 A MX9601040 A MX 9601040A
- Authority
- MX
- Mexico
- Prior art keywords
- alkenyl
- carbon atoms
- alkyl
- different
- catalysts
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 5
- 125000000217 alkyl group Chemical group 0.000 abstract 5
- 125000004432 carbon atom Chemical group C* 0.000 abstract 5
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 4
- 229910052782 aluminium Inorganic materials 0.000 abstract 3
- -1 cyclopentadienyl compound Chemical class 0.000 abstract 3
- 125000003118 aryl group Chemical group 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Se describen catalizadores para la polimerizacion de olefinas, que comprenden el producto de reaccion de: (A) un compuesto de ciclopentadienilo que forma puente y/o substituido de titanio, circonio o hafnio; (B) un compuesto de aluminio organometálico de la formula (II) A1 (CH-2C4R5R6)wR7yHz, en donde en los grupos (CH-2C4R5R&), que son los mismos o diferentes, R4 es un grupo alquilo, alquenilo o arilalquilo que tiene de 1 a 10 átomos de carbono, R5 es un grupo alquilo, alquenilo, arilo o alquilarilo que tiene de 3 a 50 átomos de carbono que es diferente de un grupo alquilo o alquenilo de cadena recta y, opcionalmente, R4 y R5 fusionados entre si pueden formar un anillo de 4 a 6 átomos de carbono, R6 es hidrogeno o un grupo alquilo, alquenilo o arilalquilo que tiene de 1 a 10 átomos de carbono, los substituyentes R7, los mismos o diferentes, son radicales alquilo, alquenilo, arilo, arilalquilo o alquilarilo que contienen de 1 a 10átomos de carbono y, opcionalmente, pueden contener átomos de Si o Ge, w es 1, 2 o 3, z es 0 o 1, y = 3-w-z; y (C) agua. La relacion molar de aluminio/agua comprende entre 1:1 y 100:1. Estos catalizadores muestran una actividad mejorada con respecto a catalizadores conocidos en donde se usa un compuesto de aluminio diferente de los de la formula anterior.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI941516A IT1273661B (it) | 1994-07-20 | 1994-07-20 | Catalizzatori per la polimerizzazione delle olefine |
PCT/EP1995/002813 WO1996002580A1 (en) | 1994-07-20 | 1995-07-18 | Catalysts and processes for the polymerization of olefins |
Publications (1)
Publication Number | Publication Date |
---|---|
MX9601040A true MX9601040A (es) | 1997-06-28 |
Family
ID=11369317
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX9601040A MX9601040A (es) | 1994-07-20 | 1995-07-18 | Catalizadores y procedimientos para la polimerizacion de olefinas. |
Country Status (25)
Country | Link |
---|---|
US (2) | US5849653A (es) |
EP (1) | EP0720627B1 (es) |
JP (1) | JP3714678B2 (es) |
KR (1) | KR100356549B1 (es) |
CN (1) | CN1113899C (es) |
AT (1) | ATE163653T1 (es) |
AU (1) | AU695214B2 (es) |
BG (1) | BG100514A (es) |
BR (1) | BR9506295A (es) |
CA (1) | CA2171834A1 (es) |
CZ (1) | CZ112796A3 (es) |
DE (1) | DE69501720T2 (es) |
ES (1) | ES2115391T3 (es) |
FI (1) | FI961269A (es) |
HU (1) | HU215264B (es) |
IL (1) | IL114659A (es) |
IT (1) | IT1273661B (es) |
MX (1) | MX9601040A (es) |
NO (1) | NO308904B1 (es) |
PL (1) | PL313588A1 (es) |
RU (1) | RU2155774C2 (es) |
SK (1) | SK49496A3 (es) |
TR (1) | TR199500876A2 (es) |
WO (1) | WO1996002580A1 (es) |
ZA (1) | ZA955988B (es) |
Families Citing this family (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1276752B1 (it) | 1995-06-20 | 1997-11-03 | Spherilene S P A Ora Montell I | Catalizzatori e procedimenti per la polimerizzazione di olefine |
IT1277696B1 (it) * | 1995-12-22 | 1997-11-11 | Enichem Spa | Catalizzatori per la polimerizzazione di alfa-olefine |
JPH10101727A (ja) * | 1996-09-24 | 1998-04-21 | Shell Internatl Res Maatschappij Bv | オレフィン又はポリマーを水素化するための触媒及び方法 |
EP0835886B1 (en) * | 1996-10-09 | 2004-02-25 | ATOFINA Research | Process for preparing and using meso/racemic-(bis(indenyl)ethane)zirconium dichloride compounds |
US6559252B1 (en) | 1997-10-29 | 2003-05-06 | Basell Technology Company Bv | Catalysts and processes for the polymerization of olefins |
AU1335899A (en) * | 1997-10-29 | 1999-05-17 | Montell Technology Company B.V. | Catalysts for the polymerization of olefins and process for the preparation thereof |
US6015766A (en) * | 1997-12-18 | 2000-01-18 | Mobil Oil Corporation | Catalyst systems for olefin polymerization based on metallocene complexes and oligoalkylaluminates with sterically hindered alkyl groups as cocatalysts |
US6001766A (en) * | 1997-12-24 | 1999-12-14 | Mobil Oil Corporation | Bimetallic catalysts for ethylene polymerization reactions activated with paraffin-soluble alkylalumoxanes |
DE69907785T2 (de) | 1998-03-09 | 2004-02-12 | Basell Poliolefine Italia S.P.A. | Mehrstufiges Verfahren zur Olefinpolymerisation |
AU751049B2 (en) | 1998-04-15 | 2002-08-08 | Shell Internationale Research Maatschappij B.V. | Catalyst system for alpha-olefin oligomerization |
EP0953582A1 (en) * | 1998-04-27 | 1999-11-03 | Fina Research S.A. | Polyolefin production |
US6555494B2 (en) | 1998-10-23 | 2003-04-29 | Albemarle Corporation | Transition metal compounds having conjugate aluminoxate anions, their preparation and their use as catalyst components |
US6812182B2 (en) | 1998-10-23 | 2004-11-02 | Albemarle Corporation | Compositions formed from hydroxyaluminoxane and their use as catalyst components |
US6492292B2 (en) | 1998-10-23 | 2002-12-10 | Albemarle Corporation | Gelatinous compositions formed from hydroxyaluminoxane, solid compositions formed therefrom, and the use of such compositions as catalyst components |
US6160145A (en) * | 1998-10-23 | 2000-12-12 | Albemarle Corporation | Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components |
US6462212B1 (en) | 1998-10-23 | 2002-10-08 | Albemarle Corporation | Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components |
ATE495202T1 (de) * | 1998-10-27 | 2011-01-15 | Westlake Longview Corp | Verfahren zur olefinpolymerisation, polyethylene und daraus hergestellte folien und artikel |
JP2002530285A (ja) | 1998-11-18 | 2002-09-17 | バセル テクノロジー カンパニー ビー.ブイ. | オレフィン−重合−触媒成分としてのメチレン橋架けメタロセン |
US6395668B1 (en) | 1998-12-15 | 2002-05-28 | Basell Technology Company Bv | Catalyst system for olefin polymerization |
WO2000053646A1 (en) | 1999-03-09 | 2000-09-14 | Basell Technology Company B.V. | Multi-stage process for the (co)polymerization of olefins |
US6774253B1 (en) | 1999-06-04 | 2004-08-10 | Basell Polyolefine Gmbh | Process for the preparation of titanium complexes |
WO2000075147A1 (en) | 1999-06-07 | 2000-12-14 | Basell Technology Company B.V. | Preparation of transition-metal-alkyl-complexes carrying a bidentate, dianionic ligand |
US6420298B1 (en) | 1999-08-31 | 2002-07-16 | Exxonmobil Oil Corporation | Metallocene catalyst compositions, processes for making polyolefin resins using such catalyst compositions, and products produced thereby |
CN1374973A (zh) * | 1999-09-22 | 2002-10-16 | 巴塞尔技术有限公司 | 用于烯烃聚合的催化剂体系及方法 |
ATE292148T1 (de) | 2000-01-18 | 2005-04-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von im wesentlichen amorphen polymeren auf propylen-basis |
WO2001090205A1 (en) | 2000-05-24 | 2001-11-29 | Basell Technology Company B.V. | Propylene polymers and process for the preparation thereof |
US6673869B2 (en) | 2000-07-27 | 2004-01-06 | Basell Poliolefine Italia S.P.A. | Transparent elastomeric thermoplastic polyolefin compositions |
DE60135502D1 (de) | 2000-09-25 | 2008-10-02 | Basell Polyolefine Gmbh | Verfahren zur herstellung von ethylenpolymeren mit einer bis-amid-titanverbindung |
US6703458B2 (en) | 2000-12-22 | 2004-03-09 | Basell Polyolefine Gmbh | Catalyst components for the polymerization of olefins |
JP4667743B2 (ja) * | 2001-06-20 | 2011-04-13 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | オリゴマーの調製方法 |
JP3964867B2 (ja) * | 2001-08-07 | 2007-08-22 | 電気化学工業株式会社 | 重合体の製造方法 |
KR20030087670A (ko) * | 2002-05-09 | 2003-11-15 | (주)다사테크 | 회전기계의 비접촉식 전원공급장치 |
JP2004149761A (ja) * | 2002-09-02 | 2004-05-27 | Sumitomo Chem Co Ltd | エチレン重合体 |
TWI555574B (zh) | 2011-03-09 | 2016-11-01 | 亞比馬利股份有限公司 | 含有碳陽離子劑之鋁氧烷催化活性劑及其於聚烯烴催化劑中之用途 |
RU2510646C2 (ru) * | 2012-06-26 | 2014-04-10 | Дэлим Индастриал Ко, Лтд. | Металлоценовое соединение, включающая его композиция катализатора и использующий его способ полимеризации олефина |
KR102165484B1 (ko) * | 2018-05-10 | 2020-10-14 | 한화솔루션 주식회사 | 올레핀 중합 촉매용 전이금속 화합물 및 이를 포함하는 올레핀 중합 촉매 |
KR20220049731A (ko) | 2020-10-15 | 2022-04-22 | 에스케이이노베이션 주식회사 | 폴리프로필렌의 제조방법 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2608933A1 (de) * | 1976-03-04 | 1977-09-08 | Basf Ag | Verfahren zum herstellen von polyaethylen |
DE2608863A1 (de) * | 1976-03-04 | 1977-09-08 | Basf Ag | Verfahren zum herstellen von polyaethylen |
DE3127133A1 (de) * | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polyolefinen und deren copolymerisaten |
DE3424697C2 (de) * | 1984-07-05 | 1999-07-08 | Targor Gmbh | Verfahren zur Polymerisation von Ethylen oder von Mischungen von Ethylen mit anderen 1-Olefinen |
MY103812A (en) * | 1988-02-12 | 1993-09-30 | Mitsui Chemicals Inc | Olefin polymerization catalyst and process for the polymerization of olefins. |
US5008228A (en) * | 1988-03-29 | 1991-04-16 | Exxon Chemical Patents Inc. | Method for preparing a silica gel supported metallocene-alumoxane catalyst |
US5321107A (en) * | 1989-01-31 | 1994-06-14 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst and process for the polymerization of olefins |
IT1237398B (it) * | 1989-01-31 | 1993-06-01 | Ausimont Srl | Catalizzatori per la polimerizzazione di olefine. |
DE3922546A1 (de) * | 1989-07-08 | 1991-01-17 | Hoechst Ag | Verfahren zur herstellung von cycloolefinpolymeren |
EP0501370B1 (de) * | 1991-02-27 | 1998-11-25 | Ticona GmbH | Verfahren zur Herstellung von Cycloolefin(co)polymeren mit enger Molekulargewichtsverteilung |
DE4205932A1 (de) * | 1992-02-27 | 1993-09-02 | Basf Ag | Verfahren zur herstellung von propenoligomeren |
EP0575875B1 (en) * | 1992-06-18 | 2000-08-09 | Montell Technology Company bv | Catalysts for the polymerization of olefins |
IT1264680B1 (it) * | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori supportati per la polimerizzazione delle olefine |
-
1994
- 1994-07-20 IT ITMI941516A patent/IT1273661B/it active IP Right Grant
-
1995
- 1995-07-18 CN CN95190907A patent/CN1113899C/zh not_active Expired - Fee Related
- 1995-07-18 AT AT95926926T patent/ATE163653T1/de not_active IP Right Cessation
- 1995-07-18 CZ CZ961127A patent/CZ112796A3/cs unknown
- 1995-07-18 BR BR9506295A patent/BR9506295A/pt not_active IP Right Cessation
- 1995-07-18 JP JP50470996A patent/JP3714678B2/ja not_active Expired - Fee Related
- 1995-07-18 AU AU31135/95A patent/AU695214B2/en not_active Ceased
- 1995-07-18 RU RU96108407/04A patent/RU2155774C2/ru active
- 1995-07-18 MX MX9601040A patent/MX9601040A/es not_active IP Right Cessation
- 1995-07-18 SK SK494-96A patent/SK49496A3/sk unknown
- 1995-07-18 CA CA002171834A patent/CA2171834A1/en not_active Abandoned
- 1995-07-18 ES ES95926926T patent/ES2115391T3/es not_active Expired - Lifetime
- 1995-07-18 DE DE69501720T patent/DE69501720T2/de not_active Expired - Fee Related
- 1995-07-18 WO PCT/EP1995/002813 patent/WO1996002580A1/en not_active Application Discontinuation
- 1995-07-18 PL PL95313588A patent/PL313588A1/xx unknown
- 1995-07-18 ZA ZA955988A patent/ZA955988B/xx unknown
- 1995-07-18 EP EP95926926A patent/EP0720627B1/en not_active Expired - Lifetime
- 1995-07-18 KR KR1019960701425A patent/KR100356549B1/ko not_active IP Right Cessation
- 1995-07-18 HU HU9601038A patent/HU215264B/hu not_active IP Right Cessation
- 1995-07-19 US US08/503,948 patent/US5849653A/en not_active Expired - Fee Related
- 1995-07-19 IL IL11465995A patent/IL114659A/xx not_active IP Right Cessation
- 1995-07-20 TR TR95/00876A patent/TR199500876A2/xx unknown
-
1996
- 1996-03-19 FI FI961269A patent/FI961269A/fi unknown
- 1996-03-19 NO NO961109A patent/NO308904B1/no not_active IP Right Cessation
- 1996-04-18 BG BG100514A patent/BG100514A/xx unknown
-
1998
- 1998-10-21 US US09/176,188 patent/US6136932A/en not_active Expired - Fee Related
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