MX369419B - Proceso de oxidación para la producción de tiosulfato de potasio. - Google Patents
Proceso de oxidación para la producción de tiosulfato de potasio.Info
- Publication number
- MX369419B MX369419B MX2018008053A MX2018008053A MX369419B MX 369419 B MX369419 B MX 369419B MX 2018008053 A MX2018008053 A MX 2018008053A MX 2018008053 A MX2018008053 A MX 2018008053A MX 369419 B MX369419 B MX 369419B
- Authority
- MX
- Mexico
- Prior art keywords
- potassium
- temperature
- conditions
- potassium thiosulfate
- thiosulfate
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 5
- FGRVOLIFQGXPCT-UHFFFAOYSA-L dipotassium;dioxido-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound [K+].[K+].[O-]S([O-])(=O)=S FGRVOLIFQGXPCT-UHFFFAOYSA-L 0.000 title abstract 4
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000011591 potassium Substances 0.000 abstract 2
- 229910052700 potassium Inorganic materials 0.000 abstract 2
- 239000000047 product Substances 0.000 abstract 2
- 238000010923 batch production Methods 0.000 abstract 1
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 230000001419 dependent effect Effects 0.000 abstract 1
- 239000003337 fertilizer Substances 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000005457 optimization Methods 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 229920001021 polysulfide Polymers 0.000 abstract 1
- 239000005077 polysulfide Substances 0.000 abstract 1
- 150000008117 polysulfides Polymers 0.000 abstract 1
- 229940016373 potassium polysulfide Drugs 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/64—Thiosulfates; Dithionites; Polythionates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/22—Alkali metal sulfides or polysulfides
- C01B17/34—Polysulfides of sodium or potassium
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D1/00—Fertilisers containing potassium
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/23—Solutions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fertilizers (AREA)
Abstract
Se describe un proceso eficiente para la preparación de tiosulfato de potasio (K2S2O3). El hidróxido de potasio (KOH) y el azufre elemental (S) se convierten en polisulfuro de potasio, que se oxida posteriormente. El proceso permite el uso de condiciones de proceso específicamente diseñadas tales como relaciones molares de hidróxido de potasio a azufre, y temperatura, para obtener una formulación optimizada del polisulfuro deseado, y un conjunto específicamente diseñado de condiciones tales como la temperatura, la presión, el índice y la duración del oxidante durante las condiciones de oxidación, a fin de obtener una concentración relativamente alta de producto de tiosulfato de potasio soluble con alta pureza, con cantidades relativamente bajas de subproductos. El proceso de elaboración puede ser un proceso en lotes o un proceso continuo que utiliza reactores de tanque agitado continuo (CSTR). El proceso CSTR depende de varios parámetros de diseño, que incluyen la presión y la optimización de la temperatura para evitar la inestabilidad del producto. El tiosulfato de potasio resultante es un fertilizante beneficioso con alto contenido de potasio como una fuente líquida al 50% de potasio.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562273385P | 2015-12-30 | 2015-12-30 | |
| US15/380,838 US9988270B2 (en) | 2015-12-30 | 2016-12-15 | Oxidation process for producing potassium thiosulfate |
| PCT/US2016/067336 WO2017116775A1 (en) | 2015-12-30 | 2016-12-16 | Oxidation process for producing potassium thiosulfate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2018008053A MX2018008053A (es) | 2018-11-29 |
| MX369419B true MX369419B (es) | 2019-11-07 |
Family
ID=59225254
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2018008053A MX369419B (es) | 2015-12-30 | 2016-12-16 | Proceso de oxidación para la producción de tiosulfato de potasio. |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US9988270B2 (es) |
| EP (1) | EP3397602B1 (es) |
| KR (1) | KR102228574B1 (es) |
| CN (2) | CN117945356A (es) |
| AU (1) | AU2016382882B2 (es) |
| BR (1) | BR112018013556B1 (es) |
| CA (1) | CA3007488C (es) |
| CL (1) | CL2018001683A1 (es) |
| CO (1) | CO2018007611A2 (es) |
| EA (1) | EA038027B1 (es) |
| ES (1) | ES2874539T3 (es) |
| HU (1) | HUE054472T2 (es) |
| MX (1) | MX369419B (es) |
| PE (1) | PE20181148A1 (es) |
| PL (1) | PL3397602T3 (es) |
| UA (1) | UA122705C2 (es) |
| WO (1) | WO2017116775A1 (es) |
| ZA (1) | ZA201803454B (es) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20220396483A1 (en) | 2019-06-24 | 2022-12-15 | Tessenderlo Kerley, Inc. | Polysulfide Compositions and Processes for Making Same |
| EP4037809A4 (en) * | 2019-10-04 | 2023-08-02 | Conocophillips Company | ELEMENTARY SULFUR ANALYSIS IN LIQUIDS |
| EP3819282A1 (en) * | 2019-11-05 | 2021-05-12 | Tessenderlo Kerley, Inc. | Polysulfide compositions and processes for making same |
| CN111003692B (zh) * | 2019-12-13 | 2020-09-08 | 南京工业大学 | 一种二氧化硫资源化回用系统及方法 |
| CN111439759A (zh) * | 2020-05-23 | 2020-07-24 | 淄博长城化工厂 | 一种采用焦亚硫酸钾母液生产食品级亚硫酸钾的方法 |
| US11214489B1 (en) | 2020-11-28 | 2022-01-04 | Ceres Technology, LLC | Crossflow scrubbing method and apparatus to produce a product such as potassium thiosulfate or ammonium thiosulfate |
| CN112920216A (zh) * | 2021-02-02 | 2021-06-08 | 山东阳谷华泰化工股份有限公司 | 双-[3-(三乙氧基硅)-丙基]-二硫化物的制备方法 |
| CN112898333A (zh) * | 2021-02-02 | 2021-06-04 | 山东阳谷华泰化工股份有限公司 | 双-[3-(三乙氧基硅)-丙基]-四硫化物的制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5656673A (en) * | 1995-11-27 | 1997-08-12 | Niklor Chemical Co., Inc. | Method of reducing emissions from soils |
| US5944868A (en) * | 1998-01-28 | 1999-08-31 | Tessenderlo Kerley, Inc. | Production of liquid fertilizers by ion exchange |
| RU2167101C2 (ru) | 1999-07-05 | 2001-05-20 | Открытое акционерное общество "Институт Гипроникель" | Способ получения тиосульфатов |
| US6984368B2 (en) * | 2003-06-09 | 2006-01-10 | Tessenderlo Kerley, Inc. | Process for preparing calcium thiosulfate solution |
| US8034318B1 (en) * | 2010-04-21 | 2011-10-11 | Tessenderlo Kerley, Inc. | Process for preparation of calcium thiosulfate liquid solution from lime, sulfur, and sulfur dioxide |
| US8454929B2 (en) * | 2010-04-21 | 2013-06-04 | Tessenderlo Kerley, Inc. | Continuous process for preparation of calcium thiosulfate liquid solution |
| EP3129515B1 (en) | 2014-04-11 | 2023-01-25 | Tessenderlo Kerley, Inc. | Depression of copper and iron sulfides in molybdenite flotation circuits |
-
2016
- 2016-12-15 US US15/380,838 patent/US9988270B2/en active Active
- 2016-12-16 ES ES16882344T patent/ES2874539T3/es active Active
- 2016-12-16 PE PE2018001080A patent/PE20181148A1/es unknown
- 2016-12-16 BR BR112018013556-9A patent/BR112018013556B1/pt active IP Right Grant
- 2016-12-16 UA UAA201808259A patent/UA122705C2/uk unknown
- 2016-12-16 PL PL16882344T patent/PL3397602T3/pl unknown
- 2016-12-16 CN CN202410100155.6A patent/CN117945356A/zh active Pending
- 2016-12-16 KR KR1020187021554A patent/KR102228574B1/ko active IP Right Grant
- 2016-12-16 AU AU2016382882A patent/AU2016382882B2/en active Active
- 2016-12-16 WO PCT/US2016/067336 patent/WO2017116775A1/en active Application Filing
- 2016-12-16 MX MX2018008053A patent/MX369419B/es active IP Right Grant
- 2016-12-16 CN CN201680077453.1A patent/CN108473382A/zh active Pending
- 2016-12-16 CA CA3007488A patent/CA3007488C/en active Active
- 2016-12-16 EP EP16882344.1A patent/EP3397602B1/en active Active
- 2016-12-16 EA EA201891400A patent/EA038027B1/ru unknown
- 2016-12-16 HU HUE16882344A patent/HUE054472T2/hu unknown
-
2018
- 2018-05-24 ZA ZA2018/03454A patent/ZA201803454B/en unknown
- 2018-06-20 CL CL2018001683A patent/CL2018001683A1/es unknown
- 2018-07-23 CO CONC2018/0007611A patent/CO2018007611A2/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PE20181148A1 (es) | 2018-07-17 |
| CO2018007611A2 (es) | 2018-07-31 |
| CN108473382A (zh) | 2018-08-31 |
| ES2874539T3 (es) | 2021-11-05 |
| BR112018013556B1 (pt) | 2022-12-20 |
| EA038027B1 (ru) | 2021-06-24 |
| KR102228574B1 (ko) | 2021-03-16 |
| AU2016382882A1 (en) | 2018-06-21 |
| ZA201803454B (en) | 2020-08-26 |
| KR20180099778A (ko) | 2018-09-05 |
| AU2016382882B2 (en) | 2020-04-30 |
| EA201891400A1 (ru) | 2019-01-31 |
| BR112018013556A2 (pt) | 2018-12-04 |
| EP3397602A1 (en) | 2018-11-07 |
| EP3397602A4 (en) | 2019-09-04 |
| PL3397602T3 (pl) | 2021-10-04 |
| HUE054472T2 (hu) | 2021-09-28 |
| CL2018001683A1 (es) | 2018-09-21 |
| CN117945356A (zh) | 2024-04-30 |
| CA3007488A1 (en) | 2017-07-06 |
| UA122705C2 (uk) | 2020-12-28 |
| EP3397602B1 (en) | 2021-03-31 |
| WO2017116775A1 (en) | 2017-07-06 |
| MX2018008053A (es) | 2018-11-29 |
| CA3007488C (en) | 2020-06-16 |
| US9988270B2 (en) | 2018-06-05 |
| US20170190576A1 (en) | 2017-07-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |