MX367409B - Metodo para eliminar sox de un gas con polietilenglicol modificado. - Google Patents
Metodo para eliminar sox de un gas con polietilenglicol modificado.Info
- Publication number
- MX367409B MX367409B MX2016003062A MX2016003062A MX367409B MX 367409 B MX367409 B MX 367409B MX 2016003062 A MX2016003062 A MX 2016003062A MX 2016003062 A MX2016003062 A MX 2016003062A MX 367409 B MX367409 B MX 367409B
- Authority
- MX
- Mexico
- Prior art keywords
- polyethylene glycol
- gas
- modified polyethylene
- sox
- removing sox
- Prior art date
Links
- 239000002202 Polyethylene glycol Substances 0.000 title abstract 5
- 229920001223 polyethylene glycol Polymers 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- 125000002252 acyl group Chemical group 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000000304 alkynyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 238000006266 etherification reaction Methods 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1425—Regeneration of liquid absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1481—Removing sulfur dioxide or sulfur trioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/202—Alcohols or their derivatives
- B01D2252/2023—Glycols, diols or their derivatives
- B01D2252/2026—Polyethylene glycol, ethers or esters thereof, e.g. Selexol
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/302—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/48—Sulfur dioxide; Sulfurous acid
- C01B17/50—Preparation of sulfur dioxide
- C01B17/60—Isolation of sulfur dioxide from gases
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Abstract
Un método para eliminar SOx de un gas mediante el uso de una solución de polietilenglicol modificado para absorber el SOx en el gas. La solución de polietilenglicol modificado entra en contacto con el gas que contiene SOx para absorber el SOx que está en el gas, en donde x = 2 y/o 3, el polietilenglicol modificado es un producto obtenido de grupos hidroxilo eterificantes en las moléculas de etilenglicol y/o polietilenglicol y tiene una fórmula general: R1-(O-C2H4) n-O-R2, en donde n es un entero positivo, R1 y R2 son iguales o distintos y cada uno independientemente es alquilo, alquenilo, alquinilo, acilo o arilo.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310409296.8A CN103432890B (zh) | 2013-09-10 | 2013-09-10 | 改性聚乙二醇脱除气体中SOx的方法 |
| PCT/CN2014/085924 WO2015035878A1 (zh) | 2013-09-10 | 2014-09-04 | 改性聚乙二醇脱除气体中SOx的方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2016003062A MX2016003062A (es) | 2016-12-08 |
| MX367409B true MX367409B (es) | 2019-08-20 |
Family
ID=49686661
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2016003062A MX367409B (es) | 2013-09-10 | 2014-09-04 | Metodo para eliminar sox de un gas con polietilenglicol modificado. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US9795917B2 (es) |
| EP (1) | EP3045219B1 (es) |
| JP (1) | JP6480457B2 (es) |
| KR (1) | KR20160055207A (es) |
| CN (1) | CN103432890B (es) |
| AU (1) | AU2014320953B2 (es) |
| BR (1) | BR112016005239B1 (es) |
| CA (1) | CA2923777C (es) |
| EA (1) | EA201690562A1 (es) |
| ES (1) | ES2966852T3 (es) |
| MX (1) | MX367409B (es) |
| PL (1) | PL3045219T3 (es) |
| WO (1) | WO2015035878A1 (es) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103432890B (zh) * | 2013-09-10 | 2015-12-09 | 北京博源恒升高科技有限公司 | 改性聚乙二醇脱除气体中SOx的方法 |
| CN103611391B (zh) * | 2013-12-12 | 2016-01-20 | 北京博源恒升高科技有限公司 | 乙二醇类复合溶液脱除气体中SOx的方法 |
| CN103623689B (zh) * | 2013-12-12 | 2016-06-29 | 北京博源恒升高科技有限公司 | 多元醇复合溶液脱除气体中SOx的方法 |
| CN105214457B (zh) | 2014-06-05 | 2018-04-17 | 魏雄辉 | 一种烟道气脱硫脱硝工艺及设备 |
| CN106031844B (zh) * | 2015-03-20 | 2020-01-07 | 江西永丰博源实业有限公司 | 一种脱硫脱硝剂 |
| CN105797783A (zh) * | 2016-04-06 | 2016-07-27 | 山东成泰化工有限公司 | 一种低温原油催化剂及其制备方法 |
| CN109621640B (zh) * | 2018-12-28 | 2021-02-26 | 河北科技大学 | 一种用于吸收so2的负载型离子液体变色材料及其制备方法和应用 |
| CN110408423A (zh) * | 2019-08-09 | 2019-11-05 | 磁悬浮润滑油(苏州)有限公司 | 一种利用改性聚乙二醇脱除燃料油中硫化物的方法 |
| CN119490350B (zh) * | 2025-01-20 | 2025-04-01 | 浙江金琨西立锆珠有限公司 | 铈稳定氧化锆珠及其制备工艺 |
Family Cites Families (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2139375A (en) * | 1937-06-14 | 1938-12-06 | Shell Dev | Removal of so from gases |
| US3737392A (en) * | 1969-06-11 | 1973-06-05 | Allied Chem | Solvent composition useful in acid gas removal from gas mixtures |
| FR2213793B2 (es) * | 1972-09-22 | 1975-08-22 | Inst Francais Du Petrole | |
| DE2333708B2 (de) | 1973-07-03 | 1977-09-15 | Dsd Dillinger Stahlbau Gmbh, 6630 Saarlouis | Verfahren zum selektiven entfernen von schwefelwasserstoff aus kohlenwasserstoffhaltigen gasen |
| SU655410A1 (ru) | 1977-10-28 | 1979-04-05 | Всесоюзный научно-исследовательский институт природных газов | Абсорбент дл сушки и очистки углеводородных газов |
| SU927282A1 (ru) | 1979-04-25 | 1982-05-15 | Всесоюзный Научно-Исследовательский И Проектный Институт По Подготовке @К Транспортировке И Переработке Природного Газа | Абсорбент дл очистки газов от кислых компонентов |
| US4368178A (en) | 1981-05-26 | 1983-01-11 | Shell Oil Company | Process for the removal of H2 S and CO2 from gaseous streams |
| FR2532190A1 (fr) | 1982-08-25 | 1984-03-02 | Raffinage Cie Francaise | Dispositif pour l'elimination a froid de l'hydrogene sulfure contenu dans un melange gazeux, par reaction sur de l'anhydride sulfureux, et pour la separation du soufre solide ainsi produit |
| FR2532189A1 (fr) | 1982-08-25 | 1984-03-02 | Raffinage Cie Francaise | Procede d'elimination de l'hydrogene sulfure contenu dans un melange gazeux |
| DE3237387A1 (de) | 1982-10-08 | 1984-04-12 | Linde Ag, 6200 Wiesbaden | Verfahren zur entfernung unerwuenschter gasfoermiger bestandteile aus heissen rauchgasen |
| DE3239603A1 (de) * | 1982-10-26 | 1984-04-26 | Linde Ag, 6200 Wiesbaden | Verfahren zum gleichzeitigen entfernen von h(pfeil abwaerts)2(pfeil abwaerts)s, so(pfeil abwaerts)2(pfeil abwaerts) und elementarem schwefel aus gasgemischen |
| DE3428548A1 (de) * | 1984-08-02 | 1986-02-13 | Linde Ag, 6200 Wiesbaden | Verfahren zur erzeugung von elementarem schwefel |
| DE3501118A1 (de) | 1985-01-15 | 1986-07-17 | Linde Ag, 6200 Wiesbaden | Verfahren zur entfernung von so(pfeil abwaerts)2(pfeil abwaerts) und no(pfeil abwaerts)x(pfeil abwaerts) aus gasen |
| JPS6227021A (ja) * | 1985-07-25 | 1987-02-05 | Nippon Shokubai Kagaku Kogyo Co Ltd | 酸性ガス吸収剤 |
| DD249856A5 (de) * | 1985-09-27 | 1987-09-23 | Linde Ag,De | Verfahren zum auswaschen von no und/oder so tief 2 aus gasgemischen |
| DE3612123A1 (de) | 1985-09-27 | 1987-04-09 | Linde Ag | Verfahren zum auswaschen von no und/oder so(pfeil abwaerts)2(pfeil abwaerts) aus gasgemischen |
| JPS6295118A (ja) | 1985-10-21 | 1987-05-01 | Mitsubishi Heavy Ind Ltd | グリコ−ルを用いる脱水方法 |
| DE3624768A1 (de) | 1986-07-22 | 1988-01-28 | Linde Ag | Verfahren zur verhinderung der korrosion von apparateteilen |
| US4741890A (en) * | 1986-07-24 | 1988-05-03 | Betz Laboratories, Inc. | Gas scrubbing method |
| US5273679A (en) * | 1986-10-30 | 1993-12-28 | Toho Kagaku Kogyo Co., Ltd. | Stabilizers for compositions for acid gas absorbent |
| SU1611411A1 (ru) | 1988-06-21 | 1990-12-07 | Всесоюзный Научно-Исследовательский И Проектный Институт По Переработке Газа | Способ очистки углеводородного газа от кислых компонентов |
| AU619375B2 (en) | 1988-12-23 | 1992-01-23 | Baker Hughes Incorporated | Composition and method for sweetening hydrocarbons |
| JPH03238022A (ja) * | 1990-02-16 | 1991-10-23 | Nkk Corp | コークス炉ガスの脱硫方法 |
| CN1087110A (zh) | 1992-11-16 | 1994-05-25 | 魏雄辉 | 半水煤气脱硫脱氧新方法 |
| JPH06228573A (ja) | 1993-02-08 | 1994-08-16 | Hitachi Ltd | 石炭ガス化プラントのテールガス処理法 |
| JPH06279007A (ja) * | 1993-03-25 | 1994-10-04 | Sumitomo Seika Chem Co Ltd | 亜硫酸ガスの回収方法 |
| RU2070423C1 (ru) | 1993-09-14 | 1996-12-20 | Акционерное общество Миннибаевский газоперерабатывающий завод | Установка для комплексной очистки нефтяного и природного газов |
| CN1133817A (zh) | 1996-02-17 | 1996-10-23 | 魏雄辉 | 加压铁-碱溶液脱碳脱硫 |
| CN1092994C (zh) | 1999-02-05 | 2002-10-23 | 魏雄辉 | 铁-碱溶液催化法气体脱碳脱硫脱氰方法 |
| US6203599B1 (en) * | 1999-07-28 | 2001-03-20 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the removal of gas contaminants from a product gas using polyethylene glycols |
| DE10136484A1 (de) | 2001-07-27 | 2003-02-13 | Uhde Gmbh | Verfahren zur Entfernung von Gasbestandteilen aus technischen Gasen mittels Ethylenglykoldimethylethern bei tieferen Temperaturen |
| CN1162203C (zh) | 2001-09-26 | 2004-08-18 | 南化集团研究院 | 一种物理溶剂脱硫脱碳新技术 |
| CN1158133C (zh) | 2002-09-09 | 2004-07-21 | 魏雄辉 | 生化铁—碱溶液催化法气体脱硫方法 |
| CN100384510C (zh) * | 2003-12-09 | 2008-04-30 | 南化集团研究院 | 一种高压脱除硫化物和二氧化碳的方法 |
| CN101053746B (zh) * | 2007-06-06 | 2010-06-09 | 北京大学 | 乙二醇脱除烟道气中sox的方法 |
| CN101502741B (zh) * | 2009-02-16 | 2011-01-05 | 北京博源恒升高科技有限公司 | 聚乙二醇脱除气体中SOx的方法 |
| US8905742B2 (en) | 2010-09-17 | 2014-12-09 | Synerdyne Corporation | Compact rotary platen 3D printer |
| EP2696970A4 (en) * | 2011-04-11 | 2014-09-03 | Electrosep Technologies Inc | METHOD FOR PURIFYING ABSORBENTS COMPRISING DIMETHYL ETHERS OF POLYETHYLENE GLYCOL |
| CN103432890B (zh) * | 2013-09-10 | 2015-12-09 | 北京博源恒升高科技有限公司 | 改性聚乙二醇脱除气体中SOx的方法 |
| CN103623689B (zh) * | 2013-12-12 | 2016-06-29 | 北京博源恒升高科技有限公司 | 多元醇复合溶液脱除气体中SOx的方法 |
-
2013
- 2013-09-10 CN CN201310409296.8A patent/CN103432890B/zh active Active
-
2014
- 2014-09-04 WO PCT/CN2014/085924 patent/WO2015035878A1/zh not_active Ceased
- 2014-09-04 PL PL14843772.6T patent/PL3045219T3/pl unknown
- 2014-09-04 ES ES14843772T patent/ES2966852T3/es active Active
- 2014-09-04 EP EP14843772.6A patent/EP3045219B1/en active Active
- 2014-09-04 AU AU2014320953A patent/AU2014320953B2/en active Active
- 2014-09-04 KR KR1020167009265A patent/KR20160055207A/ko not_active Ceased
- 2014-09-04 US US15/021,152 patent/US9795917B2/en active Active
- 2014-09-04 JP JP2016541787A patent/JP6480457B2/ja active Active
- 2014-09-04 BR BR112016005239-0A patent/BR112016005239B1/pt active IP Right Grant
- 2014-09-04 EA EA201690562A patent/EA201690562A1/ru unknown
- 2014-09-04 CA CA2923777A patent/CA2923777C/en active Active
- 2014-09-04 MX MX2016003062A patent/MX367409B/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| EP3045219A4 (en) | 2017-05-17 |
| WO2015035878A1 (zh) | 2015-03-19 |
| EP3045219A1 (en) | 2016-07-20 |
| KR20160055207A (ko) | 2016-05-17 |
| US9795917B2 (en) | 2017-10-24 |
| CA2923777C (en) | 2018-03-20 |
| US20160220946A1 (en) | 2016-08-04 |
| CA2923777A1 (en) | 2015-03-19 |
| MX2016003062A (es) | 2016-12-08 |
| EA201690562A1 (ru) | 2016-10-31 |
| JP2016533893A (ja) | 2016-11-04 |
| AU2014320953B2 (en) | 2017-03-23 |
| JP6480457B2 (ja) | 2019-03-13 |
| AU2014320953A1 (en) | 2016-04-28 |
| ES2966852T3 (es) | 2024-04-24 |
| BR112016005239B1 (pt) | 2021-11-03 |
| EP3045219B1 (en) | 2023-10-04 |
| CN103432890B (zh) | 2015-12-09 |
| PL3045219T3 (pl) | 2024-06-03 |
| BR112016005239A2 (es) | 2017-08-01 |
| CN103432890A (zh) | 2013-12-11 |
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