MX356476B - Métodos para aislar 4-cloro-2-fluor-3-fenil boronatos sustituidos y métodos para su uso. - Google Patents

Métodos para aislar 4-cloro-2-fluor-3-fenil boronatos sustituidos y métodos para su uso.

Info

Publication number
MX356476B
MX356476B MX2014008010A MX2014008010A MX356476B MX 356476 B MX356476 B MX 356476B MX 2014008010 A MX2014008010 A MX 2014008010A MX 2014008010 A MX2014008010 A MX 2014008010A MX 356476 B MX356476 B MX 356476B
Authority
MX
Mexico
Prior art keywords
chloro
fluoro
substituted
methods
phenylboronate
Prior art date
Application number
MX2014008010A
Other languages
English (en)
Other versions
MX2014008010A (es
Inventor
Oppenheimer Jossian
A Menning Catherine
R Henton Daniel
Original Assignee
Dow Agrosciences Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Agrosciences Llc filed Critical Dow Agrosciences Llc
Publication of MX2014008010A publication Critical patent/MX2014008010A/es
Publication of MX356476B publication Critical patent/MX356476B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/79—Acids; Esters
    • C07D213/803—Processes of preparation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/79—Acids; Esters
    • C07D213/803—Processes of preparation
    • C07D213/807—Processes of preparation by oxidation of pyridines or condensed pyridines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/025—Boronic and borinic acid compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pyridine Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Los métodos para aislar un 4-cloro-2-fluor-3-fenilboronato sustituido incluyen agregar un gas de dióxido de carbono o un sólido de dióxido de carbono (hielo seco) a una solución que comprende un 4-cloro-2-fluor-3-fenilboronato sustituido, un solvente orgánico inerte, y al menos una sal de litio para hacer reaccionar la al menos una sal de litio con el gas de dióxido de carbono o con el sólido de dióxido de carbono (hielo seco) y formar una mezcla que comprende al 4-cloro-2-fluor-3-fenilboronato sustituido, el solvente orgánico inerte, y un sólido precipitado. El sólido precipitado se puede retirar de la mezcla. También se describen métodos para usar 4-cloro-2-fluor-3-fenilboro natos sustituidos para producir metil-4-amino-3-cloro-6-(4-cloro-2 -fluor-3-fenilo sustituido) piridin-2-carboxilatos. Se describe también un 4-cloro-2-fluor-3-fenilboronato sustituido producido mediante uno de los métodos de aislamiento de un 4-cloro-2-fluor-3-fenilboronato sustituido, en donde el 4-cloro-2-fluor-3-fenilboronato sustituido se obtiene a un rendimiento superior o igual a aproximadamente 90%.
MX2014008010A 2011-12-30 2012-12-28 Métodos para aislar 4-cloro-2-fluor-3-fenil boronatos sustituidos y métodos para su uso. MX356476B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161582175P 2011-12-30 2011-12-30
PCT/US2012/071920 WO2013101987A1 (en) 2011-12-30 2012-12-28 Methods of isolating (4-chloro-2-fluoro-3-substituted-phenyl) boronates and methods of using the same

Publications (2)

Publication Number Publication Date
MX2014008010A MX2014008010A (es) 2015-03-05
MX356476B true MX356476B (es) 2018-05-30

Family

ID=48695352

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014008010A MX356476B (es) 2011-12-30 2012-12-28 Métodos para aislar 4-cloro-2-fluor-3-fenil boronatos sustituidos y métodos para su uso.

Country Status (16)

Country Link
US (2) US9045502B2 (es)
EP (1) EP2797932B1 (es)
JP (1) JP6068501B2 (es)
KR (1) KR102065950B1 (es)
CN (1) CN104080791B (es)
AR (1) AR089629A1 (es)
AU (1) AU2012362364B2 (es)
BR (1) BR112014016049B8 (es)
CA (2) CA2861872C (es)
CO (1) CO7010844A2 (es)
IL (1) IL233355A (es)
IN (1) IN2014DN05755A (es)
MX (1) MX356476B (es)
PL (1) PL2797932T3 (es)
RU (1) RU2626975C2 (es)
WO (1) WO2013101987A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110558321A (zh) * 2012-12-21 2019-12-13 美国陶氏益农公司 除草组合物
CA2923058A1 (en) 2013-09-05 2015-03-12 Dow Agrosciences Llc Methods for producing borylated arenes
TW201625354A (zh) 2014-06-16 2016-07-16 陶氏農業科學公司 用於製備氧硼基化芳烴之方法
MX2018014174A (es) * 2016-05-19 2019-03-14 Dow Agrosciences Llc Sintesis de 6-aril-4-aminopicolinatos y 2-aril-6-aminopirimidin-4- carboxilatos mediante acoplamiento suzuki directo.
CN106450633B (zh) * 2016-10-17 2022-07-01 北京真空电子技术研究所(中国电子科技集团公司第十二研究所） 一种正交场放大器

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AR037228A1 (es) * 2001-07-30 2004-11-03 Dow Agrosciences Llc Compuestos del acido 6-(aril o heteroaril)-4-aminopicolinico, composicion herbicida que los comprende y metodo para controlar vegetacion no deseada
DE10150615A1 (de) * 2001-10-12 2003-04-30 Clariant Gmbh Verfahren zur metallorganischen Herstellung organischer Zwischenprodukte
BR122015016965B8 (pt) * 2006-01-13 2022-06-28 Dow Agrosciences Llc 6-(aril polissubstituído)-4-aminopicolinatos, composição herbicida, e método para controle de vegetação indesejável
CN101360719B (zh) * 2006-01-13 2012-09-05 美国陶氏益农公司 2-(多取代芳基)-6-氨基-5-卤代-4-嘧啶甲酸及其作为除草剂的用途
US7964758B2 (en) * 2006-02-13 2011-06-21 Nissan Chemical Industries, Ltd. Process for production of 2-(substituted phenyl)-3,3,3-trifluoropropene compound
EP2311815B1 (en) * 2007-08-13 2012-12-19 Dow AgroSciences LLC 2-(2-Fluoro-substituted phenyl)-6-amino-5-chloro-4-pyrimidinecarboxylates and their use as herbicides
US7642220B2 (en) * 2007-08-30 2010-01-05 Dow Agrosciences Llc 2-(substituted phenyl)-6-amino-5-alkoxy, thioalkoxy and aminoalkyl-4-pyrimidinecarboxylates and their use as herbicides
AU2008308815B2 (en) * 2007-10-02 2012-02-02 Corteva Agriscience Llc 2-substituted-6-amino-5-alkyl, alkenyl or alkynyl-4-pyrimidinecarboxylic acids and 6-substituted-4-amino-3- alkyl, alkenyl or alkynyl picolinic acids and their use as herbicides
KR101599566B1 (ko) * 2008-01-11 2016-03-03 다우 아그로사이언시즈 엘엘씨 1-플루오로-2-치환된-3-클로로벤젠의 선택적 탈양성자화 및 관능화 방법
PT2725903T (pt) * 2011-06-30 2020-06-30 Dow Agrosciences Llc 3-alcoxi-, tioalquil- e amino-4-aminopicolinatos 6-substituídos e sua utilização como herbicidas

Also Published As

Publication number Publication date
CA3085614A1 (en) 2013-07-04
EP2797932B1 (en) 2017-02-01
BR112014016049A2 (pt) 2017-06-13
WO2013101987A1 (en) 2013-07-04
US9376390B2 (en) 2016-06-28
RU2626975C2 (ru) 2017-08-02
NZ627196A (en) 2015-09-25
US20150239843A1 (en) 2015-08-27
CO7010844A2 (es) 2014-07-31
AU2012362364B2 (en) 2017-06-29
CA3085614C (en) 2023-01-24
CN104080791A (zh) 2014-10-01
CA2861872C (en) 2020-09-15
CN104080791B (zh) 2016-12-07
IL233355A0 (en) 2014-08-31
EP2797932A4 (en) 2015-10-07
BR112014016049B1 (pt) 2019-12-17
US9045502B2 (en) 2015-06-02
CA2861872A1 (en) 2013-07-04
IL233355A (en) 2017-12-31
RU2014131453A (ru) 2016-02-20
EP2797932A1 (en) 2014-11-05
AU2012362364A1 (en) 2014-07-31
AR089629A1 (es) 2014-09-03
JP2015507633A (ja) 2015-03-12
PL2797932T3 (pl) 2017-08-31
BR112014016049B8 (pt) 2022-10-11
US20130172567A1 (en) 2013-07-04
MX2014008010A (es) 2015-03-05
JP6068501B2 (ja) 2017-01-25
IN2014DN05755A (es) 2015-04-10
KR102065950B1 (ko) 2020-01-14
BR112014016049A8 (pt) 2017-07-04
KR20140117443A (ko) 2014-10-07

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