MX356476B - Métodos para aislar 4-cloro-2-fluor-3-fenil boronatos sustituidos y métodos para su uso. - Google Patents
Métodos para aislar 4-cloro-2-fluor-3-fenil boronatos sustituidos y métodos para su uso.Info
- Publication number
- MX356476B MX356476B MX2014008010A MX2014008010A MX356476B MX 356476 B MX356476 B MX 356476B MX 2014008010 A MX2014008010 A MX 2014008010A MX 2014008010 A MX2014008010 A MX 2014008010A MX 356476 B MX356476 B MX 356476B
- Authority
- MX
- Mexico
- Prior art keywords
- chloro
- fluoro
- substituted
- methods
- phenylboronate
- Prior art date
Links
- -1 (4-chloro-2-fluoro-3-substituted-phenyl) boronates Chemical class 0.000 title abstract 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 10
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 4
- 239000001569 carbon dioxide Substances 0.000 abstract 4
- 239000007787 solid Substances 0.000 abstract 4
- 235000011089 carbon dioxide Nutrition 0.000 abstract 2
- 229910003002 lithium salt Inorganic materials 0.000 abstract 2
- 159000000002 lithium salts Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000003960 organic solvent Substances 0.000 abstract 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/803—Processes of preparation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/803—Processes of preparation
- C07D213/807—Processes of preparation by oxidation of pyridines or condensed pyridines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/025—Boronic and borinic acid compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyridine Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Los métodos para aislar un 4-cloro-2-fluor-3-fenilboronato sustituido incluyen agregar un gas de dióxido de carbono o un sólido de dióxido de carbono (hielo seco) a una solución que comprende un 4-cloro-2-fluor-3-fenilboronato sustituido, un solvente orgánico inerte, y al menos una sal de litio para hacer reaccionar la al menos una sal de litio con el gas de dióxido de carbono o con el sólido de dióxido de carbono (hielo seco) y formar una mezcla que comprende al 4-cloro-2-fluor-3-fenilboronato sustituido, el solvente orgánico inerte, y un sólido precipitado. El sólido precipitado se puede retirar de la mezcla. También se describen métodos para usar 4-cloro-2-fluor-3-fenilboro natos sustituidos para producir metil-4-amino-3-cloro-6-(4-cloro-2 -fluor-3-fenilo sustituido) piridin-2-carboxilatos. Se describe también un 4-cloro-2-fluor-3-fenilboronato sustituido producido mediante uno de los métodos de aislamiento de un 4-cloro-2-fluor-3-fenilboronato sustituido, en donde el 4-cloro-2-fluor-3-fenilboronato sustituido se obtiene a un rendimiento superior o igual a aproximadamente 90%.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161582175P | 2011-12-30 | 2011-12-30 | |
| PCT/US2012/071920 WO2013101987A1 (en) | 2011-12-30 | 2012-12-28 | Methods of isolating (4-chloro-2-fluoro-3-substituted-phenyl) boronates and methods of using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2014008010A MX2014008010A (es) | 2015-03-05 |
| MX356476B true MX356476B (es) | 2018-05-30 |
Family
ID=48695352
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014008010A MX356476B (es) | 2011-12-30 | 2012-12-28 | Métodos para aislar 4-cloro-2-fluor-3-fenil boronatos sustituidos y métodos para su uso. |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US9045502B2 (es) |
| EP (1) | EP2797932B1 (es) |
| JP (1) | JP6068501B2 (es) |
| KR (1) | KR102065950B1 (es) |
| CN (1) | CN104080791B (es) |
| AR (1) | AR089629A1 (es) |
| AU (1) | AU2012362364B2 (es) |
| BR (1) | BR112014016049B8 (es) |
| CA (2) | CA3085614C (es) |
| CO (1) | CO7010844A2 (es) |
| IL (1) | IL233355A (es) |
| IN (1) | IN2014DN05755A (es) |
| MX (1) | MX356476B (es) |
| PL (1) | PL2797932T3 (es) |
| RU (1) | RU2626975C2 (es) |
| WO (1) | WO2013101987A1 (es) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL2934139T3 (pl) * | 2012-12-21 | 2019-01-31 | Dow Agrosciences Llc | Kompozycje chwastobójcze zawierające kwas 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-metoksyfenylo)pirydyno-2-karboksylowy i flurtamon |
| MX2016002923A (es) | 2013-09-05 | 2017-01-19 | Dow Agrosciences Llc | Metodos para producir arenos borilados. |
| TW201625354A (zh) | 2014-06-16 | 2016-07-16 | 陶氏農業科學公司 | 用於製備氧硼基化芳烴之方法 |
| CN109415319A (zh) * | 2016-05-19 | 2019-03-01 | 美国陶氏益农公司 | 通过直接苏楚基偶联合成芳基羧酸酯 |
| CN106450633B (zh) * | 2016-10-17 | 2022-07-01 | 北京真空电子技术研究所(中国电子科技集团公司第十二研究所） | 一种正交场放大器 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR037228A1 (es) * | 2001-07-30 | 2004-11-03 | Dow Agrosciences Llc | Compuestos del acido 6-(aril o heteroaril)-4-aminopicolinico, composicion herbicida que los comprende y metodo para controlar vegetacion no deseada |
| DE10150615A1 (de) * | 2001-10-12 | 2003-04-30 | Clariant Gmbh | Verfahren zur metallorganischen Herstellung organischer Zwischenprodukte |
| JP4332589B2 (ja) * | 2006-01-13 | 2009-09-16 | ダウ アグロサイエンシィズ エルエルシー | ２−（多置換アリール）−６−アミノ−５−ハロ−４−ピリミジンカルボン酸および除草剤としてのそれらの使用 |
| TWI396682B (zh) * | 2006-01-13 | 2013-05-21 | Dow Agrosciences Llc | ６-（經多重取代之芳基）-４-胺基吡啶甲酸酯及其作為除草劑之用途 |
| JPWO2007094313A1 (ja) * | 2006-02-13 | 2009-07-09 | 日産化学工業株式会社 | ２−（置換フェニル）−３，３，３−トリフルオロプロペン化合物の製造方法 |
| ES2401348T3 (es) * | 2007-08-13 | 2013-04-18 | Dow Agrosciences, Llc | 2-(Fenil 2-fluoro-substituido)-6-amino-5-cloro-4-pirimidinacarboxilatos y su uso como herbicidas |
| DE602008005319D1 (de) * | 2007-08-30 | 2011-04-14 | Dow Agrosciences Llc | 2-(substituierte phenyl)-6-amino-5-alkoxy-, thioalkoxy- und aminoalkyl-4-pyrimidincarboxylate und ihre verwendung als herbizide |
| BR122016003312B8 (pt) * | 2007-10-02 | 2022-06-28 | Dow Agrosciences Llc | Ácidos 2-substituído-6-amino-5-alquil, alquenil ou alquinil-4-pirimidinacarboxílicos e ácidos 6-substituído-4-amino-3-alquil, alquenil ou alquinil picolínicos, composição herbicida que os compreende e método de controlar vegetação indesejável |
| BRPI0907417B8 (pt) * | 2008-01-11 | 2022-06-28 | Dow Agrosciences Llc | Processo para a desprotonação seletiva e funcionalização de 1-flúor-2-substituído-3--clorobenzenos |
| EA028844B1 (ru) * | 2011-06-30 | 2018-01-31 | Доу Агросайенсиз Ллс | 3-алкокси, тиоалкил и амино-4-амино-6-(замещенные)пиколинаты и их применение в качестве гербицидов |
-
2012
- 2012-12-28 MX MX2014008010A patent/MX356476B/es active IP Right Grant
- 2012-12-28 AU AU2012362364A patent/AU2012362364B2/en active Active
- 2012-12-28 CA CA3085614A patent/CA3085614C/en active Active
- 2012-12-28 KR KR1020147020893A patent/KR102065950B1/ko active Active
- 2012-12-28 CN CN201280068666.XA patent/CN104080791B/zh active Active
- 2012-12-28 WO PCT/US2012/071920 patent/WO2013101987A1/en not_active Ceased
- 2012-12-28 BR BR112014016049A patent/BR112014016049B8/pt active IP Right Grant
- 2012-12-28 US US13/729,580 patent/US9045502B2/en active Active
- 2012-12-28 JP JP2014550485A patent/JP6068501B2/ja active Active
- 2012-12-28 PL PL12861211T patent/PL2797932T3/pl unknown
- 2012-12-28 RU RU2014131453A patent/RU2626975C2/ru active
- 2012-12-28 CA CA2861872A patent/CA2861872C/en active Active
- 2012-12-28 EP EP12861211.6A patent/EP2797932B1/en active Active
- 2012-12-28 IN IN5755DEN2014 patent/IN2014DN05755A/en unknown
-
2013
- 2013-01-02 AR ARP130100012A patent/AR089629A1/es active IP Right Grant
-
2014
- 2014-06-24 IL IL233355A patent/IL233355A/en active IP Right Grant
- 2014-07-18 CO CO14156101A patent/CO7010844A2/es unknown
-
2015
- 2015-05-13 US US14/711,540 patent/US9376390B2/en active Active
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Legal Events
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| FG | Grant or registration |