IN2014DN05755A - - Google Patents
Info
- Publication number
- IN2014DN05755A IN2014DN05755A IN5755DEN2014A IN2014DN05755A IN 2014DN05755 A IN2014DN05755 A IN 2014DN05755A IN 5755DEN2014 A IN5755DEN2014 A IN 5755DEN2014A IN 2014DN05755 A IN2014DN05755 A IN 2014DN05755A
- Authority
- IN
- India
- Prior art keywords
- chloro
- fluoro
- substituted
- phenylboronate
- carbon dioxide
- Prior art date
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 10
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 9
- 125000001153 fluoro group Chemical group F* 0.000 abstract 8
- HXITXNWTGFUOAU-UHFFFAOYSA-N phenylboronic acid Chemical class OB(O)C1=CC=CC=C1 HXITXNWTGFUOAU-UHFFFAOYSA-N 0.000 abstract 7
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 4
- 239000001569 carbon dioxide Substances 0.000 abstract 4
- 239000007787 solid Substances 0.000 abstract 4
- 235000011089 carbon dioxide Nutrition 0.000 abstract 2
- 229910003002 lithium salt Inorganic materials 0.000 abstract 2
- 159000000002 lithium salts Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000003960 organic solvent Substances 0.000 abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- -1 pyridine 2 carboxylates Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/025—Boronic and borinic acid compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/803—Processes of preparation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/803—Processes of preparation
- C07D213/807—Processes of preparation by oxidation of pyridines or condensed pyridines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyridine Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Methods of isolating a 4 chloro 2 fluoro 3 substituted phenylboronate include adding carbon dioxide gas or carbon dioxide solid (dry ice) to a solution comprising a 4 chloro 2 fluoro 3 substituted phenylboronate an inert organic solvent and at least one lithium salt to react the at least one lithium salt with the carbon dioxide gas or carbon dioxide solid (dry ice) and form a mixture comprising the 4 chloro 2 fluoro 3 substituted phenylboronate the inert organic solvent and a precipitated solid. The precipitated solid may be removed from the mixture. Methods of using 4 chloro 2 fluoro 3 substituted phenylboronates to produce methyl 4 amino 3 chloro 6 (4 chloro 2 fluoro 3 substituted phenyl)pyridine 2 carboxylates are also disclosed. A 4 chloro 2 fluoro 3 substituted phenylboronate produced by one of the methods of isolating a 4 chloro 2 fluoro 3 substituted phenylboronate is also disclosed wherein the 4 chloro 2 fluoro 3 substituted phenylboronate may be obtained at a yield of greater than or equal to about 90%.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161582175P | 2011-12-30 | 2011-12-30 | |
| PCT/US2012/071920 WO2013101987A1 (en) | 2011-12-30 | 2012-12-28 | Methods of isolating (4-chloro-2-fluoro-3-substituted-phenyl) boronates and methods of using the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IN2014DN05755A true IN2014DN05755A (en) | 2015-04-10 |
Family
ID=48695352
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IN5755DEN2014 IN2014DN05755A (en) | 2011-12-30 | 2012-12-28 |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US9045502B2 (en) |
| EP (1) | EP2797932B1 (en) |
| JP (1) | JP6068501B2 (en) |
| KR (1) | KR102065950B1 (en) |
| CN (1) | CN104080791B (en) |
| AR (1) | AR089629A1 (en) |
| AU (1) | AU2012362364B2 (en) |
| BR (1) | BR112014016049B8 (en) |
| CA (2) | CA3085614C (en) |
| CO (1) | CO7010844A2 (en) |
| IL (1) | IL233355A (en) |
| IN (1) | IN2014DN05755A (en) |
| MX (1) | MX356476B (en) |
| PL (1) | PL2797932T3 (en) |
| RU (1) | RU2626975C2 (en) |
| WO (1) | WO2013101987A1 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL2934139T3 (en) * | 2012-12-21 | 2019-01-31 | Dow Agrosciences Llc | Herbicidal compositions comprising 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid and flurtamone |
| US10112960B2 (en) | 2013-09-05 | 2018-10-30 | Dow Agrosciences Llc | Methods for producing borylated arenes |
| TW201625354A (en) | 2014-06-16 | 2016-07-16 | 陶氏農業科學公司 | Methods for producing borylated arenes |
| KR20190007048A (en) * | 2016-05-19 | 2019-01-21 | 다우 아그로사이언시즈 엘엘씨 | Synthesis of 6-aryl-4-aminopicolinate and 2-aryl-6-aminopyrimidine-4-carboxylate by direct Suzuki coupling |
| CN106450633B (en) * | 2016-10-17 | 2022-07-01 | 北京真空电子技术研究所(中国电子科技集团公司第十二研究所） | Orthogonal field amplifier |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR037228A1 (en) * | 2001-07-30 | 2004-11-03 | Dow Agrosciences Llc | ACID COMPOUNDS 6- (ARIL OR HETEROARIL) -4-AMYNOPYCOLINIC, HERBICIDE COMPOSITION THAT UNDERSTANDS AND METHOD TO CONTROL UNWANTED VEGETATION |
| DE10150615A1 (en) * | 2001-10-12 | 2003-04-30 | Clariant Gmbh | Process for organometallic production of organic intermediates |
| CA2626103C (en) * | 2006-01-13 | 2013-07-30 | Dow Agrosciences Llc | 6-(poly-substituted aryl)-4-aminopicolinates and their use as herbicides |
| EP1971579B1 (en) * | 2006-01-13 | 2010-07-28 | Dow AgroSciences LLC | 2-(poly-substituted aryl)-6-amino-5-halo-4-pyrimidinecarboxylic acids and their use as herbicides |
| WO2007094313A1 (en) * | 2006-02-13 | 2007-08-23 | Nissan Chemical Industries, Ltd. | Process for production of 2-(substituted phenyl)-3,3,3-trifluoropropene compound |
| JP5356387B2 (en) * | 2007-08-13 | 2013-12-04 | ダウ アグロサイエンシィズ エルエルシー | 2- (2-Fluoro-substituted phenyl) -6-amino-5-chloro-4-pyrimidinecarboxylates and their use as herbicides |
| EP2181098B1 (en) * | 2007-08-30 | 2011-03-02 | Dow AgroSciences LLC | 2-(substituted phenyl)-6-amino-5-alkoxy, thioalkoxy and aminoalkyl-4-pyrimidinecarboxylates and their use as herbicides |
| ES2410504T3 (en) * | 2007-10-02 | 2013-07-02 | Dow Agrosciences, Llc | Substituted 4-amino-picolinic acids and their use as herbicides |
| CN101970446A (en) * | 2008-01-11 | 2011-02-09 | 陶氏益农公司 | Process for the selective deprotonation and functionalization of 1-fluoro-2-substituted-3-chlorobenzenes |
| EP2725903B1 (en) * | 2011-06-30 | 2020-04-15 | Dow AgroSciences LLC | 3-alkoxy, thioalkyl and amino-4-amino-6-(substituted)picolinates and their use as herbicides |
-
2012
- 2012-12-28 WO PCT/US2012/071920 patent/WO2013101987A1/en active Application Filing
- 2012-12-28 CN CN201280068666.XA patent/CN104080791B/en active Active
- 2012-12-28 RU RU2014131453A patent/RU2626975C2/en active
- 2012-12-28 AU AU2012362364A patent/AU2012362364B2/en active Active
- 2012-12-28 KR KR1020147020893A patent/KR102065950B1/en active IP Right Grant
- 2012-12-28 MX MX2014008010A patent/MX356476B/en active IP Right Grant
- 2012-12-28 CA CA3085614A patent/CA3085614C/en active Active
- 2012-12-28 PL PL12861211T patent/PL2797932T3/en unknown
- 2012-12-28 EP EP12861211.6A patent/EP2797932B1/en active Active
- 2012-12-28 BR BR112014016049A patent/BR112014016049B8/en active IP Right Grant
- 2012-12-28 CA CA2861872A patent/CA2861872C/en active Active
- 2012-12-28 JP JP2014550485A patent/JP6068501B2/en active Active
- 2012-12-28 US US13/729,580 patent/US9045502B2/en active Active
- 2012-12-28 IN IN5755DEN2014 patent/IN2014DN05755A/en unknown
-
2013
- 2013-01-02 AR ARP130100012A patent/AR089629A1/en active IP Right Grant
-
2014
- 2014-06-24 IL IL233355A patent/IL233355A/en active IP Right Grant
- 2014-07-18 CO CO14156101A patent/CO7010844A2/en unknown
-
2015
- 2015-05-13 US US14/711,540 patent/US9376390B2/en active Active
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