MX346341B - Reactor catalítico de membrana con bombeo electroquímico de hidrógeno u oxígeno y sus aplicaciones. - Google Patents

Reactor catalítico de membrana con bombeo electroquímico de hidrógeno u oxígeno y sus aplicaciones.

Info

Publication number
MX346341B
MX346341B MX2012005263A MX2012005263A MX346341B MX 346341 B MX346341 B MX 346341B MX 2012005263 A MX2012005263 A MX 2012005263A MX 2012005263 A MX2012005263 A MX 2012005263A MX 346341 B MX346341 B MX 346341B
Authority
MX
Mexico
Prior art keywords
hydrogen
reactor
electrochemical pumping
catalytic membrane
applications
Prior art date
Application number
MX2012005263A
Other languages
English (en)
Other versions
MX2012005263A (es
Inventor
Miguel Magalhaes Mendes Adèlio
Original Assignee
Cuf-Quimicos Ind S A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cuf-Quimicos Ind S A filed Critical Cuf-Quimicos Ind S A
Publication of MX2012005263A publication Critical patent/MX2012005263A/es
Publication of MX346341B publication Critical patent/MX346341B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2475—Membrane reactors
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/02—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of hydrogen atoms by amino groups
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • H01M4/921—Alloys or mixtures with metallic elements
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/94—Non-porous diffusion electrodes, e.g. palladium membranes, ion exchange membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0681—Reactant purification by the use of electrochemical cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/08—Fuel cells with aqueous electrolytes
    • H01M8/086—Phosphoric acid fuel cells [PAFC]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/002—Shape, form of a fuel cell
    • H01M8/004—Cylindrical, tubular or wound
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

La presente invención se refiere a un nuevo tipo de reactor químico, descrito como reactor catalítico de membrana con bombeo electroquímico de hidrógeno u oxígeno. Este nuevo tipo de reactor es particularmente adecuado para incrementar la selectividad y la velocidad de conversión de reacciones de deshidrogenación, hidrogenación, desoxidación y oxidación y a saber en la reacción de aminación directa de hidrocarburos. Este reactor puede ser usado para la producción de varios compuestos químicos, tales como la aminación directa de hidrocarburos y en particular para la síntesis de anilina a partir de benceno. En esta aplicación, en donde el hidrógeno es removido por bombeo electroquímico del hidrógeno formado o por bombeo de oxígeno así, conforme el hidrógeno se forma, se oxida. Este nuevo reactor presenta conversión de benceno a anilina superior del 40.
MX2012005263A 2009-11-06 2010-11-05 Reactor catalítico de membrana con bombeo electroquímico de hidrógeno u oxígeno y sus aplicaciones. MX346341B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PT104812A PT104812A (pt) 2009-11-06 2009-11-06 Reactor catal?tico de membrana com bombagem electroqu?mica de hidrog?nio ou de oxig?nio e suas aplica??es
PCT/IB2010/055045 WO2011055343A2 (pt) 2009-11-06 2010-11-05 Reactor catalítico de membrana com bombagem electroquímica de hidrogénio ou de oxigénio e suas aplicações

Publications (2)

Publication Number Publication Date
MX2012005263A MX2012005263A (es) 2012-09-07
MX346341B true MX346341B (es) 2017-03-14

Family

ID=43759121

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012005263A MX346341B (es) 2009-11-06 2010-11-05 Reactor catalítico de membrana con bombeo electroquímico de hidrógeno u oxígeno y sus aplicaciones.

Country Status (15)

Country Link
US (1) US9498765B2 (es)
EP (1) EP2497570A2 (es)
JP (1) JP5852575B2 (es)
KR (1) KR20120105461A (es)
CN (1) CN102762292B (es)
AP (1) AP3617A (es)
AU (1) AU2010316633B2 (es)
BR (1) BR112012010764A2 (es)
CA (1) CA2779953A1 (es)
EA (1) EA024313B1 (es)
MA (1) MA33728B1 (es)
MX (1) MX346341B (es)
PT (1) PT104812A (es)
WO (1) WO2011055343A2 (es)
ZA (1) ZA201204096B (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012046889A1 (ko) * 2010-10-05 2012-04-12 연세대학교 산학협력단 연료전지용 복합체 전해질 막, 이의 제조방법 및 이를 포함하는 연료전지
PT106860A (pt) * 2013-03-28 2014-09-29 Cuf Químicos Ind S A Conjunto elétrodos/eletrólito, reator e método para a aminação direta de hidrocarbonetos
CN105552411B (zh) * 2015-12-09 2017-09-22 佛山索弗克氢能源有限公司 氨气在sofc电池中的应用及其应用装置
US11136678B2 (en) 2016-08-11 2021-10-05 Massachusetts Institute Of Technology Electrochemical oxidation of aliphatic and aromatic compounds
GB2598718A (en) * 2020-09-01 2022-03-16 Enapter S R L System of the removal of hydrogen/oxygen in a gaseous stream
CN114807983B (zh) * 2021-01-18 2024-06-04 武汉理工大学 一种用于实现不饱和烯炔烃选择性催化加氢的电化学系统
CN119753703B (zh) * 2024-12-12 2025-10-31 中钢集团鞍山热能研究院有限公司 一种利用电化学反应器对粗蒽的绿色加氢方法

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US7485211B2 (en) * 2003-10-10 2009-02-03 Ohio University Electro-catalysts for the oxidation of ammonia in alkaline media
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US8133637B2 (en) * 2005-10-06 2012-03-13 Headwaters Technology Innovation, Llc Fuel cells and fuel cell catalysts incorporating a nanoring support
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Also Published As

Publication number Publication date
PT104812A (pt) 2011-05-06
WO2011055343A2 (pt) 2011-05-12
AU2010316633B2 (en) 2016-04-14
US9498765B2 (en) 2016-11-22
EA201290284A1 (ru) 2012-10-30
WO2011055343A3 (pt) 2011-06-30
CN102762292B (zh) 2015-09-30
JP2013514873A (ja) 2013-05-02
JP5852575B2 (ja) 2016-02-03
AU2010316633A1 (en) 2012-06-14
KR20120105461A (ko) 2012-09-25
AP2012006290A0 (en) 2012-06-30
EP2497570A2 (en) 2012-09-12
CN102762292A (zh) 2012-10-31
BR112012010764A2 (pt) 2018-03-06
US20120273366A1 (en) 2012-11-01
AP3617A (en) 2016-02-29
CA2779953A1 (en) 2011-05-12
MX2012005263A (es) 2012-09-07
EA024313B1 (ru) 2016-09-30
ZA201204096B (en) 2013-08-28
MA33728B1 (fr) 2012-11-01

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