MX343476B - Pelicula de poliester renovable que tiene un modulo bajo y una elongación por traccion alta. - Google Patents

Pelicula de poliester renovable que tiene un modulo bajo y una elongación por traccion alta.

Info

Publication number
MX343476B
MX343476B MX2014009538A MX2014009538A MX343476B MX 343476 B MX343476 B MX 343476B MX 2014009538 A MX2014009538 A MX 2014009538A MX 2014009538 A MX2014009538 A MX 2014009538A MX 343476 B MX343476 B MX 343476B
Authority
MX
Mexico
Prior art keywords
renewable polyester
film
tensile elongation
toughening additive
increase
Prior art date
Application number
MX2014009538A
Other languages
English (en)
Other versions
MX2014009538A (es
Inventor
J Mceneany Ryan
T Scholl Neil
A Topolkaraev Vasily
Eby Tom
Original Assignee
Kimberly Clark Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kimberly Clark Co filed Critical Kimberly Clark Co
Publication of MX2014009538A publication Critical patent/MX2014009538A/es
Publication of MX343476B publication Critical patent/MX343476B/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0869—Acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L37/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a heterocyclic ring containing oxygen; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2555/00—Personal care
    • B32B2555/02—Diapers or napkins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/674—Nonwoven fabric with a preformed polymeric film or sheet
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/674—Nonwoven fabric with a preformed polymeric film or sheet
    • Y10T442/675—Ester condensation polymer sheet or film [e.g., polyethylene terephthalate, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Laminated Bodies (AREA)
  • Absorbent Articles And Supports Therefor (AREA)

Abstract

Se proporciona una película que se forma a partir de una composición termoplástica. La composición termoplástica contiene un poliéster renovable rígido y un aditivo endurecedor polimérico. El aditivo endurecedor puede dispersarse como dominios físicos discretos dentro de una matriz continua de poliéster renovable. Un aumento en la fuerza de deformación y la tensión de elongación provoca que ocurra una perdida de adherencia en la matriz de poliéster renovable en aquellas áreas localizadas adyacentes a los dominios discretos. Esto puede resultar en la formación de una pluralidad de vacíos adyacentes a los dominios discretos que pueden ayudar a disipar la energía bajo carga y aumentar la elongación por tracción. Para aumentar aún mas la capacidad de la película para disipar la energía de esta manera, los presentes inventores descubrieron que puede emplearse un modificador interface para reducir el grado de fricción entre el aditivo endurecedor y el poliéster renovable y asi reducir la rigidez (módulo de tracci9ón de la película,.
MX2014009538A 2012-02-10 2013-01-28 Pelicula de poliester renovable que tiene un modulo bajo y una elongación por traccion alta. MX343476B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/370,900 US8980964B2 (en) 2012-02-10 2012-02-10 Renewable polyester film having a low modulus and high tensile elongation
PCT/IB2013/050733 WO2013118023A1 (en) 2012-02-10 2013-01-28 Renewable polyester film having a low modulus and high tensile elongation

Publications (2)

Publication Number Publication Date
MX2014009538A MX2014009538A (es) 2014-11-10
MX343476B true MX343476B (es) 2016-11-04

Family

ID=48945798

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014009538A MX343476B (es) 2012-02-10 2013-01-28 Pelicula de poliester renovable que tiene un modulo bajo y una elongación por traccion alta.

Country Status (10)

Country Link
US (2) US8980964B2 (es)
EP (1) EP2812381B1 (es)
JP (1) JP6153208B2 (es)
KR (2) KR102209321B1 (es)
CN (1) CN104144974B (es)
AU (1) AU2013217366B2 (es)
BR (1) BR112014019496B1 (es)
MX (1) MX343476B (es)
RU (1) RU2618561C2 (es)
WO (1) WO2013118023A1 (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8975305B2 (en) 2012-02-10 2015-03-10 Kimberly-Clark Worldwide, Inc. Rigid renewable polyester compositions having a high impact strength and tensile elongation
US9040598B2 (en) 2012-02-10 2015-05-26 Kimberly-Clark Worldwide, Inc. Renewable polyester compositions having a low density
EP3415312B8 (en) * 2013-03-14 2020-09-30 Smart Planet Technologies, Inc. Repulpable and recyclable composite packaging articles and related methods
EP2999748A4 (en) * 2013-05-23 2017-01-04 Solegear Bioplastics Inc. Thermoformable polylactic acid
AU2014304179B2 (en) 2013-08-09 2017-08-17 Kimberly-Clark Worldwide, Inc. Anisotropic polymeric material
MX364108B (es) 2013-08-09 2019-04-11 Kimberly Clark Co Técnica para controlar selectivamente la porosidad de un material polimérico.
WO2015075632A1 (en) 2013-11-20 2015-05-28 Kimberly-Clark Worldwide, Inc. Absorbent article containing a soft and durable backsheet
MX2016006439A (es) 2013-11-20 2016-07-19 Kimberly Clark Co Compuesto no tejido suave y duradero.
KR102230520B1 (ko) 2014-11-18 2021-03-22 킴벌리-클라크 월드와이드, 인크. 부드럽고 내구성이 있는 부직포 웹
MX2017006065A (es) * 2014-11-26 2017-07-27 Kimberly Clark Co Material poroso de poliolefina que contiene un polimero de buteno.
AU2015353887B2 (en) 2014-11-26 2019-07-04 Kimberly-Clark Worldwide, Inc. Annealed porous polyolefin material
EP4389843A3 (en) 2014-12-22 2024-07-31 3M Innovative Properties Company Compositions and films comprising polylactic acid polymer, polyvinyl acetate polymer and plasticizer
EP3394193B1 (en) 2015-12-22 2020-03-18 3M Innovative Properties Company Packaged pre-adhesive composition including a polylactic acid-containing packaging material, adhesives, and articles
US11066551B2 (en) 2016-05-20 2021-07-20 3M Innovative Properties Company Oriented polylactic acid polymer based film
JP7170544B2 (ja) 2016-06-21 2022-11-14 スリーエム イノベイティブ プロパティズ カンパニー 半結晶性ポリ乳酸系フィルムを含むグラフィック物品
BR112019002051B1 (pt) 2016-08-11 2022-09-06 Kimberly-Clark Worldwide, Inc. Película de elastômero de poliolefina termoplástica, e, artigo
US10662325B2 (en) 2017-07-13 2020-05-26 Exxonmobil Chemical Patents Inc. Polyester compositions, and process for making articles therefrom
WO2020102725A1 (en) * 2018-11-16 2020-05-22 Mucell Extrusion, Llc Anisotropic thin polyethylene sheet and applications thereof and the process of making the same
CN111718569B (zh) * 2020-07-09 2022-07-19 上海浦景化工技术股份有限公司 一种聚乙醇酸的回收方法及其应用
US11850785B2 (en) 2020-10-14 2023-12-26 SAM North America, LLC Polymer extruded, extrusion method, and extruded material
CN112940325B (zh) * 2021-02-24 2022-07-12 辽宁万鑫富利新材料有限公司 一种可降解塑料复合薄膜及其制备工艺
KR102567191B1 (ko) 2021-04-05 2023-08-14 도레이첨단소재 주식회사 공중합 폴리에스테르 필름과 이를 이용한 이차전지용 파우치 외장재 및 파우치형 이차전지

Family Cites Families (163)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3338992A (en) 1959-12-15 1967-08-29 Du Pont Process for forming non-woven filamentary structures from fiber-forming synthetic organic polymers
US3341394A (en) 1966-12-21 1967-09-12 Du Pont Sheets of randomly distributed continuous filaments
DE1939528A1 (de) 1969-08-02 1971-02-11 Barmag Barmer Maschf Vorrichtung zum kontinuierlichen Herstellen von Mehrschichtblasfolien
DE1950669C3 (de) 1969-10-08 1982-05-13 Metallgesellschaft Ag, 6000 Frankfurt Verfahren zur Vliesherstellung
US3726955A (en) 1971-01-11 1973-04-10 Phillips Petroleum Co Process for producing filaments and yarns of blended incompatible polymers
CA982320A (en) 1971-05-20 1976-01-27 David Gibson Voided polyester fiber
US4055702A (en) 1974-03-29 1977-10-25 M & T Chemicals Inc. Additive-containing fibers
US4937299A (en) 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US4707398A (en) 1986-10-15 1987-11-17 Kimberly-Clark Corporation Elastic polyetherester nonwoven web
ATE79386T1 (de) 1986-12-19 1992-08-15 Akzo Nv Herstellung von polymilchsaeure und copolymeren daraus.
US5162074A (en) 1987-10-02 1992-11-10 Basf Corporation Method of making plural component fibers
US5502158A (en) 1988-08-08 1996-03-26 Ecopol, Llc Degradable polymer composition
US5218071A (en) 1988-12-26 1993-06-08 Mitsui Petrochemical Industries, Ltd. Ethylene random copolymers
US5069970A (en) 1989-01-23 1991-12-03 Allied-Signal Inc. Fibers and filters containing said fibers
JP2682130B2 (ja) 1989-04-25 1997-11-26 三井石油化学工業株式会社 柔軟な長繊維不織布
US5057368A (en) 1989-12-21 1991-10-15 Allied-Signal Filaments having trilobal or quadrilobal cross-sections
KR960004143B1 (ko) 1990-04-10 1996-03-27 도오요오 보오세끼 가부시끼가이샤 공동 함유 폴리에스테르계 필름 및 적층체
US5272236A (en) 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
US5317059A (en) 1990-07-09 1994-05-31 Ferro Corporation Impact-resistant polymer blends of olefin polymers, polyamides, and terpolymer compatibilizers
US5266610A (en) 1991-03-11 1993-11-30 Ici Composites Inc. Toughened cocontinuous resin system
DE4119857A1 (de) 1991-06-17 1992-12-24 Basf Lacke & Farben Ueberzugsmittel auf der basis von carboxylgruppenhaltigen polymeren und epoxidharzen
US5277976A (en) 1991-10-07 1994-01-11 Minnesota Mining And Manufacturing Company Oriented profile fibers
US5278272A (en) 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US6326458B1 (en) 1992-01-24 2001-12-04 Cargill, Inc. Continuous process for the manufacture of lactide and lactide polymers
US5470944A (en) 1992-02-13 1995-11-28 Arch Development Corporation Production of high molecular weight polylactic acid
US5939467A (en) 1992-06-26 1999-08-17 The Procter & Gamble Company Biodegradable polymeric compositions and products thereof
US5382400A (en) 1992-08-21 1995-01-17 Kimberly-Clark Corporation Nonwoven multicomponent polymeric fabric and method for making same
US5336552A (en) 1992-08-26 1994-08-09 Kimberly-Clark Corporation Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and ethylene alkyl acrylate copolymer
US5322728A (en) 1992-11-24 1994-06-21 Exxon Chemical Patents, Inc. Fibers of polyolefin polymers
IT1256260B (it) 1992-12-30 1995-11-29 Montecatini Tecnologie Srl Polipropilene atattico
US5359026A (en) 1993-07-30 1994-10-25 Cargill, Incorporated Poly(lactide) copolymer and process for manufacture thereof
US5472775A (en) 1993-08-17 1995-12-05 The Dow Chemical Company Elastic materials and articles therefrom
US5571619A (en) 1994-05-24 1996-11-05 Exxon Chemical Patents, Inc. Fibers and oriented films of polypropylene higher α-olefin copolymers
DE69507868T2 (de) 1994-11-08 1999-08-12 Basf Corp., Mount Olive, N.J. Verfahren zur Abtrennung von Polymeren aus Polymermischungen
US5714573A (en) 1995-01-19 1998-02-03 Cargill, Incorporated Impact modified melt-stable lactide polymer compositions and processes for manufacture thereof
US5539056A (en) 1995-01-31 1996-07-23 Exxon Chemical Patents Inc. Thermoplastic elastomers
DE69631305T2 (de) 1995-07-25 2004-11-18 Toyota Jidosha K.K., Toyota Verfahren zur Herstellung von Polymilchsäure
US5770682A (en) 1995-07-25 1998-06-23 Shimadzu Corporation Method for producing polylactic acid
US5726220A (en) 1995-08-30 1998-03-10 Shin-Etsu Chemical Co., Ltd. Biodegradable polymer compositions and shrink films
JPH09151310A (ja) * 1995-08-30 1997-06-10 Shin Etsu Chem Co Ltd 生分解性を有するポリマー組成物および収縮フィルム
FI105040B (fi) 1996-03-05 2000-05-31 Neste Oy Polylaktidikalvot
JP3588907B2 (ja) 1996-03-22 2004-11-17 トヨタ自動車株式会社 ポリ乳酸の製造方法
US5844067A (en) 1996-04-18 1998-12-01 Erneta; Modesto Process for producing absorbable segmented copolymers with a substantially uniform sequence distribution
JPH09291203A (ja) * 1996-04-26 1997-11-11 Kuraray Co Ltd ポリエステル系樹脂組成物
US5948528A (en) 1996-10-30 1999-09-07 Basf Corporation Process for modifying synthetic bicomponent fiber cross-sections and bicomponent fibers thereby produced
US6200669B1 (en) 1996-11-26 2001-03-13 Kimberly-Clark Worldwide, Inc. Entangled nonwoven fabrics and methods for forming the same
US5883199A (en) 1997-04-03 1999-03-16 University Of Massachusetts Polyactic acid-based blends
US6183814B1 (en) 1997-05-23 2001-02-06 Cargill, Incorporated Coating grade polylactide and coated paper, preparation and uses thereof, and articles prepared therefrom
GB9719060D0 (en) 1997-09-09 1997-11-12 Ici Plc Polymer composition
US6309988B1 (en) 1997-12-22 2001-10-30 Kimberly-Clark Worldwide, Inc. Biodisintegratable nonwovens with improved fluid management properties
DE69918233T2 (de) 1998-03-05 2005-02-24 Mitsui Chemicals, Inc. Polymilchsäure zusammensetzung und daraus hergestellter film
US6509092B1 (en) 1999-04-05 2003-01-21 Fiber Innovation Technology Heat bondable biodegradable fibers with enhanced adhesion
US6500563B1 (en) 1999-05-13 2002-12-31 Exxonmobil Chemical Patents Inc. Elastic films including crystalline polymer and crystallizable polymers of propylene
EP1054085B1 (en) 1999-05-21 2005-03-16 Toyota Jidosha Kabushiki Kaisha Monofilament and process for producing the same
AU772567B2 (en) 1999-08-25 2004-04-29 Kimberly-Clark Worldwide, Inc. Biodisintegratable nonwovens with fluid management properties and disposable absorbent products containing same
JP3258302B2 (ja) 1999-10-26 2002-02-18 三菱樹脂株式会社 生分解性２軸延伸フィルム
EP1252376A1 (en) 1999-11-09 2002-10-30 Kimberly-Clark Worldwide, Inc. Biodegradable polylactide nonwovens with fluid management properties and disposable absorbent products containing the same
DE60137933D1 (de) 2000-07-17 2009-04-23 Mitsui Chemicals Inc Auf milchsäure basierende harzzusammensetzungen und daraus hergestellte formteile
US6914018B1 (en) 2000-10-27 2005-07-05 Kimberly-Clark Worldwide, Inc. Biaxial stretch, breathable laminate with cloth-like aesthetics and method for making same
US6838403B2 (en) 2000-12-28 2005-01-04 Kimberly-Clark Worldwide, Inc. Breathable, biodegradable/compostable laminates
US6905759B2 (en) 2001-04-23 2005-06-14 Kimberly Clark Worldwide, Inc. Biodegradable films having enhanced ductility and breathability
US6660211B2 (en) 2001-04-23 2003-12-09 Kimberly-Clark Worldwide, Inc. Methods of making biodegradable films having enhanced ductility and breathability
US20030162013A1 (en) 2001-04-23 2003-08-28 Topolkaraev Vasily A. Articles comprising biodegradable films having enhanced ductility and breathability
EP1464737B1 (en) 2001-06-15 2009-08-05 Kuraray Co., Ltd. Composite fiber
US20030039775A1 (en) 2001-08-17 2003-02-27 Dan-Cheng Kong Multilayer sleeve labels
US20030105231A1 (en) 2001-11-28 2003-06-05 Hitech Polymers Inc. Polyester composition
US20030153684A1 (en) 2001-11-28 2003-08-14 Hitech Polymers Inc. Polyester composition
US20030106568A1 (en) 2001-12-12 2003-06-12 Kimberly-Clark Worldwide, Inc. Cleaning sheet, system and apparatus
MXPA04007399A (es) 2002-02-01 2006-02-24 Johnson Polymer Llc Extensores de cadena oligomericos para procesamiento, post-procesamiento y reciclaje de polimeros de condensacion, sintesis, composiciones y aplicaciones.
US6869985B2 (en) * 2002-05-10 2005-03-22 Awi Licensing Company Environmentally friendly polylactide-based composite formulations
US7354656B2 (en) 2002-11-26 2008-04-08 Michigan State University, Board Of Trustees Floor covering made from an environmentally friendly polylactide-based composite formulation
US7994078B2 (en) 2002-12-23 2011-08-09 Kimberly-Clark Worldwide, Inc. High strength nonwoven web from a biodegradable aliphatic polyester
US7135523B2 (en) 2003-03-14 2006-11-14 Industrial Technology Research Institute Nanoscale helical microstructures and channels from chiral poly(L-lactide) block containing block copolymers
US7514503B2 (en) 2003-10-08 2009-04-07 Asahi Kasei Chemicals Corporation Molded article produced from aliphatic polyester resin composition
US7157032B2 (en) 2003-11-21 2007-01-02 Gala Industries, Inc. Method and apparatus for making crystalline PET pellets
US20050112363A1 (en) 2003-11-21 2005-05-26 Xin Ning Biodegradable polymer compositions for a breathable film
US20050119359A1 (en) * 2003-12-02 2005-06-02 Shelby Marcus D. Void-containing polyester shrink film
US6949288B2 (en) 2003-12-04 2005-09-27 Fiber Innovation Technology, Inc. Multicomponent fiber with polyarylene sulfide component
US7595363B2 (en) 2003-12-12 2009-09-29 E.I. Du Pont De Nemours And Company Toughened poly(hydroxyalkanoic acid) compositions
US7354973B2 (en) 2003-12-12 2008-04-08 E.I. Du Pont De Nemours And Company Toughened poly(lactic acid) compositions
US7368503B2 (en) 2003-12-22 2008-05-06 Eastman Chemical Company Compatibilized blends of biodegradable polymers with improved rheology
US7393590B2 (en) 2004-02-27 2008-07-01 Cereplast, Inc. Biodegradable poly(lactic acid) polymer composition and films, coatings and products comprising Biodegradable poly(lactic acid) polymer compositions
US7138439B2 (en) 2004-02-27 2006-11-21 Biocorp North America, Inc. Biodegradable compounds including poly(lactic acid) polymer compositions and products
NZ552193A (en) 2004-06-23 2010-04-30 Natureworks Llc Branched polylactic acid polymers and method of preparing same
JP5004068B2 (ja) * 2004-11-26 2012-08-22 独立行政法人産業技術総合研究所 ポリ乳酸樹脂組成物とポリ乳酸樹脂組成物の製造方法
US7619132B2 (en) 2004-12-30 2009-11-17 Kimberly-Clark Worldwide, Inc. Degradable breathable multilayer film with improved properties and method of making same
KR20080059232A (ko) 2005-10-19 2008-06-26 도레이 가부시끼가이샤 권축사 및 그의 제조 방법 및 섬유 구조체
WO2007060930A1 (ja) 2005-11-25 2007-05-31 Kuraray Co., Ltd. ポリ乳酸組成物
JP5033326B2 (ja) * 2005-12-12 2012-09-26 三菱樹脂株式会社 熱収縮性空孔含有フィルム、並びに該フィルムを用いた成形品、熱収縮性ラベル及び容器
AU2005339151B2 (en) 2005-12-15 2011-09-08 Kimberly-Clark Worldwide, Inc. Biodegradable multicomponent fibers
KR20080081259A (ko) * 2005-12-26 2008-09-09 닛신보세키 가부시키 가이샤 폴리올레핀·폴리에스테르계 필름
WO2007092417A1 (en) 2006-02-07 2007-08-16 Tepha, Inc. Toughened polylactic acid polymers and copolymers
CN103232694A (zh) 2006-02-14 2013-08-07 日本电气株式会社 聚乳酸类树脂组合物及成形体
WO2007099056A1 (en) 2006-03-03 2007-09-07 Akzo Nobel N.V. Process for the modification of biodegradable polymers
JP2007270076A (ja) * 2006-03-31 2007-10-18 Tohcello Co Ltd ポリ乳酸系延伸フィルム、延伸積層フィルム及びその用途。
JP2007269995A (ja) 2006-03-31 2007-10-18 Three M Innovative Properties Co ポリ乳酸含有樹脂組成物、ポリ乳酸含有樹脂フィルム及びポリ乳酸含有樹脂繊維
US8927443B2 (en) 2006-04-07 2015-01-06 Kimberly-Clark Worldwide, Inc. Biodegradable nonwoven laminate
FR2902433A1 (fr) 2006-06-16 2007-12-21 Arkema France Materiau composite a base d'acide polylactique et de polyamide presentant une resistance aux chocs amelioree, son procede de fabrication et utilisation
FR2902434B1 (fr) 2006-06-16 2008-08-01 Arkema France Composition d'acide polylactique presentant une resistance aux chocs amelioree
TW200801113A (en) 2006-06-27 2008-01-01 Far Eastern Textile Ltd The polylactic acid composition and the deep dyeing fiber manufactured from the same
US9089627B2 (en) 2006-07-11 2015-07-28 Abbott Cardiovascular Systems Inc. Stent fabricated from polymer composite toughened by a dispersed phase
MX2009000527A (es) 2006-07-14 2009-01-27 Kimberly Clark Co Acido polilactico biodegradable para su uso en telas no tejidas.
US7943218B2 (en) * 2006-08-14 2011-05-17 Frito-Lay North America, Inc. Environmentally-friendly multi-layer flexible film having barrier properties
JP5383011B2 (ja) * 2006-08-17 2014-01-08 三菱樹脂株式会社 熱収縮性フィルム、並びにこの熱収縮性フィルムを用いた成形品、熱収縮性ラベル、及びこの成形品を用いた、又はこのラベルを装着した容器
KR100786005B1 (ko) 2006-08-18 2007-12-14 에스케이씨 주식회사 다층 지방족 폴리에스터 필름
EP2055737B1 (en) 2006-08-23 2012-08-08 JSR Corporation Thermoplastic resin composition and molded article obtained from the same
KR101249120B1 (ko) 2006-08-31 2013-03-29 킴벌리-클라크 월드와이드, 인크. 고도 통기성 생분해성 필름
JP5233105B2 (ja) 2006-09-27 2013-07-10 豊田合成株式会社 ポリ乳酸系樹脂成形品
US7557167B2 (en) 2006-09-28 2009-07-07 Gore Enterprise Holdings, Inc. Polyester compositions, methods of manufacturing said compositions, and articles made therefrom
JP5145695B2 (ja) * 2006-11-09 2013-02-20 東レ株式会社 ポリ乳酸系樹脂フィルムの製造方法
ES2372988T3 (es) 2006-12-14 2012-01-30 Pactiv Corporation Espumas biodegradables expandidas y extruidas y de emisiones reducidas hechas con agentes de soplado basados en formiato de metilo.
US7977397B2 (en) 2006-12-14 2011-07-12 Pactiv Corporation Polymer blends of biodegradable or bio-based and synthetic polymers and foams thereof
US20100048082A1 (en) 2006-12-15 2010-02-25 Topolkaraev Vasily A Biodegradable polylactic acids for use in forming fibers
US8981013B2 (en) 2006-12-21 2015-03-17 Dow Global Technologies Llc Functionalized olefin polymers, compositions and articles prepared therefrom, and methods for making the same
WO2008078413A1 (ja) 2006-12-22 2008-07-03 Unitika Ltd. 生分解性ポリエステル樹脂組成物、および、それより得られる成形体、発泡体、成形容器
ES2385264T3 (es) * 2006-12-27 2012-07-20 Toray Industries, Inc. Composición de resina y artículo moldeado
JP2008163072A (ja) * 2006-12-27 2008-07-17 Toray Ind Inc 生分解性樹脂含有フィルム
WO2008096798A1 (ja) 2007-02-06 2008-08-14 Mitsubishi Plastics, Inc. 熱収縮性フィルム、並びにこの熱収縮性フィルムを用いた成形品、熱収縮性ラベル、およびこの成形品を用いた、またはこのラベルを装着した容器
WO2008102919A1 (ja) 2007-02-23 2008-08-28 Teijin Limited ポリ乳酸組成物
US8415008B2 (en) 2007-02-23 2013-04-09 Unitika Ltd. Resin composition, and molded article produced from the same
DE602008006294D1 (de) 2007-03-01 2011-06-01 Prs Mediterranean Ltd Verfahren zur herstellung kompatibilisierter polymermischungen und artikeln
NL1033719C2 (nl) 2007-04-19 2008-10-21 Synbra Tech Bv Deeltjesvormig expandeerbaar polymelkzuur, werkwijze voor het vervaardigen hiervan, geschuimd vormdeel op basis van deeltjesvormig expandeerbaar polymelkzuur evenals werkwijze voor het vervaardigen hiervan.
JP5298383B2 (ja) 2007-04-25 2013-09-25 Ｅｓファイバービジョンズ株式会社 嵩高性、柔軟性に優れた熱接着性複合繊維及びこれを用いた繊維成形品
JP5072077B2 (ja) * 2007-05-21 2012-11-14 三菱樹脂株式会社 遮光性熱収縮フィルム、並びにこの遮光性熱収縮フィルムを用いた成形品、熱収縮ラベル、及びこの成形品を用いた、又はこのラベルを装着した容器
WO2008156724A1 (en) 2007-06-15 2008-12-24 Tredegar Film Products Corporation Activated bicomponent fibers and nonwoven webs
WO2009012284A1 (en) 2007-07-16 2009-01-22 Groupo P.I. Mabe, S.A. De C.V. Environmentally sensitive diapers manufactured with renewable resources
US20090060860A1 (en) 2007-08-31 2009-03-05 Eva Almenar Beta-cyclodextrins as nucleating agents for poly(lactic acid)
US8287677B2 (en) 2008-01-31 2012-10-16 Kimberly-Clark Worldwide, Inc. Printable elastic composite
US20110028062A1 (en) 2008-02-14 2011-02-03 Chester Stephen O Bicomponent fibers, textile sheets and use thereof
EP2270073B1 (en) 2008-03-27 2013-05-22 Toray Industries, Inc. Process for producing thermoplastic resin composition and thermoplastic resin composition
DE102008022289B4 (de) 2008-04-25 2010-07-29 Deutsches Zentrum für Luft- und Raumfahrt e.V. Flugkörper
IT1387503B (it) 2008-05-08 2011-04-13 Novamont Spa Poliestere biodegradabile alifatico-aromatico
BRPI0822434B1 (pt) 2008-05-30 2018-05-29 Kimberly-Clark Worldwide, Inc. Trama não tecida, artigo absorvente e método para formar a trama não tecida
KR100962387B1 (ko) 2008-06-05 2010-06-10 제일모직주식회사 폴리유산 수지 조성물
WO2009151437A1 (en) 2008-06-09 2009-12-17 Kimberly-Clark Worldwide, Inc. Humidification of polylactic acid for fiber formation
WO2009151439A1 (en) 2008-06-09 2009-12-17 Kimberly-Clark Worldwide, Inc. Method for forming biodegradable polylactic acids for use in forming fibers
US8268913B2 (en) 2008-06-30 2012-09-18 Fina Technology, Inc. Polymeric blends and methods of using same
US8545971B2 (en) 2008-06-30 2013-10-01 Fina Technology, Inc. Polymeric compositions comprising polylactic acid and methods of making and using same
US8759446B2 (en) 2008-06-30 2014-06-24 Fina Technology, Inc. Compatibilized polypropylene and polylactic acid blends and methods of making and using same
US8796383B2 (en) 2008-06-30 2014-08-05 Fina Technology, Inc. Polypropylene and polylactic acid formulations for heat seal applications
US8530577B2 (en) 2008-06-30 2013-09-10 Fina Technology, Inc. Compatibilized polypropylene heterophasic copolymer and polylactic acid blends for injection molding applications
US20110132519A1 (en) 2008-06-30 2011-06-09 Fina Technology, Inc. Polyolefin polylactic acid blends for easy open packaging applications
US8642701B2 (en) 2008-06-30 2014-02-04 Fina Technology, Inc. Polypropylene and polylactic acid blends of injection stretch blow molding applications
CN102165013B (zh) 2008-09-29 2013-04-24 巴斯夫欧洲公司 可生物降解的聚合物混合物
WO2010056421A1 (en) 2008-11-13 2010-05-20 Clemson University Research Foundation Copolymer including polylactic acid, acrylic acid and polyethylene glycol and processes for making the same
US20110046281A1 (en) 2009-08-19 2011-02-24 Cereplast, Inc. Polymer compositions having poly(lactic acid)
US8658069B2 (en) * 2009-11-09 2014-02-25 Basf Se Method for producing shrink films
AU2010339869B2 (en) 2009-12-17 2014-12-18 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs and methods of making and using the same
US8466337B2 (en) 2009-12-22 2013-06-18 Kimberly-Clark Worldwide, Inc. Biodegradable and breathable film
CN102115576B (zh) * 2009-12-31 2014-09-17 金伯利-克拉克环球有限公司 天然生物聚合物热塑性膜
US20110251346A1 (en) 2010-04-12 2011-10-13 Fina Technology, Inc. Biodegradable Polymeric Compositions and Methods of Making and Using the Same
CN103025803A (zh) * 2010-07-30 2013-04-03 东丽株式会社 聚乳酸系树脂片和成型品
US20120164905A1 (en) 2010-08-13 2012-06-28 Kimberly-Clark Worldwide, Inc. Modified Polylactic Acid Fibers
US8936740B2 (en) 2010-08-13 2015-01-20 Kimberly-Clark Worldwide, Inc. Modified polylactic acid fibers
US10753023B2 (en) 2010-08-13 2020-08-25 Kimberly-Clark Worldwide, Inc. Toughened polylactic acid fibers
JP2010280921A (ja) * 2010-09-24 2010-12-16 Toray Ind Inc 白色ポリ乳酸フィルム
US20120214944A1 (en) 2011-02-18 2012-08-23 Fina Technology, Inc. Polyolefin polylactic acid in-situ blends
US8628718B2 (en) * 2011-02-18 2014-01-14 Fina Technology, Inc. Modified polylactic acid, polymeric blends and methods of making the same
US10858762B2 (en) 2012-02-10 2020-12-08 Kimberly-Clark Worldwide, Inc. Renewable polyester fibers having a low density
US8975305B2 (en) 2012-02-10 2015-03-10 Kimberly-Clark Worldwide, Inc. Rigid renewable polyester compositions having a high impact strength and tensile elongation
US8637130B2 (en) 2012-02-10 2014-01-28 Kimberly-Clark Worldwide, Inc. Molded parts containing a polylactic acid composition
US20130210621A1 (en) 2012-02-10 2013-08-15 Kimberly-Clark Worldwide, Inc. Breathable Film Formed from a Renewable Polyester
US9040598B2 (en) 2012-02-10 2015-05-26 Kimberly-Clark Worldwide, Inc. Renewable polyester compositions having a low density

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EP2812381A4 (en) 2015-10-07
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US20130209770A1 (en) 2013-08-15
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US8980964B2 (en) 2015-03-17
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