MX2020005084A - Proceso de hidroformilacion. - Google Patents

Proceso de hidroformilacion.

Info

Publication number
MX2020005084A
MX2020005084A MX2020005084A MX2020005084A MX2020005084A MX 2020005084 A MX2020005084 A MX 2020005084A MX 2020005084 A MX2020005084 A MX 2020005084A MX 2020005084 A MX2020005084 A MX 2020005084A MX 2020005084 A MX2020005084 A MX 2020005084A
Authority
MX
Mexico
Prior art keywords
reaction zone
weight percent
hydroformylation process
organophosphite
rhodium
Prior art date
Application number
MX2020005084A
Other languages
English (en)
Inventor
Michael A Brammer
Marinus A Bigi
Original Assignee
Dow Technology Investments Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Technology Investments Llc filed Critical Dow Technology Investments Llc
Publication of MX2020005084A publication Critical patent/MX2020005084A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/86—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

La presente invención se refiere a procesos de hidroformilación para producir aldehídos. En algunas modalidades, el proceso comprende poner en contacto en una zona de reacción reactivos que comprenden una olefina, hidrógeno y CO en presencia de un catalizador a base de rodio-organofosfito, opcionalmente con ligando organofosfito libre, y 0.1 a 3 por ciento en peso, en función del peso total del fluido en la zona de reacción, de ciertos polímeros especificados en la presente, de modo que la solubilidad del polímero en el aldehído sea mayor o igual a 1 por ciento en peso a 40°C.
MX2020005084A 2017-12-07 2018-11-29 Proceso de hidroformilacion. MX2020005084A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762595868P 2017-12-07 2017-12-07
PCT/US2018/062985 WO2019112866A1 (en) 2017-12-07 2018-11-29 Hydroformylation process

Publications (1)

Publication Number Publication Date
MX2020005084A true MX2020005084A (es) 2020-08-13

Family

ID=64665423

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2020005084A MX2020005084A (es) 2017-12-07 2018-11-29 Proceso de hidroformilacion.

Country Status (12)

Country Link
US (1) US11111198B2 (es)
EP (1) EP3720837B1 (es)
JP (1) JP7187556B2 (es)
KR (1) KR20200096545A (es)
CN (1) CN111344274B (es)
BR (1) BR112020009739A2 (es)
CA (1) CA3083752A1 (es)
MX (1) MX2020005084A (es)
PL (1) PL3720837T3 (es)
TW (1) TWI793216B (es)
WO (1) WO2019112866A1 (es)
ZA (1) ZA202003651B (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW202126385A (zh) 2019-11-05 2021-07-16 美商陶氏科技投資有限公司 自氫甲醯化製程回收銠之方法
CN114929660A (zh) 2019-12-19 2022-08-19 陶氏技术投资有限责任公司 用于制备异戊二烯和包含至少六个碳原子的单烯烃的方法
CN114950551B (zh) * 2022-05-31 2024-05-07 中国海洋石油集团有限公司 用于烯烃氢甲酰化的单亚磷酸酯聚合物催化剂及其制备方法和应用
WO2023249928A1 (en) 2022-06-22 2023-12-28 Eli Lilly And Company Fluid delivery cassette

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3415906A (en) 1964-05-29 1968-12-10 Hooker Chemical Corp Phosphite phospholane and phosphorinane compounds
US3527809A (en) 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US4388476A (en) 1981-05-01 1983-06-14 Eastman Kodak Company Hydroformylation process with rhodium catalyst and oxygen stabilization thereof
ATE28183T1 (de) 1982-06-11 1987-07-15 Davy Mckee London Hydroformylierungsverfahren.
GB8334359D0 (en) 1983-12-23 1984-02-01 Davy Mckee Ltd Process
US4599206A (en) 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US4737588A (en) 1984-12-28 1988-04-12 Union Carbide Corporation Transition metal complex catalyzed reactions
US4668651A (en) 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4748261A (en) 1985-09-05 1988-05-31 Union Carbide Corporation Bis-phosphite compounds
US4774361A (en) 1986-05-20 1988-09-27 Union Carbide Corporation Transition metal complex catalyzed reactions
DE3924720A1 (de) * 1989-07-26 1991-01-31 Basf Ag Hydroformylierungsverfahren
US5288918A (en) * 1992-09-29 1994-02-22 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
JP3291421B2 (ja) * 1995-08-18 2002-06-10 ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション ヒドロホルミル化方法におけるホスフィットリガンドの安定化
US5731472A (en) * 1995-12-06 1998-03-24 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
DE19700804C1 (de) * 1997-01-13 1998-08-06 Hoechst Ag Verfahren zur Herstellung von Aldehyden durch Hydroformylierung olefinischer Verbindungen mit 6 bis 16 Kohlenstoffatomen in Anwesenheit einer Rhodium und sulfonierte Triarylphosphine als Katalysator enthaltenden wäßrigen Phase
US6090987A (en) * 1998-07-06 2000-07-18 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
DE19840255A1 (de) * 1998-09-03 2000-03-09 Basf Ag Katalysator umfassend einen wasserlöslichen Übergangsmetallkomplex
JP3885414B2 (ja) 1999-06-09 2007-02-21 三菱化学株式会社 アルデヒド類の製造方法
DE10220801A1 (de) 2002-05-10 2003-11-20 Oxeno Olefinchemie Gmbh Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste
DE10327434A1 (de) * 2002-08-31 2004-03-04 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von olefinisch ungesättigten Verbindungen, insbesondere Olefinen in Gegenwart cyclischer Kohlensäureester
EP2021312B1 (en) * 2006-05-15 2014-10-15 Dow Global Technologies LLC Hydroformylation process and product separation with improved recovery of rhodium
CN102266796A (zh) * 2006-12-22 2011-12-07 中国科学院上海有机化学研究所 一种丙烯氢甲酰化催化体系和方法
ES2558465T3 (es) 2008-07-03 2016-02-04 Dow Technology Investments Llc Procedimiento de tratamiento de una descarga de hidroformilación
KR101656899B1 (ko) * 2008-11-14 2016-09-12 유니버시티 오브 캔사스 중합체-지지된 전이 금속 촉매 복합체와 사용방법
EP2681180B1 (en) * 2011-03-04 2017-08-23 The University of Kansas Single solvent gas expanded hydroformylation process
CN104045532B (zh) * 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
WO2015085503A1 (zh) * 2013-12-11 2015-06-18 中国科学院大连化学物理研究所 一种采用固体多相催化剂的用于烯烃氢甲酰化反应的方法
JP6199728B2 (ja) 2013-12-17 2017-09-20 片岡物産株式会社 折り込みバッグの製造装置および折り込みバッグの製造方法
DE102015202722A1 (de) 2014-05-20 2015-11-26 Evonik Degussa Gmbh Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Monophosphit-Gemischen
EP3031816B1 (de) 2014-12-04 2019-02-27 Evonik Degussa GmbH Terphenyl-2-oxy-phosphite als liganden in hydroformylierungs-katalysatoren
MY184826A (en) 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process

Also Published As

Publication number Publication date
CA3083752A1 (en) 2019-06-13
US20210179523A1 (en) 2021-06-17
JP7187556B2 (ja) 2022-12-12
PL3720837T3 (pl) 2023-05-02
WO2019112866A1 (en) 2019-06-13
EP3720837A1 (en) 2020-10-14
CN111344274B (zh) 2023-03-10
CN111344274A (zh) 2020-06-26
TW201925153A (zh) 2019-07-01
RU2020120072A (ru) 2021-12-20
JP2021505536A (ja) 2021-02-18
US11111198B2 (en) 2021-09-07
KR20200096545A (ko) 2020-08-12
TWI793216B (zh) 2023-02-21
ZA202003651B (en) 2022-09-28
BR112020009739A2 (pt) 2020-11-03
EP3720837B1 (en) 2023-03-08

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