MX2020002792A - Un catalizador y un proceso para la produccion de acidos o esteres carboxilicos insaturados etilenicamente. - Google Patents
Un catalizador y un proceso para la produccion de acidos o esteres carboxilicos insaturados etilenicamente.Info
- Publication number
- MX2020002792A MX2020002792A MX2020002792A MX2020002792A MX2020002792A MX 2020002792 A MX2020002792 A MX 2020002792A MX 2020002792 A MX2020002792 A MX 2020002792A MX 2020002792 A MX2020002792 A MX 2020002792A MX 2020002792 A MX2020002792 A MX 2020002792A
- Authority
- MX
- Mexico
- Prior art keywords
- catalyst
- hafnium
- zirconium
- support
- ethylenically unsaturated
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 6
- 150000002148 esters Chemical class 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 150000001735 carboxylic acids Chemical class 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 4
- 229910052751 metal Inorganic materials 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 4
- 239000003607 modifier Substances 0.000 abstract 4
- 229910052726 zirconium Inorganic materials 0.000 abstract 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 3
- 229910052735 hafnium Inorganic materials 0.000 abstract 3
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 3
- 125000005372 silanol group Chemical group 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910020175 SiOH Inorganic materials 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 150000002363 hafnium compounds Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
- B01J23/04—Alkali metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
- C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/313—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of doubly bound oxygen containing functional groups, e.g. carboxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Un catalizador tiene un soporte de sílice modificada y comprende un metal modificador, circonio y/o hafnio, y un metal catalítico sobre el soporte modificado. El catalizador tiene al menos una proporción, normalmente, al menos un 25%, del metal modificador presente en restos que tienen un total de hasta 2 átomos del metal modificador. Los restos se pueden derivar de una fuente de cationes monoméricos y/o diméricos. Un método de producción:- proporciona un soporte de sílice con grupos silanol aislados con tratamiento opcional para proporcionar grupos silanol aislados (-SiOH) en un nivel de <2.5 grupos por nm2; poner en contacto el soporte de sílice tratado opcionalmente con un compuesto del metal modificador circonio o hafnio monomérico para conseguir la adsorción sobre el soporte; calcinar opcionalmente el soporte modificado durante un tiempo y una temperatura suficientes para convertir el compuesto de circonio o hafnio monomérico adsorbido sobre la superficie en un óxido o hidróxido de circonio o hafnio como preparación para la impregnación del catalizador.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB1714756.2A GB201714756D0 (en) | 2017-09-13 | 2017-09-13 | A catalyst and a process for the production of ethylenicallly unsaturated carboxylic acids or esters |
| PCT/GB2018/052606 WO2019053438A1 (en) | 2017-09-13 | 2018-09-13 | PROCESS AND CATALYST FOR PRODUCTION OF CARBOXYLIC ACIDS OR ESTERS WITH ETHYLENE UNSATURATION |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2020002792A true MX2020002792A (es) | 2020-07-22 |
Family
ID=60117209
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2020002792A MX2020002792A (es) | 2017-09-13 | 2018-09-13 | Un catalizador y un proceso para la produccion de acidos o esteres carboxilicos insaturados etilenicamente. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US11602733B2 (es) |
| EP (1) | EP3681628A1 (es) |
| JP (2) | JP7384788B2 (es) |
| KR (1) | KR20200053567A (es) |
| CN (1) | CN111344059B (es) |
| BR (1) | BR112020004960A2 (es) |
| CA (1) | CA3074006A1 (es) |
| GB (1) | GB201714756D0 (es) |
| MX (1) | MX2020002792A (es) |
| SG (1) | SG11202001886QA (es) |
| WO (1) | WO2019053438A1 (es) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB201714756D0 (en) | 2017-09-13 | 2017-10-25 | Lucite Int Uk Ltd | A catalyst and a process for the production of ethylenicallly unsaturated carboxylic acids or esters |
| SG11202109990XA (en) * | 2019-03-12 | 2021-10-28 | Mitsubishi Chem Corp | Catalyst, method for preparing catalyst, and method for producing unsaturated carboxylic acid and/or unsaturated carboxylic acid ester |
| GB201903455D0 (en) * | 2019-03-13 | 2019-04-24 | Lucite Int Uk Ltd | A process for the protection of a catalyst, a catalyst therefrom and a process for production of ethylenically unsaturated carboxlyic acids or esters |
| GB201910754D0 (en) * | 2019-07-26 | 2019-09-11 | Lucite Int Uk Ltd | A catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters |
| CN112707814A (zh) * | 2019-10-25 | 2021-04-27 | 中国石油化工股份有限公司 | 用醋酸甲酯制备丙烯酸甲酯的方法 |
| US11806694B2 (en) | 2020-03-12 | 2023-11-07 | Mitsubishi Chemical UK Limited | Catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters |
| US20220105496A1 (en) * | 2020-09-17 | 2022-04-07 | Sk Innovation Co., Ltd. | Cobalt-Based Single-Atom Dehydrogenation Catalysts Having High Selectivity and Regenerability and Method for Producing Corresponding Olefins from Paraffins Using the Same |
| WO2022196717A1 (ja) * | 2021-03-16 | 2022-09-22 | 積水化学工業株式会社 | 触媒、触媒の製造方法、ジエン化合物の製造方法、ポリマーの製造方法、ポリマー成形品の製造方法、触媒性能測定方法および長寿命化方法 |
| EP4353355A1 (en) | 2021-06-01 | 2024-04-17 | Mitsubishi Chemical Corporation | Catalyst, method for producing catalyst, and method for producing unsaturated carboxylic acid and/or unsaturated carboxylic acid ester |
| CN115814841A (zh) * | 2021-10-31 | 2023-03-21 | 浙江新和成股份有限公司 | 功能化介孔材料催化剂及其制备方法和应用 |
| CN117205909A (zh) * | 2023-09-05 | 2023-12-12 | 中国科学院过程工程研究所 | 一种聚合物修饰的羟醛缩合催化剂的制备方法及应用 |
| CN117563577A (zh) * | 2023-11-16 | 2024-02-20 | 中国科学院过程工程研究所 | 一种二氧化硅载体表面羟基调控方法应用于合成甲基丙烯酸甲酯催化剂的制备 |
| CN117654466B (zh) * | 2024-02-01 | 2024-04-23 | 浙江新和成股份有限公司 | 催化剂及其制备方法、烯属不饱和酸或其酯的制备方法 |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3933888A (en) | 1972-10-06 | 1976-01-20 | Rohm And Haas Company | Production of unsaturated acids, esters and nitriles, and catalyst therefor |
| CA1090764A (en) * | 1977-09-21 | 1980-12-02 | Yu-Tang Hwang | Polymerization catalyst and method |
| US4308172A (en) | 1980-05-21 | 1981-12-29 | Phillips Petroleum Company | Chemical dehydroxylation of silica |
| US4357451A (en) | 1980-05-21 | 1982-11-02 | Phillips Petroleum Company | Chemical dehydroxylation of silica |
| US4412914A (en) * | 1981-08-10 | 1983-11-01 | Ashland Oil, Inc. | Endothermic removal of coke deposited on sorbent materials during carbo-metallic oil conversion |
| US5069816A (en) | 1988-01-11 | 1991-12-03 | Mmii Incorporated | Zirconium silica hydrogel compositions and methods of preparation |
| US5583085A (en) | 1994-06-13 | 1996-12-10 | W. R. Grace & Co.-Conn. | Preparation of dehydroxylated supports |
| ES2164774T3 (es) | 1994-08-03 | 2002-03-01 | Exxonmobil Chem Patents Inc | Composicion catalitica ionica soportada. |
| IT1272939B (it) * | 1995-02-01 | 1997-07-01 | Enichem Spa | Catalizzatore metallocenico supportato per la (co)polimerizzazione delle olefine |
| GB9807498D0 (en) * | 1998-04-08 | 1998-06-10 | Ici Plc | Production of unsaturated acids therfore and catalysts therfor |
| JP2001087650A (ja) * | 1999-09-22 | 2001-04-03 | Suzuki Motor Corp | 触媒担体及び触媒製造方法 |
| JP2002244781A (ja) | 2001-02-15 | 2002-08-30 | Wacom Co Ltd | 入力システム、プログラム、及び、記録媒体 |
| US6887822B2 (en) | 2001-09-25 | 2005-05-03 | Pq Corporation | Method for making silica supported, crush-resistant catalysts |
| WO2007005676A2 (en) * | 2005-07-01 | 2007-01-11 | Albemarle Corporation | Activator compositions and their use in catalysts and olefin polymerization |
| US7696125B2 (en) * | 2005-07-06 | 2010-04-13 | Lee Chang Yung Chemical Industry Corporation | Catalyst and process for preparing carboxylic acid esters |
| DE102007025223A1 (de) * | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| BRPI0801595A2 (pt) * | 2007-05-31 | 2009-03-17 | Goodyear Tire & Rubber | elastÈmeros contendo cargas siliciosas metalizadas |
| BRPI0814023A2 (pt) | 2007-07-05 | 2017-10-03 | Grace Gmbh & Co Kg | Método para fabricar catalisadores suportados por óxido inorgânico |
| GB0812297D0 (en) * | 2008-07-04 | 2008-08-13 | Lucite Int Uk Ltd | Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds |
| GB201011091D0 (en) | 2010-07-01 | 2010-08-18 | Lucite Int Uk Ltd | A catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters |
| CN103221380B (zh) * | 2010-10-07 | 2015-04-29 | 罗门哈斯公司 | 生产甲基丙烯酸酯的方法 |
| JP2013053128A (ja) | 2011-08-11 | 2013-03-21 | Sumitomo Chemical Co Ltd | メタクリル酸化合物の製造方法及び触媒 |
| GB201214122D0 (en) * | 2012-08-07 | 2012-09-19 | Oxford Catalysts Ltd | Treating of catalyst support |
| FR2997397B1 (fr) | 2012-10-29 | 2014-11-07 | Arkema France | Procede de synthese directe d'aldehydes insatures a partir de melanges d'alcools |
| US9192919B2 (en) * | 2013-03-14 | 2015-11-24 | Uchicago Argonne, Llc | Selective alkane activation with single-site atoms on amorphous support |
| US9217049B2 (en) * | 2013-11-19 | 2015-12-22 | Chevron Phillips Chemical Company Lp | Dual catalyst systems for producing polymers with a broad molecular weight distribution and a uniform short chain branch distribution |
| CN103801280A (zh) * | 2014-01-26 | 2014-05-21 | 上海华谊（集团）公司 | 一种Cs负载型硅基催化剂及其制备方法和应用 |
| GB201714756D0 (en) | 2017-09-13 | 2017-10-25 | Lucite Int Uk Ltd | A catalyst and a process for the production of ethylenicallly unsaturated carboxylic acids or esters |
-
2017
- 2017-09-13 GB GBGB1714756.2A patent/GB201714756D0/en not_active Ceased
-
2018
- 2018-09-13 SG SG11202001886QA patent/SG11202001886QA/en unknown
- 2018-09-13 US US16/646,763 patent/US11602733B2/en active Active
- 2018-09-13 CN CN201880073462.2A patent/CN111344059B/zh active Active
- 2018-09-13 MX MX2020002792A patent/MX2020002792A/es unknown
- 2018-09-13 JP JP2020514951A patent/JP7384788B2/ja active Active
- 2018-09-13 WO PCT/GB2018/052606 patent/WO2019053438A1/en unknown
- 2018-09-13 CA CA3074006A patent/CA3074006A1/en active Pending
- 2018-09-13 KR KR1020207010608A patent/KR20200053567A/ko not_active Application Discontinuation
- 2018-09-13 EP EP18773567.5A patent/EP3681628A1/en active Pending
- 2018-09-13 BR BR112020004960-3A patent/BR112020004960A2/pt active IP Right Grant
-
2023
- 2023-07-11 JP JP2023113389A patent/JP2023153789A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US20200269214A1 (en) | 2020-08-27 |
| KR20200053567A (ko) | 2020-05-18 |
| CN111344059A (zh) | 2020-06-26 |
| US11602733B2 (en) | 2023-03-14 |
| RU2020113238A (ru) | 2021-10-15 |
| JP7384788B2 (ja) | 2023-11-21 |
| CA3074006A1 (en) | 2019-03-21 |
| BR112020004960A2 (pt) | 2020-09-15 |
| WO2019053438A1 (en) | 2019-03-21 |
| CN111344059B (zh) | 2024-04-19 |
| EP3681628A1 (en) | 2020-07-22 |
| JP2023153789A (ja) | 2023-10-18 |
| SG11202001886QA (en) | 2020-03-30 |
| JP2020533170A (ja) | 2020-11-19 |
| RU2020113238A3 (es) | 2021-10-28 |
| GB201714756D0 (en) | 2017-10-25 |
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