MX356173B - Un proceso para la produccion de acidos carboxilicos o esteres etilenicamente insaturados y un catalizador para los mismos. - Google Patents

Un proceso para la produccion de acidos carboxilicos o esteres etilenicamente insaturados y un catalizador para los mismos.

Info

Publication number
MX356173B
MX356173B MX2014008392A MX2014008392A MX356173B MX 356173 B MX356173 B MX 356173B MX 2014008392 A MX2014008392 A MX 2014008392A MX 2014008392 A MX2014008392 A MX 2014008392A MX 356173 B MX356173 B MX 356173B
Authority
MX
Mexico
Prior art keywords
catalyst
ethylenically unsaturated
unsaturated carboxylic
esters
production
Prior art date
Application number
MX2014008392A
Other languages
English (en)
Other versions
MX2014008392A (es
Inventor
Ziemian Sabina
Andrew York Ian
Original Assignee
Lucite Int Uk Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lucite Int Uk Ltd filed Critical Lucite Int Uk Ltd
Publication of MX2014008392A publication Critical patent/MX2014008392A/es
Publication of MX356173B publication Critical patent/MX356173B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/10—Chlorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B01J27/1806—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with alkaline or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/038—Precipitation; Co-precipitation to form slurries or suspensions, e.g. a washcoat
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/16—Phosphorus; Compounds thereof containing oxygen
    • C07C2527/18—Phosphorus; Compounds thereof containing oxygen with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se describe un método para producir un ácido carboxílico o éster etilénicamente insaturado, usualmente, un ácido carboxílico o éster a, ß etilénicamente nsaturado. El método comprende las etapas de contactar formaldehído, o una fuente de formaldehído, con un ácido carboxílico o un éster en presencia de un catalizador y, opcionalmente, en presencia de un alcohol. El catalizador comprende cristales de bario en forma tipo lámina o placa o una fuente de los mismos. También se describe un sistema catalizador. El sistema catalizador comprende un catalizador de fosfato de bario cristalino y, opcionalmente, un soporte catalizador.
MX2014008392A 2012-01-13 2013-01-14 Un proceso para la produccion de acidos carboxilicos o esteres etilenicamente insaturados y un catalizador para los mismos. MX356173B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1200551.8A GB201200551D0 (en) 2012-01-13 2012-01-13 A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor
PCT/GB2013/050062 WO2013104924A1 (en) 2012-01-13 2013-01-14 A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor

Publications (2)

Publication Number Publication Date
MX2014008392A MX2014008392A (es) 2014-08-22
MX356173B true MX356173B (es) 2018-05-17

Family

ID=45813970

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014008392A MX356173B (es) 2012-01-13 2013-01-14 Un proceso para la produccion de acidos carboxilicos o esteres etilenicamente insaturados y un catalizador para los mismos.

Country Status (17)

Country Link
US (1) US9199907B2 (es)
EP (1) EP2802552B1 (es)
JP (1) JP6169613B2 (es)
KR (1) KR102037772B1 (es)
CN (1) CN104039751B (es)
AU (1) AU2013208789B2 (es)
BR (1) BR112014016973B1 (es)
CA (1) CA2862246C (es)
ES (1) ES2675968T3 (es)
GB (1) GB201200551D0 (es)
IN (1) IN2014MN01558A (es)
MX (1) MX356173B (es)
MY (1) MY168415A (es)
RU (1) RU2621687C2 (es)
SG (1) SG11201403610YA (es)
TW (1) TWI616233B (es)
WO (1) WO2013104924A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103209764B (zh) * 2010-11-11 2016-04-20 璐彩特国际英国有限公司 用于生产烯键式不饱和羧酸或酯的方法及其催化剂
GB201506308D0 (en) 2015-04-14 2015-05-27 Lucite Int Uk Ltd A process for the production of ethylenically unsaturated carboxylic acids or esters
CN107126970B (zh) * 2017-04-25 2019-10-01 江苏大学 一种Nd-VPO/SiO2催化剂及其制备方法和用途
CN108993612A (zh) * 2018-08-06 2018-12-14 杨彩花 一种用于制备5-己烯酸的催化剂

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2859240A (en) * 1956-01-12 1958-11-04 Minnesota Mining & Mfg Production of acrylates by catalytic dehydration of lactic acid and alkyl lactates
GB865379A (en) * 1956-04-04 1961-04-19 Minnesota Mining & Mfg Improved acrylate synthesis
US3014958A (en) * 1960-01-15 1961-12-26 Du Pont Preparation of unsaturated esters
JPS4616728B1 (es) * 1967-04-08 1971-05-08
US4118588A (en) * 1976-04-10 1978-10-03 Basf Aktiengesellschaft Manufacture of methacrylic acid and methyl methacrylate
CA1249576A (en) * 1984-06-25 1989-01-31 Gary P. Hagen Coformed catalyst
US4967016A (en) * 1989-05-19 1990-10-30 Shell Oil Company Alkoxylation process catalyzed by barium phosphate
GB9807498D0 (en) * 1998-04-08 1998-06-10 Ici Plc Production of unsaturated acids therfore and catalysts therfor
CN101186576A (zh) * 2007-11-26 2008-05-28 南京工业大学 一种丙烯酸酯的制备方法
TWI461476B (zh) * 2008-11-14 2014-11-21 Nisshinbo Holdings Inc A resin composition, and a transparent resin molded article and a coating film using the same
GB201011092D0 (en) * 2010-07-01 2010-08-18 Lucite Int Uk Ltd A catalyst system and a process for the production of ethylenically unsaturated carboxylic acids or esters
CN103209764B (zh) * 2010-11-11 2016-04-20 璐彩特国际英国有限公司 用于生产烯键式不饱和羧酸或酯的方法及其催化剂

Also Published As

Publication number Publication date
CN104039751A (zh) 2014-09-10
MX2014008392A (es) 2014-08-22
KR102037772B1 (ko) 2019-10-29
GB201200551D0 (en) 2012-02-29
RU2621687C2 (ru) 2017-06-07
AU2013208789B2 (en) 2017-02-02
EP2802552A1 (en) 2014-11-19
US20140364645A1 (en) 2014-12-11
MY168415A (en) 2018-11-09
KR20140111329A (ko) 2014-09-18
BR112014016973A2 (pt) 2017-06-13
RU2014133183A (ru) 2016-03-10
CA2862246C (en) 2020-06-02
WO2013104924A1 (en) 2013-07-18
JP2015508410A (ja) 2015-03-19
CA2862246A1 (en) 2013-07-18
JP6169613B2 (ja) 2017-07-26
US9199907B2 (en) 2015-12-01
CN104039751B (zh) 2017-04-12
TWI616233B (zh) 2018-03-01
SG11201403610YA (en) 2014-09-26
TW201334869A (zh) 2013-09-01
BR112014016973A8 (pt) 2017-07-04
EP2802552B1 (en) 2018-03-28
AU2013208789A1 (en) 2014-07-24
ES2675968T3 (es) 2018-07-16
IN2014MN01558A (es) 2015-05-08
BR112014016973B1 (pt) 2019-12-24

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