BR112014016973A8 - método para a produção de um ácido ou éster carboxílico etilenicamente insaturado, e, sistema de catalisador - Google Patents

método para a produção de um ácido ou éster carboxílico etilenicamente insaturado, e, sistema de catalisador

Info

Publication number
BR112014016973A8
BR112014016973A8 BR112014016973A BR112014016973A BR112014016973A8 BR 112014016973 A8 BR112014016973 A8 BR 112014016973A8 BR 112014016973 A BR112014016973 A BR 112014016973A BR 112014016973 A BR112014016973 A BR 112014016973A BR 112014016973 A8 BR112014016973 A8 BR 112014016973A8
Authority
BR
Brazil
Prior art keywords
ester
catalyst
carboxylic acid
ethylenically unsaturated
unsaturated carboxylic
Prior art date
Application number
BR112014016973A
Other languages
English (en)
Other versions
BR112014016973B1 (pt
BR112014016973A2 (pt
Inventor
Andrew York Ian
Ziemian Sabina
Original Assignee
Lucite Int Uk Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lucite Int Uk Ltd filed Critical Lucite Int Uk Ltd
Publication of BR112014016973A2 publication Critical patent/BR112014016973A2/pt
Publication of BR112014016973A8 publication Critical patent/BR112014016973A8/pt
Publication of BR112014016973B1 publication Critical patent/BR112014016973B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/10—Chlorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B01J27/1806—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with alkaline or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/038—Precipitation; Co-precipitation to form slurries or suspensions, e.g. a washcoat
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/16—Phosphorus; Compounds thereof containing oxygen
    • C07C2527/18—Phosphorus; Compounds thereof containing oxygen with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1 / 1 resumo “mã‰todo para a produã‡ãƒo de um ãcido ou ã‰ster carboxãlico etilenicamente insaturado, e, sistema de catalisador” um mã©todo de produã§ã£o de um ã¡cido ou ã©ster carboxã­lico etilenicamente insaturado, tipicamente î±, ãÿ etilenicamente insaturado ã© descrito. o mã©todo compreende as etapas de contatar formaldeã­do, ou uma fonte de formaldeã­do, com um ã¡cido ou ã©ster carboxã­lico na presenã§a de um catalisador e, opcionalmente, na presenã§a de um ã¡lcool. o catalisador compreende cristais de fosfato de bã¡rio conformados ou de tipo de folhas ou placas, ou uma fonte dos mesmos. um sistema catalisador tambã©m ã© descrito. o sistema catalisador compreende um catalisador de fosfato de bã¡rio cristalino e, opcionalmente, um suporte de catalisador.
BR112014016973A 2012-01-13 2013-01-14 método para a produção de um ácido ou éster carboxílico etilenicamente insaturado, e, sistema de catalisador BR112014016973B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1200551.8A GB201200551D0 (en) 2012-01-13 2012-01-13 A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor
PCT/GB2013/050062 WO2013104924A1 (en) 2012-01-13 2013-01-14 A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor

Publications (3)

Publication Number Publication Date
BR112014016973A2 BR112014016973A2 (pt) 2017-06-13
BR112014016973A8 true BR112014016973A8 (pt) 2017-07-04
BR112014016973B1 BR112014016973B1 (pt) 2019-12-24

Family

ID=45813970

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014016973A BR112014016973B1 (pt) 2012-01-13 2013-01-14 método para a produção de um ácido ou éster carboxílico etilenicamente insaturado, e, sistema de catalisador

Country Status (17)

Country Link
US (1) US9199907B2 (pt)
EP (1) EP2802552B1 (pt)
JP (1) JP6169613B2 (pt)
KR (1) KR102037772B1 (pt)
CN (1) CN104039751B (pt)
AU (1) AU2013208789B2 (pt)
BR (1) BR112014016973B1 (pt)
CA (1) CA2862246C (pt)
ES (1) ES2675968T3 (pt)
GB (1) GB201200551D0 (pt)
IN (1) IN2014MN01558A (pt)
MX (1) MX356173B (pt)
MY (1) MY168415A (pt)
RU (1) RU2621687C2 (pt)
SG (1) SG11201403610YA (pt)
TW (1) TWI616233B (pt)
WO (1) WO2013104924A1 (pt)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2637784B1 (en) * 2010-11-11 2022-05-18 Mitsubishi Chemical UK Limited A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor
GB201506308D0 (en) 2015-04-14 2015-05-27 Lucite Int Uk Ltd A process for the production of ethylenically unsaturated carboxylic acids or esters
CN107126970B (zh) * 2017-04-25 2019-10-01 江苏大学 一种Nd-VPO/SiO2催化剂及其制备方法和用途
CN108993612A (zh) * 2018-08-06 2018-12-14 杨彩花 一种用于制备5-己烯酸的催化剂

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2859240A (en) * 1956-01-12 1958-11-04 Minnesota Mining & Mfg Production of acrylates by catalytic dehydration of lactic acid and alkyl lactates
GB865379A (en) * 1956-04-04 1961-04-19 Minnesota Mining & Mfg Improved acrylate synthesis
US3014958A (en) * 1960-01-15 1961-12-26 Du Pont Preparation of unsaturated esters
JPS4616728B1 (pt) * 1967-04-08 1971-05-08
US4118588A (en) * 1976-04-10 1978-10-03 Basf Aktiengesellschaft Manufacture of methacrylic acid and methyl methacrylate
CA1249576A (en) * 1984-06-25 1989-01-31 Gary P. Hagen Coformed catalyst
US4967016A (en) * 1989-05-19 1990-10-30 Shell Oil Company Alkoxylation process catalyzed by barium phosphate
GB9807498D0 (en) * 1998-04-08 1998-06-10 Ici Plc Production of unsaturated acids therfore and catalysts therfor
CN101186576A (zh) * 2007-11-26 2008-05-28 南京工业大学 一种丙烯酸酯的制备方法
CN102216396B (zh) * 2008-11-14 2014-06-25 日清纺控股株式会社 树脂组合物和使用该树脂组合物的透明树脂成形体及涂膜
GB201011092D0 (en) * 2010-07-01 2010-08-18 Lucite Int Uk Ltd A catalyst system and a process for the production of ethylenically unsaturated carboxylic acids or esters
EP2637784B1 (en) * 2010-11-11 2022-05-18 Mitsubishi Chemical UK Limited A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor

Also Published As

Publication number Publication date
BR112014016973B1 (pt) 2019-12-24
EP2802552A1 (en) 2014-11-19
SG11201403610YA (en) 2014-09-26
CA2862246A1 (en) 2013-07-18
RU2621687C2 (ru) 2017-06-07
KR102037772B1 (ko) 2019-10-29
TWI616233B (zh) 2018-03-01
MY168415A (en) 2018-11-09
GB201200551D0 (en) 2012-02-29
MX356173B (es) 2018-05-17
CN104039751A (zh) 2014-09-10
BR112014016973A2 (pt) 2017-06-13
CA2862246C (en) 2020-06-02
MX2014008392A (es) 2014-08-22
AU2013208789B2 (en) 2017-02-02
EP2802552B1 (en) 2018-03-28
US9199907B2 (en) 2015-12-01
WO2013104924A1 (en) 2013-07-18
US20140364645A1 (en) 2014-12-11
JP2015508410A (ja) 2015-03-19
KR20140111329A (ko) 2014-09-18
ES2675968T3 (es) 2018-07-16
TW201334869A (zh) 2013-09-01
RU2014133183A (ru) 2016-03-10
JP6169613B2 (ja) 2017-07-26
AU2013208789A1 (en) 2014-07-24
IN2014MN01558A (pt) 2015-05-08
CN104039751B (zh) 2017-04-12

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Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06T Formal requirements before examination [chapter 6.20 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 14/01/2013, OBSERVADAS AS CONDICOES LEGAIS.

B25D Requested change of name of applicant approved

Owner name: MITSUBISHI CHEMICAL UK LIMITED (GB)

B25G Requested change of headquarter approved

Owner name: MITSUBISHI CHEMICAL UK LIMITED (GB)