MX2017009242A - Proceso para la alcoxicarbonilación de compuestos insaturados etilénicamente con ligandos de monofosfina. - Google Patents
Proceso para la alcoxicarbonilación de compuestos insaturados etilénicamente con ligandos de monofosfina.Info
- Publication number
- MX2017009242A MX2017009242A MX2017009242A MX2017009242A MX2017009242A MX 2017009242 A MX2017009242 A MX 2017009242A MX 2017009242 A MX2017009242 A MX 2017009242A MX 2017009242 A MX2017009242 A MX 2017009242A MX 2017009242 A MX2017009242 A MX 2017009242A
- Authority
- MX
- Mexico
- Prior art keywords
- alkyl
- cycloalkyl
- aryl
- heteroaryl
- ùoù
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 5
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 title abstract 4
- 239000003446 ligand Substances 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 238000007083 alkoxycarbonylation reaction Methods 0.000 title 1
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 abstract 11
- 125000006652 (C3-C12) cycloalkyl group Chemical group 0.000 abstract 7
- 125000006736 (C6-C20) aryl group Chemical group 0.000 abstract 4
- 125000006707 (C3-C12) heterocycloalkyl group Chemical group 0.000 abstract 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5045—Complexes or chelates of phosphines with metallic compounds or metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/62—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/12—Acetic acid esters
- C07C69/14—Acetic acid esters of monohydroxylic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/006—Palladium compounds
- C07F15/0066—Palladium compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/14—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La invención se refiere a un proceso que comprende los siguientes pasos de proceso: a) introducir un compuesto insaturado etilénicamente; b) agregar un ligando de monofosfina y un compuesto que comprende Pd, o agregar un complejo que comprende Pd y un ligando de monofosfina; c) agregar un alcohol alifático; d) suministrar CO; e) calentar la mezcla de reacción, el compuesto insaturado etilénicamente reaccionando para formar un éster; donde el ligando de monofosfina es un compuesto de la fórmula (I) ver fórmula (I) donde R1 se selecciona de -(C1-C12)-alquilo, -O-(C1-C12)-alquilo, -O-(C6-C20)-arilo, -(C6-C20)-arilo, -(C3-C12)-cicloalquilo, -(C3-C12)-heterocicloalqu ilo, -(C3-C20)-heteroarilo; R2 se selecciona de -(C6-C20)-arilo, -(C3-C12)-cicloalquilo, -(C3-C12)-heterocicloalquilo, -(C3-C20)-heteroarilo; R3 es -(C3-C20)-heteroarilo; y cada uno de R1, R2 y R3 puede sustituirse independientemente por uno o más sustituyentes seleccionados de -(C1-C12)-alquilo, -(C3-C12)-cicloalquilo,-(C3-C12)-heterocicloalquilo, -O-(C1-C12)-alquilo, -O-(C1-C12)-alquilo-(C6-C20)-arilo, -O-(C3-C12)-cicloalquilo, -S-(C1-C12)-alquilo, -S-(C3-C12)-cicloalquilo, -COO-(C1-C12)-alquilo, -COO-(C3-C12)-cicloalquilo, -CONH-(C1- C12)-alquilo, -CONH-(C3-C12)-cicloalquilo, -CO-(C1-C12)-alquilo, -CO-(C3-C12)-cicloalquilo, -N-[(C1-C12)-alquilo]2, -(C6-C20)- arilo, -(C6-C20)-arilo-(C1-C12)-alquilo, -(C6-C20)-arilo-O-(C1-C12 )-alquilo, -(C3-C20)-heteroarilo, -(C3-C20)-heteroarilo-(C1-C12)-a lquilo, -(C3-C20)-heteroarilo-O-(C1-C12)-alquilo, -COOH, -OH, -SO3H, -NH2, halógeno.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16180050.3A EP3272732B1 (de) | 2016-07-19 | 2016-07-19 | Verfahren zur alkoxycarbonylierung ethylenisch ungesättigter verbindungen mit monophosphinliganden |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2017009242A true MX2017009242A (es) | 2018-09-10 |
Family
ID=56497600
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2017009242A MX2017009242A (es) | 2016-07-19 | 2017-07-13 | Proceso para la alcoxicarbonilación de compuestos insaturados etilénicamente con ligandos de monofosfina. |
Country Status (12)
Country | Link |
---|---|
US (1) | US10544174B2 (es) |
EP (1) | EP3272732B1 (es) |
JP (1) | JP6467004B2 (es) |
KR (1) | KR102007753B1 (es) |
CN (1) | CN107628951A (es) |
CA (1) | CA2973451C (es) |
ES (1) | ES2754370T3 (es) |
MX (1) | MX2017009242A (es) |
MY (1) | MY178581A (es) |
PL (1) | PL3272732T3 (es) |
SG (1) | SG10201705854XA (es) |
TW (1) | TWI668227B (es) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3581558A1 (de) * | 2018-06-14 | 2019-12-18 | Evonik Operations GmbH | Verfahren zur alkoxycarbonylierung von diazoniumsalzen unter verwendung von tetraphenyl-bisphosphinen |
EP3581557A1 (de) * | 2018-06-14 | 2019-12-18 | Evonik Operations GmbH | Verfahren zur alkoxycarbonylierung von diazoniumsalzen unter verwendung von cyclohexyl-bisphosphinen |
EP3581556A1 (de) * | 2018-06-14 | 2019-12-18 | Evonik Operations GmbH | Verfahren zur alkoxycarbonylierung von diazoniumsalzen unter verwendung von triphenyl-monophosphinen |
EP3581560A1 (de) * | 2018-06-14 | 2019-12-18 | Evonik Operations GmbH | Verfahren zur alkoxycarbonylierung von diazoniumsalzen unter verwendung von bisphosphiten |
EP3581559A1 (de) * | 2018-06-14 | 2019-12-18 | Evonik Operations GmbH | Verfahren zur alkoxycarbonylierung von diazoniumsalzen unter verwendung von triphenyl-monophosphiten |
US11008275B2 (en) * | 2019-06-12 | 2021-05-18 | Evonik Operations Gmbh | Process for preparing carboxylic acids or salts thereof from hydrocarbons |
EP4001255A1 (de) * | 2020-11-23 | 2022-05-25 | Evonik Operations GmbH | Ru-katalysierte domino hydroformylierung/hydrierung/veresterung unter einsatz von phosphin-liganden |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8705699D0 (en) * | 1987-03-11 | 1987-04-15 | Shell Int Research | Carbonylation of olefinically unsaturated compounds |
KR0148012B1 (ko) | 1989-03-03 | 1998-08-17 | 오노 알버어스 | 신규한 포스핀으로 구성되는 촉매시스템 및 이를 이용한 아세틸렌형 또는 올레핀형 불포화화합물의 카르보닐화방법 |
CN1024635C (zh) * | 1989-03-03 | 1994-05-25 | 国际壳牌研究有限公司 | 羰基化催化剂及其应用 |
GB9002521D0 (en) | 1990-02-05 | 1990-04-04 | Shell Int Research | Carbonylation catalyst system |
JPH08299803A (ja) * | 1995-03-07 | 1996-11-19 | Daicel Chem Ind Ltd | カルボニル化触媒系およびそれを用いたカルボニル化方法 |
WO1997017320A1 (en) | 1995-11-03 | 1997-05-15 | Shell Internationale Research Maatschappij B.V. | Carbonylation reactions |
DE10322408A1 (de) | 2003-05-16 | 2004-12-02 | Degussa Ag | Stickstoffhaltige monodentate Phosphine und deren Verwendung in der Katalyse |
EP1844765B1 (en) | 2003-06-13 | 2015-01-21 | Skendi Finance, Ltd. | Slow release estradiol-progesterone formulation |
JP2008247745A (ja) | 2007-03-29 | 2008-10-16 | Sumitomo Chemical Co Ltd | メタクリル酸エステルの製造方法 |
GB201000078D0 (en) | 2010-01-05 | 2010-02-17 | Lucite Int Uk Ltd | Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands |
CN101857608A (zh) | 2010-05-28 | 2010-10-13 | 中国科学院过程工程研究所 | 咪唑离子液体膦配体及其配合物在氢酯基化反应中的应用 |
AR105389A1 (es) | 2015-07-23 | 2017-09-27 | Evonik Degussa Gmbh | Compuestos basados en ferroceno y catalizadores de paladio basados en los mismos para la alcoxicarbonilación de compuestos etilénicamente instaurados |
-
2016
- 2016-07-19 PL PL16180050T patent/PL3272732T3/pl unknown
- 2016-07-19 ES ES16180050T patent/ES2754370T3/es active Active
- 2016-07-19 EP EP16180050.3A patent/EP3272732B1/de active Active
-
2017
- 2017-07-13 MX MX2017009242A patent/MX2017009242A/es active IP Right Grant
- 2017-07-13 CA CA2973451A patent/CA2973451C/en not_active Expired - Fee Related
- 2017-07-14 US US15/649,743 patent/US10544174B2/en not_active Expired - Fee Related
- 2017-07-14 JP JP2017137954A patent/JP6467004B2/ja not_active Expired - Fee Related
- 2017-07-14 MY MYPI2017702598A patent/MY178581A/en unknown
- 2017-07-17 SG SG10201705854XA patent/SG10201705854XA/en unknown
- 2017-07-17 TW TW106123833A patent/TWI668227B/zh not_active IP Right Cessation
- 2017-07-18 CN CN201710584294.0A patent/CN107628951A/zh active Pending
- 2017-07-18 KR KR1020170090721A patent/KR102007753B1/ko active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
ES2754370T3 (es) | 2020-04-17 |
TWI668227B (zh) | 2019-08-11 |
JP2018065781A (ja) | 2018-04-26 |
KR102007753B1 (ko) | 2019-08-07 |
CA2973451A1 (en) | 2018-01-19 |
CN107628951A (zh) | 2018-01-26 |
JP6467004B2 (ja) | 2019-02-06 |
US10544174B2 (en) | 2020-01-28 |
EP3272732A1 (de) | 2018-01-24 |
US20180022764A1 (en) | 2018-01-25 |
CA2973451C (en) | 2020-03-31 |
PL3272732T3 (pl) | 2020-03-31 |
SG10201705854XA (en) | 2018-02-27 |
EP3272732B1 (de) | 2019-09-18 |
TW201815807A (zh) | 2018-05-01 |
KR20180009711A (ko) | 2018-01-29 |
MY178581A (en) | 2020-10-16 |
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Owner name: SAVANT TECHNOLOGIES LLC |
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