MX2017009231A - Proceso para la alcoxicarbonilación de éteres. - Google Patents
Proceso para la alcoxicarbonilación de éteres.Info
- Publication number
- MX2017009231A MX2017009231A MX2017009231A MX2017009231A MX2017009231A MX 2017009231 A MX2017009231 A MX 2017009231A MX 2017009231 A MX2017009231 A MX 2017009231A MX 2017009231 A MX2017009231 A MX 2017009231A MX 2017009231 A MX2017009231 A MX 2017009231A
- Authority
- MX
- Mexico
- Prior art keywords
- alkyl
- cycloalkyl
- aryl
- heteroaryl
- ùoù
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 238000007083 alkoxycarbonylation reaction Methods 0.000 title 1
- 150000002170 ethers Chemical class 0.000 title 1
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 abstract 10
- 125000006652 (C3-C12) cycloalkyl group Chemical group 0.000 abstract 8
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 4
- 125000006707 (C3-C12) heterocycloalkyl group Chemical group 0.000 abstract 3
- 125000006736 (C6-C20) aryl group Chemical group 0.000 abstract 3
- 239000003446 ligand Substances 0.000 abstract 3
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
- B01J27/13—Platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/62—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/12—Acetic acid esters
- C07C69/14—Acetic acid esters of monohydroxylic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/58—Pyridine rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La invención se refiere a un proceso que comprende las siguientes etapas del proceso: a) introducir un éter que tiene de 3 a 30 átomos de carbono; b) agregar un ligando de fosfina y un compuesto que comprende Pd, o agregar un complejo que comprende Pd y un ligando de fosfina; c) agregar un alcohol; d) suministrar CO; e) calentar la mezcla de reacción, haciendo reaccionar el éter para formar un éster; en donde el ligando de fosfina es un compuesto de fórmula (I) [ver fórmula (I)] en donde m y n son cada uno independientemente 0 ó 1; R1, R2, R3, R4 se seleccionan cada uno independientemente de -alquilo-(C1-C12), -cicloalquilo-(C3-C12), -heterocicloalquilo-(C3-C12), -arilo-(C6-C20), -heteroarilo-(C3-C20), al menos uno de los radicales R1, R2, R3, R4 es un radical heteroarilo-(C3-C20); y R1, R2, R3, R4, si son -alquilo-(C1-C12), - cicloalquilo-(C3-C12), -heterocicloalquilo-(C3-C12), -arilo- (C6-C20) o -heteroarilo-(C3-C20), cada uno puede sustituirse independientemente por uno o más sustituyentes seleccionados de -alquilo-(C1-C12), -cicloalquilo-(C3-C12), -heterocicloalquilo- (C3-C12), -O-alquilo-(C1-C12), -O-alquilo-(C1-C12)-arilo-(C6-C20), -O-cicloalquilo-(C3-C12), -S-alquilo-(C1-C12), - cicloalquilo-(C3-C12), -COO-alquilo-(C1-C12), -COOcicloalquilo-(C3-C12), -CONH-alquilo-(C1-C12), -CONH15 cicloalquilo-(C3-C12), -CO-alquilo-(C1-C12), -CO-cicloalquilo-(C3- C12), -N-[alquilo-(C1-C12)]2, -arilo-(C6-C20), -arilo-(C6-C20)-alquilo-(C1-C12), -arilo-(C6-C20)-O-alquilo-(C1-C1 2), heteroarilo-(C3-C20), heteroarilo-(C3-C20)-alquilo-(C1-C12), heteroarilo-(C3-C20)-O-alquilo-(C1-C12), -COOH, -OH, -SO3H, - NH2, halógeno.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16180054.5A EP3272730B1 (de) | 2016-07-19 | 2016-07-19 | Verfahren zur alkoxycarbonylierung von ethern |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2017009231A true MX2017009231A (es) | 2018-09-10 |
Family
ID=56464082
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2017009231A MX2017009231A (es) | 2016-07-19 | 2017-07-13 | Proceso para la alcoxicarbonilación de éteres. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US10494326B2 (es) |
| EP (1) | EP3272730B1 (es) |
| JP (1) | JP6498727B2 (es) |
| KR (1) | KR101960176B1 (es) |
| CN (1) | CN107628949B (es) |
| CA (1) | CA2973840C (es) |
| ES (1) | ES2718747T3 (es) |
| MX (1) | MX2017009231A (es) |
| MY (1) | MY172666A (es) |
| SG (1) | SG10201705861SA (es) |
| TW (1) | TWI668208B (es) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113912646B (zh) * | 2021-11-18 | 2024-05-17 | 浙江新化化工股份有限公司 | 一种双齿膦配体的制备方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1232317A (es) * | 1968-12-30 | 1971-05-19 | ||
| GB1224518A (en) * | 1968-11-11 | 1971-03-10 | Shell Int Research | Preparation of carboxylic esters |
| US5315030A (en) * | 1993-09-29 | 1994-05-24 | Ethyl Corporation | Catalytic carbonylation of ethers and thioethers |
| US5399747A (en) | 1994-01-27 | 1995-03-21 | Albemarle Corporation | Process for preparing carboxylic acids by carbonylation of ethers and thioethers |
| GB9425911D0 (en) | 1994-12-22 | 1995-02-22 | Ici Plc | Process for the carbonylation of olefins and catalyst system for use therein |
| AU5579598A (en) | 1997-02-26 | 1998-09-18 | Dsm N.V. | Process to prepare a pentenoic acid derivative |
| GB9717059D0 (en) | 1997-08-13 | 1997-10-15 | Ici Plc | Method of manufacturing phosphine compound |
| US7005537B2 (en) * | 1999-12-29 | 2006-02-28 | Exxonmobil Chemical Patents Inc. | Production of esters |
| US20060252959A1 (en) | 2005-05-05 | 2006-11-09 | The Regents Of The University Of California | Process for carbonylation of alkyl ethers |
| GB201000078D0 (en) | 2010-01-05 | 2010-02-17 | Lucite Int Uk Ltd | Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands |
| AR105389A1 (es) | 2015-07-23 | 2017-09-27 | Evonik Degussa Gmbh | Compuestos basados en ferroceno y catalizadores de paladio basados en los mismos para la alcoxicarbonilación de compuestos etilénicamente instaurados |
-
2016
- 2016-07-19 EP EP16180054.5A patent/EP3272730B1/de active Active
- 2016-07-19 ES ES16180054T patent/ES2718747T3/es active Active
-
2017
- 2017-07-13 MX MX2017009231A patent/MX2017009231A/es active IP Right Grant
- 2017-07-14 JP JP2017137959A patent/JP6498727B2/ja active Active
- 2017-07-17 US US15/651,169 patent/US10494326B2/en active Active
- 2017-07-17 MY MYPI2017702609A patent/MY172666A/en unknown
- 2017-07-17 SG SG10201705861SA patent/SG10201705861SA/en unknown
- 2017-07-17 TW TW106123840A patent/TWI668208B/zh active
- 2017-07-17 CA CA2973840A patent/CA2973840C/en active Active
- 2017-07-18 KR KR1020170090739A patent/KR101960176B1/ko active IP Right Grant
- 2017-07-18 CN CN201710585190.1A patent/CN107628949B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| TWI668208B (zh) | 2019-08-11 |
| JP6498727B2 (ja) | 2019-04-10 |
| CN107628949B (zh) | 2020-08-04 |
| US10494326B2 (en) | 2019-12-03 |
| KR101960176B1 (ko) | 2019-03-19 |
| CA2973840C (en) | 2019-06-25 |
| US20180022685A1 (en) | 2018-01-25 |
| CA2973840A1 (en) | 2018-01-19 |
| MY172666A (en) | 2019-12-09 |
| TW201815740A (zh) | 2018-05-01 |
| EP3272730A1 (de) | 2018-01-24 |
| JP2018058819A (ja) | 2018-04-12 |
| EP3272730B1 (de) | 2019-01-02 |
| CN107628949A (zh) | 2018-01-26 |
| SG10201705861SA (en) | 2018-02-27 |
| ES2718747T3 (es) | 2019-07-04 |
| KR20180009717A (ko) | 2018-01-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| HC | Change of company name or juridical status |
Owner name: DE-STA-CO EUROPE GMBH.* |
|
| FG | Grant or registration |