MX2016008089A - Óxido de boro en procesos de fcc. - Google Patents
Óxido de boro en procesos de fcc.Info
- Publication number
- MX2016008089A MX2016008089A MX2016008089A MX2016008089A MX2016008089A MX 2016008089 A MX2016008089 A MX 2016008089A MX 2016008089 A MX2016008089 A MX 2016008089A MX 2016008089 A MX2016008089 A MX 2016008089A MX 2016008089 A MX2016008089 A MX 2016008089A
- Authority
- MX
- Mexico
- Prior art keywords
- fcc
- boron oxide
- processes
- fcc processes
- oxide components
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 229910052810 boron oxide Inorganic materials 0.000 title abstract 3
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 title abstract 3
- 238000004231 fluid catalytic cracking Methods 0.000 abstract 5
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000571 coke Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000010954 inorganic particle Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/088—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/60—Synthesis on support
- B01J2229/64—Synthesis on support in or on refractory materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/80—Additives
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/134,629 US9441167B2 (en) | 2013-12-19 | 2013-12-19 | Boron oxide in FCC processes |
| PCT/US2014/069793 WO2015094916A1 (en) | 2013-12-19 | 2014-12-11 | Boron oxide in fcc processes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2016008089A true MX2016008089A (es) | 2016-10-03 |
Family
ID=53399341
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2016008089A MX2016008089A (es) | 2013-12-19 | 2014-12-11 | Óxido de boro en procesos de fcc. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9441167B2 (enExample) |
| EP (1) | EP3083898B1 (enExample) |
| JP (1) | JP6615097B2 (enExample) |
| KR (1) | KR102387083B1 (enExample) |
| CN (2) | CN112521970A (enExample) |
| BR (1) | BR112016011715B1 (enExample) |
| CA (1) | CA2930086C (enExample) |
| MX (1) | MX2016008089A (enExample) |
| RU (1) | RU2678446C1 (enExample) |
| TW (1) | TWI668303B (enExample) |
| WO (1) | WO2015094916A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108499600B (zh) * | 2018-04-19 | 2021-03-30 | 润和催化剂股份有限公司 | 一种多产柴油的催化裂化催化剂及其制备方法 |
| US10894248B2 (en) * | 2018-09-13 | 2021-01-19 | Indian Oil Corporation Limited | Catalyst composition for enhancing yield of olefins in fluid catalytic cracking process (FCC) |
| US12338208B2 (en) * | 2020-07-31 | 2025-06-24 | Basf Corporation | Fluid catalytic cracking catalyst composition for enhanced butylene to propylene selectivity ratio |
| EP4200070A4 (en) * | 2020-08-19 | 2024-11-13 | Basf Corporation | Fluid catalytic cracking catalyst composition for enhanced butylenes yields with metal passivation functionality |
| WO2022051283A1 (en) * | 2020-09-02 | 2022-03-10 | Johnson Matthey Process Technologies, Inc | Metal trapping additive |
| JP7701452B2 (ja) * | 2020-12-29 | 2025-07-01 | ルーマス テクノロジー エルエルシー | リサイクル廃プラスチックから生成された熱分解油をバージンオレフィンおよび石油化学中間体に変換するための真の循環型ソリューションのための接触クラッキング方法 |
| WO2024028884A1 (en) * | 2022-08-02 | 2024-02-08 | Hindustan Petroleum Corporaton Limited | A non-metal based metal passivator additive composition for fccu feed stocks |
| EP4613828A1 (en) * | 2024-03-07 | 2025-09-10 | Hindustan Petroleum Corporation Limited | A process for preparing bottoms cracking catalyst for fluid catalytic cracking unit |
Family Cites Families (49)
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| US2341363A (en) * | 1940-12-27 | 1944-02-08 | Standard Oil Dev Co | Conversion of hydrocarbon oils |
| US3409541A (en) | 1966-07-14 | 1968-11-05 | Chevron Res | Method of fluid catalytic cracking of metal contaminated feeds |
| GB1313174A (en) | 1969-06-02 | 1973-04-11 | Exxon Research Engineering Co | High surface area nitride catalysts of boron aluminium and silicon for hydrocarbon conversion reactions |
| FR2417540A1 (fr) * | 1978-02-20 | 1979-09-14 | Shell France | Procede de craquage catalytique d'hydrocarbures et catalyseur pour la mise en oeuvre du procede |
| US4192770A (en) | 1978-05-24 | 1980-03-11 | Shell Oil Company | Cracking catalyst restoration with boron compounds |
| US4295955A (en) | 1980-03-10 | 1981-10-20 | Uop Inc. | Attenuation of metal contaminants on cracking catalyst with a boron compound |
| US4430199A (en) | 1981-05-20 | 1984-02-07 | Engelhard Corporation | Passivation of contaminant metals on cracking catalysts by phosphorus addition |
| US4493902A (en) | 1983-02-25 | 1985-01-15 | Engelhard Corporation | Fluid catalytic cracking catalyst comprising microspheres containing more than about 40 percent by weight Y-faujasite and methods for making |
| FR2582665B1 (fr) * | 1985-06-04 | 1988-08-05 | Inst Francais Du Petrole | Procede de craquage catalytique |
| US4663018A (en) | 1985-06-27 | 1987-05-05 | Betz Laboratories, Inc. | Method for coke retardant during hydrocarbon processing |
| US5071539A (en) | 1985-08-30 | 1991-12-10 | Engelhard Corporation | FCC catalysts of increased effective heat capacity |
| CA1289543C (en) * | 1985-08-30 | 1991-09-24 | Barry K. Speronello | Fcc catalysts of increased effective heat capacity |
| US4708786A (en) * | 1986-03-26 | 1987-11-24 | Union Oil Company Of California | Process for the catalytic cracking of nitrogen-containing feedstocks |
| US4963337A (en) * | 1989-07-07 | 1990-10-16 | Chevron Research Company | Zeolite SSZ-33 |
| US5151394A (en) | 1991-01-25 | 1992-09-29 | Mobil Oil Corporation | Cracking catalysts |
| US5300215A (en) | 1991-01-25 | 1994-04-05 | Mobil Oil Corporation | Catalytic cracking with a catalyst comprising a boron phosphate matrix |
| US5258113A (en) | 1991-02-04 | 1993-11-02 | Mobil Oil Corporation | Process for reducing FCC transfer line coking |
| ES2076068B1 (es) | 1993-03-17 | 1996-06-16 | Consejo Superior Investigacion | Procedimiento de preparacion de catalizadores a base de zeolitas tratadas con acido fosforico, utiles para su aplicacion en unidades de craqueo catalitico. |
| US5378670A (en) | 1993-04-16 | 1995-01-03 | W. R. Grace & Co.-Conn. | Phosphorus zeolites/molecular sieves |
| US5395809A (en) | 1993-11-01 | 1995-03-07 | Engelhard Corporation | Modified microsphere FCC catalysts |
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| US5559067A (en) | 1995-03-31 | 1996-09-24 | Engelhard Corporation | Modified microsphere FCC catalysts and manufacture thereof |
| US5618407A (en) | 1995-07-18 | 1997-04-08 | Phillips Petroleum Company | Catalytic cracking process utilizing a catalyst comprising aluminum borate and zirconium borate |
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| JP4033249B2 (ja) | 1996-12-18 | 2008-01-16 | 財団法人石油産業活性化センター | 重質炭化水素油の水素化処理触媒及びそれを用いる水素化処理方法 |
| FR2758817B1 (fr) * | 1997-01-24 | 1999-09-03 | Inst Francais Du Petrole | Procede de craquage de charges hydrocarbonees a l'aide d'un catalyseur comprenant une zeolithe im-5 eventuellement desaluminee |
| US5968343A (en) * | 1997-05-05 | 1999-10-19 | Phillips Petroleum Company | Hydrocarbon conversion catalyst composition and processes therefor and therewith |
| CN1142019C (zh) | 2000-05-31 | 2004-03-17 | 中国石油化工集团公司 | 一种含磷的烃类裂化催化剂及制备 |
| US20030089640A1 (en) | 2001-10-17 | 2003-05-15 | Rostam Madon | FCC catalysts for feeds containing nickel and vanadium |
| US6656347B2 (en) | 2000-09-22 | 2003-12-02 | Engelhard Corporation | Structurally enhanced cracking catalysts |
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| JP4463556B2 (ja) * | 2001-10-17 | 2010-05-19 | バスフ・カタリスツ・エルエルシー | ニッケルとバナジウムを含有する供給材料用のｆｃｃ触媒 |
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| CN100540141C (zh) * | 2005-09-28 | 2009-09-16 | 华东理工大学 | 催化裂化金属钝化剂及其制备方法 |
| US7510645B2 (en) * | 2005-11-04 | 2009-03-31 | Uop Llc | Hydrocracking catalyst containing beta and Y zeolites, and process for its use to produce naphtha |
| CO5930068A1 (es) | 2006-12-06 | 2008-06-27 | Ecopetrol Sa | Proceso de produccion de trampas de vanadio por impregnacion y trampa de vanadio producida por dicho proceso |
| US9108181B2 (en) | 2007-06-20 | 2015-08-18 | Basf Corporation | Structurally enhanced cracking catalysts |
| RU2469791C2 (ru) * | 2007-08-06 | 2012-12-20 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Композиция, используемая для каталитической гидрообработки углеводородного исходного сырья, способ изготовления такого катализатора и способ применения этого катализатора |
| CN101537368B (zh) | 2008-03-19 | 2010-12-15 | 中国石油天然气股份有限公司 | 一种原位晶化型催化裂化催化剂的制备方法 |
| JP5258488B2 (ja) | 2008-09-30 | 2013-08-07 | 日揮触媒化成株式会社 | 炭化水素の流動接触分解触媒 |
| CA2758285C (en) | 2009-04-21 | 2018-01-16 | Albemarle Europe Sprl | Hydrotreating catalyst containing phosphorus and boron |
| CN102188992B (zh) * | 2011-03-18 | 2012-11-07 | 任丘市华北石油科林环保有限公司 | 一种炼厂fcc装置增产丙烯催化裂化助剂及其制备方法 |
| US9227181B2 (en) | 2011-09-13 | 2016-01-05 | Basf Corporation | Catalyst to increase propylene yields from a fluid catalytic cracking unit |
| WO2013067481A1 (en) | 2011-11-04 | 2013-05-10 | Basf Corporation | Phosphorus modified cracking catalysts with enhanced activity and hydrothermal stability |
| KR20140096134A (ko) * | 2011-11-21 | 2014-08-04 | 바스프 코포레이션 | Fcc 공정을 위한 개선된 금속 부동태화제/트랩 |
-
2013
- 2013-12-19 US US14/134,629 patent/US9441167B2/en active Active
-
2014
- 2014-12-11 JP JP2016541431A patent/JP6615097B2/ja active Active
- 2014-12-11 CN CN202011258673.9A patent/CN112521970A/zh active Pending
- 2014-12-11 KR KR1020167015865A patent/KR102387083B1/ko active Active
- 2014-12-11 RU RU2016129238A patent/RU2678446C1/ru active
- 2014-12-11 CN CN201480068545.4A patent/CN105829504A/zh active Pending
- 2014-12-11 EP EP14871500.6A patent/EP3083898B1/en active Active
- 2014-12-11 BR BR112016011715-8A patent/BR112016011715B1/pt active IP Right Grant
- 2014-12-11 WO PCT/US2014/069793 patent/WO2015094916A1/en not_active Ceased
- 2014-12-11 MX MX2016008089A patent/MX2016008089A/es active IP Right Grant
- 2014-12-11 CA CA2930086A patent/CA2930086C/en active Active
- 2014-12-19 TW TW103144632A patent/TWI668303B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| KR20160100962A (ko) | 2016-08-24 |
| CA2930086A1 (en) | 2015-06-25 |
| CN105829504A (zh) | 2016-08-03 |
| EP3083898B1 (en) | 2019-07-17 |
| JP2017506270A (ja) | 2017-03-02 |
| EP3083898A1 (en) | 2016-10-26 |
| CN112521970A (zh) | 2021-03-19 |
| JP6615097B2 (ja) | 2019-12-04 |
| WO2015094916A1 (en) | 2015-06-25 |
| US9441167B2 (en) | 2016-09-13 |
| RU2016129238A (ru) | 2018-01-23 |
| TWI668303B (zh) | 2019-08-11 |
| BR112016011715B1 (pt) | 2020-11-24 |
| KR102387083B1 (ko) | 2022-04-15 |
| CA2930086C (en) | 2022-03-01 |
| RU2678446C1 (ru) | 2019-01-29 |
| EP3083898A4 (en) | 2017-11-08 |
| TW201602329A (zh) | 2016-01-16 |
| US20150175899A1 (en) | 2015-06-25 |
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