MX2016001027A - Un proceso para la preparacion de oxido de propileno. - Google Patents

Un proceso para la preparacion de oxido de propileno.

Info

Publication number
MX2016001027A
MX2016001027A MX2016001027A MX2016001027A MX2016001027A MX 2016001027 A MX2016001027 A MX 2016001027A MX 2016001027 A MX2016001027 A MX 2016001027A MX 2016001027 A MX2016001027 A MX 2016001027A MX 2016001027 A MX2016001027 A MX 2016001027A
Authority
MX
Mexico
Prior art keywords
liquid feed
feed stream
preparation
propylene oxide
diacid phosphate
Prior art date
Application number
MX2016001027A
Other languages
English (en)
Inventor
Müller Ulrich
Parvulescu Andrei-Nicolae
Henrique Teles Joaquim
Seelig Bianca
Kampe Philip
Weber Markus
Urbanczyk Daniel
Riedel Dominic
Schröder Alexander
Weidenbach Meinolf
Witzl Werner
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MX2016001027A publication Critical patent/MX2016001027A/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/36—Use of additives, e.g. for stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7088—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/37—Crush or impact strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10—Infrared [IR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un proceso continuo para la preparación de óxido de propileno que comprende (i) proporcionar una corriente de alimentación líquida que comprende propeno, peróxido de hidrógeno, acetonitrilo, agua, fosfato diácido de potasio disuelto y de manera opcional propano; (ii) pasar la corriente de alimentación líquida provista en (i) a un reactor de epoxidación que comprende un catalizador comprendiendo una zeolita de titanio de estructura tipo MWW y someter la corriente de alimentación líquida a condiciones de reacción de epoxidación; (iii) remover una corriente de efluente del reactor de epoxidación; en donde la concentración del fosfato diácido de potasio disuelto en la corriente de alimentación liquida es al menos 10% del límite de solubilidad del fosfato diácido de potasio en la corriente de alimentación líquida.
MX2016001027A 2013-07-24 2014-07-16 Un proceso para la preparacion de oxido de propileno. MX2016001027A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13177903 2013-07-24
PCT/EP2014/065249 WO2015010992A1 (en) 2013-07-24 2014-07-16 A process for the preparation of propylene oxide

Publications (1)

Publication Number Publication Date
MX2016001027A true MX2016001027A (es) 2016-08-03

Family

ID=48832824

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016001027A MX2016001027A (es) 2013-07-24 2014-07-16 Un proceso para la preparacion de oxido de propileno.

Country Status (10)

Country Link
US (1) US9688648B2 (es)
EP (1) EP3024580B1 (es)
KR (1) KR102302531B1 (es)
CN (1) CN105813741B (es)
BR (1) BR112016001388B8 (es)
ES (1) ES2687470T3 (es)
MX (1) MX2016001027A (es)
RU (1) RU2673676C2 (es)
SG (1) SG11201600519XA (es)
WO (1) WO2015010992A1 (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MY174118A (en) 2013-07-24 2020-03-10 Basf Se A process for preparing propylene oxide
JP2017533981A (ja) 2014-10-14 2017-11-16 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 香料としてのヘキサデカ−８，１５−ジエナールの使用
WO2016128917A1 (en) 2015-02-12 2016-08-18 Basf Se Process for the preparation of a dealuminated zeolitic material having the bea framework structure
WO2016164595A1 (en) 2015-04-09 2016-10-13 Lyondell Chemical Technology, L.P. Process for forming propylene oxide from oxidation of methyl benzyl alcohol
JP6482678B2 (ja) 2015-04-09 2019-03-13 ライオンデル ケミカル テクノロジー、エル．ピー． プロピレンエポキシ化における触媒性能改善
WO2016177814A1 (en) 2015-05-04 2016-11-10 Basf Se Process for the preparation of melonal
WO2017009458A1 (en) 2015-07-15 2017-01-19 Basf Se Process for preparing an arylpropene
MX2018000609A (es) 2015-07-15 2018-05-07 Basf Se Proceso para preparar un arilpropeno.
RU2732326C2 (ru) 2015-07-22 2020-09-15 Басф Се Способ получения фуран-2,5-дикарбоновой кислоты
CN113461474A (zh) * 2021-06-30 2021-10-01 中国石油化工股份有限公司 一种丙烷工业化连续制备环氧丙烷的系统及方法
US12569841B2 (en) * 2023-06-05 2026-03-10 Saudi Arabian Oil Company Rotary evaporator and method for catalyst preparation

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DE3936854A1 (de) 1989-11-06 1991-05-08 Basf Ag Verfahren zur herstellung von methylformiat
US5646314A (en) * 1994-11-16 1997-07-08 Arco Chemical Technology, L.P. Process for titanium silicalite-catalyzed epoxidation
DE19936547A1 (de) * 1999-08-04 2001-02-15 Basf Ag Verfahren zur Umsetzung einer organischen Verbindung mit einem Hydroperoxid
US6114551A (en) 1999-10-04 2000-09-05 Mobil Oil Corporation Olefin epoxidation catalysts
EP1122249A1 (fr) 2000-02-02 2001-08-08 SOLVAY (Société Anonyme) Procédé de fabrication d'un oxiranne
DE10015246A1 (de) * 2000-03-28 2001-10-04 Basf Ag Verfahren zur Umsetzung einer organischen Verbindung mit einem Hydroperoxid
DE10044787A1 (de) * 2000-09-11 2002-04-04 Basf Ag Verfahren zur Herstellung eines Epoxides
US6498259B1 (en) * 2001-10-19 2002-12-24 Arco Chemical Technology L.P. Direct epoxidation process using a mixed catalyst system
DE10320635A1 (de) 2003-05-08 2004-11-18 Basf Ag Verfahren zur Herstellung von Propylenoxid
US7273826B2 (en) * 2005-07-26 2007-09-25 Lyondell Chemical Technology, L.P. Epoxidation catalyst
CN101730687B (zh) 2007-07-10 2012-07-04 住友化学株式会社 生产氧化丙烯的方法
MX2012000556A (es) 2009-07-16 2012-04-11 Basf Se Metodo para la separacion de acetonitrilo a partir de agua.
JP2011246423A (ja) 2010-05-31 2011-12-08 Sumitomo Chemical Co Ltd オレフィンオキサイドの製造方法
JP2012116758A (ja) 2010-11-29 2012-06-21 Sumitomo Chemical Co Ltd オレフィンオキサイドの製造方法
US8785670B2 (en) * 2010-12-07 2014-07-22 Basf Se Process for the production of propylene oxide
JP2012236177A (ja) * 2011-05-13 2012-12-06 Sumitomo Chemical Co Ltd チタノシリケート含有触媒の製造方法
CN102558100A (zh) * 2012-01-20 2012-07-11 中国天辰工程有限公司 以钛硅分子筛为催化剂催化丙烯环氧化反应的方法

Also Published As

Publication number Publication date
RU2016105803A3 (es) 2018-04-27
BR112016001388A2 (pt) 2019-12-17
CN105813741A (zh) 2016-07-27
CN105813741B (zh) 2019-02-19
ES2687470T3 (es) 2018-10-25
RU2016105803A (ru) 2017-08-28
WO2015010992A1 (en) 2015-01-29
KR102302531B1 (ko) 2021-09-16
EP3024580B1 (en) 2018-06-13
US20160185741A1 (en) 2016-06-30
US9688648B2 (en) 2017-06-27
RU2673676C2 (ru) 2018-11-29
BR112016001388B1 (pt) 2020-12-01
SG11201600519XA (en) 2016-02-26
EP3024580A1 (en) 2016-06-01
KR20160041939A (ko) 2016-04-18
BR112016001388B8 (pt) 2020-12-22

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