MX2007003902A - Proceso para preparar prepolimeros de poliuretano actinicamente curables que contienen alofanato con resistencia incrementada. - Google Patents

Proceso para preparar prepolimeros de poliuretano actinicamente curables que contienen alofanato con resistencia incrementada.

Info

Publication number
MX2007003902A
MX2007003902A MX2007003902A MX2007003902A MX2007003902A MX 2007003902 A MX2007003902 A MX 2007003902A MX 2007003902 A MX2007003902 A MX 2007003902A MX 2007003902 A MX2007003902 A MX 2007003902A MX 2007003902 A MX2007003902 A MX 2007003902A
Authority
MX
Mexico
Prior art keywords
groups
actinic radiation
nco
prepolymers
compounds
Prior art date
Application number
MX2007003902A
Other languages
English (en)
Other versions
MX276615B (es
Inventor
Wolfgang Fischer
Jan Weikard
Michael Ludewig
Nicola Stoeckel
Original Assignee
Bayer Materialscience Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Materialscience Ag filed Critical Bayer Materialscience Ag
Publication of MX2007003902A publication Critical patent/MX2007003902A/es
Publication of MX276615B publication Critical patent/MX276615B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7806—Nitrogen containing -N-C=0 groups
    • C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7837—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing allophanate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8141—Unsaturated isocyanates or isothiocyanates masked
    • C08G18/815—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
    • C08G18/8158—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
    • C08G18/8175—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Paints Or Removers (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

La presente invención se refiere a un proceso para preparar prepolímeros de poliuretano libres de NCO y que contienen alofanato de baja viscosidad, curables por radiación actínica, y a productos obtenibles por este proceso. Los prepolímeros tienen contenidos residuales de monómero de menos de 0.5 % en peso y un contenido de NCO de menos de 1 % en peso, y se preparan por un proceso en el cual se hacen reaccionar A) diisocianatos, B) compuestos con grupos funcionales hidroxi que contienen grupos quereaccionan con compuestos etilénicamente insaturados en la exposición a radiación actínica, y C) poliéster, poliéter o policarbonato-polioles que tienen una funcionalidad de al menos 1.9 y un peso molecular promedio en número (Mn) de al menos 1000 g/mol, D) opcionalmente en la presencia de un catalizador, para formar prepolímeros que contienen grupos NCO que tienen grupos de curación por radiación, que sehacen reaccionar de manera subsiguiente E) opcionalmente después de la adición de isocianatos monofuncionales en la 2 O presencia F) de un catalizador de alofanatización para dar prepolímeros que contienen alofanato, la relación de los grupos NCO de los compuestos de A) a los grupos OH de los compuestos de B) y C ) que es de 1.45 : 1.0 a 1.1 : 1.0 y la relación de los grupos OH de B) a los grupos OH de C) m e es 25 8.0 : 1 a 1.5 : 1.
MX2007003902A 2006-04-04 2007-03-30 Proceso para preparar prepolimeros de poliuretano actinicamente curables que contienen alofanato con resistencia incrementada. MX276615B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102006015709A DE102006015709A1 (de) 2006-04-04 2006-04-04 Verfahren zur Herstellung von allophanathaltigen, durch aktinische Strahlung härtbaren Polyurethanprepolymeren mit erhöhter Beständigkeit

Publications (2)

Publication Number Publication Date
MX2007003902A true MX2007003902A (es) 2009-02-16
MX276615B MX276615B (es) 2010-06-15

Family

ID=38229496

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2007003902A MX276615B (es) 2006-04-04 2007-03-30 Proceso para preparar prepolimeros de poliuretano actinicamente curables que contienen alofanato con resistencia incrementada.

Country Status (12)

Country Link
US (1) US7700662B2 (es)
EP (1) EP1842867B1 (es)
JP (2) JP2007277554A (es)
KR (1) KR101384001B1 (es)
CN (1) CN101050263B (es)
AU (1) AU2007201508B2 (es)
BR (1) BRPI0701243A (es)
CA (1) CA2583445C (es)
DE (1) DE102006015709A1 (es)
HK (1) HK1107704A1 (es)
MX (1) MX276615B (es)
TW (1) TWI404738B (es)

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DE102004043538A1 (de) * 2004-09-09 2006-03-16 Bayer Materialscience Ag Herstellung von neuen strahlenhärtenden Bindemitteln
DE102004043540A1 (de) * 2004-09-09 2006-03-30 Bayer Materialscience Ag Niedrigviskose Allophanate mit aktinisch härtbaren Gruppen
DE102004048873A1 (de) * 2004-10-07 2006-04-13 Bayer Materialscience Ag Verfahren zur Herstellung von niedrigviskosen Allophanaten mit aktinisch härtbaren Gruppen
EP1997608A3 (de) 2007-05-16 2009-05-27 Entex Rust & Mitschke GmbH Verfahren zur Verarbeitung von zu entgasenden Produkten
DE102007040239A1 (de) * 2007-08-25 2009-05-07 Bayer Materialscience Ag Verfahren zur Herstellung von niedrigviskosen Allophanaten mit aktinisch härtbaren Gruppen
DE102009008569A1 (de) * 2009-02-12 2010-08-19 Bayer Materialscience Ag Verfahren zur Herstellung von besonders reaktiven und niedrigviskosen Allophanaten mit aktinisch härtbaren Gruppen und deren Verwendung zur Herstellung besonders kratzfester Beschichtungen
US8178700B2 (en) * 2009-05-04 2012-05-15 International Business Machines Corporation Method of preparing cyclic carbonates, cyclic carbamates, cyclic ureas, cyclic thiocarbonates, cyclic thiocarbamates, and cyclic dithiocarbonates
JP5733911B2 (ja) * 2009-05-21 2015-06-10 日本合成化学工業株式会社 活性エネルギー線硬化型インクジェット用インク組成物およびインクジェットインク用樹脂組成物
EP2435036A2 (en) * 2009-05-28 2012-04-04 Merck Patent GmbH Ammoniumcarboxylates
US8143369B2 (en) 2009-06-02 2012-03-27 International Business Machines Corporation Polymers bearing pendant pentafluorophenyl ester groups, and methods of synthesis and functionalization thereof
RU2012107131A (ru) 2009-07-29 2013-09-10 Байер Матириальсайенс Аг Многослойные изделия, включающие покрытия, содержащие акрилаты
DE102009040333A1 (de) * 2009-09-05 2011-03-10 Bayer Materialscience Ag Verfahren zur kontinuierlichen Herstellung von Allophanaten
CN101735764B (zh) * 2010-02-09 2012-05-23 浙江林学院 环保型低成本聚氨酯胶粘剂生产方法
US8207351B2 (en) 2010-04-30 2012-06-26 International Business Machines Corporation Cyclic carbonyl compounds with pendant carbonate groups, preparations thereof, and polymers therefrom
CN103080175B (zh) 2010-06-30 2015-11-25 陶氏环球技术有限责任公司 低粘度甲硅烷基改性的聚合物
CA2824945A1 (en) 2011-01-20 2012-07-26 Bayer Materialscience Llc Non-aqueous polyurethane coating compositions
CN103797041B (zh) 2011-06-30 2015-11-25 陶氏环球技术有限责任公司 制备低粘度、快速固化硅烷封端聚合物的改进方法
CN104955862B (zh) * 2013-01-29 2018-01-09 日本优必佳株式会社 氨基甲酸酯(甲基)丙烯酸酯化合物
JP6088287B2 (ja) * 2013-02-25 2017-03-01 株式会社オートネットワーク技術研究所 高感度（メタ）アクリレート及びラジカル硬化材料
US10100223B2 (en) * 2013-03-14 2018-10-16 Allnex Netherlands B.V. Methods for making elastomers, elastomer compositions and related elastomers
US20140275320A1 (en) 2013-03-14 2014-09-18 Allnex IP S.à.r.I. Methods for making elastomers, elastomer compositions and related elastomers
JP6428208B2 (ja) * 2014-12-02 2018-11-28 東ソー株式会社 塗料組成物、該組成物を用いた自己修復型形成塗膜
WO2020131185A2 (en) 2018-09-26 2020-06-25 Dvorchak Enterprises Llc One component uv curable compositions and methods for making same
CN115651507A (zh) * 2022-11-18 2023-01-31 杭州立威化工涂料股份有限公司 一种用于笔记本的高抗油污弹性涂料及其使用方法

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Also Published As

Publication number Publication date
TWI404738B (zh) 2013-08-11
DE102006015709A1 (de) 2007-10-11
CA2583445C (en) 2014-07-08
EP1842867A2 (de) 2007-10-10
US7700662B2 (en) 2010-04-20
MX276615B (es) 2010-06-15
EP1842867B1 (de) 2015-08-12
KR101384001B1 (ko) 2014-04-10
AU2007201508A1 (en) 2007-10-18
US20070232751A1 (en) 2007-10-04
CN101050263A (zh) 2007-10-10
JP2014231611A (ja) 2014-12-11
CN101050263B (zh) 2011-07-27
KR20070099468A (ko) 2007-10-09
TW200808848A (en) 2008-02-16
HK1107704A1 (en) 2008-04-11
CA2583445A1 (en) 2007-10-04
BRPI0701243A (pt) 2007-12-11
EP1842867A3 (de) 2009-05-06
JP2007277554A (ja) 2007-10-25
AU2007201508B2 (en) 2013-07-18

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