MX172428B - Procedimiento para el hidrotratamiento de un aceite de hidrocarburo pesado que contiene asfaltenos y metales pesados - Google Patents

Procedimiento para el hidrotratamiento de un aceite de hidrocarburo pesado que contiene asfaltenos y metales pesados

Info

Publication number
MX172428B
MX172428B MX015258A MX1525880A MX172428B MX 172428 B MX172428 B MX 172428B MX 015258 A MX015258 A MX 015258A MX 1525880 A MX1525880 A MX 1525880A MX 172428 B MX172428 B MX 172428B
Authority
MX
Mexico
Prior art keywords
catalyst
hydrocarbon oil
degrees
heavy
metals
Prior art date
Application number
MX015258A
Other languages
English (en)
Inventor
Sachio Asaoka
Takeo Ono
Yoshimi Shiroto
Original Assignee
Chiyoda Chem Eng Construct Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chiyoda Chem Eng Construct Co filed Critical Chiyoda Chem Eng Construct Co
Publication of MX172428B publication Critical patent/MX172428B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/14—Silica and magnesia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B01J35/32—Bulk density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/80—Catalysts, in general, characterised by their form or physical properties characterised by their amorphous structures
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

La presente invención se refiere a un procedimiento para el hidrotratamiento de un aceite de hidrocarburo pesado que contiene asfaltenos y metales pesados, caracterizado por los pasos de a) hacer reaccionar el aceite de hidrocarburo pesado con hidrógeno a una temperatura de entre 350 y 450 grados C, una presión de entre 30 y 250 kg/cm cuadrado manometricos y una velocidad espacial de líquido de entre 0.1 y 10 horas -1, con una relación de hidrógeno a aceite de entre 100 y 2000 N1/1, en presencia de un catalizador que comprende un portador que es un cuerpo mixto calcinado de una mezcla de un mineral de arcilla que consiste principalmente de silicato de magnesio que tiene una estructura de doble cadena y una pseudoboehmita que muestra un espectro de difracción de rayos-X de polvo obtenido aplicando un rayo de CuKa tal, que la anchura del valor medio del máximo sobre el plano (020), es de entre aproximadamente 0.8 y 4.0 grados C y la intensidad de dicho máximo es de entre 1.2 y 8.0 veces más que a 20 10 grados; y por lo menos un componnte metálico catalítico en forma de cuerpo mixto con dicho portador, el metal que consiste de los metales que pertenecen a los grupos VB, VIB, VIII y IB de la tabla periódica, la proporción de la boehmita en dicho catalizador siendo tal que la cantidad de componentes de aluminio formada de dicha pseudoboehmita es de entre 10 y 80 por ciento en terminos de A1203, con base en el peso total del catalizador; y la proporción de dicho componente metálico catalítico siendo tal que la cantidad del elemento metálico producido por dicho componente catalítico es de entre aproximadamente 0.1 y aproximada mente 20 por ciento, con base en el peso total del catalizador y b) refinar el producto crudo así obtenido.
MX015258A 1979-11-27 1980-11-27 Procedimiento para el hidrotratamiento de un aceite de hidrocarburo pesado que contiene asfaltenos y metales pesados MX172428B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP54153132A JPS594182B2 (ja) 1979-11-27 1979-11-27 重質炭化水素油の水素化処理用触媒およびその製造法

Publications (1)

Publication Number Publication Date
MX172428B true MX172428B (es) 1993-12-16

Family

ID=15555683

Family Applications (2)

Application Number Title Priority Date Filing Date
MX015258A MX172428B (es) 1979-11-27 1980-11-27 Procedimiento para el hidrotratamiento de un aceite de hidrocarburo pesado que contiene asfaltenos y metales pesados
MX184933A MX159547A (es) 1979-11-27 1980-11-27 Mejoras en un catalizador para el hidrotratamiento de aceites de hidrocarburo pesados,y metodo para preparar el mismo

Family Applications After (1)

Application Number Title Priority Date Filing Date
MX184933A MX159547A (es) 1979-11-27 1980-11-27 Mejoras en un catalizador para el hidrotratamiento de aceites de hidrocarburo pesados,y metodo para preparar el mismo

Country Status (9)

Country Link
US (2) US4367165A (es)
JP (1) JPS594182B2 (es)
CA (1) CA1147715A (es)
DE (1) DE3044071C2 (es)
FR (1) FR2469954B1 (es)
GB (1) GB2063699B (es)
IT (1) IT1141092B (es)
MX (2) MX172428B (es)
NL (1) NL188080C (es)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS601056B2 (ja) * 1980-02-19 1985-01-11 千代田化工建設株式会社 アスファルテンを含む重質炭化水素油の水素化処理
US4465779A (en) * 1982-05-06 1984-08-14 Gulf Research & Development Company Modified cracking catalyst composition
US4519897A (en) * 1982-12-27 1985-05-28 Akzo Nv Fluid cracking process using sepiolite-containing catalyst composition
JPS60193539A (ja) * 1984-03-15 1985-10-02 Chiyoda Chem Eng & Constr Co Ltd 繊維性粘土鉱物を含有する組成物の製造方法
JPS60227833A (ja) * 1984-04-27 1985-11-13 Nippon Oil Co Ltd 重質炭化水素油の水素化処理用触媒
US4623530A (en) * 1985-02-20 1986-11-18 United States Steel Corporation Crystalline magnesia-silica composites and process for producing same
JPS61278351A (ja) * 1985-05-31 1986-12-09 ダブリユー・アール・グレイス・アンド・カンパニー−コネチカツト 接触クラツキング触媒及びその使用法
US4585751A (en) * 1985-06-24 1986-04-29 Phillips Petroleum Company Hydrotreating catalysts
US4701435A (en) * 1986-04-07 1987-10-20 Intevep, S.A. Catalyst and method of preparation from a naturally occurring material
US4762814A (en) * 1986-11-14 1988-08-09 Phillips Petroleum Company Hydrotreating catalyst and process for its preparation
US4707246A (en) * 1986-11-14 1987-11-17 Phillips Petroleum Company Hydrotreating catalyst and process
US4988654A (en) * 1989-12-29 1991-01-29 Chevron Research Company Dual component cracking catalyst with vanadium passivation and improved sulfur tolerance
US5002653A (en) * 1989-12-29 1991-03-26 Chevron Research Company Catalytic cracking process with vanadium passivation and improved
US5071807A (en) * 1989-12-29 1991-12-10 Chevron Research Company Hydrocarbon processing composition
DK0517300T3 (da) * 1991-06-03 1995-10-16 Akzo Nobel Nv Borholdig katalysator
WO1996007477A1 (en) * 1994-09-02 1996-03-14 Akzo Nobel N.V. Catalyst comprising at least a hydrogenation metal component and a synthetic clay
JP2883299B2 (ja) 1994-09-16 1999-04-19 キヤノン株式会社 被記録媒体、その製造方法、被記録媒体を用いたインクジェット記録方法
IL118088A0 (en) * 1995-06-07 1996-08-04 Anzon Inc Colloidal particles of solid flame retardant and smoke suppressant compounds and methods for making them
IL116121A0 (en) * 1995-11-23 1996-01-31 Univ Ben Gurion Negev Res & De Process and catalysts for the production of motor fuels from shale oils
US5935890A (en) * 1996-08-01 1999-08-10 Glcc Technologies, Inc. Stable dispersions of metal passivation agents and methods for making them
JP3920966B2 (ja) * 1997-06-06 2007-05-30 東燃ゼネラル石油株式会社 重質油分解用添加触媒
JPH11561A (ja) * 1997-06-13 1999-01-06 Tonen Corp 重質油の接触分解用添加触媒
US5929295A (en) * 1997-08-06 1999-07-27 Phillips Petroleum Company Hydrodealkylation and transalkylation of C9 + aromatic compounds
US6156283A (en) * 1998-03-23 2000-12-05 Engelhard Corporation Hydrophobic catalytic materials and method of forming the same
FR2778583B1 (fr) * 1998-05-13 2000-06-16 Inst Francais Du Petrole Catalyseur comprenant un phyllosilicate contenant du bore et/ou du silicium et procede d'hydrocraquage
DE69925580D1 (de) 1998-12-08 2005-07-07 Japan Energy Corp Katalysator zur hydrodesulforierung und verfahren zu seiner herstellung
US6303020B1 (en) * 2000-01-07 2001-10-16 Catalytic Distillation Technologies Process for the desulfurization of petroleum feeds
US6416659B1 (en) 2000-08-17 2002-07-09 Catalytic Distillation Technologies Process for the production of an ultra low sulfur
WO2006070007A1 (en) * 2004-12-31 2006-07-06 Shell Internationale Research Maatschappij B.V. Hydrogenation catalyst and use thereof for hydrogenating fischer-tropsch endproducts
WO2006110660A1 (en) * 2005-04-11 2006-10-19 Shell Internationale Research Maatschappij B.V. Method and catalyst for producing a crude product having a reduced mcr content
EP1976629A1 (en) * 2006-01-23 2008-10-08 Shell Internationale Research Maatschappij B.V. Hydrogenation catalyst and use thereof for hdrogenating fischer-tropsch endproducts
US8372269B2 (en) * 2009-10-02 2013-02-12 Basf Corporation Heavy metals trapping co-catalyst for FCC processes
JP2014175389A (ja) * 2013-03-07 2014-09-22 Mitsubishi Materials Corp アルミナ絶縁膜の形成方法
ES2781554T3 (es) * 2016-06-16 2020-09-03 Wilh Schlechtendahl & Soehne Gmbh & Co Kg Ensamblaje de hoja y procedimiento para el montaje frontal de un componente de herraje en un ensamblaje de hoja de este tipo
CN116060100A (zh) * 2021-10-31 2023-05-05 中国石油化工股份有限公司 一种用于氨化反应的催化剂及其制备方法和应用

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US4152250A (en) * 1975-12-09 1979-05-01 Chiyoda Chemical Engineering & Construction Demetallation of hydrocarbons with catalysts supported on sepiolite
US4196102A (en) * 1975-12-09 1980-04-01 Chiyoda Chemical Engineering & Construction Co., Ltd. Catalysts for demetallization treatment of _hydrocarbons supported on sepiolite
GB1561629A (en) * 1975-12-10 1980-02-27 Ici Ltd Catalyst
JPS5850636B2 (ja) * 1977-07-15 1983-11-11 千代田化工建設株式会社 重質炭化水素油の脱硫処理方法

Also Published As

Publication number Publication date
DE3044071A1 (de) 1981-10-01
CA1147715A (en) 1983-06-07
NL8006444A (nl) 1981-07-01
NL188080C (nl) 1992-04-01
FR2469954B1 (fr) 1988-05-06
IT1141092B (it) 1986-10-01
US4439312A (en) 1984-03-27
DE3044071C2 (de) 1987-04-02
IT8026250A0 (it) 1980-11-26
MX159547A (es) 1989-06-30
JPS5676246A (en) 1981-06-23
JPS594182B2 (ja) 1984-01-28
FR2469954A1 (fr) 1981-05-29
GB2063699B (en) 1983-10-12
US4367165A (en) 1983-01-04
GB2063699A (en) 1981-06-10

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