MX170995B - Procedimiento para la preparacion de n-fenilsulfonil-n'-pirimidinil y triazinil-ureas - Google Patents
Procedimiento para la preparacion de n-fenilsulfonil-n'-pirimidinil y triazinil-ureasInfo
- Publication number
- MX170995B MX170995B MX005729A MX572981A MX170995B MX 170995 B MX170995 B MX 170995B MX 005729 A MX005729 A MX 005729A MX 572981 A MX572981 A MX 572981A MX 170995 B MX170995 B MX 170995B
- Authority
- MX
- Mexico
- Prior art keywords
- ureas
- triazinyl
- formula
- pirimidinyl
- phenylsulphonyl
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/32—One oxygen, sulfur or nitrogen atom
- C07D239/42—One nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D521/00—Heterocyclic compounds containing unspecified hetero rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/14—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Amplifiers (AREA)
- Magnetic Resonance Imaging Apparatus (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Spinning Or Twisting Of Yarns (AREA)
Abstract
La presente invención se refiere a procedimiento para preparar N-fenilsulfonil-N'-pirimidinil- y -triazinil-ureas de la fórmula general I: caracterizado porque se hace reaccionar a una temperatura entre -20 y 120 grados C un N-fenil-sulfonilcarbamato de la fórmula VII: con una amina de la fórmula V: y eventualmente se convierte en su sal, porque se hace reaccionar una sulfonilurea de la fórmula I, con una amina, un hidróxido de metal alcalino o alcalino-terreo, o con una base de amonio cuaternario. El uso descrito de los compuestos es como: agentes herbicidas.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH5481/80A CH657849A5 (en) | 1980-07-17 | 1980-07-17 | N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinyl ureas |
CH821680 | 1980-11-05 | ||
CH399181 | 1981-06-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
MX170995B true MX170995B (es) | 1993-09-24 |
Family
ID=27174660
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX005729A MX170995B (es) | 1980-07-17 | 1981-07-17 | Procedimiento para la preparacion de n-fenilsulfonil-n'-pirimidinil y triazinil-ureas |
MX819558U MX6981E (es) | 1980-07-17 | 1981-07-17 | Procedimiento para la preparacion de n fenilsulfonil-n'-pirimidinil y-triazinil-ureas |
MX005728A MX170994B (es) | 1980-07-17 | 1981-07-17 | Procedimiento para la preparacion de n-fenilsulfonil-n'-pirimidinil y triazinil-ureas |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX819558U MX6981E (es) | 1980-07-17 | 1981-07-17 | Procedimiento para la preparacion de n fenilsulfonil-n'-pirimidinil y-triazinil-ureas |
MX005728A MX170994B (es) | 1980-07-17 | 1981-07-17 | Procedimiento para la preparacion de n-fenilsulfonil-n'-pirimidinil y triazinil-ureas |
Country Status (25)
Country | Link |
---|---|
US (11) | US4510325A (es) |
EP (3) | EP0044808B1 (es) |
KR (1) | KR850000495B1 (es) |
AT (3) | ATE17431T1 (es) |
AU (1) | AU545208B2 (es) |
BG (2) | BG60335B2 (es) |
BR (3) | BR8104619A (es) |
CA (2) | CA1330438C (es) |
CY (1) | CY1438A (es) |
DD (2) | DD215461A5 (es) |
DE (3) | DE3172974D1 (es) |
DK (4) | DK163664C (es) |
EG (1) | EG15401A (es) |
ES (2) | ES504013A0 (es) |
GR (1) | GR74308B (es) |
IL (3) | IL63324A (es) |
KE (1) | KE3819A (es) |
MA (1) | MA19205A1 (es) |
MX (3) | MX170995B (es) |
MY (2) | MY8600581A (es) |
NZ (1) | NZ197733A (es) |
PH (1) | PH18233A (es) |
RO (1) | RO83456B (es) |
TR (1) | TR21355A (es) |
ZW (1) | ZW16681A1 (es) |
Families Citing this family (128)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4452628A (en) * | 1979-07-26 | 1984-06-05 | E. I. Du Pont De Nemours And Company | Herbicidal sulfonamides |
US4645531A (en) * | 1980-03-07 | 1987-02-24 | Du Pont | Alkyl sulfones |
CA1330438C (en) * | 1980-07-17 | 1994-06-28 | Willy Meyer | N-phenylsulfonyl-n'-pyrimidinyl-and-triazinylureas |
US4534789A (en) * | 1981-05-19 | 1985-08-13 | E. I. Du Pont De Nemours And Company | Herbicidal o-alkylsulfonyloxy- and o-alkylsulfonylaminobenzenesulfonamides |
US4443243A (en) * | 1981-07-16 | 1984-04-17 | Ciba-Geigy Corporation | N-Phenylsulfonyl-N-triazinylureas |
US4523944A (en) * | 1981-07-16 | 1985-06-18 | Ciba-Geigy Corporation | N-Phenylsulfonyl-N'-pyrimidinylureas |
US4545811A (en) * | 1981-08-06 | 1985-10-08 | Ciba-Geigy Corporation | N-Phenylsulfonyl-N'-triazinyl-ureas |
US4528024A (en) * | 1981-09-09 | 1985-07-09 | E. I. Du Pont De Nemours And Company | Herbicidal alkyl sulfones |
US4579584A (en) * | 1981-10-13 | 1986-04-01 | Ciba-Geigy Corporation | N-phenylsulfonyl-N'-triazinylureas |
DK536582A (da) * | 1981-12-07 | 1983-06-08 | Du Pont | Herbicide sulfonamider |
US4618363A (en) * | 1982-01-25 | 1986-10-21 | Ciba-Geigy Corporation | N-phenylsulfonyl-N'-triazinylureas |
US4537618A (en) * | 1982-05-26 | 1985-08-27 | Ciba Geigy Corporation | N-phenylsulfonyl-N'-pyrimidinylureas |
MA19797A1 (fr) * | 1982-06-14 | 1983-12-31 | Ciba Geigy Ag | N-heterocyclosulfonyl -n- pyrimidinyl et triazinylurees . |
US4584011A (en) * | 1982-07-16 | 1986-04-22 | E. I. Du Pont De Nemours And Company | Triazinyl-amino carbonyl-benzene sulfonamides |
US4518776A (en) * | 1982-07-19 | 1985-05-21 | Ciba Geigy Corporation | Process for producing sulfonylureas |
ATE32892T1 (de) * | 1982-08-23 | 1988-03-15 | Ciba Geigy Ag | Verfahren zur herstellung von herbiziden und pflanzenwuchsregulierenden sulfonylharnstoffen. |
US4780125A (en) * | 1982-09-01 | 1988-10-25 | Ciba-Geigy Corporation | N-phenylsulfonyl-N'-triazinylureas |
US4579583A (en) * | 1982-09-08 | 1986-04-01 | Ciba-Geigy Corporation | Novel sulfonylureas |
US4515626A (en) * | 1982-10-06 | 1985-05-07 | Ciba Geigy Corporation | N-(Cyclopropyl-triazinyl-n'-(arylsulfonyl) ureas having herbicidal activity |
US4521597A (en) * | 1982-10-25 | 1985-06-04 | Ciba Geigy Corporation | Process for producing sulfonylureas having a herbicidal action |
US4581059A (en) * | 1982-11-05 | 1986-04-08 | E. I. Du Pont De Nemours And Company | Herbicidal phenoxy esters of N-(heterocyclic)aminocarbonyl)sulfamic acid |
USH168H (en) | 1982-12-13 | 1986-12-02 | E. I. Du Pont De Nemours And Company | Herbicidal sulfonamides |
US4562210A (en) * | 1983-01-17 | 1985-12-31 | Ciba-Geigy Corporation | Bactericides |
US4515624A (en) * | 1983-03-23 | 1985-05-07 | E. I. Du Pont De Nemours And Company | Herbicidal sulfonamides |
EP0125205A1 (de) * | 1983-04-13 | 1984-11-14 | Ciba-Geigy Ag | N-Phenylsulfonyl-N'-pyrimidinyl- und -triazinylharnstoffe |
IT1161220B (it) * | 1983-04-21 | 1987-03-18 | Montedison Spa | Diidro-benzofurano derivati ad attivita' erbicida |
US4589911A (en) * | 1983-05-11 | 1986-05-20 | Ciba-Geigy Corporation | Fused N-phenylsulfonyl-N-triazinylureas |
DE3474447D1 (en) * | 1983-07-18 | 1988-11-10 | Ciba Geigy Ag | Process for the preparation of sulfonyl urea |
EP0135332B1 (en) * | 1983-08-05 | 1988-12-07 | E.I. Du Pont De Nemours And Company | Herbicidal benzenesulfonamides, benzylsulfonamides and benzenesulfamates |
US4705556A (en) * | 1984-07-12 | 1987-11-10 | E. I. Du Pont De Nemours And Company | Herbicidal sulfonamides |
US4604131A (en) * | 1983-08-05 | 1986-08-05 | E. I. Du Pont De Nemours And Company | Herbicidal sulfonamides |
US4764204A (en) * | 1983-08-05 | 1988-08-16 | E. I. Du Pont De Nemours And Company | Herbicidal sulfonamides |
US4639264A (en) * | 1983-08-26 | 1987-01-27 | Ciga-Geigy Corporation | Herbicidal N-arylsulfonyl-N'-(4-mercaptomethylpyrimdinyl)-ureas |
US4602936A (en) * | 1983-09-09 | 1986-07-29 | Ciba-Geigy Corporation | Herbicidal sulfonylureas |
DE3332780A1 (de) * | 1983-09-10 | 1985-03-28 | Hoechst Ag, 6230 Frankfurt | 6-sulfoxyphenolderivate, ihre herstellung und ihre verwendung als cytoprotekiva |
EP0151554A1 (de) * | 1984-02-03 | 1985-08-14 | Ciba-Geigy Ag | Neue Phenylsulfonamidderivate |
US4685961A (en) * | 1984-02-14 | 1987-08-11 | Ciba-Geigy Corporation | Herbicidal sulfonylureas |
US4588432A (en) * | 1984-02-27 | 1986-05-13 | E. I. Du Pont De Nemours And Company | Herbicidal selenylsulfonamides |
US4840963A (en) * | 1984-03-14 | 1989-06-20 | Merck & Co., Inc. | 2-Sulfamoyl-1H-indole derivatives for the treatment of elevated intraocular pressure |
JPS60215660A (ja) * | 1984-04-11 | 1985-10-29 | Nippon Tokushu Noyaku Seizo Kk | ビフエニリルスルホニルウレア誘導体の製法、その中間体及び該中間体の製法 |
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US4637829A (en) * | 1984-04-27 | 1987-01-20 | Ciba-Geigy Corporation | Sulfonylureas |
CA1229086A (en) * | 1984-05-09 | 1987-11-10 | Hugh M. Brown | Herbicidal halopyrimidines |
US4871847A (en) * | 1984-05-24 | 1989-10-03 | E. I. Du Pont De Nemours And Company | Herbicidal sulfonamides |
US4981509A (en) * | 1984-05-24 | 1991-01-01 | E. I. Du Pont De Nemours And Company | Herbicidal sulfonamides |
US4849010A (en) * | 1985-04-10 | 1989-07-18 | E. I. Dupont De Nemours And Company | Herbicidal sulfonamides |
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US4656273A (en) * | 1984-07-09 | 1987-04-07 | Ciba-Geigy Corporation | Process for producing sulfonylureas |
US4659369A (en) | 1984-08-27 | 1987-04-21 | E. I. Du Pont De Nemours And Company | Herbicidal acetals and ketals |
US4780126A (en) * | 1984-08-30 | 1988-10-25 | Bayer Aktiengesellschaft | 3-substituted 1-(2-halogenoalkoxy-benzenesulphonyl)-3-heteroaryl-(thio)ureas |
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US4678855A (en) * | 1985-10-09 | 1987-07-07 | Merck & Co., Inc. | Substituted benzenesulfonamides |
CA1230119A (en) | 1985-11-22 | 1987-12-08 | Craig L. Hillemann | N-2-carboxylphenylsulfonyl-n'-pyrimidin-2-yl or triazin-2-yl-urea compounds |
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US4709092A (en) * | 1986-03-05 | 1987-11-24 | Ciba-Geigy Corporation | Process for the preparation of 2-alkoxybenzosulfonamides |
US4798688A (en) * | 1986-03-05 | 1989-01-17 | Ciba-Geigy Corporation | 2-alkoxy-5-chloro-benzenesulfonates useful for the preparation of 2-alkoxybenzosulfonamides |
US4759792A (en) * | 1986-06-05 | 1988-07-26 | Ciba-Geigy Corporation | Phenylsulfonylureas |
US4795486A (en) * | 1986-09-26 | 1989-01-03 | Boehner Beat | Aminopyrazinones and aminotriazinones |
US4927453A (en) * | 1986-10-17 | 1990-05-22 | E. I. Du Pont De Nemours And Company | Herbicidal sulfonamides |
US5108487A (en) * | 1986-10-17 | 1992-04-28 | E. I. Du Pont De Nemours And Company | Herbicidal sulfonamides |
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US5217525A (en) * | 1986-10-22 | 1993-06-08 | Ciba-Geigy Corporation | Synergistic composition and method for selective weed control in rice |
US5017215A (en) * | 1987-08-07 | 1991-05-21 | E. I. Du Pont De Nemours And Company | Herbicides for weed control in rice |
US4806528A (en) * | 1987-09-04 | 1989-02-21 | Hanreich Reinhard G | Process for the preparation of 2-(2-chloroethoxy)-benzenesulfonamide |
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DE3811777A1 (de) * | 1988-04-08 | 1989-10-19 | Hoechst Ag | Heterocyclisch substituierte alkyl- und alkenylsulfonylharnstoffe, verfahren zu ihrer herstellung und ihre verwendung als herbizide oder pflanzenwachstumsregulatoren |
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ATE119163T1 (de) * | 1989-01-11 | 1995-03-15 | Ciba Geigy Ag | Antidots zur verbesserung der kulturpflanzenvertäglichkeit agrochemischer wirkstoffe. |
US5272129A (en) * | 1989-03-18 | 1993-12-21 | Hoechst Aktiengesellschaft | Phenoxysulfonylureas based on 3-substituted alkyl salicylates, and their use as herbicides and plant growth regulators |
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US5062878A (en) * | 1989-11-13 | 1991-11-05 | Toby's Chemical Company | Method and apparatus for clearing flora from sewer lines |
DE59006512D1 (de) * | 1989-12-08 | 1994-08-25 | Ciba Geigy Ag | Verfahren zur Herstellung von Phenylsulfonamiden. |
ES2082175T3 (es) * | 1990-05-30 | 1996-03-16 | Ciba Geigy Ag | Sulfonilureas con actividad herbicida y utiles como reguladores del crecimiento de las plantas. |
ATE147788T1 (de) * | 1990-06-29 | 1997-02-15 | Ciba Geigy Ag | Immunologisches nachweisverfahren für triasulfuron |
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DE59106466D1 (de) * | 1990-08-15 | 1995-10-19 | Ciba Geigy Ag | Sulfonylharnstoffe als Herbizide. |
MY136106A (en) * | 1990-09-06 | 2008-08-29 | Novartis Ag | Synergistic composition comprising a sulfonylurea anda thiadiazolo (3,4-a)pyridazine and method of selective weed control. |
DE4038430A1 (de) * | 1990-12-01 | 1992-06-04 | Basf Ag | Herbizide n-((1,3,5-triazin-2-yl)-aminocarbonyl) benzolsulfonamide |
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BR9713395A (pt) * | 1996-11-22 | 2000-03-21 | Du Pont | paração de um sal de amÈnio quaternário |
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BE1012386A3 (fr) * | 1999-01-15 | 2000-10-03 | Univ Liege | Derives de sulfonamides benzeniques et leurs utilisations. |
AU4521700A (en) * | 1999-01-27 | 2000-08-18 | Aventis Cropscience Gmbh | Herbicidal formulation |
DE19963383A1 (de) | 1999-12-28 | 2001-07-05 | Aventis Cropscience Gmbh | Formulierung von Herbiziden und Pflanzenwachstumsregulatoren |
DE10111649A1 (de) * | 2001-03-12 | 2002-09-19 | Bayer Ag | Substituierte Fluoralkoxyphenylsulfonylharnstoffe |
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EP2052604A1 (de) | 2007-10-24 | 2009-04-29 | Bayer CropScience AG | Salz des 2-lodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl] benzolsulfonamids,Verfahren zu deren Herstellung, sowie deren Verwendung als Herbizide und Pflanzenwachstumregulatoren |
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DE102008037620A1 (de) | 2008-08-14 | 2010-02-18 | Bayer Crop Science Ag | Herbizid-Kombination mit Dimethoxytriazinyl-substituierten Difluormethansulfonylaniliden |
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-
1980
- 1980-07-15 CA CA000381786A patent/CA1330438C/en not_active Expired - Lifetime
-
1981
- 1981-07-01 MA MA19405A patent/MA19205A1/fr unknown
- 1981-07-13 DE DE8181810281T patent/DE3172974D1/de not_active Expired
- 1981-07-13 DE DE8181810283T patent/DE3160818D1/de not_active Expired
- 1981-07-13 EP EP81810282A patent/EP0044808B1/de not_active Expired
- 1981-07-13 AT AT81810282T patent/ATE17431T1/de active
- 1981-07-13 EP EP81810281A patent/EP0044807B1/de not_active Expired
- 1981-07-13 EP EP81810283A patent/EP0044809B1/de not_active Expired
- 1981-07-13 AT AT81810283T patent/ATE4526T1/de not_active IP Right Cessation
- 1981-07-13 AT AT81810281T patent/ATE16555T1/de not_active IP Right Cessation
- 1981-07-13 DE DE8181810282T patent/DE3173493D1/de not_active Expired
- 1981-07-15 EG EG402/81A patent/EG15401A/xx active
- 1981-07-15 IL IL8163324A patent/IL63324A/xx not_active IP Right Cessation
- 1981-07-15 RO RO104891A patent/RO83456B/ro unknown
- 1981-07-15 IL IL8179463A patent/IL79463A/xx unknown
- 1981-07-15 ZW ZW166/81A patent/ZW16681A1/xx unknown
- 1981-07-15 PH PH25917A patent/PH18233A/en unknown
- 1981-07-16 TR TR21355A patent/TR21355A/xx unknown
- 1981-07-16 AU AU73036/81A patent/AU545208B2/en not_active Expired
- 1981-07-16 NZ NZ197733A patent/NZ197733A/en unknown
- 1981-07-16 DD DD81231843A patent/DD215461A5/de not_active IP Right Cessation
- 1981-07-16 GR GR65532A patent/GR74308B/el unknown
- 1981-07-16 KR KR1019810002603A patent/KR850000495B1/ko active
- 1981-07-16 ES ES504013A patent/ES504013A0/es active Granted
- 1981-07-16 DD DD81269168A patent/DD220601A5/de not_active IP Right Cessation
- 1981-07-16 DK DK318681A patent/DK163664C/da not_active IP Right Cessation
- 1981-07-17 BR BR8104619A patent/BR8104619A/pt not_active IP Right Cessation
- 1981-07-17 BR BR8104617A patent/BR8104617A/pt unknown
- 1981-07-17 MX MX005729A patent/MX170995B/es unknown
- 1981-07-17 BR BR8104618A patent/BR8104618A/pt unknown
- 1981-07-17 MX MX819558U patent/MX6981E/es unknown
- 1981-07-17 MX MX005728A patent/MX170994B/es unknown
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1982
- 1982-09-13 US US06/417,743 patent/US4510325A/en not_active Expired - Lifetime
- 1982-09-24 US US06/423,344 patent/US4476321A/en not_active Expired - Lifetime
- 1982-12-16 ES ES518258A patent/ES8401950A1/es not_active Expired
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1983
- 1983-01-17 US US06/458,691 patent/US4444583A/en not_active Expired - Lifetime
- 1983-01-17 US US06/458,696 patent/US4425154A/en not_active Expired - Lifetime
- 1983-01-17 US US06/458,594 patent/US4514212A/en not_active Expired - Lifetime
- 1983-01-17 US US06/458,693 patent/US4561878A/en not_active Expired - Lifetime
- 1983-01-17 US US06/458,695 patent/US4479821A/en not_active Expired - Lifetime
- 1983-01-17 US US06/458,694 patent/US4537619A/en not_active Expired - Lifetime
- 1983-01-17 US US06/458,584 patent/US4419121A/en not_active Expired - Lifetime
- 1983-03-23 CA CA000424330A patent/CA1205482A/en not_active Expired
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1985
- 1985-01-22 US US06/693,481 patent/US4629810A/en not_active Expired - Lifetime
- 1985-08-02 US US06/761,941 patent/US4681619A/en not_active Expired - Lifetime
-
1986
- 1986-07-21 IL IL8679463A patent/IL79463A0/xx unknown
- 1986-12-30 MY MY581/86A patent/MY8600581A/xx unknown
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1987
- 1987-12-30 MY MY138/87A patent/MY8700138A/xx unknown
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1988
- 1988-05-11 KE KE3819A patent/KE3819A/xx unknown
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1989
- 1989-03-10 CY CY1438A patent/CY1438A/xx unknown
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1990
- 1990-06-13 DK DK144190A patent/DK165182C/da not_active IP Right Cessation
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1991
- 1991-11-20 DK DK189391A patent/DK164901C/da not_active IP Right Cessation
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1992
- 1992-01-08 DK DK002392A patent/DK166082C/da not_active IP Right Cessation
- 1992-06-15 BG BG096468A patent/BG60335B2/bg unknown
- 1992-06-15 BG BG096470A patent/BG61518B2/bg unknown
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