MX167235B - Polimeros absorbentes de tratados superficialmente - Google Patents
Polimeros absorbentes de tratados superficialmenteInfo
- Publication number
- MX167235B MX167235B MX004150A MX415086A MX167235B MX 167235 B MX167235 B MX 167235B MX 004150 A MX004150 A MX 004150A MX 415086 A MX415086 A MX 415086A MX 167235 B MX167235 B MX 167235B
- Authority
- MX
- Mexico
- Prior art keywords
- water
- plus
- amount
- monomer mixture
- weight
- Prior art date
Links
- 239000002250 absorbent Substances 0.000 title abstract 5
- 230000002745 absorbent Effects 0.000 title abstract 4
- 238000004381 surface treatment Methods 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 7
- 239000011347 resin Substances 0.000 abstract 6
- 229920005989 resin Polymers 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 238000010521 absorption reaction Methods 0.000 abstract 2
- 150000001412 amines Chemical group 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000003505 polymerization initiator Substances 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Abstract
La presente invención se refiere a un método para mejorar las propiedades de absorción de agua de una resina absorbente de agua, el cual comprende el tratamiento superficial de la resina absorbente de agua con una cantidad suficiente de una amina policuaternaria, para incrementar substancialmente la absorción de agua de dicha resina absorbente de agua. Un proceso para preparar una resina cruzada sólida absorbente de agua, el cual comprende: combinar una mezcla de monómero de (A) acrilato de potasio; (B) estireno y/o metacrilato de metilo en una cantidad del 0 al 25 por ciento basándose en la cantidad de acrialto computada basada en el peso del ácido acrílico; y (C) un monómero de polivinilo, con agua en una cantidad de por lo menos 30 por ciento en peso combinado de (A) más (B) más (C), basándose en el peso total de (A) más (B) más (C) más agua, para formar una mezcla de monómero caracterizada porque los monómeros de la mezcla de monómero consisten esencialmente en (A), (B) y (C); añadir un iniciador de polimerización a dicha mezcla de monóemro, copolimerizar dicha mezcla de monómero utilizando el calor exotérmico de reacción; y poner dicho copolímero de resina cruzada en contacto con una amina policuaternaria en una cantidad desde aproximadamente el 0.1 hasta aproximadamente el 5.0 por ciento basándose en el peso de dicho copolímero de resina cruzada.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/872,654 US4755562A (en) | 1986-06-10 | 1986-06-10 | Surface treated absorbent polymers |
Publications (1)
Publication Number | Publication Date |
---|---|
MX167235B true MX167235B (es) | 1993-03-11 |
Family
ID=25360045
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX004150A MX167235B (es) | 1986-06-10 | 1986-10-24 | Polimeros absorbentes de tratados superficialmente |
Country Status (6)
Country | Link |
---|---|
US (2) | US4755562A (es) |
EP (1) | EP0248963B1 (es) |
AT (1) | ATE81137T1 (es) |
CA (1) | CA1276370C (es) |
DE (1) | DE3686884T2 (es) |
MX (1) | MX167235B (es) |
Families Citing this family (92)
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JPS6221365B2 (es) * | 1979-12-26 | 1987-05-12 | Goodrich Co B F | |
US4295987A (en) * | 1979-12-26 | 1981-10-20 | The Procter & Gamble Company | Cross-linked sodium polyacrylate absorbent |
US4473689A (en) * | 1979-12-26 | 1984-09-25 | Basf Wyandotte Corporation | Process for the aqueous polymerization of acrylamide |
JPS6025045B2 (ja) * | 1980-03-19 | 1985-06-15 | 製鉄化学工業株式会社 | 塩水吸収能のすぐれたアクリル酸重合体の製造方法 |
JPS6056724B2 (ja) * | 1980-10-22 | 1985-12-11 | 株式会社クラレ | 吸水性樹脂の製造方法 |
US4415388A (en) * | 1981-06-22 | 1983-11-15 | Johnson & Johnson | Method of making absorbent bearing products |
JPS6037202B2 (ja) * | 1981-08-10 | 1985-08-24 | 日本エクスラン工業株式会社 | 吸水性アクリル繊維 |
US4677174A (en) * | 1986-04-21 | 1987-06-30 | American Colloid Company | Water absorbent styrene-acrylic acid copolymers |
DE3239476C2 (de) * | 1981-10-26 | 1984-06-20 | Arakawa Kagaku Kogyo K.K., Osaka | Verfahren zur Herstellung eines festen, trockenen und wasserabsorbierenden harzes |
US4525527A (en) * | 1982-01-25 | 1985-06-25 | American Colloid Company | Production process for highly water absorbable polymer |
DE3225555A1 (de) * | 1982-07-08 | 1984-01-12 | Cassella Ag, 6000 Frankfurt | Vernetzer fuer wasserquellbare polymere |
US4500670B1 (en) * | 1983-11-22 | 1994-12-27 | Dow Chemical Co | Composite mixtures for improving gel strength of water absorbent gels |
US4535098A (en) * | 1984-03-12 | 1985-08-13 | The Dow Chemical Company | Material for absorbing aqueous fluids |
US4654039A (en) * | 1985-06-18 | 1987-03-31 | The Proctor & Gamble Company | Hydrogel-forming polymer compositions for use in absorbent structures |
-
1986
- 1986-06-10 US US06/872,654 patent/US4755562A/en not_active Expired - Lifetime
- 1986-10-24 MX MX004150A patent/MX167235B/es unknown
- 1986-11-19 EP EP86309037A patent/EP0248963B1/en not_active Expired - Lifetime
- 1986-11-19 DE DE8686309037T patent/DE3686884T2/de not_active Expired - Fee Related
- 1986-11-19 AT AT86309037T patent/ATE81137T1/de not_active IP Right Cessation
- 1986-11-20 CA CA000523413A patent/CA1276370C/en not_active Expired - Fee Related
-
1988
- 1988-04-25 US US07/185,853 patent/US4824901A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE3686884D1 (de) | 1992-11-05 |
US4824901A (en) | 1989-04-25 |
DE3686884T2 (de) | 1993-02-25 |
EP0248963B1 (en) | 1992-09-30 |
US4755562A (en) | 1988-07-05 |
EP0248963A2 (en) | 1987-12-16 |
ATE81137T1 (de) | 1992-10-15 |
CA1276370C (en) | 1990-11-13 |
EP0248963A3 (en) | 1989-07-12 |
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