MX166107B - Metodo para reducir al minimo o impedir la precipitacion del rodio - Google Patents
Metodo para reducir al minimo o impedir la precipitacion del rodioInfo
- Publication number
- MX166107B MX166107B MX006566A MX656687A MX166107B MX 166107 B MX166107 B MX 166107B MX 006566 A MX006566 A MX 006566A MX 656687 A MX656687 A MX 656687A MX 166107 B MX166107 B MX 166107B
- Authority
- MX
- Mexico
- Prior art keywords
- rhodium
- phosphite
- solubilized
- aldehyde
- complex
- Prior art date
Links
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 229910052703 rhodium Inorganic materials 0.000 title abstract 4
- 239000010948 rhodium Substances 0.000 title abstract 4
- 150000001299 aldehydes Chemical class 0.000 abstract 5
- 239000000047 product Substances 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 3
- APVDIAOSUXFJNU-UHFFFAOYSA-N rhodium(3+) phosphite Chemical compound [Rh+3].[O-]P([O-])[O-] APVDIAOSUXFJNU-UHFFFAOYSA-N 0.000 abstract 3
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 238000004821 distillation Methods 0.000 abstract 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 abstract 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000524 functional group Chemical group 0.000 abstract 1
- 238000007037 hydroformylation reaction Methods 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229920000620 organic polymer Polymers 0.000 abstract 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/865,061 US4717775A (en) | 1984-12-28 | 1986-05-20 | Transition metal complex catalyzed reactions |
| US07/046,821 US4774361A (en) | 1986-05-20 | 1987-05-11 | Transition metal complex catalyzed reactions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX166107B true MX166107B (es) | 1992-12-21 |
Family
ID=26724327
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX006566A MX166107B (es) | 1986-05-20 | 1987-05-20 | Metodo para reducir al minimo o impedir la precipitacion del rodio |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4774361A (en:Method) |
| EP (1) | EP0276231B1 (en:Method) |
| JP (1) | JPS63503385A (en:Method) |
| CN (1) | CN1010011B (en:Method) |
| AU (1) | AU613312B2 (en:Method) |
| CA (1) | CA1312094C (en:Method) |
| DE (1) | DE3773890D1 (en:Method) |
| ES (1) | ES2004935A6 (en:Method) |
| IN (1) | IN169727B (en:Method) |
| MX (1) | MX166107B (en:Method) |
| NO (1) | NO166583C (en:Method) |
| WO (1) | WO1987007261A2 (en:Method) |
Families Citing this family (85)
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|---|---|---|---|---|
| US4835299A (en) * | 1987-03-31 | 1989-05-30 | Union Carbide Corporation | Process for purifying tertiary organophosphites |
| IT1237530B (it) * | 1989-12-12 | 1993-06-08 | Eniricerche Spa | Procedimento per la sintesi diretta di alcoli da olefine,ossidi di carbonio e idrogeno,promossa da un catalizzatore di rodio supportato |
| US5210318A (en) * | 1990-05-04 | 1993-05-11 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes |
| US5087763A (en) * | 1990-11-09 | 1992-02-11 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process |
| JP2946790B2 (ja) * | 1991-03-14 | 1999-09-06 | 三菱化学株式会社 | アルデヒド類の製造法 |
| US5360938A (en) * | 1991-08-21 | 1994-11-01 | Union Carbide Chemicals & Plastics Technology Corporation | Asymmetric syntheses |
| GB9119955D0 (en) * | 1991-09-18 | 1991-10-30 | Imperial College | Treatment of aqueous supplies containing organic material |
| US5243099A (en) * | 1991-12-06 | 1993-09-07 | Union Carbide Chemicals & Plastics Technology Corporation | Synthesis of alpha-substituted alkadienes |
| US5169981A (en) * | 1991-12-06 | 1992-12-08 | Union Carbide Chemicals & Plastics Technology Corporation | Synthesis of alpha-substituted alkadienes |
| US5756855A (en) | 1994-08-19 | 1998-05-26 | Union Carbide Chemicals & Plastics Technology Corporation | Stabilization of phosphite ligands in hydroformylation process |
| US5672766A (en) * | 1994-12-12 | 1997-09-30 | Mitsubishi Chemical Corporation | Method for producing aldehydes |
| KR970703805A (ko) * | 1995-05-01 | 1997-08-09 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션 | 막 분리방법(Membrane Separation) |
| US5739352A (en) * | 1995-10-19 | 1998-04-14 | United Carbide Chemicals & Plastics Technology Corporation | Process for preparing carboxylic acids |
| DE19605435A1 (de) * | 1996-02-14 | 1997-08-21 | Basf Ag | Verfahren zur Herstellung von Aldehyden durch Hydroformylierung mit einem Rhodiumkatalysator und Wiedergewinnung des Rhodiumkatalysators durch Extraktion |
| US6090987A (en) * | 1998-07-06 | 2000-07-18 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| CN1163463C (zh) * | 1998-12-10 | 2004-08-25 | 三菱化学株式会社 | 醛的制备方法 |
| JP3921853B2 (ja) * | 1998-12-10 | 2007-05-30 | 三菱化学株式会社 | アルデヒド類及びアルコール類の製造方法 |
| GB9918229D0 (en) † | 1999-08-04 | 1999-10-06 | Ici Plc | Improvements relating to metal-compound catalysed processes |
| DE19954510A1 (de) | 1999-11-12 | 2001-05-17 | Oxeno Olefinchemie Gmbh | Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Ligandenmischungen |
| EP2453320B1 (en) | 2000-06-27 | 2016-06-29 | Dai Nippon Printing Co., Ltd. | Multilayer volume hologram, and label for multilayer volume hologram fabrication |
| EP1249441A1 (en) | 2001-04-13 | 2002-10-16 | Dsm N.V. | Continuous hydroformylation process |
| DE10220801A1 (de) * | 2002-05-10 | 2003-11-20 | Oxeno Olefinchemie Gmbh | Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste |
| AU2003250219A1 (en) | 2002-08-31 | 2004-04-30 | Oxeno Olefinchemie Gmbh | Method for producing aldehydes by means of hydroformylation of olefinically unsaturated compounds, said hydroformylation being catalysed by unmodified metal complexes in the presence of cyclic carbonic acid esters |
| PL206145B1 (pl) * | 2002-08-31 | 2010-07-30 | Oxeno Olefinchemie Gmbhoxeno Olefinchemie Gmbh | Sposób hydroformylowania związków nienasyconych olefinowo, w szczególności olefin, w obecności cyklicznych estrów kwasów karboksylowych |
| AU2003292815A1 (en) * | 2003-01-16 | 2004-08-10 | Teijin Fibers Limited | Differential-shrinkage polyester combined filament yarn |
| CN101654462B (zh) * | 2003-07-03 | 2013-05-29 | 陶氏技术投资有限责任公司 | 配体降解产物的最小化,或其向有用的膦配体的转化 |
| DE10349343A1 (de) * | 2003-10-23 | 2005-06-02 | Basf Ag | Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden |
| CN1993311B (zh) | 2004-08-02 | 2010-06-23 | 陶氏技术投资有限责任公司 | 加氢甲酰基化过程的稳定化 |
| RU2458906C2 (ru) * | 2007-03-20 | 2012-08-20 | Дау Текнолоджи Инвестментс Ллс | Способ гидроформилирования с усовершенствованным контролем над изомерами продуктов |
| CN101681776B (zh) * | 2007-04-09 | 2011-10-05 | Lg化学株式会社 | 含有亚磷酸酯配体的催化剂组合物和使用该催化剂组合物的加氢甲酰化方法 |
| PL2703380T3 (pl) | 2008-07-03 | 2016-05-31 | Dow Technology Investments Llc | Sposób obróbki produktu wyjściowego z hydroformylowania |
| US8921486B2 (en) | 2008-11-14 | 2014-12-30 | University Of Kansas | Polymer-supported transition metal catalyst complexes and methods of use |
| JP5603407B2 (ja) | 2009-03-31 | 2014-10-08 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | 二重オープンエンド型ビスホスファイトリガンドによるヒドロホルミル化方法 |
| US7928267B1 (en) * | 2009-06-22 | 2011-04-19 | Eastman Chemical Company | Phosphite containing catalysts for hydroformylation processes |
| JP5823967B2 (ja) | 2009-10-16 | 2015-11-25 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | 気相ヒドロホルミル化方法 |
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| JP5912084B2 (ja) | 2009-12-22 | 2016-04-27 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | オレフィン分圧の制御による、混合リガンドヒドロホルミル化プロセスにおけるノルマル：イソアルデヒド比の制御 |
| EP2624953B1 (en) | 2010-10-05 | 2018-10-24 | Dow Technology Investments LLC | Hydroformylation process |
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| SA112330271B1 (ar) | 2011-04-18 | 2015-02-09 | داو تكنولوجى انفستمنتس ال ال سى | تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء |
| PL2822921T3 (pl) | 2012-03-07 | 2018-11-30 | Basf Se | SPOSÓB INTEGRACJI CIEPŁA PRZY UWODORNIANIU I DESTYLACJI C<sub>3</sub>-C<sub>20</sub>- ALDEHYDÓW |
| US8889917B2 (en) | 2012-04-12 | 2014-11-18 | Basf Se | Method of supplementing the catalyst in continuous hydroformylation |
| CN104245654B (zh) | 2012-04-12 | 2016-10-12 | 巴斯夫欧洲公司 | 在连续加氢甲酰化中补充催化剂的方法 |
| KR102067305B1 (ko) | 2012-06-04 | 2020-01-16 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 하이드로포밀화 공정 |
| RU2639874C2 (ru) | 2012-08-29 | 2017-12-25 | Дау Текнолоджи Инвестментс Ллс | Способ получения катализатора |
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| CN104045532B (zh) | 2013-03-15 | 2018-05-25 | 陶氏技术投资有限责任公司 | 加氢甲酰化方法 |
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| CN104725170B (zh) | 2013-12-19 | 2019-08-23 | 陶氏技术投资有限责任公司 | 加氢甲酰化方法 |
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| MY184826A (en) * | 2014-12-04 | 2021-04-24 | Dow Technology Investments Llc | Hydroformylation process |
| TWI709568B (zh) | 2015-09-30 | 2020-11-11 | 美商陶氏科技投資公司 | 用於製造有機磷化合物的方法 |
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| JP6908602B2 (ja) | 2015-11-10 | 2021-07-28 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | アルデヒドの生成プロセス |
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| TWI758353B (zh) | 2016-11-08 | 2022-03-21 | 美商陶氏科技投資有限公司 | 使去活化的氫甲醯化催化劑溶液再生的方法 |
| TW201840362A (zh) | 2016-11-08 | 2018-11-16 | 美商陶氏科技投資有限公司 | 使去活化的氫甲醯化催化劑溶液再生的方法 |
| US10981851B2 (en) | 2017-10-25 | 2021-04-20 | Dow Technology Investments Llc | Hydroformylation process |
| JP7269238B2 (ja) | 2017-11-13 | 2023-05-08 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | ヒドロホルミル化プロセスからロジウムを回収するためのプロセス |
| TWI793216B (zh) | 2017-12-07 | 2023-02-21 | 美商陶氏科技投資公司 | 氫甲醯化方法 |
| KR20210013702A (ko) | 2018-05-30 | 2021-02-05 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 하이드로포밀화 공정에서 촉매의 탈활성화를 느리게 하고/하거나 테트라포스핀 리간드 사용을 느리게 하는 방법 |
| BR112020022065A2 (pt) | 2018-05-30 | 2021-02-02 | Dow Technology Investments Llc | composição de catalisador que compreende a combinação de uma monofosfina, um ligante de tetrafosfina e um processo de hidroformilação com o uso dos mesmos |
| CA3100779A1 (en) | 2018-05-30 | 2019-12-05 | Dow Technology Investments Llc | Methods of controlling hydroformylation processes |
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| GB202307175D0 (en) | 2023-05-15 | 2023-06-28 | Johnson Matthey Davy Technologies Ltd | Process for hydrogenating a substrate |
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| WO2025029369A1 (en) | 2023-08-03 | 2025-02-06 | Dow Technology Investments Llc | Process for improving rhodium/phosphite- based homogenous hydroformylation catalyst activity |
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| DE2326489A1 (de) * | 1973-05-24 | 1974-12-12 | Ernst Prof Dr Bayer | Verfahren zur katalyse unter verwendung von loeslichen metallverbindungen synthetischer polymerer |
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| US4504684A (en) * | 1982-01-06 | 1985-03-12 | The Standard Oil Company | Metal coordination polymers as hydroformylation and hydrogenation catalysts |
| EP0096988B1 (en) * | 1982-06-11 | 1987-07-08 | DAVY McKEE (LONDON) LIMITED | Hydroformylation process |
| US4528403A (en) * | 1982-10-21 | 1985-07-09 | Mitsubishi Chemical Industries Ltd. | Hydroformylation process for preparation of aldehydes and alcohols |
| US4528404A (en) * | 1983-03-16 | 1985-07-09 | Exxon Research And Engineering Co. | High temperature hydroformylation in the presence of triarylphosphine rhodium carbonyl hydride complex catalyst systems |
| GB8334359D0 (en) * | 1983-12-23 | 1984-02-01 | Davy Mckee Ltd | Process |
| US4599206A (en) * | 1984-02-17 | 1986-07-08 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
| US4599456A (en) * | 1984-12-20 | 1986-07-08 | Phillips Petroleum Company | Novel aldehyde-phosphine compositions and uses therefor |
| US4668651A (en) * | 1985-09-05 | 1987-05-26 | Union Carbide Corporation | Transition metal complex catalyzed processes |
| US4613701A (en) * | 1985-09-19 | 1986-09-23 | Celanese Corporation | Recovery of rhodium from hydroformylation reaction product |
-
1987
- 1987-05-11 US US07/046,821 patent/US4774361A/en not_active Expired - Lifetime
- 1987-05-19 EP EP87903774A patent/EP0276231B1/en not_active Expired - Lifetime
- 1987-05-19 JP JP62503400A patent/JPS63503385A/ja active Granted
- 1987-05-19 WO PCT/US1987/001124 patent/WO1987007261A2/en not_active Ceased
- 1987-05-19 DE DE8787903774T patent/DE3773890D1/de not_active Expired - Lifetime
- 1987-05-19 AU AU74898/87A patent/AU613312B2/en not_active Ceased
- 1987-05-20 CA CA000537549A patent/CA1312094C/en not_active Expired - Lifetime
- 1987-05-20 ES ES8701486A patent/ES2004935A6/es not_active Expired
- 1987-05-20 IN IN373/MAS/87A patent/IN169727B/en unknown
- 1987-05-20 CN CN87104311A patent/CN1010011B/zh not_active Expired
- 1987-05-20 MX MX006566A patent/MX166107B/es unknown
-
1988
- 1988-01-19 NO NO880207A patent/NO166583C/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE3773890D1 (de) | 1991-11-21 |
| WO1987007261A2 (en) | 1987-12-03 |
| NO166583B (no) | 1991-05-06 |
| NO166583C (no) | 1991-08-14 |
| NO880207D0 (no) | 1988-01-19 |
| AU7489887A (en) | 1987-12-22 |
| EP0276231A1 (en) | 1988-08-03 |
| CA1312094C (en) | 1992-12-29 |
| JPH0548215B2 (en:Method) | 1993-07-20 |
| EP0276231B1 (en) | 1991-10-16 |
| US4774361A (en) | 1988-09-27 |
| WO1987007261A3 (en) | 1988-04-07 |
| CN87104311A (zh) | 1988-06-08 |
| NO880207L (no) | 1988-01-19 |
| JPS63503385A (ja) | 1988-12-08 |
| AU613312B2 (en) | 1991-08-01 |
| ES2004935A6 (es) | 1989-02-16 |
| IN169727B (en:Method) | 1991-12-14 |
| CN1010011B (zh) | 1990-10-17 |
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