KR970702337A - 수희석성 공기 건조 니스 결합제의 제조방법 및 이의 용도(Process for preparing water-dilutable, air-drying varnish binders and use thereof) - Google Patents

수희석성 공기 건조 니스 결합제의 제조방법 및 이의 용도(Process for preparing water-dilutable, air-drying varnish binders and use thereof) Download PDF

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KR970702337A
KR970702337A KR1019960705507A KR19960705507A KR970702337A KR 970702337 A KR970702337 A KR 970702337A KR 1019960705507 A KR1019960705507 A KR 1019960705507A KR 19960705507 A KR19960705507 A KR 19960705507A KR 970702337 A KR970702337 A KR 970702337A
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South Korea
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weight
dilutable
acid
alkyd resin
water
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KR1019960705507A
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KR100354199B1 (ko
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요한 빌리아니
미카엘 고벡
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슐링만 메르텐, 하누스 한스-디터
비아노바 레진스 아크티엔게젤샤프트
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Publication of KR970702337A publication Critical patent/KR970702337A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/46—Polyesters chemically modified by esterification
    • C08G63/48—Polyesters chemically modified by esterification by unsaturated higher fatty oils or their acids; by resin acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C09D133/064—Copolymers with monomers not covered by C09D133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/08—Polyesters modified with higher fatty oils or their acids, or with resins or resin acids

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Paper (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

본 발명은 아크릴 및 비닐 개질 알키드 수지 에멀젼을 기재로 하는 수회석성 공기 건조 니스 결합제를 제조하는 방법에 관한 것이다. 결합제는 특정 (메트)아크릴레이트 단량체를 통해서 도입된 폴리옥시알킬렌 그룹을 함유하고, “보조 용매”를 사용하지 않고도 광택이 우수한 니스 피복용 결합제로서 매우 적합하다.

Description

수희석성 공기 건조 니스 결합제의 제조방법 및 이의 용도(Process for preparing water-dilutable, air-drying varnish binders and use thereof)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. A) 불포화 지방산(a1) 25 내지 50중량%, 메트아크릴산(a2) 10 내지 25중량%, 폴리옥시알킬렌 그룹을 함유하는 (메트)아크릴레이트 단량체(a3) 1 내지 15중량% 및 C-C 이중 결합 이외에는 어떠한 작용 그룹도 함유하지 않는 기타의 (메트)아크릴레이트 및/또는 비닐 단량체(a4) 25 내지 50중량%를 함유하는 단량체 혼합물을 95중량% 이상이 전환되도록 유리 라디칼 개시제의 존재하에 중합시키고, B) 추가의 반응 단계에서 공중합체(A) (b1) 33 내지 44중량%, 불포화 지방산(b2) 20 내지 42중량%, 2 내지 6개의 하이드록실 그룹을 갖는 폴리알콜(b3) 10 내지 25중량%, 방향족 및/또는 지방족 디카복실산(b4) 10 내지 20중량% 및 사이클릭 및/또는 폴리사이클릭 카복실산(b5) 0 내지 15중량%를 반응시켜, 개질된 알키드 수지(B)[이는, 고체 함량을 기준으로 하여, 불포화 지방산의 함량이 30 내지 70중량%, 바람직하게는 40 내지 60중량%이고 고유점도가 8 내지 15㎖/g(클로로포름, 20℃) 이며 산가가 g당 KOH 25 내지 70mg고 상응하는 카복실 그룹의 80% 이상이 공중합체(A)의 메트아크릴산 단위로부터 유도된다]를 형성시키고 이렇게 수득한 개질된 알키드 수지(B)를 유기 용매를 사용하지 않고 물 속에서 유화시킴(각각의 경우, 성분(a1) 내지 성분(a4)의 % 합과 성분(b1) 내지 성분(a5)의 % 합은 각각 반드시 100이어야 하며, 단 단계(B)에서 성분(b2) 내지 성분(b5)는 투명한 용융물이 되고 산가가 g당 KOH 3 내지 30mg에 이를 때가지 예비에스테르화된다)을 특징으로 하여 아크릴 개질되고 비닐 개질된 알키드 수지 에멀젼을 기재로 하는 수희석성 공기 건조 도료 결합제를 제조하는 방법.
  2. 제1항에 있어서, 성분(a3)이 3개 이상의 옥시알킬렌 그룹을 함유하고 화학식 CH2=CHR1-CO-O-(CH2-CHR1-O)n-R2에 상응하는 (메트)아크릴레이트 단량체(여기서, R1은 H 또는 CH3이고 R2는 H, CH3또는 C2H5이며 n은 3 내지 45이다)로 이루어짐을 특징으로 하는 방법.
  3. 100℃ 이하의 온도에서 산화적으로 건조되는 수희석성 도료 재료의 제형에 있어서의 제1항 및 제2항에 따라서 제조된 도료 결합제의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960705507A 1994-04-07 1995-04-06 수희석성공기건조도료결합제의제조방법및이방법으로제조된도료결합제를포함하는수희석성도료재료 KR100354199B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT0071194A AT400719B (de) 1994-04-07 1994-04-07 Verfahren zur herstellung von wasserverdünnbaren lufttrocknenden lackbindemitteln und deren verwendung
ATA711/94 1994-04-07

Publications (2)

Publication Number Publication Date
KR970702337A true KR970702337A (ko) 1997-05-13
KR100354199B1 KR100354199B1 (ko) 2005-01-25

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KR1019960705507A KR100354199B1 (ko) 1994-04-07 1995-04-06 수희석성공기건조도료결합제의제조방법및이방법으로제조된도료결합제를포함하는수희석성도료재료

Country Status (17)

Country Link
US (1) US5698625A (ko)
EP (1) EP0758365B1 (ko)
JP (1) JP3822235B2 (ko)
KR (1) KR100354199B1 (ko)
CN (1) CN1060791C (ko)
AT (2) AT400719B (ko)
AU (1) AU2208295A (ko)
BR (1) BR9507292A (ko)
CA (1) CA2186599C (ko)
CZ (1) CZ287508B6 (ko)
DE (1) DE59503078D1 (ko)
DK (1) DK0758365T3 (ko)
ES (1) ES2122578T3 (ko)
HU (1) HU221739B1 (ko)
NO (1) NO311091B1 (ko)
SI (1) SI0758365T1 (ko)
WO (1) WO1995027762A1 (ko)

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PL236351B1 (pl) 2011-07-24 2021-01-11 Allnex Austria Gmbh Mieszaniny co najmniej jednej dyspersji żywicy akrylowej i ich zastosowanie
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CZ2012147A3 (cs) * 2012-03-01 2013-05-22 SYNPO, akciová spolecnost Zpusob prípravy alkydových pryskyric, urethanizovaných alkydu a urethanových oleju
EP2889318A1 (en) 2013-12-31 2015-07-01 ALLNEX AUSTRIA GmbH Modified water-borne alkyd resin
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Also Published As

Publication number Publication date
HU221739B1 (hu) 2002-12-28
NO311091B1 (no) 2001-10-08
NO964057L (no) 1996-09-26
AT400719B (de) 1996-03-25
DK0758365T3 (da) 1999-05-03
CZ287508B6 (en) 2000-12-13
DE59503078D1 (de) 1998-09-10
HUT74969A (en) 1997-03-28
CN1060791C (zh) 2001-01-17
NO964057D0 (no) 1996-09-26
JPH09512566A (ja) 1997-12-16
EP0758365B1 (de) 1998-08-05
CA2186599A1 (en) 1995-10-19
ATE169327T1 (de) 1998-08-15
CN1145084A (zh) 1997-03-12
AU2208295A (en) 1995-10-30
EP0758365A1 (de) 1997-02-19
ES2122578T3 (es) 1998-12-16
CA2186599C (en) 2006-05-23
CZ293596A3 (en) 1997-03-12
HU9602737D0 (en) 1996-11-28
ATA71194A (de) 1995-07-15
KR100354199B1 (ko) 2005-01-25
WO1995027762A1 (de) 1995-10-19
JP3822235B2 (ja) 2006-09-13
US5698625A (en) 1997-12-16
BR9507292A (pt) 1997-09-23
MX9604325A (es) 1997-12-31
SI0758365T1 (en) 1998-10-31

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