KR970063009A - 인-몰드 성형용 라벨 및 이를 부착한 용기 - Google Patents

인-몰드 성형용 라벨 및 이를 부착한 용기 Download PDF

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KR970063009A
KR970063009A KR1019960035258A KR19960035258A KR970063009A KR 970063009 A KR970063009 A KR 970063009A KR 1019960035258 A KR1019960035258 A KR 1019960035258A KR 19960035258 A KR19960035258 A KR 19960035258A KR 970063009 A KR970063009 A KR 970063009A
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weight
mold
resin
container
peak
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KR100443434B1 (ko
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아키히코 오노
다카토시 니시자와
마사키 시이나
쥰이치 야스다
하지메 이케노
게이코 시치조
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다나베 마사히코
오지유카고세이시 가부시키가이샤
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    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/24—Lining or labelling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02—Physical, chemical or physicochemical properties
    • B32B7/027—Thermal properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D23/00—Details of bottles or jars not otherwise provided for
    • B65D23/08—Coverings or external coatings
    • B65D23/0842—Sheets or tubes applied around the bottle with or without subsequent folding operations
    • B65D23/0864—Applied in mould
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/04—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps to be fastened or secured by the material of the label itself, e.g. by thermo-adhesion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04—Polymers of ethylene
    • B29K2023/06—PE, i.e. polyethylene
    • B29K2023/0608—PE, i.e. polyethylene characterised by its density
    • B29K2023/065—HDPE, i.e. high density polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/10—Polymers of propylene
    • B29K2023/12—PP, i.e. polypropylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/744—Labels, badges, e.g. marker sleeves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/02—Cellular or porous
    • B32B2305/026—Porous
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514—Oriented
    • B32B2307/518—Oriented bi-axially
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2519/00—Labels, badges
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02—Column chromatography
    • G01N30/26—Conditioning of the fluid carrier; Flow patterns
    • G01N30/28—Control of physical parameters of the fluid carrier
    • G01N30/30—Control of physical parameters of the fluid carrier of temperature
    • G01N2030/3084—Control of physical parameters of the fluid carrier of temperature ovens
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02—Column chromatography
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/91—Product with molecular orientation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1376—Foam or porous material containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249967—Inorganic matrix in void-containing component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31913—Monoolefin polymer

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Theoretical Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Laminated Bodies (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

이의 전면에 인쇄물이 있는 열가소성 수지 필름 기재층(Ⅰ) 및, 열가소성 수지 기재층(Ⅰ)의 배면에 형성된, 열가소성 수지 필름 기재층(Ⅰ)의 구성 수지보다 융점이 낮고, 메탈로센 촉매를 사용하여 에틸렌 40 내지 98중량%와 탄소수 3 내지 30의-올레핀 60 내지 2중량%를 공중합시켜 수득한 에틸렌/

Description

인-몰드 성형용 라벨 및 이를 부착한 용기
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 인-몰드 성형용 라벨(in-mold label)의 단면도이다.
제2도는 표면 조도 미터를 사용한 측정 결과를 나타내는, 배면에서 바라본 제1도의 인-몰드 성형용 라벨의 확대 평면도이다.
제3도는 제1도의 인-몰드 성형용 라벨 일부의 확대 단면도이다.
제4도는 TREF 곡선을 나타낸다.

Claims (13)

  1. 전면에 인쇄물이 있는 열가소성 수지 필름 기재층(Ⅰ)과, 열가소성 수지 필름 기재층(Ⅰ)의 배면에 형성되어 있으며 융점이 열가소성 수지 필름 기재층(Ⅰ)의 구성 수지보다 낮고 메탈로센 촉매를 사용하여 에틸렌 40 내지 98중량%의 탄소수 3 내지 30의-올레핀 60 내지 2중량%를 공중합시켜 수득한 에틸렌/-올레핀 공중합체를 주성분으로서 함유하는 열 접착성 수지층(Ⅱ)을 포함하는 인-몰드 성형용 라벨(in-mold label).
  2. 제1항에 있어서, 에틸렌/-올레핀 공중합체가, (1) MFR이 2 내지 30g/10min이고, (2) 밀도가 0.935g/cm3이하이며, (3) 온도 상승 용리 분별화(TREF)에 있어서, 피크가 하나이며, 이때 피크 온도는 20 내지 85C이고 H/W(여기서, H는 피크의 높이이며, W는 1/2 높이에서의 피크 너비이다) 값은 1 이상이며 공중합체가 피크 용리온도와는 다른 온도에서 용리되는 하나 이상의 성분을 실제로 함유하는 것으로 나타난 용리 곡선이 수득되는 특성 요건을 만족시키는 인-몰드 성형용 라벨.
  3. 제1항에 있어서, 열 접착성 수지층(Ⅱ)이, (1) MFR이 2 내지 30g/10min이고, (2) 밀도가 0.935g/cm3이하이며, (3) 온도 상승 용리 분별화(TREF)에 있어서, 피크가 하나이며, 이때 피크 온도는 20내지 85C이고 H/W(여기서, H는 피크의 높이이며, W는 1/2높이에서의 피크 너비이다) 값은 1 이상이며 공중합체가 피크 용리온도와는 다른 온도에서 용리되는 하나 이상의 성분을 실제로 함유하는 것으로 나타난 용리 곡선이 수득되는 특성 요건을 만족시키는, 메탈로센 촉매를 사용하여 에틸렌 40 내지 98중량%와 탄소수 3 내지 30의-올레핀 60 내지 2중량%를 공중합시켜 수득한 에틸렌/-올레핀 공중합체(a) 50 내지 90중량%와 (1') MFR이 0.1 내지 20g/10min이고, (2') 밀도가 0.195 내지 0.93g/cm3이며, (3') 기억 효과(ME)가 1.6 이상이고, (4') 응용장력(MT)이 1.5g 이상인 특성요건을 만족시키는 고압 저밀도 폴리에틸렌(b) 50 내지 10중량%를 포함하는 수지 조성물을 필수적으로 이루어진 인-몰드 성형용 라벨.
  4. 제1항에 있어서, 열가소성 수지 필름 기재층(Ⅰ)이 무기 미립자 5 내지 30중량%, 고밀도 폴리에틸렌 3 내지 20중량% 및 폴리프로필렌 수지 92 내지 50중량%를 포함하는 이축 신장된 필름 기재층(A), 기재층(A)의 한 면에 적층되고 무기 미립자 35 내지 65중량%, 고밀도 폴리에틸렌 0 내지 10중량% 및 폴리프로필렌 수지 55 내지 35중량%를 포함하는 수지 조성물의 단축 신장된 필름으로 이루어진 제지형 층(B) 및 제지형 층(B)와 마주보는 면의 기재층(A)에 적층되고 무기 미립자 35 내지 65중량%, 고밀도 폴리에틸렌 0 내지 10중량% 및 폴리프로필렌 수지 55 내지 35중량%를 포함하는 수지 조성물의 단축 신장된 필름으로 이루어진 제지형 층(C)를 포함하는 미소 다공성 적층 수지 필름이며, 제지형 층(B) 면에는 인쇄물이 존재하고 제지형 층(C) 면에는 열 접착성 수지층(Ⅱ)이 존재하는 인-몰드 성형용 라벨.
  5. 제1항에서 청구한 인-몰드 성형용 라벨이 이의 표면에 부착된 중공 용기를 포함하는 용기.
  6. 제2항에서 청구한 인-몰드 성형용 라벨이 이의 표면에 부착된 중용 용기를 포함하는 용기.
  7. 제3항에서 청구한 인-몰드 성형용 라벨이 이의 표면에 부착된 중용 용기를 포함하는 용기.
  8. 제1항에서 청구한 인-몰드 성형용 라벨을 금형의 공동에 고정시키고, 파리손을 공동에 도입시킨 다음, 금형을 밀폐시키고, 압축 공기를 파리손으로 공급하여 이를 팽창시킴을 포함하는, 라벨이 부착된 용기의 성형방법.
  9. 제8항에 있어서, 파리손용 수지가 폴리프로필렌 또는 고밀도 폴리에틸렌인, 라벨이 부착된 용기의 성형방법.
  10. 제2항에서 청구한 인-몰드 성형용 라벨을 금형의 공동에 고정시키고, 파리손을 공동에 도입시킨 다음, 금형을 밀폐시키고, 압축 공기를 파리손으로 공급하여 이를 팽창시킴을 포함하는, 라벨이 부착된 용기의 성형방법.
  11. 제10항에 있어서, 파리손용 수지가 폴리프로필렌 또는 고밀도 폴리에틸렌인, 라벨이 부착된 용기의 성형방법.
  12. 제3항에서 청구한 인-몰드 성형용 라벨을 금형의 공동에 고정시키고, 파리손을 공동에 도입시킨 다음, 금형을 밀폐시키고, 압축 공기를 파리손으로 공급하여 이를 팽창시킴을 포함하는, 라벨이 부착된 용기의 성형방법.
  13. 제12항에 있어서, 파리손용 수지가 폴리프로필렌 또는 고밀도 폴리에틸렌인, 라벨이 부착된 용기의 성형방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960035258A 1996-02-02 1996-08-24 인-몰드성형용라벨,이를부착한용기및이러한용기의성형방법 KR100443434B1 (ko)

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JP03912896A JP3920373B2 (ja) 1996-02-02 1996-02-02 インモールド成形用ラベル

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EP0787581B1 (en) 2003-11-12
JP3920373B2 (ja) 2007-05-30
EP0787581A1 (en) 1997-08-06
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KR100443434B1 (ko) 2004-10-22
AU6442996A (en) 1997-08-07

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