KR970021046A - 시클로알킬 히드로퍼옥시드의 분해 방법 - Google Patents

시클로알킬 히드로퍼옥시드의 분해 방법 Download PDF

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KR970021046A
KR970021046A KR1019960046012A KR19960046012A KR970021046A KR 970021046 A KR970021046 A KR 970021046A KR 1019960046012 A KR1019960046012 A KR 1019960046012A KR 19960046012 A KR19960046012 A KR 19960046012A KR 970021046 A KR970021046 A KR 970021046A
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South Korea
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alkali metal
salt
decomposition
cycloalkyl
weight
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KR1019960046012A
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English (en)
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KR100446374B1 (ko
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프란시스쿠스 크라그텐 우발두스
안나 크리스티아안 바우르 헨리쿠스
게라르두스 후베르투스 마리아 하우스만스 죠한네스
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죠한나 아드리아나 마리아 기르츠
디에스엠 엔. 브이.
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • C07C27/10—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons
    • C07C27/12—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons with oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Abstract

본 발명은 시클로알킬 히드로퍼옥시드를 함유하는 혼합물의 분해방법에 관한 것으로서, 이는 알칼리 금속 수산화물 이외에 또한 적어도 10중량%의 하나 이상의 알칼리 금속 염의 수상이 존재하는 수상내 용해된 알칼리 금속 수산화물의 존재시, 시클로알킬 히드로퍼옥시드를 함유하는 혼합물을 분해하는 것이며, 이때 상기 알칼리 금속 염은 바람직하게는 알칼리 금속 탄산염, 또는 1 내지 24개의 탄소원자로 구성된 카르복실산을 갖는 모노- 및 폴리카르복실산의 알칼리 금속 염인 것을 특징으로 한다.

Description

시클로알킬 히드로퍼옥시드의 분해 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 수상내 용해된 알칼리 금속 수산화물의 존재시 시클로알킬 히드로퍼옥시드로 구성된 혼합물을 분해하는 방법에 있어서, 알칼리 금속 수산화물 이외에, 수상에 대해서 적어도 10중량%의 한개 이상의 알칼리 금속 염이 존재하는 것을 특징으로 하는 시클로알킬 히드로퍼옥시드를 함유하는 혼합물의 분해 방법.
  2. 제1항에 있어서, 상기 알칼리 금속 염은 알칼리 금속 탄산염 또는 모노- 및 폴리카르복실산의 알칼리 금속염으로서, 모노카르복실산 또는 폴리카르복실산의 카르복실산 절반은 1 내지 24개의 탄소원자를 함유하는 것을 특징으로 하는 방법.
  3. 제1항 또는 제2항에 있어서, 상기 알칼리 금속이 나트륨 또는 칼륨인 것을 특징으로 하는 방법.
  4. 제1항 내지 제3항 중 어느 한 항에 있어서, 시클로알킬 히드로퍼옥시드를 함유하는 상 이외에 존재하는 수상을 기본으로 상기 염 농도가 45중량% 이하인 것을 특징으로 하는 방법.
  5. 제1항 내지 제4항 중 어느 한 항에 있어서, 상기 염 농도가 20 내지 35중량%인 것을 특징으로 하는 방법.
  6. 제1항 내지 제5항 중 어느 한 항에 있어서, 알칼리 금속 수산화물의 양이, 분해 반응의 끝에서 OH의 농도가 0.1 내지 2N이 되도록 사용되는 것을 특징으로 하는 방법.
  7. 제1항 내지 제6항 중 어느 한 항에 있어서, 분해중 전이 금속의 분해-촉진염이 0.1 내지 1000ppm 범위로 또한 존재하는 것을 특징으로 하는 방법.
  8. 제1항 내지 제7항 중 어느 한 항에 있어서, 시클로알킬 히드로퍼옥시드를 함유하는 혼합물이, 산화 촉매가 없을때 0.3 내지 5MPa의 압력, 120 내지 200℃의 온도에서 상응의 시클로알킬을 산화시킴으로써 수득되는 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960046012A 1995-10-13 1996-10-12 시클로알킬히드로퍼옥시드의분해방법 KR100446374B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
BE9500853 1995-10-13
BE9500853A BE1009662A3 (nl) 1995-10-13 1995-10-13 Werkwijze voor het ontleden van cycloalkylhydroperoxide.

Publications (2)

Publication Number Publication Date
KR970021046A true KR970021046A (ko) 1997-05-28
KR100446374B1 KR100446374B1 (ko) 2004-11-03

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KR1019960046012A KR100446374B1 (ko) 1995-10-13 1996-10-12 시클로알킬히드로퍼옥시드의분해방법

Country Status (22)

Country Link
US (1) US5905173A (ko)
EP (1) EP0768292B1 (ko)
JP (1) JP3897384B2 (ko)
KR (1) KR100446374B1 (ko)
CN (1) CN1062259C (ko)
AR (1) AR003877A1 (ko)
AU (1) AU700696B2 (ko)
BE (1) BE1009662A3 (ko)
BR (1) BR9605132A (ko)
CA (1) CA2187709C (ko)
CO (1) CO4560461A1 (ko)
CZ (1) CZ296696A3 (ko)
DE (1) DE69606128T2 (ko)
ES (1) ES2143714T3 (ko)
HU (1) HU216540B (ko)
IL (1) IL119410A (ko)
MX (1) MX9604783A (ko)
PL (1) PL188039B1 (ko)
RU (1) RU2185366C2 (ko)
SK (1) SK282415B6 (ko)
TW (1) TW338762B (ko)
ZA (1) ZA968565B (ko)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE1011041A3 (nl) * 1997-03-12 1999-04-06 Dsm Nv Werkwijze voor het ontleden van cycloalkylhydroperoxide.
WO2001079966A2 (en) * 2000-04-14 2001-10-25 American Express Travel Related Services Company, Inc. A system and method for using loyalty points
US6700022B2 (en) * 2002-06-05 2004-03-02 E. I. Du Pont De Nemours And Company High yield cyclohexyl hydroperoxide decompostition process
WO2006033740A1 (en) * 2004-08-24 2006-03-30 Invista Technologies S.A.R.L. Method for reducing cyclohexenone content of a cyclohexenone-containing organic mixture
MX2007008981A (es) * 2005-01-25 2007-09-21 Dsm Ip Assets Bv Procedimiento para preparar ciclohexanona y ciclohexanol.
US8376224B2 (en) 2006-05-25 2013-02-19 Sean I. Mcghie Self-service stations for utilizing non-negotiable credits earned from a game of chance
US7834217B2 (en) * 2006-12-05 2010-11-16 Daicel Chemical Industries, Ltd. Method for producing oxidation product of cycloalkane
CN103372462B (zh) * 2012-04-26 2016-03-23 中国科学院大连化学物理研究所 一种分解环烷基过氧化氢水溶性催化剂体系及应用
CN105339332B (zh) * 2013-04-18 2018-04-10 罗地亚经营管理公司 环烷烃氧化催化剂以及生产醇和酮的方法
EP3214061A4 (en) 2014-10-31 2018-07-18 UBE Industries, Ltd. Method for producing ketone and/or alcohol, and system thereof
EP3388409A4 (en) 2015-12-07 2019-07-24 UBE Industries, Ltd. METHOD FOR PRODUCING KETONE AND / OR ALCOHOL AND SYSTEM THEREFOR

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2127520A1 (de) * 1971-06-03 1972-12-14 Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Cycloalkanol- und Cycloalkanon-Gemischen
NL7802125A (nl) * 1978-02-25 1979-08-28 Stamicarbon Werkwijze voor het bereiden van cycloalkanolen en cycloalkanonen.
JPS5738735A (en) * 1980-08-19 1982-03-03 Mitsui Petrochem Ind Ltd Method for treating hydroperoxide mixture
NL8201695A (nl) * 1982-04-23 1983-11-16 Stamicarbon Werkwijze voor de bereiding van cyclohexanol en cyclohexanon.
US5206441A (en) * 1992-04-06 1993-04-27 E. I. Du Pont De Nemours And Company High rate process for preparation of cyclohexanol and cyclohexanone
BE1007904A3 (nl) * 1993-12-23 1995-11-14 Dsm Nv Werkwijze voor de bereiding van een alkanol en/of een alkanon.

Also Published As

Publication number Publication date
PL316490A1 (en) 1997-04-14
BE1009662A3 (nl) 1997-06-03
EP0768292B1 (en) 2000-01-12
RU2185366C2 (ru) 2002-07-20
CZ296696A3 (en) 1997-06-11
TW338762B (en) 1998-08-21
CN1062259C (zh) 2001-02-21
BR9605132A (pt) 1998-07-07
US5905173A (en) 1999-05-18
CA2187709C (en) 2005-03-29
CO4560461A1 (es) 1998-02-10
DE69606128T2 (de) 2000-08-31
MX9604783A (es) 1997-08-30
EP0768292A1 (en) 1997-04-16
HUP9602820A2 (en) 1997-05-28
AU700696B2 (en) 1999-01-14
SK282415B6 (sk) 2002-01-07
ZA968565B (en) 1997-05-13
AR003877A1 (es) 1998-09-09
IL119410A0 (en) 1997-01-10
AU6818496A (en) 1997-04-17
JP3897384B2 (ja) 2007-03-22
IL119410A (en) 2000-11-21
SK129096A3 (en) 1997-05-07
CA2187709A1 (en) 1997-04-14
HU216540B (hu) 1999-07-28
ES2143714T3 (es) 2000-05-16
CN1156714A (zh) 1997-08-13
HUP9602820A3 (en) 1998-04-28
KR100446374B1 (ko) 2004-11-03
PL188039B1 (pl) 2004-11-30
DE69606128D1 (de) 2000-02-17
JPH09194408A (ja) 1997-07-29
HU9602820D0 (en) 1996-11-28

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