KR890002435A - 로듐 착화합물을 함유하는 수용액으로부터 로듐의 회수방법 - Google Patents

로듐 착화합물을 함유하는 수용액으로부터 로듐의 회수방법 Download PDF

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KR890002435A
KR890002435A KR1019870007451A KR870007451A KR890002435A KR 890002435 A KR890002435 A KR 890002435A KR 1019870007451 A KR1019870007451 A KR 1019870007451A KR 870007451 A KR870007451 A KR 870007451A KR 890002435 A KR890002435 A KR 890002435A
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rhodium
aqueous solution
solution containing
complex compound
compound according
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KR1019870007451A
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KR900006628B1 (ko
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백스텐 루두가
구피스 디텔
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파파 콘콜, 파파 마이첼트
루루케미 악크티엔 게젤샤프트
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/64—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using alkaline material; using salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • C01G55/001—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/32—Carboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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  • Environmental & Geological Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Removal Of Specific Substances (AREA)
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Abstract

내용 없음

Description

로듐 착화합물을 함유하는 수용액으로부터 로듐의 회수방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 로듐 착화합물을 함유하는 수용액으로부터 로듐을 회수하는 방법으로서, 7-22의 탄소 원자를 갖는 카르복시산의 수용성염을 로듐에 대해 과량으로 용액에 부가한 다음, 50-200℃에서 용액을 산화제로 처리하고, 불수용성 화합물로서 분리된 로듐을 제거함을 특징으로 하는, 로듐 착화합물을 함유하는 수용액으로부터의 로듐 회수방법.
  2. 제1항에 있어서, 포화, 직쇄 또는 측쇄 모노카르복시간의 염을 수용액을 부가함을 특징으로 하는, 로듐 착화합물을 함유하는 수용액르로부터 로듐 회수방법.
  3. 제1항 또는 2항에 있어서, 카르복시산내에 8-13의 탄소 원자가 함유되어 있음을 특징으로 하는, 로듐 착화합물을 함유하는 수용액르로부터의 로듐 회수방법.
  4. 제1항에 있어서, 카르복시간의 염을 알칼리 금속염임을 특징으로 하는 로듐 측화합물을 함유하는 수용액르로부터의 로듐 회수방법.
  5. 제1항에 있어서, 20-500몰의 카르복시산염을 단위 그램-원자 로듐 당 수용액에 부가함을 특징으로 하는 로듐 착화합물을 함유하는 수용액으로부터의 로듐 회수방법.
  6. 제1항에 있어서, 산소 또는 산소를 함유하는 기체를 산화제로서 사용함을 특징으로 하는 로듐 착화합물을 함유하는 수용액르로부터의 로듐 회수방법.
  7. 제1항에 있어서, 공기를 산화제로서 사용함을 특징으로 하는 로듐 착화합물을 함유하는 수용액으로부터의 로듐 회수방법.
  8. 제1항에 있어서, 수용액의 pH값이 4-8임을 특징으로 하는 로듐 착화합물을 함유하는 수용액으로부터의 로듐 방법.
  9. 제1항에 있어서, 0.1-2.0MPa 압력하에서 수용액을 산화제로 처리함을 특징으로 하는 로듐 착화합물을 함유하는 수용액으로부터의 로듐 회수방법.
  10. 제1항에 있어서, 분리된 불 수용성 로듐 화합물을 불수용성 유기용매로 추출함을 특징으로 하는 로듐 착화합물을 함유하는 수용액으로부터의 로듐 회수방법.
  11. 제10항에 있어서, 유기 용매로서 톨루엔을 사용함을 특징으로 하는 로듐 착화합물을 함유하는 수용액으로부터의 로듐 회수방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870007451A 1986-08-06 1987-07-10 로듐 착화합물을 함유하는 수용액으로부터 로듐의 회수방법 KR900006628B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19863626536 DE3626536A1 (de) 1986-08-06 1986-08-06 Verfahren zur rueckgewinnung von rhodium aus rhodiumkomplexverbindungen enthaltenden waessrigen loesungen
DEP3626536.5 1986-08-06

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KR890002435A true KR890002435A (ko) 1989-04-10
KR900006628B1 KR900006628B1 (ko) 1990-09-15

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US (1) US4990639A (ko)
EP (1) EP0255673B1 (ko)
JP (1) JPH01125393A (ko)
KR (1) KR900006628B1 (ko)
AT (1) ATE69177T1 (ko)
AU (1) AU604735B2 (ko)
BR (1) BR8703985A (ko)
CA (1) CA1325015C (ko)
CS (1) CS274732B2 (ko)
DE (2) DE3626536A1 (ko)
ES (1) ES2028004T3 (ko)
HU (1) HU200314B (ko)
IE (1) IE60960B1 (ko)
SU (1) SU1498380A3 (ko)
YU (1) YU44809B (ko)
ZA (1) ZA875693B (ko)

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DE3744213A1 (de) * 1987-12-24 1989-07-06 Ruhrchemie Ag Verfahren zur rueckgewinnung von rhodium aus rhodiumkomplexverbindungen enthaltenden waessrigen loesungen
US5294415A (en) * 1988-06-30 1994-03-15 Hoechst Aktiengesellschaft Process for the separation and recovery of rhodium from the products of the oxo synthesis
DE3833427A1 (de) * 1988-10-01 1990-04-05 Hoechst Ag Verfahren zur rueckgewinnung von rhodium
US4950629A (en) * 1988-12-27 1990-08-21 Eli Lilly And Company Process for catalyst recovery
DE3934824A1 (de) * 1989-10-19 1991-04-25 Hoechst Ag Verfahren zur wiedergewinnung von rhodium aus den rueckstaenden der destillation von produkten der oxosynthese
US5149854A (en) * 1990-12-10 1992-09-22 Mooney Chemicals, Inc. Preparation of platinum group metal and rhenium carboxylates
DE4110212A1 (de) * 1991-03-28 1992-10-01 Hoechst Ag Verfahren zur wiedergewinnung von rhodium aus den rueckstaenden der destillation von produkten oder oxosynthese
US5348712A (en) * 1993-02-09 1994-09-20 Texaco Chemical Company Use of carbonates in metal ion extraction
CZ283697A3 (cs) * 1996-09-11 1998-04-15 Mitsubishi Chemical Corporation Způsob přípravy roztoku komplexu rhodia a jeho použití
FR2773368B1 (fr) * 1998-01-06 2001-03-02 Sarl Soc Rhodanienne De Transa Procede de preparation de derives de sulfonylarylphosphines et de metalloides et derives de sulfonylarylphosphines et de metalloides
DE19940250B4 (de) * 1999-08-25 2005-06-16 Celanese Chemicals Europe Gmbh Verfahren zur Regenerierung gebrauchter wasserlöslicher Hydroformylierungskatalysatoren
US6764662B2 (en) * 2002-06-20 2004-07-20 Conocophillips Company Recover and recycle rhodium from spent partial oxidation catalysts
DE102007053385A1 (de) 2007-11-09 2009-05-20 Oxea Deutschland Gmbh Verfahren zur Herstellung von Aldehyden
DE102008057857B4 (de) 2008-11-18 2014-09-11 Oxea Gmbh Verfahren zur Rückgewinnung von Rhodium aus Rhodiumkomplexverbindungen enthaltenden wässrigen Lösungen

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US3547964A (en) * 1968-07-24 1970-12-15 Union Oil Co Group viii noble metal catalyst recovery
GB1283389A (en) * 1969-10-22 1972-07-26 Atlantic Richfield Co Process and solution for recovering contaminated catalyst metals
FR2314910A1 (fr) * 1975-06-20 1977-01-14 Rhone Poulenc Ind Procede d'hydroformylation des olefines
US4404146A (en) * 1980-12-17 1983-09-13 Biosystems Research Inc. Metal oxyalkylates and method of making same
US4337208A (en) * 1981-02-17 1982-06-29 Tenneco Chemicals, Inc. Process for the production of oil-soluble metal salts
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DE3235029A1 (de) * 1982-09-22 1984-03-22 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur rueckgewinnung von wasserloeslichen, rhodium enthaltenden hydroformylierungskatalysatoren
US4465635A (en) * 1982-11-22 1984-08-14 Ashland Oil, Inc. Manufacture of palladous carboxylates

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CS570087A2 (en) 1990-11-14
AU7659087A (en) 1988-02-11
IE60960B1 (en) 1994-09-07
DE3774355D1 (de) 1991-12-12
CA1325015C (en) 1993-12-07
EP0255673B1 (de) 1991-11-06
YU145187A (en) 1988-10-31
ZA875693B (en) 1988-04-27
HUT44761A (en) 1988-04-28
IE872073L (en) 1988-02-06
EP0255673A3 (en) 1990-07-11
JPH01125393A (ja) 1989-05-17
US4990639A (en) 1991-02-05
CS274732B2 (en) 1991-10-15
HU200314B (en) 1990-05-28
BR8703985A (pt) 1988-04-05
ATE69177T1 (de) 1991-11-15
JPH0476999B2 (ko) 1992-12-07
AU604735B2 (en) 1991-01-03
YU44809B (en) 1991-02-28
KR900006628B1 (ko) 1990-09-15
DE3626536A1 (de) 1988-02-11
EP0255673A2 (de) 1988-02-10
ES2028004T3 (es) 1992-07-01
SU1498380A3 (ru) 1989-07-30

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