KR920017711A - 옥소 합성 생성물의 증류 잔사로부터 로듐을 회수하는 방법 - Google Patents

옥소 합성 생성물의 증류 잔사로부터 로듐을 회수하는 방법 Download PDF

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KR920017711A
KR920017711A KR1019920002968A KR920002968A KR920017711A KR 920017711 A KR920017711 A KR 920017711A KR 1019920002968 A KR1019920002968 A KR 1019920002968A KR 920002968 A KR920002968 A KR 920002968A KR 920017711 A KR920017711 A KR 920017711A
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oxygen
rhodium
acid
starting material
containing gas
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KR950007581B1 (ko
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랏페 피-터
스프링거 헬무트
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코트맨, 라이첼트
훽스트악티엔 게젤샤프트
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/58—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids and gas addition thereto
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
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  • Chemical & Material Sciences (AREA)
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  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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  • Manufacture And Refinement Of Metals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

내용 없음

Description

옥소 합성 생성물의 증류 잔사로부터 로듐을 회수하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 잔사룰 산소 또는 산소 함유 가스로 처리하여 옥소 합성 생성물의 증류 잔사 중의 유기 인(Ⅲ) 화합물과의 착제 결합 중에 함유된 로듐을 회수하는 방법에 있어서, 로듐 g원자당 10∼1200몰의 알데하이드를 함유하는 잔사가 포함된 출발 물질을 로듐 g원자당 1.0∼15몰의의 탄소수 2∼5의 모노카르복실산 및 탄소수 2∼5의 모노카르복실산의 알칼리 금속염 존재하에 60∼120℃에서 대기압 또는 승압하에 산소 또는 산소 함유 가스로 처리한 다음, 물로 추출하여 로듐을 수용성 화합물로서 분리하고 수성상과 유기상을 분리하는 것을 특징으로 하는 로듐의 회수 방법.
  2. 제1항에 있어서, 공기를 산소 함유 가스로서 사용하는 것을 특징으로 하는 방법.
  3. 제1항 또는 제2항에 있어서, 출발물질 kg당 1∼10, 구체적으로는 2∼6몰의 산소를 사용하는 것을 특징으로 하는 방법.
  4. 제1항 내지 제3항 중 어느 한 항에 있어서, 출발물질에 아세트산, 프로피온산, n-부티르산, i-부티르산 또는 n-발레르산을 가하는 것을 특징으로 하는 방법.
  5. 제1항 내지 제4항 중 어느 한 항에 있어서, 로듐 g 원자당 1.2∼10구체적으로는 1.5∼6몰의 모노카르복실산을 출발물질에 가하는 것을 특징으로 하는 방법.
  6. 제1항 내지 제5항 중 어느 한 항에 있어서, 출발불질에 아세트산, 프로피온산, n-부티르산, i-부티르산 또는 n-발레스산의 나트륨염 또는 칼륨염을 가하는 것을 특징으로 하는 방법.
  7. 제1항 내지 제6항 중 어느 한 항에 있어서, 로듐 g 원자당 10∼100,구체적으로는 15∼50, 바람직하게는 12∼30몰의 탄소수 2∼5인 모노카르복실산의 알칼리 금속염을 출발물질에 가하는 것을 특징으로 하는 방법.
  8. 제1항 내지 제7항중 어느 한 항에 있어서, 출발물질의 산소 또는 산소함유 가스처리를 70∼105, 바람직하게는 80∼100℃에서 실시하는 것을 특징으로 하는 방법.
  9. 제1항 내지 제8항중 어느 한 항에 있어서, 출발물질의 산소 또는 산소함유 가스처리를 0.2∼1.0MPa의 압력하에서 실시하는 것을 특징으로 하는 방법.
  10. 제1항 내지 제9항중 어느 한 항에 있어서, 출발물질 중의 로듐 농도가 약 300 중량 ppm이하, 구체적으로는 20∼200, 바람직하게는 30∼150중량 ppm인 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920002968A 1991-03-28 1992-02-26 옥소 합성 생성물의 증류 잔사로부터 로듐을 회수하는 방법 KR950007581B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4110212.6 1991-03-28
DE4110212A DE4110212A1 (de) 1991-03-28 1991-03-28 Verfahren zur wiedergewinnung von rhodium aus den rueckstaenden der destillation von produkten oder oxosynthese

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KR920017711A true KR920017711A (ko) 1992-10-21
KR950007581B1 KR950007581B1 (ko) 1995-07-12

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US (1) US5264600A (ko)
EP (1) EP0510358B1 (ko)
JP (1) JPH078336B2 (ko)
KR (1) KR950007581B1 (ko)
CN (1) CN1036248C (ko)
AT (1) ATE110587T1 (ko)
AU (1) AU645189B2 (ko)
BR (1) BR9201076A (ko)
CA (1) CA2063644C (ko)
DE (2) DE4110212A1 (ko)
ES (1) ES2063539T3 (ko)
MX (1) MX9201289A (ko)
PL (1) PL293943A1 (ko)
ZA (1) ZA922066B (ko)

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WO1988000727A1 (en) * 1986-04-22 1988-01-28 Seiko Epson Corporation Locking construction of timepiece
CZ283697A3 (cs) * 1996-09-11 1998-04-15 Mitsubishi Chemical Corporation Způsob přípravy roztoku komplexu rhodia a jeho použití
US6291717B1 (en) 1998-12-10 2001-09-18 Mitsubishi Chemical Corporation Process for producing aldehyde
DE10005084C1 (de) * 2000-02-04 2001-09-13 Celanese Chem Europe Gmbh Verfahren zur Wiedergewinnung von Rhodium aus Reaktionsprodukten der Oxosynthese
GB0113079D0 (en) * 2001-05-30 2001-07-18 Kvaerner Process Tech Ltd Process
JP4595495B2 (ja) * 2004-11-08 2010-12-08 三菱化学株式会社 アルデヒドの製造方法
DE102006011867A1 (de) * 2006-03-15 2007-09-20 Saltigo Gmbh Verfahren zur Rückgewinnung von phosphorhaltigen Liganden, aus Metallkomplexen mit Phosphinliganden
EP3976732A4 (en) 2019-05-24 2023-05-17 Eastman Chemical Company MIXING SMALL QUANTITIES OF PYROLYTIC OIL INTO A LIQUID STREAM WHICH IS PROCESSED INTO A GAS CRACKER
US11365357B2 (en) 2019-05-24 2022-06-21 Eastman Chemical Company Cracking C8+ fraction of pyoil
US11945998B2 (en) 2019-10-31 2024-04-02 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
US11319262B2 (en) 2019-10-31 2022-05-03 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
EP4054997A4 (en) 2019-11-07 2024-02-21 Eastman Chem Co ALPHA-OLEFINS AND FAT ALCOHOLS WITH RECYCLING CONTENT

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* Cited by examiner, † Cited by third party
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US4196096A (en) * 1979-02-12 1980-04-01 Eastman Kodak Company Process for regeneration of rhodium hydroformylation catalysts
US4578386A (en) * 1984-02-10 1986-03-25 Usv Pharmaceutical Corp. 7,8-Dihydroimidazo[1,5-a]pyrazin-8-ones
US4578368A (en) * 1985-05-06 1986-03-25 Eastman Kodak Company Catalyst recovery process
DE3626536A1 (de) * 1986-08-06 1988-02-11 Ruhrchemie Ag Verfahren zur rueckgewinnung von rhodium aus rhodiumkomplexverbindungen enthaltenden waessrigen loesungen
DE3934824A1 (de) * 1989-10-19 1991-04-25 Hoechst Ag Verfahren zur wiedergewinnung von rhodium aus den rueckstaenden der destillation von produkten der oxosynthese
DE4025074A1 (de) * 1990-08-08 1992-02-13 Hoechst Ag Verfahren zur wiedergewinnung von rhodium aus den rueckstaenden der destillation von produkten der oxosynthese

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JPH06126194A (ja) 1994-05-10
CN1065220A (zh) 1992-10-14
US5264600A (en) 1993-11-23
EP0510358B1 (de) 1994-08-31
DE59200429D1 (de) 1994-10-06
PL293943A1 (en) 1992-11-30
DE4110212A1 (de) 1992-10-01
ES2063539T3 (es) 1995-01-01
ATE110587T1 (de) 1994-09-15
CA2063644C (en) 1995-08-08
AU1381892A (en) 1992-10-01
BR9201076A (pt) 1992-11-24
AU645189B2 (en) 1994-01-06
MX9201289A (es) 1993-01-01
KR950007581B1 (ko) 1995-07-12
CN1036248C (zh) 1997-10-29
EP0510358A1 (de) 1992-10-28
ZA922066B (en) 1992-11-25
JPH078336B2 (ja) 1995-02-01

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