KR970015658A - 신디오탁틱 폴리스티렌계 수지 조성물 - Google Patents

신디오탁틱 폴리스티렌계 수지 조성물 Download PDF

Info

Publication number
KR970015658A
KR970015658A KR1019960038814A KR19960038814A KR970015658A KR 970015658 A KR970015658 A KR 970015658A KR 1019960038814 A KR1019960038814 A KR 1019960038814A KR 19960038814 A KR19960038814 A KR 19960038814A KR 970015658 A KR970015658 A KR 970015658A
Authority
KR
South Korea
Prior art keywords
weight
component
styrene
parts
resin composition
Prior art date
Application number
KR1019960038814A
Other languages
English (en)
Other versions
KR100403071B1 (ko
Inventor
신지 지노
아키히코 오카다
노부유키 사토
Original Assignee
가와노 에이지로
이데미쓰 세키유가가쿠 가부시키가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 가와노 에이지로, 이데미쓰 세키유가가쿠 가부시키가이샤 filed Critical 가와노 에이지로
Publication of KR970015658A publication Critical patent/KR970015658A/ko
Application granted granted Critical
Publication of KR100403071B1 publication Critical patent/KR100403071B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L35/06—Copolymers with vinyl aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12—Polyphenylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00—Printed circuits
    • H05K1/02—Details
    • H05K1/03—Use of materials for the substrate
    • H05K1/0313—Organic insulating material
    • H05K1/032—Organic insulating material consisting of one material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/905—Polyphenylene oxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 내열성 또는 탄성률이 양호하며, 또한 인성을 현저하게 향상시키면서 표면 박리 억제 효과를 갖는 신디오탁틱 폴리스티렌(SPS)계 수지 조성물을 제공한다.
본 발명은 수지 조성물은 (A) 신디오탁틱(syndiotactic) 구조를 갖는 스티렌계 중합체 10 내지 98중량% 및 폴리올레핀 90 내지 2중량%로 구성되는 성분 100중량부에 대해, (B) 스티렌 성분 함유량이 40 내지 85중량%인 스티렌-올레핀 공중합체 0.5 내지 50중량부, 경우에 따라 (C) (A) 성분의 스티렌계 중합체 100중량부에 대해 0.5 내지 10.0중량부의 폴리페닐렌에테르(클로로포름중 온도 25℃에서 고유점도가 0.4㎗/g 이상) 및/또는 (D) (A) 성분의 스티렌-올레핀 공중합체 100중량부에 대해 0 내지 200중량부의 스티렌 성분 함유량이 5 내지 35중량%인 스티렌-올레핀 공중합체 및/또는 (E) (A) 성분의 스티렌-올레핀 공중합체 100중량부에 대해 0 내지 200중량부의 (E) 파라핀계 오일, 파라핀계 왁스, 광유 및 실록산계 오일로 구성되는 신디오탁틱 폴리스티렌계수지 조성물이다. 또한, 이들은 수지 성분 100중량부당, (F) 무기 충진재 0.5 내지 350중량부, 또는 (G) (A) 의 스티렌계 중합체 성분과의 상용성 또는 친화성을 갖고 또한 극성기를 갖는 중합체 0.1 내지 10중량부를 함유하여 이루어지는 신디오탁틱 폴리스티렌계 수지 조성물이다.

Description

신디오탁틱 폴리스티렌계 수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. (A) 신디오탁틱(syndiotactic) 구조를 갖는 스티렌계 중합체 10 내지 98중량% 및 폴리올레핀 90 내지 2중량%로 되는 성분 100중량부에 대해, (B) 스티렌 성분 함유량이 40 내지 85중량%인 스티렌-올레핀 공중합체 0.5 내지 50중량부로 되는 수지 성분을 함유하는 것을 특징으로 하는 신디오탁틱 폴리스티렌계 수지 조성물.
  2. (A) 신디오탁틱 구조를 갖는 스티렌계 중합체 10 내지 98중량% 및 폴리올레핀 90 내지 2중량%로 되는 성분 100중량부에 대해, (B) 스티렌 성분 함유량이 40 내지 85중량%인 스티렌-올레핀 공중합체 0.5 내지 50중량부 및 (C) (A) 성분의 스티렌계 중합체 100중량부에 대해 0.5 내지 10.0중량부의 폴리페닐렌에테르(클로로포름중 온도 25℃에서 고유점도가 0.4㎗/g 이상)로 되는 수지 성분을 함유하는 것을 특징으로 하는 신디오탁틱 폴리스티렌계 수지 조성물.
  3. 제1항 또는 제2항에 있어서, 상기 (A) 성분의 폴리올레핀 성분 100중량부에 대해 (D) 스티렌 성분 함유량이 5 내지 35중량%인 스티렌-올레핀 공중합체 0 내지 200중량부를 함유하는 신디오탁틱 폴리스티렌계 수지 조성물.
  4. 제1항 또는 제2항에 있어서, 상기 (A) 성분의 폴리올레핀 100중량부에 대해 (E) 파리핀계 오일, 파라핀계 왁스, 광유 및 실록산계 오일로부터 선택된 하나 이상의 성분 0 내지 200중량부를 함유하는 신디오탁틱 폴리스티렌계 수지 조성물.
  5. 제1항 또는 제2항에 있어서, (A) 성분의 폴리올레핀 100중량부에 대해 (D) 스티렌 성분 함유량이 5 내지 35중량%인 스티렌-올레핀 공중합체 0 내지 200중량부, 및 (A) 성분의 폴리올레핀 100중량부에 대해 (E) 파라핀계 오일, 파라핀계 왁스, 광유 및 실록산계 오일로부터 선택된 하나 이상의 성분 0 내지 200중량부를 함유하는 신디오탁틱 폴리스티렌계 수지 조성물.
  6. 제1항 내지 제5항 중 어느 한 항에 있어서, 상기 수지 성분 100중량부당 (F) 무기 충진재 0.5 내지 350중량부를 함유하는 신디오탁틱 폴리스티렌계 수지 조성물.
  7. 제1항 내지 제5항 중 어느 한 항에 있어서, 상기 수지 성분 100중량부당 (F) 무기 충진재 0.5 내지 350중량부 및 (G) 상기 (A) 의 스티렌계 중합체와 상용성 또는 친화성을 갖고 또한 극성기를 갖는 중합체 0.1 내지 10중량부를 함유하는 신디오탁틱 폴리스티렌계 수지 조성물.
  8. 제1항 내지 제7항 중 어느 한 항에 있어서, (B) 성분이 수소 첨가 스티렌-부타디엔-스티렌 블록 공중합체, 수소 첨가 스티렌-이소프렌-스티렌 블록 공중합체, 수소 첨가 스티렌-부티디엔 블록 공중합체 및 수소 첨가 스티렌-이소프렌 블록 공중합체로부터 선택된 하나 이상의 성분인 신디오탁틱 폴리스티렌계 수지 조성물.
  9. 제1항 내지 제8항 중 어느 한 항에 있어서, (A)의 폴리올레핀 성분이 에틸렌-프로플렌 공중합체, 에틸렌-프로필렌-디엔 공중합체, 폴리프로필렌 및 폴리에틸렌으로부터 선택된 하나 이상의 신디오탁틱 폴리스티렌계 수지 조성물.
  10. 제3항 또는 제5항 내지 제9항 중 어느 한 항에 있어서, (D) 성분이 수소 첨가 스티렌-부타디엔-스티렌 블록 공중합체, 수소 첨가 스티렌-이소프렌-스티렌 블록 공중합체, 수소 첨가 스티렌-부타디엔 블록 공중합체, 수소 첨가 스티렌-이소프렌 블록 공중합체로부터 선택된 하나 이상의 성분인 신디오탁틱 폴리스티렌계 수지 조성물.
  11. 제4항 내지 제9항 중 어느 한 항에 있어서, (E) 성분이 폴리에틸렌계 올리고머, 폴리에틸렌계 왁스, 광유, 폴리디메틸실록산, 디메틸실록산-디페닐실록산 공중합체 또는 폴리메틸페닐실록산인 신디오탁틱 폴리스티렌계 수지 조성물.
  12. 제7항 내지 제11항 중 어느 한 항에 있어서, (G) 성분이 극성기 변성 폴리페닐렌에테르 및/또는 극성기 변성 신디오탁틱 폴리스티렌인 신디오탁틱 폴리스티렌계 수지 조성물.
  13. 제12항에 있어서, (G) 성분이 무수 말레산, 푸말산 또는 이들의 유도체에 의해 변성된 폴리페닐렌에테르 및/또는 신디오탁틱 폴리스티렌인 신디오탁틱 폴리스티렌계 수지 조성물
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960038814A 1995-09-08 1996-09-07 신디오탁틱폴리스티렌계수지조성물 KR100403071B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP23097895 1995-09-08
JP95-230978 1995-09-08

Publications (2)

Publication Number Publication Date
KR970015658A true KR970015658A (ko) 1997-04-28
KR100403071B1 KR100403071B1 (ko) 2004-02-05

Family

ID=16916313

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019960038814A KR100403071B1 (ko) 1995-09-08 1996-09-07 신디오탁틱폴리스티렌계수지조성물

Country Status (5)

Country Link
US (4) US5902850A (ko)
EP (1) EP0767211B1 (ko)
KR (1) KR100403071B1 (ko)
CN (1) CN1152001A (ko)
DE (1) DE69602150T2 (ko)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100678401B1 (ko) * 2005-07-22 2007-02-02 동서화학공업 주식회사 물성이 향상된 폴리올레핀 발포체
KR100762609B1 (ko) * 2001-07-25 2007-10-04 삼성토탈 주식회사 폴리프로필렌-신디오탁틱 폴리스티렌 수지 조성물

Families Citing this family (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6005050A (en) * 1994-11-28 1999-12-21 Idemitsu Petrochemical Co., Ltd. Impact resistant polystyrene composition
DE69602150T2 (de) 1995-09-08 1999-09-02 Idemitsu Petrochemical Co Harzzusammensetzung auf Styrolbasis
JPH09180689A (ja) * 1995-12-27 1997-07-11 Idemitsu Petrochem Co Ltd 密閉型二次電池用電槽材料及びそれを用いた密閉型二次電池用電槽
FR2763075B1 (fr) * 1997-05-06 1999-07-23 Gen Electric Plastics Abs Euro Compositions de polymeres et copolymeres styreniques et d'alliages de ceux-ci et articles moules resistant aux marques de frottement obtenus a partir de ces compositions
CA2305380A1 (en) * 1997-09-29 1999-04-22 National Research Council Of Canada Trivalent thrombin inhibitor
JP3456416B2 (ja) * 1998-06-03 2003-10-14 住友化学工業株式会社 樹脂組成物
IT1302000B1 (it) * 1998-08-05 2000-07-20 Enichem Spa Composizioni polimeriche ad elevata tenacita' a base di polimerivinilaromatici a struttura predominantemente sindiotattica.
WO2000014156A1 (fr) * 1998-09-09 2000-03-16 Asahi Kasei Kabushiki Kaisha Materiau pour recipients hermetiques de stockage de fluides
GB9822822D0 (en) * 1998-10-19 1998-12-16 Dyno Particles As Particles
US6413699B1 (en) 1999-10-11 2002-07-02 Macdermid Graphic Arts, Inc. UV-absorbing support layers and flexographic printing elements comprising same
KR100407724B1 (ko) * 1999-12-30 2003-12-31 삼성아토피나주식회사 난연성 폴리프로필렌 수지조성물
DE10016262A1 (de) * 2000-04-03 2001-10-04 Basf Ag Schlagzähe thermoplastische Formmassen aus syndiotaktischem Polystyrol Glasfasern und TPE-Schlagzähmodifier
US6593428B2 (en) * 2000-09-19 2003-07-15 E. I. Dupont De Nemours And Company Syndiotactic polystyrene alloy compositions
US6627701B2 (en) * 2000-12-28 2003-09-30 General Electric Company Method for the preparation of a poly(arylene ether)-polyolefin composition, and composition prepared thereby
US6815491B2 (en) 2000-12-28 2004-11-09 General Electric Reinforced thermoplastic composition and articles derived therefrom
US6495630B2 (en) 2000-12-28 2002-12-17 General Electric Company Poly(arylene ether)-polyolefin compositions and articles derived therefrom
JP2004517998A (ja) * 2000-12-28 2004-06-17 ゼネラル・エレクトリック・カンパニイ 強化熱可塑性組成物及びそれから得られる物品
US6861472B2 (en) 2000-12-28 2005-03-01 General Electric Company Poly(arylene ether)-polyolefin compositions and articles derived therefrom
US6545080B2 (en) 2000-12-28 2003-04-08 General Electric Company Glass-filled poly(arylene ether)-polyolefin composition and articles derived therefrom
US6855767B2 (en) 2000-12-28 2005-02-15 General Electric Poly(arylene ether)-polyolefin composition and articles derived therefrom
US6660794B2 (en) 2000-12-28 2003-12-09 General Electric Company Glass-filled poly(arylene ether)-polyolefin composition and articles derived therefrom
WO2002057364A2 (en) * 2000-12-28 2002-07-25 General Electric Company Poly(arylene ether)-polyolefin composition and articles derived therefrom
JP4865952B2 (ja) * 2001-03-23 2012-02-01 出光興産株式会社 スチレン系重合体組成物及びこれを用いた成形品
US20030027897A1 (en) * 2001-04-26 2003-02-06 Mei Henry L. Modified silane treated pigments or fillers and compositions containing the same
US20040152838A1 (en) * 2001-05-30 2004-08-05 Akihiko Okada Chemical-resitant polystyrene resin compositon and molded article
US6872777B2 (en) * 2001-06-25 2005-03-29 General Electric Poly(arylene ether)-polyolefin composition, method for the preparation thereof, and articles derived therefrom
US6830555B2 (en) * 2001-10-09 2004-12-14 Advanced Medical Optics Multi-functional second instrument for cataract removal
US7196137B2 (en) 2002-02-08 2007-03-27 Teknor Apex Company Polymer compositions
US6810333B2 (en) * 2002-02-12 2004-10-26 General Electric Company Method, system, storage medium, and data signal for supplying a multi-component composition
EP1362886A1 (en) * 2002-05-16 2003-11-19 Bmw Ag A resin composition for producing a bodywork component
US6894102B2 (en) * 2002-05-20 2005-05-17 General Electric Syndiotactic polystyrene blends
EP1543076A2 (en) * 2002-09-20 2005-06-22 General Electric Company Underhood components
US6887938B2 (en) * 2003-02-04 2005-05-03 General Electric Company Compositions containing polyphenylene ether and/or polystyrene having improved tribological properties and methods for improving tribological properties of polyphenylene ether and/or polystyrene compositions
US7214739B2 (en) 2003-04-22 2007-05-08 General Electric Company Composition and method for improving the surface adhesion of resin compositions to polyurethane foam
US7582693B2 (en) * 2003-04-22 2009-09-01 Sabic Innovative Plastics Ip B.V. Composition and method for enhancing the weld strength of polyphenylene ether compositions
US7022765B2 (en) * 2004-01-09 2006-04-04 General Electric Method for the preparation of a poly(arylene ether)-polyolefin composition, and composition prepared thereby
US20060115613A1 (en) * 2004-12-01 2006-06-01 Cryovac, Inc. Patch bag and barrier bag
US7473473B2 (en) * 2004-12-01 2009-01-06 Cryovac, Inc. Tear resistant shrink film
JP4901106B2 (ja) * 2005-01-27 2012-03-21 東レ・ダウコーニング株式会社 車両モールディング用熱可塑性エラストマー組成物および車両用モールディング付きガラス板
CN101133093A (zh) * 2005-02-10 2008-02-27 恰根有限公司 反应表面的样品裂解和涂层
US8449328B2 (en) 2009-08-10 2013-05-28 Yazaki Corporation Thermoplastic elastomer resin composition and connector
WO2011019026A1 (ja) 2009-08-10 2011-02-17 矢崎総業株式会社 熱可塑性エラストマー樹脂組成物及びコネクタ
BR112013027626A2 (pt) * 2011-04-29 2017-02-14 General Cable Tech Corp composições de isolamento
US9051465B1 (en) 2012-02-21 2015-06-09 Park Electrochemical Corporation Thermosetting resin composition containing a polyphenylene ether and a brominated fire retardant compound
US9243164B1 (en) 2012-02-21 2016-01-26 Park Electrochemical Corporation Thermosetting resin composition containing a polyphenylene ether and a brominated fire retardant compound
CN103122137A (zh) * 2013-02-05 2013-05-29 苏州市沃特新材料科技有限公司 聚苯醚复合材料、其制备方法和应用
EA031457B1 (ru) * 2013-08-30 2019-01-31 ДСМ АйПи АССЕТС Б.В. Полимерная композиция для нанесения при высокой температуре, содержащая вещество, высвобождаемое при нагревании
SG11201605144TA (en) * 2013-12-27 2016-08-30 Zeon Corp Block copolymer composition, production method therefor, and film
CN104830008A (zh) * 2015-04-16 2015-08-12 安徽雄亚塑胶科技有限公司 抗折痕弹性体及其制备方法
JPWO2017065300A1 (ja) * 2015-10-16 2018-08-02 株式会社ブリヂストン 多元共重合体、樹脂組成物、架橋樹脂組成物、及び製品
CN105219012B (zh) * 2015-11-09 2017-12-01 沈阳化工大学 一种接枝改性abs抗静电材料及其制备方法
EP3646097B1 (en) * 2017-06-30 2024-06-12 Dow Global Technologies LLC Filling composition for optical fiber cables
DE112019003305T5 (de) * 2018-06-29 2021-04-22 Idemitsu Kosan Co., Ltd. Harz-metall-verbundkörper und verfahren zur herstellung desselben
CN113150457A (zh) * 2021-01-05 2021-07-23 广州辰东新材料有限公司 一种改性碳氢-改性间规聚苯乙烯复合材料及含其覆铜板和制备方法

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3375228A (en) * 1967-05-10 1968-03-26 Gen Electric Hot capping of polyphenylene ethers
JPS5217880B2 (ko) * 1974-05-25 1977-05-18
NL8301284A (nl) * 1983-04-12 1984-11-01 Gen Electric Polymeermengsel dat een polyfenyleenether en eventueel een polystyreen en/of een met rubber gemodificeerd polystyreen bevat en daaruit gevormde voorwerpen.
US4654405A (en) * 1985-12-05 1987-03-31 Borg-Warner Chemicals, Inc. Carboxylated phenylene ether resins
US5166238A (en) * 1986-09-22 1992-11-24 Idemitsu Kosan Co., Ltd. Styrene-based resin composition
US5395890A (en) 1987-09-14 1995-03-07 Idemitsu Kosan Co., Ltd. Styrene-based resin composition
US5891951A (en) * 1987-09-14 1999-04-06 Idemitsu Kosan Co., Ltd. Styrene-based resin composition
JP2502989B2 (ja) * 1986-11-18 1996-05-29 三菱化学株式会社 樹脂組成物
EP0282664B1 (en) * 1987-03-18 1993-09-01 Asahi Kasei Kogyo Kabushiki Kaisha Novel impact-resistant polyamide resin composition and process for producing the same
US6013726A (en) 1987-04-12 2000-01-11 Idemitsu Kosan Co., Ltd. Composition of styrene resin, thermoplastic resin and rubber
US6008293A (en) 1987-09-14 1999-12-28 Idemitsu Kosan Co., Ltd. Syndiotactic polystyrene and polycarbonate resin compositions
US6046275A (en) 1987-09-14 2000-04-04 Idemitsu Kosan Co., Ltd. Styrene resin with rubber polymer particles
MY104125A (en) * 1988-01-13 1994-02-28 Idemitsu Kosan Co Styrene-based resin composition.
US5200454A (en) * 1988-01-14 1993-04-06 Idemitsu Kosan Company Limited Flame-retardant resin composition
US5109068A (en) * 1988-08-31 1992-04-28 Idemitsu Kosan Co., Ltd. Styrene-based polymer composition, stretched molding thereof and process for producing the same
US5089353A (en) * 1988-10-14 1992-02-18 Kuraray Co., Ltd. Multi-layer material having gas barrier properties
US5270353A (en) * 1989-02-10 1993-12-14 Idemitsu Kosan Co., Ltd. Resin composition
GB8916637D0 (en) * 1989-07-20 1989-09-06 Exxon Chemical Patents Inc Aromatic polymer blends
US5127158A (en) * 1989-09-06 1992-07-07 Idemitsu Kosan Co., Ltd. Process for producing a printed circuit board with a syndiotactic polystyrene support
US5219940A (en) * 1989-10-13 1993-06-15 Idemitsu Kosan Co., Ltd. Styrene polymer composition
US5360350A (en) * 1991-08-23 1994-11-01 The Whitaker Corporation Sealant compositions and sealed electrical connectors
EP0546497A3 (en) * 1991-12-10 1993-11-18 Idemitsu Kosan Co Thermoplastic resin composition
ATE153680T1 (de) * 1992-03-03 1997-06-15 Idemitsu Kosan Co Pfropfcopolymer, verfahren zu seiner herstellung und harzzusammensetzung, worin es enthalten ist
JP3166788B2 (ja) * 1992-03-04 2001-05-14 出光興産株式会社 スチレン系樹脂組成物
JP3255243B2 (ja) * 1992-09-10 2002-02-12 出光興産株式会社 ポリスチレン系樹脂組成物
JPH0693151A (ja) * 1992-09-10 1994-04-05 Idemitsu Kosan Co Ltd ポリスチレン系樹脂組成物
JP3292320B2 (ja) * 1993-03-03 2002-06-17 出光興産株式会社 耐衝撃性ポリスチレン系樹脂組成物
US5568525A (en) 1993-08-19 1996-10-22 International Business Machines Corporation System and method for connection of multiple protocol terminals
JPH08104785A (ja) * 1994-10-05 1996-04-23 Idemitsu Kosan Co Ltd 耐衝撃性ポリスチレン系樹脂組成物
US6005050A (en) * 1994-11-28 1999-12-21 Idemitsu Petrochemical Co., Ltd. Impact resistant polystyrene composition
CN1140461A (zh) * 1994-12-07 1997-01-15 出光石油化学株式会社 苯乙烯属树脂组合物和聚苯乙烯取向薄膜
JPH08319385A (ja) 1995-05-26 1996-12-03 Idemitsu Petrochem Co Ltd ポリスチレン系樹脂組成物及びその成形品
DE69602150T2 (de) 1995-09-08 1999-09-02 Idemitsu Petrochemical Co Harzzusammensetzung auf Styrolbasis
JPH09180689A (ja) 1995-12-27 1997-07-11 Idemitsu Petrochem Co Ltd 密閉型二次電池用電槽材料及びそれを用いた密閉型二次電池用電槽
CN1127541C (zh) * 1996-03-05 2003-11-12 陶氏环球技术公司 含间规乙烯基芳族聚合物的模塑组合物

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100762609B1 (ko) * 2001-07-25 2007-10-04 삼성토탈 주식회사 폴리프로필렌-신디오탁틱 폴리스티렌 수지 조성물
KR100678401B1 (ko) * 2005-07-22 2007-02-02 동서화학공업 주식회사 물성이 향상된 폴리올레핀 발포체

Also Published As

Publication number Publication date
DE69602150D1 (de) 1999-05-27
EP0767211B1 (en) 1999-04-21
EP0767211A1 (en) 1997-04-09
US6096829A (en) 2000-08-01
CN1152001A (zh) 1997-06-18
US6031049A (en) 2000-02-29
DE69602150T2 (de) 1999-09-02
KR100403071B1 (ko) 2004-02-05
US5902850A (en) 1999-05-11
US6469081B1 (en) 2002-10-22

Similar Documents

Publication Publication Date Title
KR970015658A (ko) 신디오탁틱 폴리스티렌계 수지 조성물
BR9714409A (pt) Composiçãos termoplásticas de olefina
US20090018253A1 (en) Perfromance additives for thermoplastic elastomers
BR0108450A (pt) Pelìculas de polietileno tendo propriedades óticas melhoradas
KR940011574A (ko) 열가소성 엘라스토머 조성물
EP1437384A1 (en) Block copolymer compositions
Liu et al. Extrusion of ultrahigh molecular weight polyethylene under ultrasonic vibration field
MY132209A (en) Styrene-based resin composition
TW314536B (ko)
DE69316196D1 (de) Heissschmelzklebstoffzusammensetzung die niedermolekulare ethylencopolymere enthalten
Samthong et al. Effect of acrylonitrile content of acrylonitrile butadiene rubber on mechanical and thermal properties of dynamically vulcanized poly (lactic acid) blends
BR0111655A (pt) Composições de polìmeros olefìnicos
ATE386077T1 (de) Polymerzusammensetzungen
Singh et al. The dynamic mechanical analysis, impact, and morphological studies of EPDM–PVC and MMA‐g‐EPDM–PVC blends
EP1118638A4 (en) COMPOSITIONS AND MOLDED OBJECT IN FLEXIBLE SYNDIOTACTIC POLYMER
RU2003132868A (ru) Защитное покрытие для труб
Yousefi Segmental mobility in the vicinity of Tg in PS/SBR blends: Nanodomain size prediction of the dispersed phase
JP2009191176A (ja) ルーフィング用ポリマー改質アスファルト組成物
BR0014576A (pt) Misturas de polìmero de carbonato de fluxo melhorado; método para prepará-las e artigos das mesmas
Ha et al. Effects of the viscosity ratio on polyolefin ternary blends
KR890003887A (ko) 스티렌계- 폴리아미드-엘라스토머 블렌드
JPH09296093A (ja) 熱可塑性エラストマー組成物
KR970074856A (ko) 우수한 내충격성과 신율이 조화된 종이질감 특성을 갖는 열가소성 수지 조성물
KR970061971A (ko) 스티렌계 수지 조성물
KR920000855A (ko) 내충격성 중합체 조성물

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
LAPS Lapse due to unpaid annual fee