KR960700322A - 방수방유제 조성물 및 그의 제조 방법(water-and oil-repellent composition and process for producing the same) - Google Patents

방수방유제 조성물 및 그의 제조 방법(water-and oil-repellent composition and process for producing the same)

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KR960700322A
KR960700322A KR1019950702611A KR19950702611A KR960700322A KR 960700322 A KR960700322 A KR 960700322A KR 1019950702611 A KR1019950702611 A KR 1019950702611A KR 19950702611 A KR19950702611 A KR 19950702611A KR 960700322 A KR960700322 A KR 960700322A
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carbon atoms
dichloro
monomer
boiling point
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모또노부 구보
가쯔노리 하야시
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이노우에 노리유끼
다이낑 고교 가부시끼가이샤
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/22—Esters containing halogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Fats And Perfumes (AREA)
  • Sealing Material Composition (AREA)
  • Paints Or Removers (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

본 발명은 비등점이 0 내지 150℃이고, 탄소원자수가 2 또는 3의 하이드로클로로플루오로카본 및 탄소원자수가 4 내지 6이고, 불소원자수가 4 이상인 하이드로플루오로카본으로 이루어진 군중에서 선택된 하나 이상의 화합물을 5중량% 이상 함유하는 중합 용매중에서 폴리플루오로알킬 그룹을 갖는 단량체를 최소한 함유하는 중합가능한 단량체 성분을 용액 중합시킴을 포함하는 방수방유제 조성물의 제조 방법에 관한 것이다.

Description

방수방유제 조성물 및 그의 제조 방법(WATER－AND OIL－REPELLENT COMPOSITION AND PROCESS FOR PRODUCING THE SAME)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 비등점이 0 내지 150℃이고, 탄소원자수가 2 또는 3의 하이드로클로로플루오로카본 및 탄소원자수가 4 내지 6이고, 불소원자수가 4 이상인 하이드로플루오로카본으로 이루어진 군중에서 선택된 하나 이상의 화합물을 5중량% 이상 함유하는 중합 용매중에서 폴리플루오로알킬 그룹을 갖는 단량체를 최소한 함유하는 중합가능한 단량체 성분을 용액 중합시키므로써 수득하는 방수방유제 조성물.
  2. 제1항에 있어서, 상기 단량체 성분이 폴리플루오로알킬 그룹을 갖는 단량체와 폴리플루오로알킬 그룹을 갖지 않는 단량체의 중량비 20/80 내지 100/0의 혼합물이고, 단량체 성분과 중합 용매의 합계 중량을 기준으로, 0.5 내지 50중량%의 단량체 성분을 함유하는 방수방유제 조성물.
  3. 제1 또는 제2항에 있어서, 상기 중합 용매가 1,1－디클로로－1－플루오로에탄올 10중량% 이상 함유하는 방수방유제 조성물.
  4. 제1항에 있어서, 비등점이 0 내지 150℃이고, 탄소원자수가 2 또는 3인 하이드로클로로플루오로카본 및 탄소원자수가 4 내지 6이고, 불소원자수가 4 이상인 하이드로플루오로카본으로 이루어진 군중에서 선택된 하나 이상의 화합물이 1,1－디클로로－1－플루오로에탄, 1,1－디클로로－2,2,3,3,3－펜타플루오로프로판, 1,3－디클로로－1,1,2,2,3－펜타플루오로프로판,1,1,1,2,2－펜타플루오로부탄,1,1,1,2,3,3,4－헵타플루오로부탄, 1,1,1,2,3,4,4－헵타플루오로부탄, 1,1,2,2,3,3,4,4,－옥타플루오로부탄, 1,1,2,2－테트라플루오로사이클로부탄, 1,2,3,3,4,4－헥사플루오로사이클로부탄, 2－트리플루오로부틸, 1,1,1,2,4,4－헥사플루오로펜탄, 1,1,1,2,2,5,5,5－옥타플루오로펜탄, 2－트리플루오로메틸－1,1,1,2,3,3,4,4－옥타플루오로펜탄,1,1,1,2,2,3,4,5,5,5－데카플루오로펜탄,2－트리플루오로메틸－1,1,1,4,4,5,5,5－옥타플루오로헥산, 2－트리플루오로메틸－1,1,1,2,3,4,5,5,5－노나플루오로헥산 및 2－트리플루우로메틸－1,1,1,3,3,4,4,5,5,5－데카플루오로헥산으로 이루어진 군중에서 선택된 하나 이상의 화합물인 방수방유제 조성물.
  5. 제1항에 있어서, 비등점이 0 내지 150℃이고, 탄소원자수가 2 또는 3인 하이드로클로로플루오로카본 및 탄소원자수가 4 내지 6이고, 불소원자수가 4 이상인 하이드로플루오로카본으로 이루어진 군중에서 선택된 하나 이상의 화합물이 1,1－디클로로－1－플루오로에탄, 1,1,2,2,3,3,4,4－옥타플루오로부탄, 1,2,3,3,4,4－헥사플루오로사이클로부탄 및 1,1,1,2,2,3,4,5,5,5－데카플루오로펜탄으로 이루어진 군중에서 선택된 하나 이상의 화합물인 방수방유제 조성물.
  6. 비등점은 0 내지 150℃이고, 탄소원자수가 2 또는 3인 하이드로클로로플루오로카본 및 탄소원자수가 4 내지 6이고, 불소원자수가 4 이상인 하이드로플루오로카본으로 이루어진 군중에서 선택된 하나 이상의 화합물을 5중량% 이상 함유하는 중합 용매중에서 폴리플루오로알킬 그룹을 갖는 단량체를 최소한 함유하는 중합가능한 단량체 성분을 용액 중합시키는 방수방유제 조성물의 제조 방법.
  7. 제6항에 있어서, 상기 단량체 성분이 폴리플루오로알킬 그룹을 갖는 단량체와 폴리플로오로알킬 그룹을 갖지 않는 단량체의 중량비 20/80 내지 100/0의 혼합물이고, 단량체 성분과 중합 용매의 합계 중량을 기준으로, 0.5 내지 50중량%의 단량체 성분을 함유하는 방수방유제 조성물의 제조 방법.
  8. 제6항 또는 7항에 있어서, 상기 중합 용매가 1,1－디클로로－1－플루오로에탄올 10중량% 이상 함유하는 방수방유제 조성물의 제조 방법.
  9. 제6항에 있어서, 비등점이 0 내지 150℃이고, 탄소원자수가 2 또는 3인 하이드로클로로플루오로카본 및 탄소원자수가 4 내지 6이고, 불소원자수가 4 이상인 하이드로플루오루카본으로 이루어진 군중에서 선택된 하나 이상의 화합물이 1,1－디클로로－1－플루오로에탄, 1,1－디클로로－2,2,3,3,3－펜타플루오로프로판, 1,3－디클로로－1,1,2,2,3－펜타플루오로프로판,1,1,1,2,2－펜타플루오로부탄,1,1,1,2,3,3,4－헵타플루오로부탄, 1,1,1,2,3,4,4－헵타플루오로부탄, 1,1,2,2,3,4,4－헵타플루오로부탄, 1,1,2,2,3,3,4,4－옥타플루오루부탄, 1,1,2,2－테트라플루오로사이클로부탄,1,2,3,3,4,4－헥사플루오로사이클로부탄,2－트리플루오로메틸－1,1,1,2,4,4,－헥사플루오로펜탄, 1,1,1,2,2,5,5,5－옥타플루오로펜탄, 2－트리플루오로메틸－1,1,1,2,3,3,4,4－옥타플루오로펜탄, 1,1,1,2,2,3,4,5,5,5－데카플루오로펜탄, 2－트리플루오로메틸－1,1,1,4,4,5,5,5,－옥타플루오로헥산,2－트리플루오로메틸－1,1,1,2,3,4,5,5,5－노나플루오로헥산및 2－트리플루오로메틸－1,1,1,3,3,4,4,5,5,5－데카플루오로헥산으로 이루어진 군중에서 선택된 하나 이상의 화합물인 방수방유제 조성물의 제조 방법.
  10. 제6항에 있어서, 비등점이 0 내지 150℃이고, 탄소원자수가 2 또는 3인 하이드로클로로플루오로카본 및 탄소원자수가 4 내지 6이고, 블소원자수가 4 이상인 하이드로플루오로카본으로 이루어진 군중에서 선택된 하나 이상의 화합물이 1,1－디클로로－1－플루오로에탄, 1,1,2,2,3,3,4,4－옥타플루오로부탄, 1,2,3,3,4,4－헥사플루오로사이클로부탄 및 1,1,1,2,2,3,4,5,5,5－데카플루오로펜탄으로 이루어진 군중에서 선택된 하나 이상의 화합물인 방수방유제 조성물의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950702611A 1993-10-25 1994-10-21 방수방유제조성물 및 그의 제조방법 KR100240315B1 (ko)

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JP5266103A JPH07118596A (ja) 1993-10-25 1993-10-25 撥水撥油剤組成物およびその製法
JP93-266103 1993-10-25
PCT/JP1994/001778 WO1995011949A1 (fr) 1993-10-25 1994-10-21 Composition hydrophobe et oleophobe et procede de production de cette composition

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KR960700322A true KR960700322A (ko) 1996-01-19
KR100240315B1 KR100240315B1 (ko) 2000-01-15

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US (1) US5608002A (ko)
EP (1) EP0676458B1 (ko)
JP (1) JPH07118596A (ko)
KR (1) KR100240315B1 (ko)
CN (1) CN1060201C (ko)
AT (1) ATE198346T1 (ko)
CA (1) CA2152793A1 (ko)
DE (1) DE69426486T2 (ko)
WO (1) WO1995011949A1 (ko)

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DE69426486D1 (de) 2001-02-01
EP0676458A4 (en) 1996-04-17
EP0676458A1 (en) 1995-10-11
CA2152793A1 (en) 1995-05-04
EP0676458B1 (en) 2000-12-27
DE69426486T2 (de) 2001-06-07
CN1060201C (zh) 2001-01-03
WO1995011949A1 (fr) 1995-05-04
CN1116857A (zh) 1996-02-14
US5608002A (en) 1997-03-04
ATE198346T1 (de) 2001-01-15
KR100240315B1 (ko) 2000-01-15
JPH07118596A (ja) 1995-05-09

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